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1.发明授权公开(公告)号：US09411209B2
公开(公告)日：2016-08-09
申请号：US14127702
申请日：2012-06-28
申请人： John R. Reynolds , Aubrey Lynn Dyer
发明人： John R. Reynolds , Aubrey Lynn Dyer
CPC分类号： G02F1/15 , G02F1/0018 , G02F2001/1502 , G02F2001/1515 , G02F2203/11
摘要： An electrochromic cell includes a minimally color changing polymer (MCCP) and a non-color changing polymer (NCCP), where the neutral state or the oxidized state is highly transmissive in the NIR and the oxidized state or the neutral state, respectively, is significantly less transmissive in the NIR. An electrochromic device (ECD) can include the electrochromic cell, or a combination of electrochromic cells. The ECD can be part of a window or a laminate for a window to permit the control of IR transmittance through the window.
摘要翻译： 电致变色元件包括最小变色聚合物（MCCP）和不变色聚合物（NCCP），其中中性态或氧化态分别在NIR和氧化态或中性状态下具有高度透射性，显着 在NIR中传输较少。 电致变色装置（ECD）可以包括电致变色细胞，或电致变色细胞的组合。 ECD可以是窗户的一部分或用于允许通过窗口控制IR透射率的窗户的层压板。
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公开(公告)号：US08284473B2
公开(公告)日：2012-10-09
申请号：US12746541
申请日：2009-03-24
申请人： John R. Reynolds , Aubrey Lynn Dyer , Ece Unur
发明人： John R. Reynolds , Aubrey Lynn Dyer , Ece Unur
IPC分类号： G02F1/153
CPC分类号： G02F1/155 , G02F1/15 , G02F1/1521 , G02F2001/1515 , G02F2001/1552 , G02F2001/1555
摘要： A dual active electrochromic device is a combination of at least two working electrodes that contain electrochromic materials and at least one counter electrode where the potentials between each working electrode and a counter electrode are independently supplied. No more than one electrode is reflective. The color of the device results from the additive color of the electrochromic materials and varies according to the potentials applied independently. The electrochromic materials can be electrochromic polymers that are deposited as film on substrates to form the working electrodes. The electrochromic device can be used for display or window applications.
摘要翻译： 双活性电致变色装置是包含电致变色材料的至少两个工作电极和至少一个相对电极的组合，其中每个工作电极和对电极之间的电位被独立地供给。 不超过一个电极是反射的。 设备的颜色来自电致变色材料的添加颜色，并根据独立应用的电位而变化。 电致变色材料可以是电沉积聚合物，其在基底上作为膜沉积以形成工作电极。 电致变色装置可用于显示或窗口应用。
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3.发明申请公开(公告)号：US20150138621A1
公开(公告)日：2015-05-21
申请号：US14127702
申请日：2012-06-28
申请人： John R. Reynolds , Aubrey Lynn Dyer
发明人： John R. Reynolds , Aubrey Lynn Dyer
CPC分类号： G02F1/15 , G02F1/0018 , G02F2001/1502 , G02F2001/1515 , G02F2203/11
摘要： An electrochromic cell includes a minimally color changing polymer (MCCP) and a non-color changing polymer (NCCP), where the neutral state or the oxidized state is highly transmissive in the NIR and the oxidized state or the neutral state, respectively, is significantly less transmissive in the NIR. An electrochromic device (ECD) can include the electrochromic cell, or a combination of electrochromic cells. The ECD can be part of a window or a laminate for a window to permit the control of IR transmittance through the window.
摘要翻译： 电致变色元件包括最小变色聚合物（MCCP）和不变色聚合物（NCCP），其中中性态或氧化态分别在NIR和氧化态或中性状态下具有高度透射性，显着 在NIR中传输较少。 电致变色装置（ECD）可以包括电致变色细胞，或电致变色细胞的组合。 ECD可以是窗户的一部分或用于允许通过窗口控制IR透射率的窗户的层压板。
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4.发明申请公开(公告)号：US20140175281A1
公开(公告)日：2014-06-26
申请号：US14127816
申请日：2012-06-28
申请人： John R. Reynolds , Ryan M. Walczak , Andrew Gabriel Rinzler , Svetlana V. Vasilyeva , Aubrey Lynn Dyer
发明人： John R. Reynolds , Ryan M. Walczak , Andrew Gabriel Rinzler , Svetlana V. Vasilyeva , Aubrey Lynn Dyer
CPC分类号： G02F1/163 , B82Y20/00 , B82Y30/00 , B82Y99/00 , G01J1/0407 , G01J1/44 , G02F1/15 , G02F1/15165 , G02F1/155 , G02F1/157 , G02F2001/1536 , G02F2201/16 , G02F2201/58 , G02F2202/28 , G02F2202/36 , G02F2203/11 , Y02A30/257 , Y02B80/50 , Y10S977/742
摘要： An electrochromic device (ECD) includes an electrochromic cell and, optionally, one or more additional electrochromic cells where all cells are parallel, and where at least one of the electrodes of one of the cells comprises a single-walled carbon nanotube (SWNT) film The electrochromic cells allow the control of transmittance of two or more different portions of the electro-magnetic spectrum through the ECD. One cell can control the transmittance of visible radiation while the other cell can control the transmittance of IR radiation. The ECD can be employed as a “smart window” to control the heat and light transmission through the window. The ECD can be in the form of a laminate that can be added to an existing window.
