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公开(公告)号：US20080171208A1
公开(公告)日：2008-07-17
申请号：US12001158
申请日：2007-12-10
IPC分类号： C09J175/04 , C08G18/02 , B32B27/40
CPC分类号： C08G18/792 , C08G18/222 , C08G18/4238 , C08G18/5024 , C08G18/722 , C08G2170/80 , Y10T428/31551
摘要： The invention relates to adhesives based on aqueous dispersions and surface-deactivated isocyanate particles and to latently reactive coatings, films and powders produced from such dispersions. The adhesives are prepared from aqueous compositions containing a) dispersed polymers with isocyanate-reactive groups; b) at least one dispersed surface-deactivated aliphatic solid polyisocyanate with a softening temperature of ≧40° C.; c) one or more compounds of elements from subgroups 5 and 6 of the periodic system of elements, in which the particular element has an oxidation number of at least +4 and, d) optionally further additives and auxiliaries.
摘要翻译： 本发明涉及基于水性分散体和表面失活的异氰酸酯颗粒的粘合剂以及由这种分散体制备的潜在反应性涂料，膜和粉末。 粘合剂由含有a）具有异氰酸酯反应性基团的分散聚合物的水性组合物制备; b）软化温度> 40℃的至少一种分散的表面失活的脂族固体多异氰酸酯; c）一种或多种元素周期性系统的亚组5和6的元素化合物，其中特定元素具有至少+4的氧化数，以及d）任选的其它添加剂和助剂。
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公开(公告)号：US20090240005A1
公开(公告)日：2009-09-24
申请号：US12370786
申请日：2009-02-13
申请人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt , Erkut Ilter
发明人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt , Erkut Ilter
IPC分类号： C08G71/04
CPC分类号： C08L75/04 , C08G18/0823 , C08G18/0828 , C08G18/10 , C08G18/12 , C08G18/4213 , C08G18/4238 , C08G18/6651 , C08G18/6659 , C08G18/722 , C08G18/73 , C08G18/755 , C08L75/06 , C08L2666/20 , C09D175/04 , C09D175/06 , C09J175/04 , C09J175/06 , C08G18/3228
摘要： The invention relates to aqueous dispersion adhesives based on a mixture of aqueous polyurethane or polyurethane-urea dispersions, to a process for their preparation, and to the use of the dispersion adhesives in the production of adhesive composites.
摘要翻译： 本发明涉及基于水性聚氨酯或聚氨酯 - 脲分散体的混合物的水性分散粘合剂，其制备方法，以及分散粘合剂在制备粘合剂复合材料中的用途。
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公开(公告)号：US20110217502A1
公开(公告)日：2011-09-08
申请号：US13127874
申请日：2009-10-31
IPC分类号： B32B27/06 , C09J175/08 , B32B27/00 , B32B27/40
CPC分类号： C08G18/0823 , C08G18/12 , C08G18/6692 , C08G18/7621 , C08G2170/80 , C09J175/04 , Y10T428/21 , Y10T428/249921 , Y10T428/2896 , Y10T428/31551 , Y10T428/31591 , C08G18/302
摘要： The present invention relates to an aqueous polyurethane urea dispersion comprising a polyurethane urea polymer comprising structural units of the formula (I) wherein Aromat represents a compound selected from the group consisting of phenylene, tolylene, xylylene, tetramethylxylylene and diphenylenemethane, and wherein the polyurethane urea is obtained from components comprising A) at least one aromatic diisocyanate, B) at least one polyether polyol having a number-average molecular weight of from 300 to 1500 Da, C) at least one compound having one to two isocyanate-reactive groups and at least one ionogenic group, D) at least one polyol having a number-average molecular weight of from 60 to 499 Da, and E) water, wherein the average overall functionality of compounds B) to D) is from 1.85 to 2.2 and wherein the sum of the amount of aromatic urea groups and the amount of urethane groups is 2700 to 5000 mmol per kg polyurethane urea polymer.
