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    Metal-ligand complex catalyzed processes
    2.
    发明授权
    Metal-ligand complex catalyzed processes 有权
    金属 - 配体络合物催化方法

    公开(公告)号：US06303830B1

    公开(公告)日：2001-10-16

    申请号：US09526638

    申请日：2000-03-15

    申请人： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant

    发明人： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant

    IPC分类号： C07C4550

    CPC分类号： C07B63/00 ,  C07C67/58 ,  Y02P20/582 ,  C07C69/716

    摘要： This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

    摘要翻译： 本发明涉及一种从包含一种或多种未反应的不饱和酯反应物，金属 - 有机磷配位体配合物催化剂，任选的一种或多种反应产物流体的反应产物流体中分离一种或多种有机磷配体降解产物，一种或多种反应副产物和一种或多种甲酰酯产物的方法 所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，极性溶剂和非极性溶剂通过相分离，其中（i）极性相对于有机磷配体的选择性 对于一种或多种产物，由分配系数比Ef1表示，该分配系数比Ef1大于约2.5，（ii）极性相对于一种或多种有机磷配体降解产物的有机磷配体的选择性为 由大于约2.5的值的分配系数比Ef2表示，a d（iii）极性相对于一种或多种反应副产物的有机磷配体的选择性由分配系数比Ef3表示，该分配系数比Ef3是大于约2.5的值。

    Metal-ligand complex catalyzed processes
    3.
    发明授权
    Metal-ligand complex catalyzed processes 有权
    金属 - 配体络合物催化方法

    公开(公告)号：US06307108B1

    公开(公告)日：2001-10-23

    申请号：US09525651

    申请日：2000-03-15

    申请人： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant

    发明人： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant

    IPC分类号： C07C4550

    CPC分类号： C07C227/08 ,  C07C67/347 ,  C07C67/58 ,  Y02P20/582 ,  C07C69/716 ,  C07C229/08

    摘要： This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophoshorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a nonpolar solvent and a polar solvent by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5 (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

    摘要翻译： 本发明涉及一种从包含一种或多种未反应的不饱和酯反应物，金属有机磷配体配合物催化剂的反应产物流体中分离一种或多种有机磷配体降解产物，一种或多种反应副产物和一种或多种甲酰酯产物的方法， 所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，非极性溶剂和极性溶剂通过相分离，其中（i）所述非极性相对于所述有机磷配体的选择性 对于一种或多种产物，通过分配系数比Ef1表示，该分配系数比Ef1是大于约2.5的值（ii）表示非极性相对于一种或多种有机磷配体降解产物的非极性相对于有机磷配体的选择性 通过大于约2的值的分配系数比Ef2。 5，和（iii）非极性相对于有机磷配体相对于一种或多种反应副产物的选择性由分配系数比Ef3表示，该分配系数比Ef3是大于约2.5的值。

    Separation processes
    4.
    发明授权
    Separation processes 有权
    分离过程

    公开(公告)号：US06310260B1

    公开(公告)日：2001-10-30

    申请号：US09526191

    申请日：2000-03-15

    申请人： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant ,  Ailene Gardner Phillips ,  Brian Michael Roesch ,  John Robert Briggs ,  Max Min Lee ,  John Michael Maher

    发明人： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant ,  Ailene Gardner Phillips ,  Brian Michael Roesch ,  John Robert Briggs ,  Max Min Lee ,  John Michael Maher

    IPC分类号： C07C4550

    CPC分类号： C07C45/50 ,  C07B63/00 ,  Y02P20/582 ,  C07C47/02

    摘要： This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more polar solvents and one or more nonpolar solvents by phase separation wherein (i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

    摘要翻译： 本发明涉及从连续生成的反应产物流体中分离一种或多种有机磷配体降解产物，一种或多种反应副产物和一种或多种产物，所述反应产物流体包含一种或多种未反应的反应物，金属 - 有机磷配体络合物催化剂， 有机磷配体，所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，一种或多种极性溶剂和一种或多种非极性溶剂通过相分离，其中（i）极性相的选择性为 相对于一种或多种产物的有机磷配体由分配系数比Ef1表示，分配系数比Ef1大于约2.5，（ii）有机磷配体的极性相对于一种或多种有机磷配体的选择性 降解产物由分配系数比Ef2表示，该分配系数比Ef2是大于th的值 约为2.5，和（iii）极性相对于一种或多种反应副产物的有机磷配体的选择性由分配系数比Ef3表示，该分配系数比Ef3是大于约2.5的值。

