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    In-line process for generating comonomer
    1.
    发明授权
    In-line process for generating comonomer 失效
    产生共聚单体的在线方法

    公开(公告)号：US07982085B2

    公开(公告)日：2011-07-19

    申请号：US11518456

    申请日：2006-09-08

    申请人： John Scott Buchanan ,  Timothy D. Shaffer ,  James R. Lattner ,  John F. Walzer

    发明人： John Scott Buchanan ,  Timothy D. Shaffer ,  James R. Lattner ,  John F. Walzer

    IPC分类号： C07C2/22

    CPC分类号： C07C2/32 ,  C07C2/36 ,  C07C2531/22 ,  C07C2531/24 ,  Y02P20/52 ,  C07C11/02

    摘要： The present invention relates to an in-line method for generating comonomer from monomer, such as ethylene. The comonomer generated is directly transported, without isolation or storage, to a polyethylene polymerization reactor. The in-line method includes the steps of providing an in-line comonomer synthesis reactor and a downstream gas/liquid phase separator prior to the polymerization reactor; feeding ethylene monomer and a catalyst in a solvent and/or diluent to the comonomer synthesis reactor; reacting the ethylene monomer and the catalyst in solvent and/or diluent under reaction conditions to produce an effluent stream including ethylene monomer and comonomer; passing the effluent stream from the comonomer synthesis reactor to the downstream gas/liquid phase separator to separate a gas stream from a bottom stream, wherein the gas stream is a mixture of ethylene monomer and comonomer; and passing the gas stream to the polymerization reactor to provide the necessary comonomer input.

    摘要翻译： 本发明涉及从单体如乙烯生成共聚单体的在线方法。 生成的共聚单体直接输送到聚乙烯聚合反应器中，无需隔离或储存。 在线方法包括在聚合反应器之前提供在线共聚单体合成反应器和下游气/液相分离器的步骤; 将乙烯单体和催化剂在溶剂和/或稀释剂中加入到共聚单体合成反应器中; 在反应条件下使乙烯单体和催化剂在溶剂和/或稀释剂中反应以产生包括乙烯单体和共聚单体的流出物流; 将来自共聚单体合成反应器的流出物流输送到下游气/液相分离器以从底部流分离气流，其中气流是乙烯单体和共聚单体的混合物; 并将气流送入聚合反应器以提供所需的共聚单体输入。

    In-line process for generating comonomer
    2.
    发明申请
    In-line process for generating comonomer 失效
    产生共聚单体的在线方法

    公开(公告)号：US20070185361A1

    公开(公告)日：2007-08-09

    申请号：US11518456

    申请日：2006-09-08

    申请人： John Scott Buchanan ,  Timothy D. Shaffer ,  James R. Lattner ,  John F. Walzer

    发明人： John Scott Buchanan ,  Timothy D. Shaffer ,  James R. Lattner ,  John F. Walzer

    IPC分类号： C07C2/02

    CPC分类号： C07C2/32 ,  C07C2/36 ,  C07C2531/22 ,  C07C2531/24 ,  Y02P20/52 ,  C07C11/02

    摘要： The present invention relates to an in-line method for generating comonomer from monomer, such as ethylene. The comonomer generated is directly transported, without isolation or storage, to a polyethylene polymerization reactor. The in-line method includes the steps of providing an in-line comonomer synthesis reactor and a downstream gas/liquid phase separator prior to the polymerization reactor; feeding ethylene monomer and a catalyst in a solvent and/or diluent to the comonomer synthesis reactor; reacting the ethylene monomer and the catalyst in solvent and/or diluent under reaction conditions to produce an effluent stream including ethylene monomer and comonomer; passing the effluent stream from the comonomer synthesis reactor to the downstream gas/liquid phase separator to separate a gas stream from a bottom stream, wherein the gas stream is a mixture of ethylene monomer and comonomer; and passing the gas stream to the polymerization reactor to provide the necessary comonomer input

    摘要翻译： 本发明涉及从单体如乙烯生成共聚单体的在线方法。 生成的共聚单体直接输送到聚乙烯聚合反应器中，无需隔离或储存。 在线方法包括在聚合反应器之前提供在线共聚单体合成反应器和下游气/液相分离器的步骤; 将乙烯单体和催化剂在溶剂和/或稀释剂中加入到共聚单体合成反应器中; 在反应条件下使乙烯单体和催化剂在溶剂和/或稀释剂中反应以产生包括乙烯单体和共聚单体的流出物流; 将来自共聚单体合成反应器的流出物流输送到下游气/液相分离器以从底部流分离气流，其中气流是乙烯单体和共聚单体的混合物; 并将气流送入聚合反应器以提供所需的共聚单体输入

