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    Process for co-production and separation of ethylbenzene and paraxylene
    2.
    发明授权
    Process for co-production and separation of ethylbenzene and paraxylene 有权
    共同生产和分离乙苯和对二甲苯的方法

    公开(公告)号：US06369287B1

    公开(公告)日：2002-04-09

    申请号：US09597468

    申请日：2000-06-19

    申请人： Julia Magne-Drisch ,  Gérard Hotier ,  Fabio Alario ,  Alain Methivier

    发明人： Julia Magne-Drisch ,  Gérard Hotier ,  Fabio Alario ,  Alain Methivier

    IPC分类号： C07C700

    CPC分类号： C07C15/08 ,  C07C5/2754 ,  C07C15/073 ,  C07C2523/42 ,  C07C2529/74

    摘要： A process for co-production of paraxylene and ethylbenzene comprises: (A) an adsorption stage of a feedstock of xylenes and ethylbenzene in a simulated moving bed that produces an extract of pure paraxylene and an ethylbenzene-rich raffinate; (B) an adsorption stage in a simulated moving bed, of raffinate from which desorbent has been removed that supplies an essentially pure ethylbenzene extract and an orthoxylene and metaxylene raffinate that contains desorbent; (C) a recover stage for the desorbent; (D) an isomerization stage for the orthoxylene and metaxylene raffinate in the presence of a catalyst that comprises an EUO-type zeolite; and (E) a stage for recycling the isomerate that is produced with adsorption.

    摘要翻译： 共同生产对二甲苯和乙苯的方法包括：（A）在模拟移动床中的二甲苯和乙苯的原料的吸附阶段，其产生纯对二甲苯和富含乙苯的萃余液的提取物; （B）在模拟移动床中的萃余液中的吸附阶段，其中已经从其中除去了解吸剂，提供基本上纯的乙苯提取物和含有解吸附剂的邻二甲苯和间二甲苯萃余液; （C）解吸剂的回收阶段; （D）在包含EUO型沸石的催化剂存在下，邻二甲苯和间二甲苯残液的异构化阶段; 和（E）用于回收利用吸附产生的异构体的阶段。

    Process for co-production and separation of ethylbenzene and paraxylene
    3.
    发明授权
    Process for co-production and separation of ethylbenzene and paraxylene 有权
    共同生产和分离乙苯和对二甲苯的方法

    公开(公告)号：US06177604B1

    公开(公告)日：2001-01-23

    申请号：US09219392

    申请日：1998-12-23

    申请人： Gerard Hotier ,  Fabio Alario ,  Alain Methivier

    发明人： Gerard Hotier ,  Fabio Alario ,  Alain Methivier

    IPC分类号： C07C712

    CPC分类号： C07C15/08 ,  B01D15/185 ,  B01D2215/023 ,  C07C5/2708 ,  C07C5/2737 ,  C07C7/13 ,  C07C15/073 ,  C07C2529/40 ,  C07C15/067

    摘要： Paraxylene and ethylbenzene are produced from an aromatic hydrocarbon feedstock by using adsorption zones in a simulated fluid bed. The feedstock is first passed into a first adsorption zone to produce a first paraxylene-rich fraction and a second ethylbenzene-rich fraction. The second fraction is then passed into a second adsorption zone to produce a third fraction containing essentially pure ethylbenzene and a fourth fraction containing a majority of orthoxylene and metaxylene. The fourth stream is then passed into an isomerization zone to produce an isomerate which is then recycled back to the first adsorption zone.

    摘要翻译： 对二甲苯和乙苯由芳烃原料通过在模拟流化床中使用吸附区产生。 原料首先进入第一吸附区以产生富含第二对二甲苯馏分和第二富含乙苯的级分。 然后将第二级分进入第二吸附区以产生含有基本上纯的乙苯的第三级分和含有大部分邻二甲苯和间二甲苯的第四级分。 然后将第四个物流进入异构化区以产生异构体，然后将其再循环回第一吸附区。

    Process for co-production of paraxylene, metaxylene and/or orthoxylene
    4.
    发明授权
    Process for co-production of paraxylene, metaxylene and/or orthoxylene 有权
    共生产对二甲苯，间二甲苯和/或邻二甲苯的方法

    公开(公告)号：US06841714B2

    公开(公告)日：2005-01-11

    申请号：US10247830

    申请日：2002-09-20

    申请人： Philibert Leflaive ,  Luc Wolff ,  Gérard Hotier ,  Alain Methivier

    发明人： Philibert Leflaive ,  Luc Wolff ,  Gérard Hotier ,  Alain Methivier

    IPC分类号： C07C7/00 ,  C07C7/13 ,  C07C15/08 ,  C07C7/12

    CPC分类号： C07C15/08 ,  C07C7/005 ,  C07C7/13

    摘要： A process for co-production of paraxylene, metaxylene and/or orthoxylene from a hydrocarbon feedstock (1) that comprises [1] a separation stage of the feedstock in a simulated moving bed in a chromatographic column (9) that contains a number of beds of an adsorbent, interconnected in a loop, is described, whereby said column comprises an injection (3) of the feedstock, a draw-off (10) of an extract that consists of paraxylene and desorbent, an intermediate fraction (11) (extract or raffinate) that contains ethylbenzene, and a raffinate (12) that contains a mixture of metaxylene and orthoxylene that is virtually free of ethylbenzene and paraxylene and [2] a crystallization stage (27) of the metaxylene and/or orthoxylene fraction. Upstream from the adsorption zone and/or upstream from the crystallization zone, it is possible to distill the entering mixture to produce an orthoxylene-enriched fraction at the bottom and a metaxylene-enriched fraction at the top.