摘要翻译： 本发明涉及包含式（I）结构单元的聚氨酯脲聚合物的水性聚氨酯脲分散体，其中芳族化合物表示选自亚苯基，甲苯，亚二甲苯，四甲基亚二甲苯和二苯基甲烷的化合物，其中聚氨酯脲 包括A）至少一种芳族二异氰酸酯，B）至少一种数均分子量为300至1500Da的聚醚多元醇，C）至少一种具有一至二个异氰酸酯反应性基团的化合物和 至少一种离子型基团，D）至少一种数均分子量为60至499Da的多元醇，和E）水，其中化合物B）至D）的平均总官能度为1.85至2.2，其中 芳族脲基团的量和氨基甲酸酯基团的量的总和为2700至5000mmol / kg聚氨酯脲聚合物。
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4.发明授权Aqueous polyurethane-polyurethane urea dispersions, adhesives containing the same, processes for the preparation thereof and uses therefore 有权水性聚氨酯 - 聚氨酯脲分散体，含有它们的粘合剂，其制备方法和用途公开(公告)号：US08586185B2
公开(公告)日：2013-11-19
申请号：US12741887
申请日：2008-10-24
申请人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt
发明人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt
IPC分类号： B32B27/40 , C08L75/04 , C09J175/04
CPC分类号： C08G18/4238 , C08G18/0828 , C08G18/12 , C08G18/283 , C08G18/4202 , C08G18/664 , C08G18/722 , C08G2170/80 , C09J175/12 , Y10T428/31551 , Y10T428/31573 , Y10T428/31591 , C08G18/3271 , C08G18/3857
摘要： Aqueous polyurethane-polyurethane urea dispersions comprising a reaction product of: (i) an NCO prepolymer prepared from; (A) one or more di- or higher-functional polyols having a mean molecular weight of 400 to 5000 daltons, (B) optionally one or more di- or higher-functional polyol components having a molecular weight of from 62 to 399 daltons, (C) one or more compounds which are monofunctional within the scope of the isocyanate polyaddition reaction and have an ethylene oxide content of at least 50 wt. % and a molecular weight of at least 400 daltons, and (D) one or more di- or poly-isocyanate components; and (ii) a mixture (E) of primary and/or secondary monoamino compounds (E1) and primary and/or secondary diamino compounds (E2); wherein at least one of the amino compounds of the mixture (E) has a functional group selected from sulfonates and carboxylates; wherein mixture (E) has a mean amino functionality of 1.65 to 1.95; and wherein the equivalent ratio of NCO groups in the NCO prepolymer to the total amount of isocyanate-reactive groups of the mixture (E) is 1.04 to 1.9; to processes for their preparation and to use thereof in the production of adhesive composites.
摘要翻译： 水性聚氨酯 - 聚氨酯脲分散体包含以下反应产物：（i）由下列物质制备的NCO预聚物： （A）一种或多种平均分子量为400至5000道尔顿的二官能或更高官能的多元醇，（B）任选的一种或多种分子量为62至399道尔顿的二官能或更高官能的多元醇组分， （C）一种或多种在异氰酸酯加聚反应范围内是单官能的化合物，其环氧乙烷含量至少为50wt。 ％和分子量至少400道尔顿，和（D）一种或多种二异氰酸酯或多异氰酸酯组分; 和（ii）伯和/或仲单氨基化合物（E1）和伯和/或仲二氨基化合物（E2）的混合物（E）; 其中所述混合物（E）的至少一种氨基化合物具有选自磺酸盐和羧酸盐的官能团; 其中混合物（E）的平均氨基官能度为1.65至1.95; 并且其中NCO预聚物中NCO基团与混合物（E）的异氰酸酯反应性基团的总量的当量比为1.04至1.9; 其制备方法及其在粘合剂复合材料的制备中的应用。
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5.发明授权Aqueous polyurethane-polyurethane urea dispersions, adhesives containing the same, processes for the preparation thereof and uses therefore 有权水性聚氨酯 - 聚氨酯脲分散体，含有它们的粘合剂，其制备方法和用途公开(公告)号：US08557387B2
