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1.发明授权Radiation curable resin composition and rapid three-dimensional imaging process using the same 有权辐射固化树脂组合物和使用其的快速三维成像方法公开(公告)号：US08501033B2
公开(公告)日：2013-08-06
申请号：US13001655
申请日：2010-03-12
申请人： John Southwell , Brett A. Register , Satyendra Kumar Sarmah , Paulus Antonius Maria Steeman , Beert Jacobus Keestra , Marcus Matheus Driessen
发明人： John Southwell , Brett A. Register , Satyendra Kumar Sarmah , Paulus Antonius Maria Steeman , Beert Jacobus Keestra , Marcus Matheus Driessen
CPC分类号： B29C67/0055 , B29C64/106 , B33Y10/00 , B33Y70/00 , B33Y80/00 , C08G65/18 , C08L63/00 , G03F7/0037 , G03F7/027 , G03F7/038 , Y10T428/31511 , C08L2666/04
摘要： The invention relates to a liquid radiation curable resin capable of curing into a solid upon irradiation comprising: (A) from about 0 to about 12 wt % of a cycloaliphatic epoxide having a linking ester group; (B) from about 30 to about 65 wt % of one or more epoxy functional components other than A; (C) from about 10 to about 30 wt % of one or more oxetanes; (D) from, about 1 to about 10 wt % of one or more polyols; (E) from about 2 to about 20 wt % of one or more radically curable (meth)acrylate components; (F) from about 2 to about 12 wt % of one or more impact modifiers; (G) from about 0.1 to about 8 wt % of one or more free radical photoinitiators; and (H) from about 0.1 to about 8 wt % of one or more cationic photoinitiators; wherein the liquid radiation curable resin has a viscosity at 30° C. of from about 600 cps to about 1300 cps.
摘要翻译： 本发明涉及能够在照射时固化成固体的液体辐射固化树脂，其包含：（A）约0至约12重量％的具有连接酯基的脂环族环氧化物; （B）约30至约65重量％的除A之外的一种或多种环氧官能组分; （C）约10至约30重量％的一种或多种氧杂环丁烷; （D）约1至约10重量％的一种或多种多元醇; （E）约2至约20重量％的一种或多种可自由基固化的（甲基）丙烯酸酯组分; （F）约2至约12重量％的一种或多种抗冲改性剂; （G）约0.1至约8重量％的一种或多种自由基光引发剂; 和（H）约0.1至约8重量％的一种或多种阳离子光引发剂; 其中所述液体辐射可固化树脂在30℃下的粘度为约600cps至约1300cps。
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2.发明申请公开(公告)号：US20100304088A1
公开(公告)日：2010-12-02
申请号：US12667108
申请日：2007-04-26
申请人： Paulus Antonius Maria Steeman , Beert Jacobus Keestra , Marco Marcus Matheus Driessen , Debra Lynn Fish Repko , Melvin Zussman
发明人： Paulus Antonius Maria Steeman , Beert Jacobus Keestra , Marco Marcus Matheus Driessen , Debra Lynn Fish Repko , Melvin Zussman
CPC分类号： C08G59/68 , B33Y70/00 , G03F7/0037 , G03F7/038 , Y10T428/24479
摘要： The invention relates to a radiation curable resin composition comprising a cationically polymerizable component, a cationic photoinitiator, a hydroxy component, an impact modifier and wherein the resin composition after full cure has a modulus of >2 GPa; a yield stress 1.3 MPa. (m)1/2 or an Izod value>0.45 J/cm. The resin composition can preferably be used in the preparation of three dimensional objects.