    Separation processes
    5.
    发明授权
    Separation processes 有权
    分离过程

    公开(公告)号：US06307110B1

    公开(公告)日：2001-10-23

    申请号：US09526337

    申请日：2000-03-15

    申请人： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant ,  Ailene Gardner Phillips ,  Brian Michael Roesch ,  John Robert Briggs ,  Max Min Lee ,  John Michael Maher

    发明人： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant ,  Ailene Gardner Phillips ,  Brian Michael Roesch ,  John Robert Briggs ,  Max Min Lee ,  John Michael Maher

    IPC分类号： C07C4550

    CPC分类号： C07C45/50 ,  C07B63/00 ,  Y02P20/582 ,  C07C47/02

    摘要： This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more products from a continuously generated reaction product fluid comprising one or more unreacted reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, one or more nonpolar solvents and one or more polar solvents by phase separation wherein (i) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1which is a value greater than about 2.5, (ii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the nonpolar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

    摘要翻译： 本发明涉及从连续生成的反应产物流体中分离一种或多种有机磷配体降解产物，一种或多种反应副产物和一种或多种产物，所述反应产物流体包含一种或多种未反应的反应物，金属 - 有机磷配体络合物催化剂， 有机磷配体，所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，一种或多种非极性溶剂和一种或多种极性溶剂通过相分离，其中（i）非极性相的选择性为 相对于一种或多种产物的有机磷配体由分配系数比Ef1表示，分配系数比Ef1大于约2.5，（ii）非极性相对于有机磷配体相对于一种或多种有机磷配体降解的选择性 产品由分配系数比Ef2表示，该分配系数比Ef2是一个很大的值 （iii）非极性相对于一种或多种反应副产物对有机磷配体的选择性由分配系数比Ef3表示，该分配系数比Ef3是大于约2.5的值。

    Enzymatic resolution of propylene glycol alkyl (or aryl) ethers and ether acetates
    6.
    发明授权
    Enzymatic resolution of propylene glycol alkyl (or aryl) ethers and ether acetates 失效
    丙二醇烷基（或芳基）醚和醚乙酸酯的酶解

    公开(公告)号：US07264960B2

    公开(公告)日：2007-09-04

    申请号：US10502692

    申请日：2003-03-21

    申请人： Sol M. Resnick ,  Felipe A. Donate ,  Timothy C. Frank ,  Thomas C. Thyne ,  Paul Foley

    发明人： Sol M. Resnick ,  Felipe A. Donate ,  Timothy C. Frank ,  Thomas C. Thyne ,  Paul Foley

    IPC分类号： C12P41/00

    CPC分类号： C12P7/18 ,  C12P41/004

    摘要： Glycol ether acetates, and in particular propylene glycol alkyl (or aryl) ether acetates, can be resolved enzymatically by enantioselective hydrolysis with a hydrolase at high concentrations of substrates; in some embodiments, the hydrolase is a lipase. Glycol ethers, and in particular propylene glycol alkyl (or aryl) ethers, can be resolved enzymatically by enantioselective transesterification with a hydrolase, in the presence of an acyl donor, at high concentrations of substrates; in some embodiments, the hydrolase is a lipase.

    摘要翻译： 乙二醇醚乙酸酯，特别是丙二醇烷基（或芳基）醚乙酸酯可以通过在高浓度底物下用水解酶进行对映选择性水解来酶解; 在一些实施方案中，水解酶是脂肪酶。 乙二醇醚，特别是丙二醇烷基（或芳基）醚可以通过在酰基供体存在下，在高浓度底物下用水解酶进行对映选择性酯交换酶解解; 在一些实施方案中，水解酶是脂肪酶。

    Polyurethane dispersion and articles prepared therefrom
    7.
    发明授权
    Polyurethane dispersion and articles prepared therefrom 有权
    聚氨酯分散体及其制备的制品