公开(公告)日：2013-10-15
申请号：US12741865
申请日：2008-10-24
申请人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt
发明人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt
CPC分类号： C08G18/4238 , C08G18/0828 , C08G18/12 , C08G18/283 , C08G18/4202 , C08G18/664 , C08G18/722 , C08G2170/80 , C09J175/12 , Y10T428/31551 , Y10T428/31573 , Y10T428/31591 , C08G18/3271 , C08G18/3857
摘要： Aqueous polyurethane-polyurethane urea dispersions comprising a reaction product of: (i) an NCO prepolymer prepared from; (A) one or more di- or higher-functional polyols having a mean molecular weight of 400 to 5000 daltons, (B) optionally one or more di- or higher-functional polyol components having a molecular weight of from 62 to 399 daltons, and (C) one or more di- or poly-isocyanate components; and (ii) a mixture (D) of primary and/or secondary monoamino compounds (D1) and primary and/or secondary diamino compounds (D2); wherein at least one of the amino compounds of the mixture (D) has a functional group selected from sulfonates and carboxylates; wherein mixture (D) has a mean amino functionality of 1.65 to 1.95; and wherein the equivalent ratio of NCO groups in the NCO prepolymer to the total amount of isocyanate-reactive groups of the mixture (D) is 1.04 to 1.9; to processes for their preparation and to use thereof in the production of adhesive composites.
摘要翻译： 水性聚氨酯 - 聚氨酯脲分散体包含以下反应产物：（i）由下列物质制备的NCO预聚物： （A）一种或多种平均分子量为400至5000道尔顿的二官能或更高官能的多元醇，（B）任选的一种或多种分子量为62至399道尔顿的二官能或更高官能的多元醇组分， 和（C）一种或多种二异氰酸酯或多异氰酸酯组分; 和（ii）伯和/或仲单氨基化合物（D1）和伯和/或仲二氨基化合物（D2）的混合物（D）; 其中所述混合物（D）的至少一种氨基化合物具有选自磺酸盐和羧酸盐的官能团; 其中混合物（D）的平均氨基官能度为1.65至1.95; 并且其中NCO预聚物中NCO基团与混合物（D）的异氰酸酯反应性基团的总量的当量比为1.04至1.9; 其制备方法及其在粘合剂复合材料的制备中的应用。
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公开(公告)号：US08114931B2
公开(公告)日：2012-02-14
申请号：US10939803
申请日：2004-09-13
申请人： Wolfgang Arndt , Rüdiger Musch , Knut Panskus , Thorsten Rische , Ralf Werner , Wolfgang Henning
发明人： Wolfgang Arndt , Rüdiger Musch , Knut Panskus , Thorsten Rische , Ralf Werner , Wolfgang Henning
CPC分类号： C08G18/706 , C08G2170/80
摘要： An aqueous polymer dispersion that includes a) a polyurethane dispersion having an average particle size of 60 to 350 nm and b) an aqueous silicon dioxide dispersion having a particle diameter of the SiO2 particles of 20 to 400 nm. The dispersion is prepared by mixing the polyurethane dispersion (a) with the silicon dioxide dispersion (b). The aqueous polymer dispersion can be used in adhesive compositions, which can be used to bond substrates together, especially substrates that are structural components of shoes.