    摘要翻译： 一种从烃原料（1）共同生产对二甲苯，间二甲苯和/或邻二甲苯的方法，其包括[1]在色谱柱（9）中的模拟移动床中的原料的分离阶段，其包含多个床 描述了以循环相互连接的吸附剂，其中所述柱包括原料的注入物（3），由对二甲苯和解吸剂组成的萃取物的萃取物（10），中间馏分（11） 或萃余液）和含有实际上不含乙苯和对二甲苯的间二甲苯和邻二甲苯混合物的萃余液（12），[2]间二甲苯和/或邻二甲苯馏分的结晶阶段（27）。 从吸附区上游和/或结晶区上游，可以蒸馏进入的混合物，在底部产生富含邻二甲苯的馏分，并在顶部产生富含甲炔的馏分。

    Process for co-producing para-xylene and metaxylene, comprising two separation steps
    5.
    发明授权
    Process for co-producing para-xylene and metaxylene, comprising two separation steps 有权
    共同生产对二甲苯和间二甲苯的方法，包括两个分离步骤

    公开(公告)号：US06838588B2

    公开(公告)日：2005-01-04

    申请号：US10108392

    申请日：2002-03-29

    申请人： Philibert Leflaive ,  Alain Methivier ,  Gérard Hotier

    发明人： Philibert Leflaive ,  Alain Methivier ,  Gérard Hotier

    IPC分类号： C07C7/04 ,  C07C7/00 ,  C07C7/12 ,  C07C7/13 ,  C07C15/08

    CPC分类号： C07C7/005 ,  C07C7/13 ,  C07C15/08

    摘要： A process is described for co-producing metaxylene and paraxylene from a hydrocarbon feed comprising two separation steps. The first step of the process is a counter-current simulated moving bed system in a chromatographic column containing at least five zones, comprising injecting the feed and injecting a desorbent and delivering an extract, a raffinate and an intermediate raffinate either continuously or discontinuously. The extract is distilled to obtain a paraxylene with a purity of at least 99.7%. The raffinate, which is richer in metaxylene, is distilled to extract the desorbent and injected into a counter-current simulated moving bed continuously delivering an extract and a raffinate. One of these two streams is enriched in metaxylene. The most metaxylene-rich stream is distilled to obtain metaxylene with a purity of more than 99%.

    摘要翻译： 描述了从包含两个分离步骤的烃进料共同生产间二甲苯和对二甲苯的方法。 该方法的第一步是在含有至少五个区域的色谱柱中的逆流模拟移动床系统，包括注射进料并注入解吸剂并连续地或不连续地递送提取物，萃余液和中间萃余液。 蒸馏提取物，得到纯度至少为99.7％的对二甲苯。 富含中间二甲苯的萃余液被蒸馏以提取解吸剂并注入到逆流模拟移动床中，连续输送提取物和萃余液。 这两条河中的一条富含间二甲苯。 蒸馏出最富含中间二甲烷的料流，得到纯度大于99％的间二甲苯。

    Coproduction process for para-xylene and ortho-xylene comprising two separation steps
    6.
    发明授权
    Coproduction process for para-xylene and ortho-xylene comprising two separation steps 失效
    对二甲苯和邻二甲苯的共同生产方法包括两个分离步骤

    公开(公告)号：US06828470B2

    公开(公告)日：2004-12-07

    申请号：US10321724

    申请日：2002-12-18

    申请人： Philibert Leflaive ,  Luc Wolff ,  Alain Methivier ,  Gérard Hotier

    发明人： Philibert Leflaive ,  Luc Wolff ,  Alain Methivier ,  Gérard Hotier

    IPC分类号： C07C712

    CPC分类号： C07C7/005 ,  C07C7/13 ,  C07C15/08

    摘要： A coproduction process for ortho-xylene and para-xylene starting with a batch of hydrocarbons comprises a simulated counter-current fluidized bed system in a chromatographic column (6) containing at least five zones, comprising injection (1) of the batch and injection (2) of desorption agent and delivering an extract (3), a refined product (5), and an intermediate refined product (4). Refined product (5), richer in ortho-xylene than the intermediate refined product, is distilled (9) to extract desorption agent (15) and is injection, according to the second step of the process, into a simulated counter-current fluidized bed system (17) delivering an extract (18) and a refined product (19) continuously.

