公开(公告)号：US20120237688A1

公开(公告)日：2012-09-20

申请号：US13513039

申请日：2010-12-01

申请人： Jozef Huybrechts ,  Leen Tanghe ,  Richard Milic

发明人： Jozef Huybrechts ,  Leen Tanghe ,  Richard Milic

IPC分类号： C09D175/04 ,  B05D3/02

CPC分类号： C08G18/6254 ,  C08G18/242 ,  C08G18/792 ,  C09D175/04

摘要： The invention is directed to coating compositions comprising A) at least one hydroxyl-functional and optionally acid-functional binder, preferably with an acid number of 0 to 150 mg KOH/g binder solids, B) at least one polyisocyanate curing agent with free isocyanate groups, C) at least one thermally latent tetrahydrocarbyl tin catalyst of general formula (I) RnR′4-nSn  (I) wherein R is an alkyl group, R′ is an aryl, arylalkyl or alkenyl group and n is 1, 2 or 3, and D) optionally at least one acid-functional compound, that is different from component A), with the proviso that the acid number of a composition, consisting of the at least one binder A) and optionally of the at least one acid-functional compound D), has an acid number of at least 5 mg KOH/g solids, preferably of least 10 mg KOH/g solids, and to a process for coating substrates comprising the steps: I) applying the coating composition to an optionally pre-coated substrate, and II) curing the applied coating composition by means of thermal energy.

摘要翻译： 本发明涉及涂料组合物，其包含A）至少一种羟基官能和任选酸官能的粘合剂，优选具有0至150mg KOH / g粘合剂固体的酸值，B）至少一种具有游离异氰酸酯的多异氰酸酯固化剂 基团，C）至少一种通式（I）RnR'4-nSn（I）的热潜在四烃基锡催化剂，其中R是烷基，R'是芳基，芳基烷基或烯基，n是1,2或 3和D）任选的至少一种酸官能化合物，其不同于组分A），条件是由至少一种粘合剂A）和任选的至少一种酸组成的组合物的酸值 官能化合物D）具有至少5mg KOH / g固体，优选至少10mg KOH / g固体的酸值，以及用于涂覆基材的方法，包括以下步骤：I）将涂料组合物施用到任选地 预涂底物，和II）固化涂覆组合物 通过热能。

公开(公告)号：US08822622B2

公开(公告)日：2014-09-02

申请号：US13513039

申请日：2010-12-01

申请人： Jozef Huybrechts ,  Leen Tanghe ,  Richard Milic

发明人： Jozef Huybrechts ,  Leen Tanghe ,  Richard Milic

IPC分类号： C09D175/04 ,  B05D3/02 ,  C08G18/79 ,  C08G18/62 ,  C08G18/24

CPC分类号： C08G18/6254 ,  C08G18/242 ,  C08G18/792 ,  C09D175/04

摘要： The invention is directed to coating compositions comprising A) at least one hydroxyl-functional and optionally acid-functional binder, preferably with an acid number of 0 to 150 mg KOH/g binder solids, B) at least one polyisocyanate curing agent with free isocyanate groups, C) at least one thermally latent tetrahydrocarbyl tin catalyst of general formula (I) RnR′4-nSn  (I) wherein R is an alkyl group, R′ is an aryl, arylalkyl or alkenyl group and n is 1, 2 or 3, and D) optionally at least one acid-functional compound, that is different from component A), with the proviso that the acid number of a composition, consisting of the at least one binder A) and optionally of the at least one acid-functional compound D), has an acid number of at least 5 mg KOH/g solids, preferably of least 10 mg KOH/g solids, and to a process for coating substrates comprising the steps: I) applying the coating composition to an optionally pre-coated substrate, and II) curing the applied coating composition by means of thermal energy.