摘要翻译： 一种含水聚合物分散体，其包括a）平均粒径为60至350nm的聚氨酯分散体和b）具有20至400nm的SiO 2颗粒的粒径的二氧化硅水分散体。 通过将聚氨酯分散体（a）与二氧化硅分散体（b）混合来制备分散体。 聚合物水分散体可用于粘合剂组合物中，粘合剂组合物可用于将基材粘合在一起，特别是作为鞋结构部件的基材。
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7.发明申请AQUEOUS POLYURETHANE-POLYURETHANE UREA DISPERSIONS, ADHESIVES CONTAINING THE SAME, PROCESSES FOR THE PREPARATION THEREOF AND USES THEREFORE 有权水性聚氨酯 - 聚氨酯尿素分散剂，含有它们的粘合剂，其制备方法及其用途公开(公告)号：US20100266854A1
公开(公告)日：2010-10-21
申请号：US12741865
申请日：2008-10-24
申请人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt
发明人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt
CPC分类号： C08G18/4238 , C08G18/0828 , C08G18/12 , C08G18/283 , C08G18/4202 , C08G18/664 , C08G18/722 , C08G2170/80 , C09J175/12 , Y10T428/31551 , Y10T428/31573 , Y10T428/31591 , C08G18/3271 , C08G18/3857
摘要： Aqueous polyurethane-polyurethane urea dispersions comprising a reaction product of: (i) an NCO prepolymer prepared from; (A) one or more di- or higher-functional polyols having a mean molecular weight of 400 to 5000 daltons, (B) optionally one or more di- or higher-functional polyol components having a molecular weight of from 62 to 399 daltons, and (C) one or more di- or poly-isocyanate components; and (ii) a mixture (D) of primary and/or secondary monoamino compounds (D1) and primary and/or secondary diamino compounds (D2); wherein at least one of the amino compounds of the mixture (D) has a functional group selected from sulfonates and carboxylates; wherein mixture (D) has a mean amino functionality of 1.65 to 1.95; and wherein the equivalent ratio of NCO groups in the NCO prepolymer to the total amount of isocyanate-reactive groups of the mixture (D) is 1.04 to 1.9; to processes for their preparation and to use thereof in the production of adhesive composites.
摘要翻译： 水性聚氨酯 - 聚氨酯脲分散体包含以下反应产物：（i）由下列物质制备的NCO预聚物： （A）一种或多种平均分子量为400至5000道尔顿的二官能或更高官能的多元醇，（B）任选的一种或多种分子量为62至399道尔顿的二官能或更高官能的多元醇组分， 和（C）一种或多种二异氰酸酯或多异氰酸酯组分; 和（ii）伯和/或仲单氨基化合物（D1）和伯和/或仲二氨基化合物（D2）的混合物（D）; 其中所述混合物（D）的至少一种氨基化合物具有选自磺酸盐和羧酸盐的官能团; 其中混合物（D）的平均氨基官能度为1.65至1.95; 并且其中NCO预聚物中NCO基团与混合物（D）的异氰酸酯反应性基团的总量的当量比为1.04至1.9; 其制备方法及其在粘合剂复合材料的制备中的应用。
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8.发明申请AQUEOUS POLYURETHANE-POLYURETHANE UREA DISPERSIONS, ADHESIVES CONTAINING THE SAME, PROCESSES FOR THE PREPARATION THEREOF AND USES THEREFORE 有权水性聚氨酯 - 聚氨酯尿素分散剂，含有它们的粘合剂，其制备方法及其用途公开(公告)号：US20100266853A1
公开(公告)日：2010-10-21
申请号：US12741887
申请日：2008-10-24
申请人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt
发明人： Harald Kraus , Wolfgang Henning , Wolfgang Arndt
IPC分类号： B32B27/40 , C08L75/04 , C09J175/04
CPC分类号： C08G18/4238 , C08G18/0828 , C08G18/12 , C08G18/283 , C08G18/4202 , C08G18/664 , C08G18/722 , C08G2170/80 , C09J175/12 , Y10T428/31551 , Y10T428/31573 , Y10T428/31591 , C08G18/3271 , C08G18/3857
摘要： Aqueous polyurethane-polyurethane urea dispersions comprising a reaction product of: (i) an NCO prepolymer prepared from; (A) one or more di- or higher-functional polyols having a mean molecular weight of 400 to 5000 daltons, (B) optionally one or more di- or higher-functional polyol components having a molecular weight of from 62 to 399 daltons, (C) one or more compounds which are monofunctional within the scope of the isocyanate polyaddition reaction and have an ethylene oxide content of at least 50 wt. % and a molecular weight of at least 400 daltons, and (D) one or more di- or poly-isocyanate components; and (ii) a mixture (E) of primary and/or secondary monoamino compounds (E1) and primary and/or secondary diamino compounds (E2); wherein at least one of the amino compounds of the mixture (E) has a functional group selected from sulfonates and carboxylates; wherein mixture (E) has a mean amino functionality of 1.65 to 1.95; and wherein the equivalent ratio of NCO groups in the NCO prepolymer to the total amount of isocyanate-reactive groups of the mixture (E) is 1.04 to 1.9; to processes for their preparation and to use thereof in the production of adhesive composites.