摘要翻译： 本发明涉及一种包含阳离子可聚合组分，阳离子光引发剂，羟基组分，抗冲改性剂的辐射固化树脂组合物，其中完全固化后的树脂组合物具有> 2GPa的模量; 屈服应力<70MPa; K1c值> 1.3MPa。 （m）1/2或Izod值> 0.45J / cm。 树脂组合物可以优选用于制备三维物体。
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3.发明授权公开(公告)号：US09676899B2
公开(公告)日：2017-06-13
申请号：US12667108
申请日：2007-04-26
申请人： Paulus Antonius Maria Steeman , Beert Jacobus Keestra , Marco Marcus Matheus Driessen , Debra Lynn Fish Repko , Melvin Zussman
发明人： Paulus Antonius Maria Steeman , Beert Jacobus Keestra , Marco Marcus Matheus Driessen , Debra Lynn Fish Repko , Melvin Zussman
CPC分类号： C08G59/68 , B33Y70/00 , G03F7/0037 , G03F7/038 , Y10T428/24479
摘要： The invention relates to a radiation curable resin composition comprising a cationically polymerizable component, a cationic photoinitiator, a hydroxy component, an impact modifier and wherein the resin composition after full cure has a modulus of >2 GPa; a yield stress 1.3 MPa·(m)1/2 or an Izod value >0.45 J/cm. The resin composition can preferably be used in the preparation of three dimensional objects.
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公开(公告)号：US20100329617A1
公开(公告)日：2010-12-30
申请号：US12517838
申请日：2007-12-04
申请人： Markus Johannes Henricus Bulters , Paulus Antonius Maria Steeman , Aylvin Jorge Angelo Athanasi Dias , Beert Jacobus Keestra
发明人： Markus Johannes Henricus Bulters , Paulus Antonius Maria Steeman , Aylvin Jorge Angelo Athanasi Dias , Beert Jacobus Keestra
CPC分类号： C08L51/003 , C03C25/1065 , C08F290/00 , C08F290/06 , C08G18/672 , C09D4/06 , C09D151/003 , C08G18/48 , C08L2666/14 , C08L2666/02
摘要： The invention relates to a radiation-curable primary coating composition comprising 0.6-10 vol % of particles which when cured has an equilibrium modulus of about 1.5 MPa or less, and a cavitation strength at which a tenth cavity appears (α10cav) of at least about 1.1 MPa.
摘要翻译： 本发明涉及一种可辐射固化的一次涂料组合物，其包含0.6-10vol％的颗粒，当固化时其平衡模量为约1.5MPa或更小，以及第十个空腔出现的空化强度（α10cav）为至少约 1.1 MPa。
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公开(公告)号：US20140353878A1
公开(公告)日：2014-12-04
申请号：US14126675
申请日：2012-06-15
申请人： Marco Marcus Matheus Driessen , Michelle Elizabeth Seitz , Paulus Antonius Maria Steeman , John Edmond Southwell , Jigeng Xu , Richard Thomas , Micha Sandor Nicolaas Hubert Mulders
发明人： Marco Marcus Matheus Driessen , Michelle Elizabeth Seitz , Paulus Antonius Maria Steeman , John Edmond Southwell , Jigeng Xu , Richard Thomas , Micha Sandor Nicolaas Hubert Mulders
IPC分类号： B29C67/00
CPC分类号： B29C64/106 , B29C64/129 , B29C64/135 , B29C64/40 , B33Y10/00 , B33Y30/00
摘要： A method and apparatus for additive fabrication which provides a substrate which helps the newly hardened resin layer to separate from the substrate while providing a substrate of appropriate strength and durability. In an embodiment, the substrate is a multi-layer substrate comprising a transport layer and a structural layer, the transport layer comprising a polyolefin or a fluoropolymer, and the structural layer comprising a semi-crystal line thermoplastic polymer.
摘要翻译： 一种用于添加剂制造的方法和装置，其提供有助于新硬化的树脂层与基底分离的基底，同时提供具有适当强度和耐久性的基底。 在一个实施方案中，所述基材是包含传输层和结构层的多层基材，所述输送层包含聚烯烃或含氟聚合物，所述结构层包含半结晶线热塑性聚合物。
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公开(公告)号：US09862146B2
公开(公告)日：2018-01-09
申请号：US14126675
申请日：2012-06-15
申请人： Marco Marcus Matheus Driessen , Michelle Elizabeth Seitz , Paulus Antonius Maria Steeman , John Edmond Southwell , Jigeng Xu , Richard Thomas , Micha Sandor Nicolaas Hubert Mulders
发明人： Marco Marcus Matheus Driessen , Michelle Elizabeth Seitz , Paulus Antonius Maria Steeman , John Edmond Southwell , Jigeng Xu , Richard Thomas , Micha Sandor Nicolaas Hubert Mulders
CPC分类号： B29C64/106 , B29C64/129 , B29C64/135 , B29C64/40 , B33Y10/00 , B33Y30/00
摘要： A method and apparatus for additive fabrication which provides a substrate which helps the newly hardened resin layer to separate from the substrate while providing a substrate of appropriate strength and durability. In an embodiment, the substrate is a multi-layer substrate comprising a transport layer and a structural layer, the transport layer comprising a polyolefin or a fluoropolymer, and the structural layer comprising a semi-crystal line thermoplastic polymer.