摘要翻译： 本发明涉及涂料组合物，其包含A）至少一种羟基官能和任选酸官能的粘合剂，优选具有0至150mg KOH / g粘合剂固体的酸值，B）至少一种具有游离异氰酸酯的多异氰酸酯固化剂 基团，C）至少一种通式（I）RnR'4-nSn（I）的热潜在四烃基锡催化剂，其中R是烷基，R'是芳基，芳基烷基或烯基，n是1,2或 3和D）任选的至少一种酸官能化合物，其不同于组分A），条件是由至少一种粘合剂A）和任选的至少一种酸组成的组合物的酸值 官能化合物D）具有至少5mg KOH / g固体，优选至少10mg KOH / g固体的酸值，以及用于涂覆基材的方法，包括以下步骤：I）将涂料组合物施用到任选地 预涂底物，和II）固化涂覆组合物 通过热能。

公开(公告)号：US20070082992A1

公开(公告)日：2007-04-12

申请号：US11526467

申请日：2006-09-25

申请人： Jozef Huybrechts ,  Leen Tanghe

发明人： Jozef Huybrechts ,  Leen Tanghe

IPC分类号： C08K5/05 ,  B05D7/00 ,  B05D3/02

CPC分类号： C08G18/4887 ,  B05D7/14 ,  B05D7/57 ,  C08G18/722 ,  C09D171/02 ,  C09D175/04

摘要： The invention is directed to solvent-based coating compositions comprising a binder component and a crosslinking component, wherein the binder component comprises at least one hydroxy-functional polyether A) having at least two secondary hydroxyl groups per molecule, a number average molecular weight Mn in the range of 200 to 5,000 and a polydispersity of

摘要翻译： 本发明涉及包含粘合剂组分和交联组分的溶剂型涂料组合物，其中粘合剂组分包含至少一种每分子具有至少两个仲羟基的羟基官能聚醚A），数均分子量Mn 200〜5000的范围，多分散性<2，其中聚醚A）由具有至少三个羟基的至少一种多元醇Aa）和至少一种具有5个碳原子的支化单羧酸的单缩水甘油酯Ab 原子，并且其中所述交联组分包含至少一种交联剂B），其能够与所述羟基官能聚醚A）的羟基进行交联反应。 涂料组合物具有低含量的挥发性有机化合物，并且适用于汽车和工业涂料的透明涂层或着色面漆。

公开(公告)号：US20050222425A1

公开(公告)日：2005-10-06

申请号：US10960656

申请日：2004-10-07

申请人： Douglas Adelman ,  Neville Drysdale ,  Christian Lenges ,  Mark Scialdone ,  Leen Tanghe ,  Jozef Huybrechts ,  Laura Lewin ,  Robert Barsotti

发明人： Douglas Adelman ,  Neville Drysdale ,  Christian Lenges ,  Mark Scialdone ,  Leen Tanghe ,  Jozef Huybrechts ,  Laura Lewin ,  Robert Barsotti

IPC分类号： C07D491/04 ,  C07D498/04 ,  C08G18/12 ,  C08G18/20 ,  C08G18/38 ,  C08G18/75 ,  C08G18/76

CPC分类号： C07D498/04 ,  C08G18/12 ,  C08G18/755 ,  C08G18/765 ,  C08G18/3256

摘要： Described in this invention is a catalytic process for making amide acetals from nitrites and diethanolamines. Amide acetals can be further crosslinked by hydrolyzing the amide acetal groups, and subsequently reacting the hydroxyl groups and/or the amine functions that are formed, to crosslink the composition.

摘要翻译： 在本发明中描述的是从亚硝酸盐和二乙醇胺制备酰胺缩醛的催化方法。 酰胺缩醛可以通过水解酰胺缩醛基团进一步交联，随后使所形成的羟基和/或胺官能团反应以使组合物交联。

公开(公告)号：US07071286B2

公开(公告)日：2006-07-04

申请号：US10725889

申请日：2003-12-02

申请人： Robert J. Barsotti ,  Jos Huybrechts ,  Leen Tanghe

发明人： Robert J. Barsotti ,  Jos Huybrechts ,  Leen Tanghe

IPC分类号： C08G63/02

CPC分类号： C08G18/4244 ,  C08G18/3221 ,  C09D175/04 ,  Y10T428/31551

摘要： The invention is directed to coating compositions comprising: A) 20–80 wt-% of at least one orthoester compound having at least one non-cyclic orthoester group and at least one hydroxyl group per molecule, which compound is obtained by reacting a) at least one orthoester compound with b) at least one diol with a number average molecular weight (Mn) of 200–1000 g/mol, wherein solely diols are used having hydroxyl groups with different reactivity and having more than 3 carbon atoms between the hydroxyl groups, B) 0–40 wt-% of at least one hydroxy-functional binder and/or hydroxy-functional reactive diluent, different from component A) and C) 80–20 wt-% of at least one cross-linking agent with functional groups reactive with hydroxyl groups.

