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公开(公告)号：US08143431B2
公开(公告)日：2012-03-27
申请号：US12126333
申请日：2008-05-23
CPC分类号： H05K3/105 , C09D11/30 , H05K3/125 , H05K2203/013 , H05K2203/1105 , H05K2203/121
摘要： Novel copper alkoxide compound based ink formulations and their chemical syntheses are disclosed. The method of using the ink formulations to print conducting copper metal lines with standard ink jet printing and curing at
摘要翻译： 公开了新的烷基酚化合物基油墨配方及其化学合成。 还公开了使用油墨配方在<150℃下用标准喷墨印刷和固化印刷导电铜金属线的方法。
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公开(公告)号：US20080305268A1
公开(公告)日：2008-12-11
申请号：US12126333
申请日：2008-05-23
CPC分类号： H05K3/105 , C09D11/30 , H05K3/125 , H05K2203/013 , H05K2203/1105 , H05K2203/121
摘要： Novel copper alkoxide compound based ink formulations and their chemical syntheses are disclosed. The method of using the ink formulations to print conducting copper metal lines with standard ink jet printing and curing at
摘要翻译： 公开了新的烷基酚化合物基油墨配方及其化学合成。 还公开了使用油墨配方在<150℃下用标准喷墨印刷和固化印刷导电铜金属线的方法。
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公开(公告)号：US09018387B2
公开(公告)日：2015-04-28
申请号：US13152885
申请日：2011-06-03
申请人： John Anthony Thomas Norman , Melanie K. Perez , Xinjian Lei , Daniel P. Spence , Sergei Vladimirovich Ivanov , Wade Hampton Bailey, III
发明人： John Anthony Thomas Norman , Melanie K. Perez , Xinjian Lei , Daniel P. Spence , Sergei Vladimirovich Ivanov , Wade Hampton Bailey, III
IPC分类号： C07F5/00 , C07F7/28 , C07F15/00 , C07F17/02 , C07F15/02 , C07F15/04 , C07F15/06 , C07F17/00 , C07F7/00
CPC分类号： C07F17/02 , C07F5/00 , C07F5/003 , C07F7/003 , C07F7/28 , C07F15/02 , C07F15/04 , C07F15/06 , C07F17/00
摘要： Metal imidazolate complexes are described where imidazoles ligands functionalized with bulky groups and their anionic counterpart, i.e., imidazolates are described. Compounds comprising one or more such polyalkylated imidazolate anions coordinated to a metal or more than one metal, selected from the group consisting of alkali metals, transition metals, lanthanide metals, actinide metals, main group metals, including the chalcogenides, are contemplated. Alternatively, multiple different imidazole anions, in addition to other different anions, can be coordinated to metals to make new complexes. The synthesis of novel compounds and their use to form thin metal containing films is also contemplated.
摘要翻译： 描述了金属咪唑盐络合物，其中描述了用大体积基团官能化的咪唑配体及其阴离子配对物，即咪唑盐。 包括一种或多种这样的多烷基化咪唑酸盐阴离子配位到金属或一种以上选自碱金属，过渡金属，镧系元素金属，锕系金属，主要金属（包括硫族化物）的金属中。 或者，除了其它不同的阴离子之外，多种不同的咪唑阴离子可以与金属配位以制备新的络合物。 还考虑了新化合物的合成及其用于形成含薄金属膜的用途。
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公开(公告)号：US20120035351A1
公开(公告)日：2012-02-09
申请号：US13016127
申请日：2011-01-28
IPC分类号： C07F3/00 , H01L21/3205 , C07D403/06 , C07D233/58 , C07D401/06 , C07D487/06 , C07D405/06 , C30B25/02 , C07D471/18
CPC分类号： H01L21/28556 , C07D233/54
摘要： Sterically hindered imidazole ligands are described, along with their synthesis, which are capable of coordinating to Group 2 metals, such as: calcium, magnesium, strontium, in an eta-5 coordination mode which permits the formation of monomeric or dimeric volatile complexes.A compound comprising one or more polysubstituted imidazolate anions coordinated to a metal selected from the group consisting of barium, strontium, magnesium, radium or calcium or mixtures thereof. Alternatively, one anion can be substituted with and a second non-imidazolate anion.Synthesis of the novel compounds and their use to form BST films is also contemplated
摘要翻译： 描述了咪唑配位体以及它们的合成，它们能够以能够形成单体或二聚挥发性络合物的eta-5配位模式配合第2族金属，例如：钙，镁，锶。 包含与选自钡，锶，镁，镭或钙的金属或其混合物配位的一种或多种多取代咪唑酸盐阴离子的化合物。 或者，一个阴离子可以被第二个非咪唑酸阴离子取代。 还考虑了新型化合物的合成及其用于形成BST膜的用途
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公开(公告)号：US08703103B2
公开(公告)日：2014-04-22
申请号：US13016127
申请日：2011-01-28
IPC分类号： A61B5/055
CPC分类号： H01L21/28556 , C07D233/54
摘要： Sterically hindered imidazole ligands are described, along with their synthesis, which are capable of coordinating to Group 2 metals, such as: calcium, magnesium, strontium, in an eta-5 coordination mode which permits the formation of monomeric or dimeric volatile complexes.A compound comprising one or more polysubstituted imidazolate anions coordinated to a metal selected from the group consisting of barium, strontium, magnesium, radium or calcium or mixtures thereof. Alternatively, one anion can be substituted with and a second non-imidazolate anion.Synthesis of the novel compounds and their use to form BST films is also contemplated.