    公开(公告)号：US07232859B2

    公开(公告)日：2007-06-19

    申请号：US10531944

    申请日：2003-10-28

    申请人： John N. Argyropoulos ,  Paul Foley ,  Debkumar Bhattacharjee ,  Bedri Erdem

    发明人： John N. Argyropoulos ,  Paul Foley ,  Debkumar Bhattacharjee ,  Bedri Erdem

    IPC分类号： C08J3/00 ,  C08K3/20 ,  C08L75/00 ,  B32B27/00

    CPC分类号： C08G18/757 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/283 ,  C08G18/4018 ,  C08G18/4277 ,  C08G18/4854 ,  C08G18/664 ,  C08G18/6692 ,  Y10T428/31551 ,  C08G18/302 ,  C08G18/3234 ,  C08G18/3228

    摘要： The present invention is to a polyurethane dispersion and products produced therefrom wherein the dispersion contains a polyurethane prepolymer produced from the a reaction of an excess of a polyisocyanate with an isocyanate reactive molecule wherein the polyisocyanate is a bis(isocyanatomethyl)cyclohexane. Preferably the isocyanate comprises (i) trans-1,4-bis(isocyanatomethyl)cyclohexane or (ii) an isomeric mixture of two or more of cis-1,3-bis(isocyanatomethyl)cyclohexane, trans-1,3-bis(isocyanatomethyl)cyclohexane, cis-1,4-bis(isocyanatomethyl)cyclohexane and trans-1,4-bis(isocyanatomethyl)cyclohexane, with the proviso said isomeric mixture comprises at least about 5 weight percent of said trans-1,4-bis(isocyanatomethyl)cyclohexane.

    摘要翻译： 本发明涉及聚氨酯分散体及其制备的产品，其中分散体含有由过量的多异氰酸酯与异氰酸酯反应性分子的反应生成的聚氨酯预聚物，其中多异氰酸酯是双（异氰酸酯基甲基）环己烷。 优选地，异氰酸酯包含（i）反式-1,4-双（异氰酸甲酯基）环己烷或（ii）顺式-1,3-双（异氰酸甲酯基）环己烷，反式-1,3-双（异氰酸根合甲基） 异氰酸酯基甲基）环己烷，顺式-1,4-双（异氰酸甲酯基）环己烷和反式-1,4-双（异氰酸甲酯基）环己烷，条件是所述异构体混合物包含至少约5重量％的所述反式-1,4-双 （异氰酸甲酯基）环己烷。

    Dimeric carbonylation of 1,3-alkadiene
    8.
    发明授权
    Dimeric carbonylation of 1,3-alkadiene 失效
    1,3-链二烯的二元羰基化

    公开(公告)号：US4471067A

    公开(公告)日：1984-09-11

    申请号：US505006

    申请日：1983-06-16

    申请人： Paul Foley

    发明人： Paul Foley

    IPC分类号： C07C69/52 ,  C11C3/02 ,  B01J31/24

    CPC分类号： C07C69/52 ,  C11C3/02

    摘要： This invention provides a process for dimeric hydroesterification of 1,3-alkadiene in the presence of a catalyst which is a stabilized complex of palladium, tertiary phosphine ligand and thiol compound.

    摘要翻译： 本发明提供了在催化剂存在下1,3-二烯加成酯化1,3-丁二烯的方法，催化剂是钯，叔膦配位体和硫醇化合物的稳定络合物。

    Dimeric carbonylation of 1,3-alkadiene
    9.
    发明授权
    Dimeric carbonylation of 1,3-alkadiene 失效
    1,3-链二烯的二元羰基化

    公开(公告)号：US4416823A

    公开(公告)日：1983-11-22

    申请号：US319818

    申请日：1981-11-09

    申请人： Paul Foley

    发明人： Paul Foley

    IPC分类号： C07C69/52 ,  C11C3/02

    CPC分类号： C07C69/52 ,  C11C3/02

    摘要： This invention provides a process for dimeric hydroesterification of 1,3-alkadiene in the presence of a catalyst which is a stabilized complex of palladium, tertiary phosphine ligand and thiol compound.

    摘要翻译： 本发明提供了在催化剂存在下1,3-二烯加成酯化1,3-丁二烯的方法，催化剂是钯，叔膦配位体和硫醇化合物的稳定络合物。