摘要翻译： 本发明涉及涂料组合物，其包含：A）20-80重量％的至少一种每分子具有至少一个非环状原酸酯基和至少一个羟基的原酸酯化合物，该化合物通过使a）在 至少一种原酸酯化合物，其中b）至少一种数均分子量（Mn）为200-1000g / mol的二醇，其中仅使用具有不同反应性的羟基并且在羟基之间具有多于3个碳原子的二醇 ，B）0-40重量％的至少一种羟基官能的粘合剂和/或羟基官能的反应性稀释剂，不同于组分A）和C）80-20重量％的至少一种具有官能团的交联剂 基团与羟基反应。

公开(公告)号：US07230112B2

公开(公告)日：2007-06-12

申请号：US10960656

申请日：2004-10-07

申请人： Douglas J. Adelman ,  Neville Everton Drysdale ,  Christian Peter Lenges ,  Mark A. Scialdone ,  Leen Tanghe ,  Jozef Theresia Huybrechts ,  Laura Ann Lewin ,  Robert John Barsotti

发明人： Douglas J. Adelman ,  Neville Everton Drysdale ,  Christian Peter Lenges ,  Mark A. Scialdone ,  Leen Tanghe ,  Jozef Theresia Huybrechts ,  Laura Ann Lewin ,  Robert John Barsotti

IPC分类号： C07D498/02

CPC分类号： C07D498/04 ,  C08G18/12 ,  C08G18/755 ,  C08G18/765 ,  C08G18/3256

摘要： Described in this invention is a catalytic process for making amide acetals from nitrites and diethanolamines. Amide acetals can be further crosslinked by hydrolyzing the amide acetal groups, and subsequently reacting the hydroxyl groups and/or the amine functions that are formed, to crosslink the composition.

摘要翻译： 在本发明中描述的是从亚硝酸盐和二乙醇胺制备酰胺缩醛的催化方法。 酰胺缩醛可以通过水解酰胺缩醛基团进一步交联，随后使所形成的羟基和/或胺官能团反应以使组合物交联。

公开(公告)号：US06902820B2

公开(公告)日：2005-06-07

申请号：US10671217

申请日：2003-09-25

申请人： Jos Huybrechts ,  Ann Vaes ,  Lieve Bastin ,  Leen Tanghe

发明人： Jos Huybrechts ,  Ann Vaes ,  Lieve Bastin ,  Leen Tanghe

IPC分类号： C08G18/40 ,  C08G18/42 ,  C08G18/79 ,  C08L33/08 ,  C08L33/10 ,  C08L33/12 ,  C08L61/28 ,  C09D167/00 ,  C09D167/04 ,  C09D175/06 ,  B32B27/36 ,  C08F20/00

CPC分类号： C09D175/06 ,  C08G18/4063 ,  C08G18/4283 ,  C08G18/4291 ,  C08G18/792 ,  C08L33/08 ,  C08L33/10 ,  C08L33/12 ,  C08L61/28 ,  C09D167/00 ,  C09D167/04 ,  Y10T428/31794 ,  C08L2666/14 ,  C08L2666/16 ,  C08L2666/02

摘要： Coating compositions comprising: A) least one hydroxy-functional polyester with at least two hydroxyl groups per molecule, wherein at least one of which hydroxyl groups is a tertiary hydroxyl group, and the polyester has a number average molecular weight Mw of 200 to 5000, and contains as a structural element 10-90 wt-%, relative to the total quantity of polyester, of at least one acid ester group comprising a tertiary hydroxyl group and of the following general formula I  wherein R1 is a single bond or a C1-C6 alkyl group, R2 and R3 mutually independently mean a C1-C4 alkyl group, B) optionally, at least one additional hydroxy-functional binder other than A) and C) at least one cross-linking agent which is capable of entering into a cross-linking reaction with the OH-groups of components A) and B.