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公开(公告)号：US20100286728A1
公开(公告)日：2010-11-11
申请号：US12681700
申请日：2008-10-06
IPC分类号： D01F6/04 , C08F110/02 , B29C43/22 , A61L17/04
CPC分类号： D01F6/04 , B29C47/0004 , B29K2023/0683 , B29L2031/731 , C08F110/02 , D01D5/04 , Y10T428/2913
摘要： The invention relates to a process for producing gel-spun ultra high molecular weight polyethylene (UHMWPE) fibres having high tensile strengths and improved creep rates wherein the UHMWPE used in said process is characterized by a difference in the phase angle according to Formula (1) Δδ=δ0.001−δ100 of at most 42°, wherein δ0.001 is the phase angle at an angular frequency of 0.001 rad/sec; and δ100 is the phase angle at an angular frequency of 100 rad/sec as measured with a frequency sweep dynamic rheological technique at 150° C. on a 10% solution of UHMWPE in paraffin oil, provided that δ100 is at most 18°. The invention further relates to gel-spun UHMWPE fibres produced thereof. The gel-spun UHMWPE fibres of the invention have a tensile strength of at least 4 GPa, and a creep rate of at most 5×10−7 sec−1 as measured at 70° C. under a load of 600 MPa. The gel-spun UHMWPE fibres produced thereof are useful in a variety of applications, the invention relating in particular to ropes, medical devices, composite articles and ballistic-resistant articles containing said UHMWPE fibres.
摘要翻译： 本发明涉及一种制备具有高拉伸强度和改进的蠕变速率的凝胶纺超高分子量聚乙烯（UHMWPE）纤维的方法，其中在所述方法中使用的UHMWPE的特征在于根据式（1）的相位角的差异， ＆Dgr;δ=δ0.001-δ100至多42°，其中δ0.001是角度频率为0.001rad / sec的相位角; 而δ100是在150℃下用UHMWPE在石蜡油中的10％溶液进行频率扫描动态流变学技术测量的角度频率为100rad / sec的相位角，条件是δ100至多为18°。 本发明还涉及其生产的凝胶纺丝UHMWPE纤维。 本发明的凝胶纺丝UHMWPE纤维的拉伸强度至少为4GPa，蠕变速率在70℃，600MPa的载荷下测得的最大为5×10-7秒-1。 其生产的凝胶纺丝UHMWPE纤维可用于各种应用中，本发明特别涉及包含所述UHMWPE纤维的绳索，医疗装置，复合制品和防弹制品。
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公开(公告)号：US07906566B2
公开(公告)日：2011-03-15
申请号：US10571758
申请日：2004-09-17
申请人： Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Antonius Maria Steeman
发明人： Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Antonius Maria Steeman
CPC分类号： C08G18/672 , C03C25/1061 , C03C25/1065 , C08G18/4854 , C08L75/16 , C09D175/16 , Y10T428/2933 , C08G18/48 , C08L2666/14
摘要： The invention relates to a curable liquid resin composition comprising: (A) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 800 g/mol or more, but less than 6,000 g/mol, and (B) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 6,000 g/mol or more, but less than 20,000 g/mol, wherein the total amount of the component (A) and component (B) is 20-95 wt % of the curable liquid resin composition and the content of the component (B) is 0.1-30 wt % of the total of the component (A) and component (B).