摘要翻译： 电致变色装置（ECD）包括电致变色电池和任选的一个或多个附加的电致变色细胞，其中所有细胞平行，并且其中一个电池的至少一个电极包括单壁碳纳米管（SWNT）膜 电致变色细胞允许通过ECD控制电磁光谱的两个或多个不同部分的透射率。 一个电池可以控制可见光的透射率，而另一个电池可以控制IR辐射的透射率。 ECD可以用作“智能窗口”来控制通过窗户的热和光透射。 ECD可以是可以添加到现有窗口的层压板的形式。
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公开(公告)号：US08120245B2
公开(公告)日：2012-02-21
申请号：US12936854
申请日：2009-04-15
申请人： John R. Reynolds , Aubrey Lynn Dyer
发明人： John R. Reynolds , Aubrey Lynn Dyer
CPC分类号： H01L51/5203 , G02F1/155
摘要： A dual electrochromic/electroluminescent (EC/EL) device of at least one pixel includes an interdigitated electrode where an electroactive layer is dispersed on and between the digits of the two electrodes of the interdigitated electrode. The electroactive layer is in contact with an electrolyte layer that also contacts a third electrode. The device acts as an electroluminescence device when an electrical bias between the two electrodes of the interdigitated electrode is established. The device acts as an electrochromic device when the electrical bias is established between the combined electrodes of the interdigitated electrode and the third electrode.
摘要翻译： 至少一个像素的双电致变色/电致发光（EC / EL）器件包括交叉电极，其中电活性层分散在交叉电极的两个电极的数位之间和之间。 电活性层与也与第三电极接触的电解质层接触。 当建立交叉电极的两个电极之间的电偏压时，该器件用作电致发光器件。 当在交叉电极和第三电极的组合电极之间建立电偏压时，器件用作电致变色器件。
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公开(公告)号：US20100265562A1
公开(公告)日：2010-10-21
申请号：US12746541
申请日：2009-03-24
申请人： John R. Reynolds , Aubrey Lynn Dyer , Ece Unur
发明人： John R. Reynolds , Aubrey Lynn Dyer , Ece Unur
IPC分类号： G02F1/15
CPC分类号： G02F1/155 , G02F1/15 , G02F1/1521 , G02F2001/1515 , G02F2001/1552 , G02F2001/1555
摘要： A dual active electrochromic device is a combination of at least two working electrodes that contain electrochromic materials and at least one counter electrode where the potentials between each working electrode and a counter electrode are independently supplied. No more than one electrode is reflective. The color of the device results from the additive color of the electrochromic materials and varies according to the potentials applied independently. The electrochromic materials can be electrochromic polymers that are deposited as film on substrates to form the working electrodes. The electrochromic device can be used for display or window applications.
摘要翻译： 双活性电致变色装置是包含电致变色材料的至少两个工作电极和至少一个相对电极的组合，其中每个工作电极和对电极之间的电位被独立地供给。 不超过一个电极是反射的。 设备的颜色来自电致变色材料的添加颜色，并根据独立应用的电位而变化。 电致变色材料可以是在基底上作为膜沉积以形成工作电极的电致变色聚合物。 电致变色装置可用于显示或窗口应用。
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7.发明授权Cathodically coloring yellow soluble electrochromic and light emitting polymers 有权阴极染色黄色可溶性电致变色和发光聚合物公开(公告)号：US08399603B2
公开(公告)日：2013-03-19
申请号：US13282999
申请日：2011-10-27
IPC分类号： C08G75/00
CPC分类号： C09K9/02 , C07D495/04 , C09K2211/1458 , C09K2211/1466
摘要： Embodiments of the invention are directed to yellow-to-transmissive conjugated polymers, a method to prepare the yellow conjugated polymers, the use of the yellow conjugated polymers in an electrochromic and/or electroluminescent device comprising neutral state primary subtractive colored conjugated polymers, and a method to prepare the device comprising the yellow conjugated polymer. The yellow conjugated polymers comprise a sequence of dioxythiophene units alternating with aromatic units, thiophene units, furan units, and/or pyrrole units. The yellow conjugated polymers are prepared by cross-condensation reactions. The yellow conjugated polymers can be soluble and preparation of the device involves deposition of the yellow conjugated polymer from solution onto a surface.