    Polydispersity-controlled isoolefin polymerization with polymorphogenates
    3.
    发明授权
    Polydispersity-controlled isoolefin polymerization with polymorphogenates 有权
    多分散控制的异烯烃聚合与多形态

    公开(公告)号：US08178465B2

    公开(公告)日：2012-05-15

    申请号：US13005325

    申请日：2011-01-12

    申请人： Timothy D. Shaffer ,  Michael F. McDonald ,  David Y. Chung ,  Robert N. Webb ,  Deborah J. Davis ,  Pamela J. Wright

    发明人： Timothy D. Shaffer ,  Michael F. McDonald ,  David Y. Chung ,  Robert N. Webb ,  Deborah J. Davis ,  Pamela J. Wright

    IPC分类号： C08F4/52 ,  C08F4/14 ,  C08F4/76 ,  C08F10/10

    CPC分类号： C08F210/12 ,  C08F2/04 ,  C08F2/12 ,  C08F236/08 ,  C08F2500/04 ,  C08F4/00

    摘要： The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.

    摘要翻译： 本公开提供了一种方法和聚合体系，以在催化剂体系中利用多形态（16,26）来产生异构烯烃聚合物（72）以控制多分散性（MWD）。 本公开还提供了催化剂体系（20），其包含通过路易斯酸（24），引发剂（22）和多形态（26）的组合形成的多种活性催化剂络合物（34），以及使用 催化剂体系或工艺。 聚异构体（16,26）可以促进或模拟具有不同聚合速率的不同活性催化剂复合物（34）的形成，即不同的传播速率，链转移或终止，如通过相对存在导致的不同多分散性所观察到的 不同比例的多形态。

    Method for reducing depositions in polymerization vessels
    5.
    发明授权
    Method for reducing depositions in polymerization vessels 有权
    降低聚合容器沉积的方法

    公开(公告)号：US07557170B2

    公开(公告)日：2009-07-07

    申请号：US12179375

    申请日：2008-07-24

    申请人： Timothy D. Shaffer ,  Pamela J. Wright ,  J. Davis Deborah ,  Michael F. McDonald

    发明人： Timothy D. Shaffer ,  Pamela J. Wright ,  J. Davis Deborah ,  Michael F. McDonald

    IPC分类号： C08F2/00 ,  C08F10/10

    CPC分类号： C08F210/12 ,  C08F2/01 ,  C08F2/14 ,  C08F236/08 ,  C08F2500/02 ,  C08F2500/03

    摘要： The method of polymerization includes the steps of a) providing a catalyst system, b) providing at least one monomer or comonomer mixture in a reaction vessel, c) introducing the catalyst into the reaction vessel, and d) polymerizing the at least one monomer or comonomer mixture to produce an isoolefin polymer. The catalyst may be soluble in the diluent used for polymerization. The polymerization contact surfaces of the reaction vessel have an arithmetic average surface roughness of less than 0.3 μm (12 microinches).

    摘要翻译： 聚合方法包括以下步骤：a）提供催化剂体系，b）在反应容器中提供至少一种单体或共聚单体混合物，c）将催化剂引入反应容器中，和d）聚合至少一种单体或 共聚单体混合物以产生异烯烃聚合物。 催化剂可溶于用于聚合的稀释剂中。 反应容器的聚合接触表面的算术平均表面粗糙度小于0.3μm（12微英寸）。

    Process to produce a hydrocarbon rubber cement utilizing a hydrofluorocarbon diluent
    7.
    发明授权
    Process to produce a hydrocarbon rubber cement utilizing a hydrofluorocarbon diluent 有权
    使用氢氟烃稀释剂生产烃橡胶水泥的方法

    公开(公告)号：US08148450B2

    公开(公告)日：2012-04-03

    申请号：US11473732

    申请日：2006-06-23

    申请人： Michael F. McDonald ,  Scott T. Milner ,  Timothy D. Shaffer ,  Robert N. Webb ,  Richard D. Hembree

    发明人： Michael F. McDonald ,  Scott T. Milner ,  Timothy D. Shaffer ,  Robert N. Webb ,  Richard D. Hembree

