Refractory compositions for use in fluid bed chlorinators
    1.
    发明授权
    Refractory compositions for use in fluid bed chlorinators 失效
    用于流化床氯化钠的耐火组合物

    公开(公告)号:US5807798A

    公开(公告)日:1998-09-15

    申请号:US962851

    申请日:1997-11-03

    摘要: This invention provides new refractory binder compositions comprising silica and titania which can be used to make ceramic bodies, particularly bricks. The refractory binder compositions comprise about 70 to about 92 wt. % silica (SiO.sub.2) and about 8 to about 30% titania (TiO.sub.2). The refractory binder compositions may further comprise alumina and a metal oxide selected from the group consisting of calcium oxide, strontium oxide, and sodium oxide, and mixtures thereof. The refractory ceramic bodies can be used in hot corrosive/erosive environments such as in fluid bed chlorinators in the manufacture of titanium dioxide.

    摘要翻译: 本发明提供了可用于制造陶瓷体,特别是砖的新型耐火粘合剂组合物,其包含二氧化硅和二氧化钛。 耐火粘合剂组合物包含约70-约92wt。 %二氧化硅(SiO 2)和约8至约30%的二氧化钛(TiO 2)。 难熔粘合剂组合物还可包含氧化铝和选自氧化钙,氧化锶和氧化钠的金属氧化物及其混合物。 耐火陶瓷体可用于热腐蚀/腐蚀性环境中,例如在二氧化钛生产中的流化床二氧化氯中。

    PROCESS FOR IN-SITU FORMATION OF CHLORIDES IN THE PREPARATION OF TITANIUM DIOXIDE
    2.
    发明申请
    PROCESS FOR IN-SITU FORMATION OF CHLORIDES IN THE PREPARATION OF TITANIUM DIOXIDE 有权
    二氧化钛制备中氯化物的现状形成过程

    公开(公告)号:US20120219493A1

    公开(公告)日:2012-08-30

    申请号:US13505471

    申请日:2010-11-09

    IPC分类号: C01G23/07

    CPC分类号: C01G23/07 C01B9/02

    摘要: This disclosure relates to a process for producing titanium dioxide, comprising: a) reacting an alloy comprising a metal selected from the group consisting of aluminum, titanium and mixtures thereof, wherein one metal is a major component of the alloy, and an element selected from the group consisting of Li, Be, B, Na, Mg, Al, P, S, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, and Bi, with chlorine gas to form chlorides of aluminum, titanium or mixtures thereof and chlorides of the element selected from the group consisting of Li, Be, B, Na, Mg, Al, P, S, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, and Bi, at or above the boiling point of the chloride of the major component of the alloy; with the proviso that the element does not comprise Ti when the metal is Ti and does not comprise Al when the metal is Al; (b) adding titanium tetrachloride to the chlorides formed in step (a); (c) oxidizing the chlorides formed in step (a), and titanium tetrachloride of step (b); and (d) forming titanium dioxide.

    摘要翻译: 本公开涉及一种生产二氧化钛的方法,包括:a)使包含选自铝,钛及其混合物的金属的合金反应,其中一种金属是合金的主要成分,以及选自 由Li,Be,B,Na,Mg,Al,P,S,K,Ca,Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Ga,Ge,As, Se,Rb,Sr,Y,Zr,Nb,Mo,Ru,Rh,Pd,Ag,Cd,In,Sn,Sb,Te,Cs,Ba,La,Ce,Pr,Nd,Sm,Eu, Tb,Dy,Ho,Er,Tm,Yb,Lu,Hf,Ta,W,Re,Os,Ir,Pt,Au,Hg,Tl,Pb和Bi,与氯气形成铝,钛或 它们的混合物和选自Li,Be,B,Na,Mg,Al,P,S,K,Ca,Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu ,Zn,Ga,Ge,As,Se,Rb,Sr,Y,Zr,Nb,Mo,Ru,Rh,Pd,Ag,Cd,In,Sn,Sb,Te,Cs,Ba,La,Ce,Pr ,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Hf,Ta,W,Re,Os,Ir,Pt,Au,Hg,Tl,Pb和Bi, 在boi之上 合金主要成分氯化物的点; 条件是当金属为Ti并且当金属为Al时不包含Al时元素不包含Ti; (b)向步骤(a)中形成的氯化物中加入四氯化钛; (c)氧化步骤(a)中形成的氯化物和步骤(b)的四氯化钛; 和(d)形成二氧化钛。

    Process for in-situ formation of chlorides in the preparation of titanium dioxide
    8.
    发明授权
    Process for in-situ formation of chlorides in the preparation of titanium dioxide 有权
    在二氧化钛制备中原位形成氯化物的方法

    公开(公告)号:US08734756B2

    公开(公告)日:2014-05-27

    申请号:US13505471

    申请日:2010-11-09

    IPC分类号: C01G23/047

    CPC分类号: C01G23/07 C01B9/02

    摘要: A process for producing titanium dioxide, comprising: a) reacting an alloy comprising a metal selected from the group consisting of aluminum, titanium and mixtures thereof, wherein one metal is a major component of the alloy, and an element, with chlorine gas to form chlorides of aluminum, titanium or mixtures thereof and chlorides of the element, at or above the boiling point of the chloride of the major component of the alloy; with the proviso that the element does not comprise Ti when the metal is Ti and does not comprise Al when the metal is Al; (b) adding titanium tetrachloride to the chlorides formed in step (a); (c) oxidizing the chlorides formed in step (a), and titanium tetrachloride of step (b); and (d) forming titanium dioxide.

    摘要翻译: 一种制备二氧化钛的方法,包括:a)使包含选自铝,钛及其混合物的金属的合金反应,其中一种金属是合金的主要成分,以及一种与氯气形成的元素 铝,钛或其混合物的氯化物和元素的氯化物等于或高于合金主要成分的氯化物的沸点; 条件是当金属为Ti并且当金属为Al时不包含Al时元素不包含Ti; (b)向步骤(a)中形成的氯化物中加入四氯化钛; (c)氧化步骤(a)中形成的氯化物和步骤(b)的四氯化钛; 和(d)形成二氧化钛。