摘要翻译： 涂料组合物，其包含：A）每分子具有至少两个羟基的至少一个羟基官能聚酯，其中至少一个羟基是叔羟基，所述聚酯的数均分子量Mw为200-5000， 并且包含相对于聚酯的总量为10-90重量％的至少一个包含叔羟基的酸酯基团和以下通式I的结构元素，其中R 1是 是单键或C1-C6烷基，R 2和R 3相互独立地表示C 1 -C 4烷基，B）任选地至少一种另外的羟基 除了A）和C）之外的官能性粘合剂，和C）至少一种能够与组分A）和B的OH-基团进行交联反应的交联剂。

公开(公告)号：US20050119443A1

公开(公告)日：2005-06-02

申请号：US10725889

申请日：2003-12-02

申请人： Robert Barsotti ,  Jos Huybrechts ,  Leen Tanghe

发明人： Robert Barsotti ,  Jos Huybrechts ,  Leen Tanghe

IPC分类号： C07C43/32 ,  C08G18/32 ,  C08G18/42 ,  C09D175/04 ,  C08G63/00

CPC分类号： C08G18/4244 ,  C08G18/3221 ,  C09D175/04 ,  Y10T428/31551

摘要： The invention is directed to coating compositions comprising: A) 20-80 wt-% of at least one orthoester compound having at least one non-cyclic orthoester group and at least one hydroxyl group per molecule, which compound is obtained by reacting a) at least one orthoester compound with b) at least one diol with a number average molecular weight (Mn) of 200-1000 g/mol, wherein solely diols are used having hydroxyl groups with different reactivity and having more than 3 carbon atoms between the hydroxyl groups, B) 0-40 wt-% of at least one hydroxy-functional binder and/or hydroxy-functional reactive diluent, different from component A) and C) 80-20 wt-% of at least one cross-linking agent with functional groups reactive with hydroxyl groups.

摘要翻译： 本发明涉及涂料组合物，其包含：A）20-80重量％的至少一种每分子具有至少一个非环状原酸酯基和至少一个羟基的原酸酯化合物，该化合物通过使a）在 至少一种原酸酯化合物，其中b）至少一种数均分子量（Mn）为200-1000g / mol的二醇，其中仅使用二醇，其羟基具有不同的反应性并且在羟基之间具有多于3个碳原子 ，B）0-40重量％的至少一种羟基官能的粘合剂和/或羟基官能的反应性稀释剂，不同于组分A）和C）80-20重量％的至少一种具有官能团的交联剂 基团与羟基反应。

公开(公告)号：US08197905B2

公开(公告)日：2012-06-12

申请号：US11526467

申请日：2006-09-25

申请人： Jozef Theresia Huybrechts ,  Leen Tanghe

发明人： Jozef Theresia Huybrechts ,  Leen Tanghe

IPC分类号： B05D1/36 ,  B05D3/00 ,  B05D7/16

CPC分类号： C08G18/4887 ,  B05D7/14 ,  B05D7/57 ,  C08G18/722 ,  C09D171/02 ,  C09D175/04

摘要： The present invention is directed to a process of applying a solvent-based coating composition on a substrate to produce a multi-layer coating thereon. The binder component of the composition includes at least one hydroxy-functional polyether obtained from at least one polyol having at least three hydroxyl groups and at least one monoglycidyl ester of a branched monocarboxylic acid. The crosslinking component of the composition includes at least one cross-linking agent that is capable of entering into a cross-linking reaction with the hydroxyl groups of- the hydroxy-functional polyether. The process further includes curing the multi-layer coating. The process is well suited for producing clear coats and pigmented topcoats in automotive refinishing.

摘要翻译： 本发明涉及在基材上涂布溶剂基涂料组合物以在其上产生多层涂层的方法。 组合物的粘合剂组分包括至少一种由至少一种具有至少三个羟基的多元醇和至少一种支化单羧酸单缩水甘油酯获得的羟基官能聚醚。 组合物的交联组分包括至少一种能够与羟基官能聚醚的羟基进行交联反应的交联剂。 该方法还包括固化多层涂层。 该工艺非常适合在汽车修补中生产透明涂层和着色面漆。