摘要翻译： 水性聚氨酯 - 聚氨酯脲分散体包含以下反应产物：（i）由下列物质制备的NCO预聚物： （A）一种或多种平均分子量为400至5000道尔顿的二官能或更高官能的多元醇，（B）任选的一种或多种分子量为62至399道尔顿的二官能或更高官能的多元醇组分， （C）一种或多种在异氰酸酯加聚反应范围内是单官能的化合物，其环氧乙烷含量至少为50wt。 ％和分子量至少400道尔顿，和（D）一种或多种二异氰酸酯或多异氰酸酯组分; 和（ii）伯和/或仲单氨基化合物（E1）和伯和/或仲二氨基化合物（E2）的混合物（E）; 其中所述混合物（E）的至少一种氨基化合物具有选自磺酸盐和羧酸盐的官能团; 其中混合物（E）的平均氨基官能度为1.65至1.95; 并且其中NCO预聚物中NCO基团与混合物（E）的异氰酸酯反应性基团的总量的当量比为1.04至1.9; 其制备方法及其在粘合剂复合材料的制备中的应用。
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公开(公告)号：US20050256261A1
公开(公告)日：2005-11-17
申请号：US11122890
申请日：2005-05-05
IPC分类号： C08G18/08 , C08G18/28 , C08J5/12 , C08K3/20 , C08L75/02 , C08L75/04 , C09D5/02 , C09J175/02 , C09J175/04
CPC分类号： C09J175/04 , C08G18/0828 , C08G18/283
摘要： The present invention relates to new polyurethane and/or polyurethane-urea dispersions having ionic or potentially ionic or nonionic groups in the polymer backbone, to a process for preparing these dispersions and to their use as adhesives.
摘要翻译： 本发明涉及在聚合物主链中具有离子或潜在离子或非离子基团的新的聚氨酯和/或聚氨酯 - 脲分散体，制备这些分散体的方法和用作粘合剂。
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公开(公告)号：US20050131109A1
公开(公告)日：2005-06-16
申请号：US10939803
申请日：2004-09-13
申请人： Wolfgang Arndt , Rudiger Musch , Knut Panskus , Thorsten Rische , Ralf Werner , Wolfgang Henning
发明人： Wolfgang Arndt , Rudiger Musch , Knut Panskus , Thorsten Rische , Ralf Werner , Wolfgang Henning
CPC分类号： C08G18/706 , C08G2170/80
摘要： An aqueous polymer dispersion that includes a) a polyurethane dispersion having an average particle size of 60 to 350 nm and b) an aqueous silicon dioxide dispersion having a particle diameter of the SiO2 particles of 20 to 400 nm. The dispersion is prepared by mixing the polyurethane dispersion (a) with the silicon dioxide dispersion (b). The aqueous polymer dispersion can be used in adhesive compositions, which can be used to bond substrates together, especially substrates that are structural components of shoes.
摘要翻译： 一种含水聚合物分散体，其包括a）平均粒径为60至350nm的聚氨酯分散体和b）具有20-400nm的SiO 2颗粒的粒径的二氧化硅水分散体 。 通过将聚氨酯分散体（a）与二氧化硅分散体（b）混合来制备分散体。 聚合物水分散体可用于粘合剂组合物中，粘合剂组合物可用于将基材粘合在一起，特别是作为鞋结构部件的基材。
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