摘要翻译： 描述了咪唑配位体以及它们的合成，它们能够以能够形成单体或二聚挥发性络合物的eta-5配位模式配合第2族金属，例如：钙，镁，锶。 包含与选自钡，锶，镁，镭或钙的金属或其混合物配位的一种或多种多取代咪唑酸盐阴离子的化合物。 或者，一个阴离子可以被第二个非咪唑酸阴离子取代。 还考虑了新型化合物的合成及其用于形成BST膜的用途。
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公开(公告)号：US08680289B2
公开(公告)日：2014-03-25
申请号：US13363918
申请日：2012-02-01
申请人： John Anthony Thomas Norman , Melanie K. Perez , Xinjian Lei , Daniel P. Spence , Sergei Vladimirovich Ivanov , Wade Hampton Bailey, III
发明人： John Anthony Thomas Norman , Melanie K. Perez , Xinjian Lei , Daniel P. Spence , Sergei Vladimirovich Ivanov , Wade Hampton Bailey, III
CPC分类号： C07F17/02 , C07F5/00 , C07F5/003 , C07F7/003 , C07F7/28 , C07F15/02 , C07F15/04 , C07F15/06 , C07F17/00
摘要： Metal imidazolate complexes are described where imidazoles ligands functionalized with bulky groups and their anionic counterpart, i.e., imidazolates are described. Compounds comprising one or more such polyalkylated imidazolate anions coordinated to a metal or more than one metal, selected from the group consisting of alkali metals, transition metals, lanthanide metals, actinide metals, main group metals, including the chalcogenides, are contemplated. Alternatively, multiple different imidazole anions, in addition to other different anions, can be coordinated to metals to make new complexes. The synthesis of novel compounds and their use to form thin metal containing films is also contemplated.
摘要翻译： 描述了金属咪唑盐络合物，其中描述了用大体积基团官能化的咪唑配体及其阴离子配对物，即咪唑盐。 包括一种或多种这样的多烷基化咪唑酸盐阴离子配位到金属或一种以上选自碱金属，过渡金属，镧系元素金属，锕系金属，主要金属（包括硫族化物）的金属中。 或者，除了其它不同的阴离子之外，多种不同的咪唑阴离子可以与金属配位以制备新的络合物。 还考虑了新化合物的合成及其用于形成含薄金属膜的用途。
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公开(公告)号：US08263795B2
公开(公告)日：2012-09-11
申请号：US12258996
申请日：2008-10-27
CPC分类号： H01L21/28562 , C07F7/1804 , C23C16/18 , H01L21/28556
摘要： Non-fluorinated copper precursors and methods for making and using same are described herein. In certain embodiments, the copper precursors described herein may be used as precursors to deposit copper films and alloys thereof on a substrate through, for example, atomic layer deposition or chemical vapor deposition conditions.
