Chromene compound
    2.
    发明授权
    Chromene compound 有权
    色烯化合物

    公开(公告)号:US06719926B2

    公开(公告)日:2004-04-13

    申请号:US10069168

    申请日:2002-02-19

    IPC分类号: G03C1675

    摘要: A chromene compound which develops yellow to red color, a high color density and a little initial color and which, when used in combination with an existing photochromic compound that exhibits blue color so as to develop a neutral tint, maintains uniformity in the color tone at the time of developing color or fading color, or exhibits a very large color fading rate. The chromene compound has a naphthopyran cyclic skeleton, and is expressed by, for example, the following formula in which a substituent such as substituted amino group or morpholino group is bonded to the sixth position of the naphthopyran ring through a nitrogen atom, and two aryl groups having a particular substituent are bonded to the third position thereof,

    摘要翻译: 发色为黄色至红色,色度高,初始颜色较浅的色烯化合物,当与现有的显色性蓝色发生中性色调的光致变色化合物结合使用时,可以保持色调均匀性 显色或褪色的时间,或表现出非常大的褪色速度。 色烯化合物具有萘并吡喃环状骨架,并且通过例如通过氮原子与萘并吡喃环的第六位相连的取代氨基或吗啉代基等取代基如下式表示, 具有特定取代基的基团键合到其第三位置,

    Chromene compound
    3.
    发明授权
    Chromene compound 有权
    色烯化合物

    公开(公告)号:US06525194B1

    公开(公告)日:2003-02-25

    申请号:US10153911

    申请日:2002-05-24

    IPC分类号: C07D3792

    摘要: A chromene compound which develops yellow to red color, a high color density and a little initial color and which, when used in combination with an existing photochromic compound that exhibits blue color so as to develop a neutral tint, maintains uniformity in the color tone at the time of developing color or fading color, or exhibits a very large color fading rate. The chromene compound has a naphthopyran cyclic skeleton, and is expressed by, for example, the following formula in which a substituent such as substituted amino group or morpholino group is bonded to the sixth position of the naphthopyran ring through a nitrogen atom, and two aryl groups having a particular substituent are bonded to the third position thereof,

    摘要翻译: 发色为黄色至红色,色度高,初始颜色较浅的色烯化合物,当与现有的显色性蓝色发生中性色调的光致变色化合物结合使用时,可以保持色调均匀性 显色或褪色的时间,或表现出非常大的褪色速度。 色烯化合物具有萘并吡喃环状骨架,并且通过例如通过氮原子与萘并吡喃环的第六位相连的取代氨基或吗啉代基等取代基如下式表示, 具有特定取代基的基团键合到其第三位置,

    Curable composition comprising a photochromic compound
    5.
    发明授权
    Curable composition comprising a photochromic compound 有权
    包含光致变色化合物的可固化组合物

    公开(公告)号:US06802993B2

    公开(公告)日:2004-10-12

    申请号:US10148319

    申请日:2002-05-29

    IPC分类号: G02B523

    摘要: A photochromic cured product which has excellent photochromism such as high color density and high fading speed, excellent adhesion to a hard coat and high striping work efficiency. This cured product is obtained by polymerizing and curing a curable composition which comprises (A) a polyfunctional polymerizable monomer such as trimethylolpropane trimethacrylate, (B) a silyl monomer such as &ggr;-methacryloyloxypropyl trimethoxysilane, (C) another radically polymerizable monomer and (D) a photochromic compound. As for the contents of the polymerizable monomers, the content of the component (A) is 1 to 50 wt %, the content of the component (B) is 0.5 to 20 wt % and the balance consists of the component (C) based on the total of the components (A), (B) and (C). The photochromic compound (D) is contained in an amount of 0.0001 to 10 parts by weight based on 100 parts by weight of the total of the components (A), (B) and (C).

    摘要翻译: 具有高色密度和高褪色速度的优异光致变色的光致变色固化产物,对硬涂层的优异粘附性和高剥离效率。 该固化产物通过聚合和固化包含(A)多官能可聚合单体如三羟甲基丙烷三甲基丙烯酸酯,(B)甲硅烷基单体如γ-甲基丙烯酰氧基丙基三甲氧基硅烷,(C)另一种可自由基聚合的单体和(D) 光致变色化合物。 对于可聚合单体的含量,组分(A)的含量为1至50重量%,组分(B)的含量为0.5至20重量%,余量基于组分(C)基于 组分(A),(B)和(C)的总和。 基于100重量份的组分(A),(B)和(C)的总量,光致变色化合物(D)的含量为0.0001至10重量份。

    Polymerization curable composition
    6.
    发明授权
    Polymerization curable composition 有权
    聚合固化性组合物

    公开(公告)号:US08691926B2

    公开(公告)日:2014-04-08

    申请号:US11667317

    申请日:2005-11-08

    CPC分类号: C08F222/1006 G02B1/041

    摘要: A polymerization curable composition prepared by blending specific amounts of a photochromic compound and a specific light stabilizer such as bis(1,2,2,6,6-pentamethyl-4-piperidyl)sebacate with monomer components including a specific bifunctional monomer having a structure that two phenylene groups are bonded together by a specific group, such as 2,2-bis(4-methacryloyloxypolyethoxyphenyl)propane, a polyfunctional polymerizable monomer having a functionality of 3 or more such as trimethylolpropane trimethacrylate, and a monomer other than these in a specific ratio.The polymerization curable composition provides a cured product having excellent photochromic properties such as fast fading rate and sufficiently high drilling strength that allows for its use in rimless spectacles and has high long-term storage stability.