    IPC分类号： C08F6/00

    CPC分类号： C08F6/003 ,  C08C1/02 ,  C08C2/04 ,  C08C2/06 ,  C08J3/09 ,  C08J2321/00

    摘要： Provided for herein is a process to produce an essentially homogeneous single liquid phase hydrocarbon-rubber cement from a polymer slurry comprising a hydrocarbon-rubber, a diluent, and unreacted monomer(s), the process comprising: (a) contacting the polymer slurry with a hydrocarbon solvent; and (b) removing the diluent in amounts not sufficiently more than is necessary to produce the essentially homogeneous single liquid phase hydrocarbon-rubber cement wherein the mass fraction of monomer(s) in the hydrocarbon-rubber cement, based on the total amount of hydrocarbon-rubber present in the hydrocarbon-rubber cement, is less than the mass fraction of monomer(s) in the hydrocarbon-rubber slurry, based on the total amount of hydrocarbon-rubber present in the hydrocarbon-rubber slurry, wherein the diluent comprises a hydrofluorocarbon.

    摘要翻译： 本文提供了一种从包含烃橡胶，稀释剂和未反应单体的聚合物浆料制备基本均匀的单液相烃 - 橡胶胶泥的方法，该方法包括：（a）使聚合物浆料与 烃溶剂; 和（b）以不足于制备基本上均匀的单液相烃橡胶胶浆所需量的量除去稀释剂，其中基于烃总量的烃 - 橡胶胶浆中单体的质量分数 存在于烃 - 橡胶胶浆中的橡胶基于烃 - 橡胶浆料中存在的烃 - 橡胶的总量小于烃 - 橡胶浆料中单体的质量分数，其中稀释剂包含 氢氟碳化合物。

    In-line process for generating comonomer
    8.
    发明授权
    In-line process for generating comonomer 失效
    产生共聚单体的在线方法

    公开(公告)号：US07687672B2

    公开(公告)日：2010-03-30

    申请号：US11346651

    申请日：2006-02-03

    申请人： John S. Buchanan ,  Timothy D. Shaffer

    发明人： John S. Buchanan ,  Timothy D. Shaffer

    IPC分类号： C07C2/24

    CPC分类号： C07C2/26 ,  C08F10/02 ,  C08F210/16 ,  Y02P20/52 ,  C08F2/00

    摘要： The present invention relates to an in-line method for generating comonomer, such as 1-hexene or 1-octene, from monomer, such as ethylene. The comonomer generated is directly transported, without isolation or storage, to a polyethylene polymerization reactor. The in-line method for generating comonomer includes the steps of providing an in-line comonomer synthesis reactor and a downstream gas/liquid phase separator prior to a polyethylene polymerization reactor; feeding ethylene monomer and a catalyst in a solvent to the comonomer synthesis reactor; reacting the ethylene monomer and the catalyst in solvent under reaction conditions to produce an effluent stream including ethylene monomer and comonomer; passing the effluent stream from the comonomer synthesis reactor to the downstream gas/liquid phase separator to separate a gas stream from a bottom stream, wherein the gas stream is a mixture of ethylene monomer, and comonomer; and passing the gas stream to the polyethylene polymerization reactor to provide the necessary comonomer input. The in-line method is useful in the production of LLDPE, and other branched polyethylene based polymers. Some benefits include process simplification and reduced capital and operating costs.

    摘要翻译： 本发明涉及从单体如乙烯生成共聚单体如1-己烯或1-辛烯的直列方法。 生成的共聚单体直接输送到聚乙烯聚合反应器中，无需隔离或储存。 用于生成共聚单体的在线方法包括在聚乙烯聚合反应器之前提供在线共聚单体合成反应器和下游气/液相分离器的步骤; 将乙烯单体和催化剂在溶剂中加入到共聚单体合成反应器中; 在反应条件下使乙烯单体和催化剂在溶剂中反应，以产生包括乙烯单体和共聚单体的流出物流; 将来自共聚单体合成反应器的流出物流输送到下游气/液相分离器以从底部流分离气流，其中气流是乙烯单体和共聚单体的混合物; 并将气流送入聚乙烯聚合反应器以提供所需的共聚单体输入。 在线方法可用于生产LLDPE和其他支化聚乙烯基聚合物。 一些好处包括流程简化，降低资本和运营成本。