摘要翻译： 本文描述了非氟化铜前体及其制备和使用方法。 在某些实施方案中，本文所述的铜前体可用作通过例如原子层沉积或化学气相沉积条件将铜膜及其合金沉积在衬底上的前体。
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公开(公告)号：US20090114874A1
公开(公告)日：2009-05-07
申请号：US12258996
申请日：2008-10-27
CPC分类号： H01L21/28562 , C07F7/1804 , C23C16/18 , H01L21/28556
摘要： Non-fluorinated copper precursors and methods for making and using same are described herein. In certain embodiments, the copper precursors described herein may be used as precursors to deposit copper films and alloys thereof on a substrate through, for example, atomic layer deposition or chemical vapor deposition conditions.
摘要翻译： 本文描述了非氟化铜前体及其制备和使用方法。 在某些实施方案中，本文所述的铜前体可用作通过例如原子层沉积或化学气相沉积条件将铜膜及其合金沉积在衬底上的前体。
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公开(公告)号：US20130078391A1
公开(公告)日：2013-03-28
申请号：US13363918
申请日：2012-02-01
申请人： John Anthony Thomas Norman , Melanie K. Perez , Xinjian Lei , Daniel P. Spence , Sergie Vladimirovich Ivanov , Wade Hampton Bailey, III
发明人： John Anthony Thomas Norman , Melanie K. Perez , Xinjian Lei , Daniel P. Spence , Sergie Vladimirovich Ivanov , Wade Hampton Bailey, III
IPC分类号： C07F17/02
CPC分类号： C07F17/02 , C07F5/00 , C07F5/003 , C07F7/003 , C07F7/28 , C07F15/02 , C07F15/04 , C07F15/06 , C07F17/00
摘要： Metal imidazolate complexes are described where imidazoles ligands functionalized with bulky groups and their anionic counterpart, i.e., imidazolates are described. Compounds comprising one or more such polyalkylated imidazolate anions coordinated to a metal or more than one metal, selected from the group consisting of alkali metals, transition metals, lanthanide metals, actinide metals, main group metals, including the chalcogenides, are contemplated. Alternatively, multiple different imidazole anions, in addition to other different anions, can be coordinated to metals to make new complexes. The synthesis of novel compounds and their use to form thin metal containing films is also contemplated.
摘要翻译： 描述了金属咪唑盐络合物，其中描述了用大体积基团官能化的咪唑配体及其阴离子配对物，即咪唑盐。 包括一种或多种这样的多烷基化咪唑酸盐阴离子配位到金属或一种以上选自碱金属，过渡金属，镧系元素金属，锕系金属，主要金属（包括硫族化物）的金属中。 或者，除了其它不同的阴离子之外，多种不同的咪唑阴离子可以与金属配位以制备新的络合物。 还考虑了新化合物的合成及其用于形成含薄金属膜的用途。
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公开(公告)号：US20120121806A1
公开(公告)日：2012-05-17
申请号：US13152885
申请日：2011-06-03
申请人： John Anthony Thomas Norman , Melanie K. Perez , Xinjian Lei , Daniel P. Spence , Sergei Vladimirovich Ivanov , Wade Hampton Bailey, III
发明人： John Anthony Thomas Norman , Melanie K. Perez , Xinjian Lei , Daniel P. Spence , Sergei Vladimirovich Ivanov , Wade Hampton Bailey, III
CPC分类号： C07F17/02 , C07F5/00 , C07F5/003 , C07F7/003 , C07F7/28 , C07F15/02 , C07F15/04 , C07F15/06 , C07F17/00
摘要： Metal imidazolate complexes are described where imidazoles ligands functionalized with bulky groups and their anionic counterpart, i.e., imidazolates are described. Compounds comprising one or more such polyalkylated imidazolate anions coordinated to a metal or more than one metal, selected from the group consisting of alkali metals, transition metals, lanthanide metals, actinide metals, main group metals, including the chalcogenides, are contemplated. Alternatively, multiple different imidazole anions, in addition to other different anions, can be coordinated to metals to make new complexes. The synthesis of novel compounds and their use to form thin metal containing films is also contemplated.
摘要翻译： 描述了金属咪唑盐络合物，其中描述了用大体积基团官能化的咪唑配体及其阴离子配对物，即咪唑盐。 包括一种或多种这样的多烷基化咪唑酸盐阴离子配位到金属或一种以上选自碱金属，过渡金属，镧系元素金属，锕系金属，主要金属（包括硫族化物）的金属中。 或者，除了其它不同的阴离子之外，多种不同的咪唑阴离子可以与金属配位以制备新的络合物。 还考虑了新化合物的合成及其用于形成含薄金属膜的用途。
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