摘要翻译： 本发明的实施方案涉及黄色至透射的共轭聚合物，制备黄色共轭聚合物的方法，在含有中性状态的主要减色共轭聚合物的电致变色和/或电致发光装置中使用黄色共轭聚合物，以及 制备包含黄色共轭聚合物的装置的方法。 黄色共轭聚合物包含与芳族单元，噻吩单元，呋喃单元和/或吡咯单元交替的二氧噻吩单元的序列。 通过交联缩合反应制备黄色共轭聚合物。 黄色共轭聚合物可以是可溶的，并且该装置的制备涉及将黄色共轭聚合物从溶液沉积到表面上。
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8.发明申请CATHODICALLY COLORING YELLOW SOLUBLE ELECTROCHROMIC AND LIGHT EMITTING POLYMERS 有权阴极颜色黄色可溶性电致发光和发光聚合物公开(公告)号：US20120108778A1
公开(公告)日：2012-05-03
申请号：US13282999
申请日：2011-10-27
CPC分类号： C09K9/02 , C07D495/04 , C09K2211/1458 , C09K2211/1466
摘要： Embodiments of the invention are directed to yellow-to-transmissive conjugated polymers, a method to prepare the yellow conjugated polymers, the use of the yellow conjugated polymers in an electrochromic and/or electroluminescent device comprising neutral state primary subtractive colored conjugated polymers, and a method to prepare the device comprising the yellow conjugated polymer. The yellow conjugated polymers comprise a sequence of dioxythiophene units alternating with aromatic units, thiophene units, furan units, and/or pyrrole units. The yellow conjugated polymers are prepared by cross-condensation reactions. The yellow conjugated polymers can be soluble and preparation of the device involves deposition of the yellow conjugated polymer from solution onto a surface.
摘要翻译： 本发明的实施方案涉及黄色至透射的共轭聚合物，制备黄色共轭聚合物的方法，在含有中性状态的主要减色共轭聚合物的电致变色和/或电致发光装置中使用黄色共轭聚合物，以及 制备包含黄色共轭聚合物的装置的方法。 黄色共轭聚合物包含与芳族单元，噻吩单元，呋喃单元和/或吡咯单元交替的二氧噻吩单元的序列。 通过交联缩合反应制备黄色共轭聚合物。 黄色共轭聚合物可以是可溶的，并且该装置的制备涉及将黄色共轭聚合物从溶液沉积到表面上。
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公开(公告)号：US20110062860A1
公开(公告)日：2011-03-17
申请号：US12936854
申请日：2009-04-15
申请人： John R. Reynolds , Aubrey Lynn Dyer
发明人： John R. Reynolds , Aubrey Lynn Dyer
IPC分类号： H01J1/62
CPC分类号： H01L51/5203 , G02F1/155
摘要： A dual electrochromic/electroluminescent (EC/EL) device of at least one pixel includes an interdigitated electrode where an electroactive layer is dispersed on and between the digits of the two electrodes of the interdigitated electrode. The electroactive layer is in contact with an electrolyte layer that also contacts a third electrode. The device acts as an electroluminescence device when an electrical bias between the two electrodes of the interdigitated electrode is established. The device acts as an electrochromic device when the electrical bias is established between the combined electrodes of the interdigitated electrode and the third electrode.
摘要翻译： 至少一个像素的双电致变色/电致发光（EC / EL）器件包括交叉电极，其中电活性层分散在交叉电极的两个电极的数位之间和之间。 电活性层与也与第三电极接触的电解质层接触。 当建立交叉电极的两个电极之间的电偏压时，该器件用作电致发光器件。 当在交叉电极和第三电极的组合电极之间建立电偏压时，器件用作电致变色器件。
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公开(公告)号：US09775241B2
公开(公告)日：2017-09-26
申请号：US14009922
申请日：2012-04-03
申请人： Ryan M. Walczak , John R. Reynolds , Andrew Gabriel Rinzler , Andrew M. Spring , Svetlana V. Vasilyeva , Pooja Wadhwa
发明人： Ryan M. Walczak , John R. Reynolds , Andrew Gabriel Rinzler , Andrew M. Spring , Svetlana V. Vasilyeva , Pooja Wadhwa
IPC分类号： C09D147/00 , C09D101/02 , C09D11/00 , H05K1/09 , C08J3/02 , C09D5/02 , C09D7/12 , C01B31/02 , C01B31/04 , C09D11/30 , C09D11/52 , B82Y30/00 , B82Y40/00 , B05D1/04 , B05D1/18 , B05D1/28 , B05D3/00 , C08K7/24
CPC分类号： H05K1/092 , B05D1/04 , B05D1/18 , B05D1/28 , B05D3/007 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B32/194 , C08J3/02 , C08J2300/10 , C08K3/041 , C08K7/24 , C09D5/027 , C09D7/70 , C09D11/30 , C09D11/52 , C09D101/02 , C09D147/00 , H05K2201/0323 , C08L1/284 , C08L101/02
摘要： A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses. Upon deposition of the film, the degradable polymeric nanotube (NT) dispersant can be cleaved and the cleavage residues removed from the film to yield a film where contact between NTs is unencumbered by dispersants, resulting in highly conductive NT films.
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