摘要翻译： 本发明涉及一种可固化液体树脂组合物，其包含：（A）具有起始于多元醇的结构和数均分子量为800g / mol以上但小于6,000g / mol的氨基甲酸酯（甲基）丙烯酸酯，以及 （B）具有来自多元醇的结构和数均分子量为6000g / mol以上但小于20,000g / mol的氨基甲酸酯（甲基）丙烯酸酯，其中组分（A）和组分 （B）为可固化液体树脂组合物的20-95重量％，组分（B）的含量为组分（A）和组分（B）的总量的0.1-30重量％。
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公开(公告)号：US20080226909A1
公开(公告)日：2008-09-18
申请号：US11955541
申请日：2007-12-13
申请人： Steven R. Schmid , Petrus Jacobus Hubertus Niels , Paulus Antonius Maria Steeman , Xiaosong Wu , Wendell Wayne Cattron , Tyson Dean Norlin , Edward J. Murphy , John M. Zimmerman , Anthony Joseph Tortorello
发明人： Steven R. Schmid , Petrus Jacobus Hubertus Niels , Paulus Antonius Maria Steeman , Xiaosong Wu , Wendell Wayne Cattron , Tyson Dean Norlin , Edward J. Murphy , John M. Zimmerman , Anthony Joseph Tortorello
CPC分类号： G02B1/14 , C03C25/1065 , C08G18/672 , C08G18/724 , C09D5/002 , C09D175/16 , G02B1/10 , G02B6/02395 , Y10T428/24942 , Y10T428/2933 , Y10T428/2942 , Y10T428/2947 , C08G18/48
摘要： The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%;B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about −25° C. to about −55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.
摘要翻译： 本发明提供涂覆有超涂层的光纤，其中超涂层包括至少两层，其中第一层是与光纤的外表面接触的主涂层，第二层是接触的第二涂层 其中主要涂层的外表面，其中光纤上的固化的一次涂层在初始固化后和在85℃和85％相对湿度下老化一个月后具有以下性质：A）约84％的％RAU， 至约99％; B）约0.15MPa至约0.60MPa的原位模量; 和C）管Tg，约-25℃至约-55℃; 其中光纤上的固化的二次涂层在初始固化之后和在85℃和85％相对湿度下老化一个月后具有以下性能：A）约80％至约98％的％RAU; B）原位模量在约0.60GPa和约1.90GPa之间; 和C）管Tg，为约50℃至约80℃
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公开(公告)号：US09005753B2
公开(公告)日：2015-04-14
申请号：US12681700
申请日：2008-10-06
CPC分类号： D01F6/04 , B29C47/0004 , B29K2023/0683 , B29L2031/731 , C08F110/02 , D01D5/04 , Y10T428/2913
摘要： The invention relates to a process for producing gel-spun ultra high molecular weight polyethylene (UHMWPE) fibres having high tensile strengths and improved creep rates wherein the UHMWPE used in said process is characterized by a difference in the phase angle according to Formula (1) Δδ=δ0.001−δ100 of at most 42°, wherein δ0.001 is the phase angle at an angular frequency of 0.001 rad/sec; and δ100 is the phase angle at an angular frequency of 100 rad/sec as measured with a frequency sweep dynamic rheological technique at 150° C. on a 10% solution of UHMWPE in paraffin oil, provided that δ100 is at most 18°. The invention further relates to gel-spun UHMWPE fibres produced thereof. The gel-spun UHMWPE fibres of the invention have a tensile strength of at least 4 GPa, and a creep rate of at most 5×10−7 sec−1 as measured at 70° C. under a load of 600 MPa. The gel-spun UHMWPE fibres produced thereof are useful in a variety of applications, the invention relating in particular to ropes, medical devices, composite articles and ballistic-resistant articles containing said UHMWPE fibres.
摘要翻译： 本发明涉及一种制备具有高拉伸强度和改进的蠕变速率的凝胶纺超高分子量聚乙烯（UHMWPE）纤维的方法，其中在所述方法中使用的UHMWPE的特征在于根据式（1）的相位角的差异， ＆Dgr;δ=δ0.001-δ100至多42°，其中δ0.001是角度频率为0.001rad / sec的相位角; 而δ100是在150℃下用UHMWPE在石蜡油中的10％溶液进行频率扫描动态流变学技术测量的角度频率为100rad / sec的相位角，条件是δ100至多为18°。 本发明还涉及其生产的凝胶纺丝UHMWPE纤维。 本发明的凝胶纺丝UHMWPE纤维的拉伸强度至少为4GPa，蠕变速率在70℃，600MPa的载荷下测得的最大为5×10-7秒-1。 其生产的凝胶纺丝UHMWPE纤维可用于各种应用中，本发明特别涉及包含所述UHMWPE纤维的绳索，医疗装置，复合制品和防弹制品。
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