    摘要翻译： 从一批烃开始的邻二甲苯和对二甲苯的共生产方法包括在色谱柱（6）中的模拟逆流流化床系统，其包含至少五个区域，包括批料和注射（1）的注射（1） 2）的解吸剂和递送提取物（3），精制产物（5）和中间精制产物（4）。 精制产品（5），比中间精制产物富含邻二甲苯，蒸馏（9）提取脱附剂（15），并根据该方法的第二步将注射成模拟逆流流化床 系统（17）连续递送提取物（18）和精制产品（19）。

    Process for improving gasoline cuts and conversion into gas oils
    8.
    发明授权
    Process for improving gasoline cuts and conversion into gas oils 失效
    改善汽油馏分和转化为瓦斯油的工艺

    公开(公告)号：US07847141B2

    公开(公告)日：2010-12-07

    申请号：US11144739

    申请日：2005-06-06

    申请人： Patrick Briot ,  Arnaud Baudot ,  Vincent Coupard ,  Alain Methivier

    发明人： Patrick Briot ,  Arnaud Baudot ,  Vincent Coupard ,  Alain Methivier

    IPC分类号： C07C2/00

    CPC分类号： C10G50/00 ,  C10G31/10

    摘要： The invention relates to a process for converting a hydrocarbon charge of linear and branched olefins, comprises the following stages: a) a stage of membrane separation of the hydrocarbon charge under conditions making it possible to produce a cut β containing the majority of the linear olefins present in said charge, and a cut γ containing the majority of the branched olefins, b) a stage of treatment of the linear olefins contained in the effluents originating from the membrane separation stage (cut β) under moderate oligomerization conditions, c) a stage of distillation separation of the effluents originating from the oligomerization stage into at least two cuts, d) a stage of hydrogenation of the cut η under conditions for obtaining a gas oil with a high cetane number.

    摘要翻译： 本发明涉及一种用于转化直链和支链烯烃的烃装料的方法，包括以下阶段：a）在使得能够产生切割的条件下进行烃装料的膜分离阶段; 含有大部分存在于所述电荷中的直链烯烃，和含有大部分支链烯烃的切割γ，b）处理源自膜分离阶段（切割）的流出物中的直链烯烃的处理阶段 中等低聚条件，c）将源自低聚阶段的流出物蒸馏分离成至少两个馏分的阶段，d）切割的氢化阶段; 在获得具有高十六烷值的瓦斯油的条件下。

    Process for improving gasoline fractions and gasoil conversion with additional treatment to increase the gasoil fraction yield
    9.
    发明申请
    Process for improving gasoline fractions and gasoil conversion with additional treatment to increase the gasoil fraction yield 有权
    用于通过额外处理来提高汽油馏分和油烟转化率的方法以增加汽油馏分产率

    公开(公告)号：US20060009670A1

    公开(公告)日：2006-01-12

    申请号：US11144740

    申请日：2005-06-06

    申请人： Patrick Briot ,  Arnaud Baudot ,  Vincent Coupard ,  Stephane Morin ,  Alain Methivier

    发明人： Patrick Briot ,  Arnaud Baudot ,  Vincent Coupard ,  Stephane Morin ,  Alain Methivier

    IPC分类号： C07C2/02

    CPC分类号： C10G50/00 ,  C10G31/10 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/305 ,  C10G2300/307 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04

    摘要： The invention relates to a process for conversion of a gasoline-range hydrocarbon feed into a gasoline fraction with a higher octane rating than that of the feedstream, and a gasoil fraction with a cetane number higher than 45, including the following steps: a) a membrane separation step (B) applied to the hydrocarbon feed under conditions enabling selective separation of the majority of the linear olefins present in said feed and constituting the β fraction, the fraction containing the majority of the branched olefins, termed the γ fraction, constituting a gasoline with a high octane rating, greater than that of the feed, b) an oligomerisation step (C) applied to the linear olefins (β fraction) contained in the effluent stream from the membrane separation step (B) under moderate oligomerisation conditions, c) a distillation separation step (D) applied to the effluent stream arising from the oligomerisation step in at least two fractions, d) a hydrogenation step (E) applied to one of the fractions obtained at step c).

    摘要翻译： 本发明涉及一种将汽油范围烃进料转化为辛烷值高于进料流的汽油馏分和十六烷值高于45的汽油馏分的方法，包括以下步骤：a） 膜分离步骤（B），其在能够选择性分离所述进料中存在的大部分直链烯烃并构成β馏分的条件下应用于烃进料，所述馏分含有大部分称为γ馏分的支链烯烃，构成 具有高辛烷值的汽油，大于进料的汽油，b）在中等低聚条件下将来自膜分离步骤（B）的流出物流中所含的线性烯烃（β馏分）应用到低聚步骤（C），c ）蒸馏分离步骤（D），其应用于由低聚步骤在至少两个馏分中产生的流出物流; d）施加氢化步骤（E）t o步骤c）获得的级分之一。