    摘要翻译: 通过将特定量的光致变色化合物和特定光稳定剂如双(1,2,2,6,6-五甲基-4-哌啶基)癸二酸酯与单体组分共混而制备的聚合可固化组合物,所述单体组分包括具有结构的特定双官能单体 两个亚苯基通过特殊基团结合在一起,例如2,2-双(4-甲基丙烯酰氧基聚乙氧基苯基)丙烷,官能度为3以上的多官能团聚合性单体,例如三羟甲基丙烷三甲基丙烯酸酯,以及除 具体比例。 聚合可固化组合物提供了具有优异的光致变色特性的固化产物,例如快速褪色速率和足够高的钻孔强度,其允许其在无框眼镜中使用并且具有高的长期储存稳定性。

    Photochromic curable composition
    7.
    发明授权
    Photochromic curable composition 有权
    光致变色固化组合物

    公开(公告)号:US08663508B2

    公开(公告)日:2014-03-04

    申请号:US13638101

    申请日:2011-03-28

    摘要: A photochromic curable composition comprising 100 parts by mass of polymerizable monomers which include 70 to 100 mass % of polymerizable monomers having two to four (meth)acrylic groups and 0 to 30 mass % of a polymerizable monomer having one (meth)acrylic group and 0.01 to 20 parts by mass of a photochromic compound, wherein the number of moles of the methacrylic group existent in the polymerizable monomer composition is 3 to 7 times the number of moles of the acrylic group. This composition can provide a lens having a photochromic coating which exhibits excellent photochromic properties, comprises a hard coat layer having sufficiently high adhesion and scratch resistance and has no delay in fading and has excellent storage stability.

    摘要翻译: 一种光致变色固化性组合物,其包含100质量份的可聚合单体,其包含70至100质量%的具有2-4个(甲基)丙烯酸基团的可聚合单体和0至30质量%的具有一个(甲基)丙烯酸基团的可聚合单体和0.01 至20质量份的光致变色化合物,其中存在于可聚合单体组合物中的甲基丙烯酸基团的摩尔数为丙烯酸类的摩尔数的3至7倍。 该组合物可以提供具有优异的光致变色特性的光致变色涂层的透镜,包括具有足够高的粘附性和耐划伤性的硬涂层,并且没有褪色的延迟并且具有优异的储存稳定性。

    CHROMENE COMPOUND
    8.
    发明申请
    CHROMENE COMPOUND 有权
    铬化合物

    公开(公告)号:US20140034884A1

    公开(公告)日:2014-02-06

    申请号:US13982132

    申请日:2012-01-26

    IPC分类号: G02B1/04

    摘要: A chromene compound which develops a color of a neutral tint and has little initial coloration, high double peak characteristic and high color development sensitivity, rarely experiences the reduction of color optical density though it has high fading speed, is excellent in the durability of photochromic properties and can dissolve in a monomer composition which will become a substrate for optical articles in a high concentration, and a photochromic curable composition comprising the chromene compound and polymerizable monomers.The chromene compound is represented by the following formula (1). (wherein R3 at the 11-position is a second sulfur-containing substituent selected from the group consisting of thiol group, alkylthio group, alkoxyalkylthio group, haloalkylthio group, cycloalkylthio group, arylthio group, heteroarylthio group, sulfonyl group and sulfinyl group, R1 and R2 at the 6-position and the 7-position are a combination of an aryl group or a heteroaryl group and an electron donating group having a Hammett constant σp of −0.1 or less, or R1 and/or R2 is a first sulfur-containing substituent selected from thiol group, alkylthio group, alkoxyalkylthio group, haloalkylthio group, cycloalkylthio group, arylthio group and heteroarylthio group.).

    摘要翻译: 产生中性色调的色素并且初始着色少,双峰特征高,显色灵敏度高的色烯化合物虽然具有高的褪色速度,但很少经历着色光密度的降低,光致变色性能的耐久性优异 并且可以溶解在将成为高浓度的光学制品的基材的单体组合物中,以及包含色烯化合物和可聚合单体的光致变色固化组合物。 色烯化合物由下式(1)表示。 (其中,11位的R 3为选自硫醇基,烷硫基,烷氧基烷硫基,卤代烷硫基,环烷硫基,芳硫基,杂芳硫基,磺酰基和亚磺酰基的第二含硫取代基,R 1和 6-位和7-位的R2是芳基或杂芳基的组合和具有-0.5以下的哈米特常数sigmap的给电子基团,或者R 1和/或R 2是第一含硫的 选自硫醇基,烷硫基,烷氧基烷硫基,卤代烷硫基,环烷硫基,芳硫基和杂芳基硫基的取代基)。

    PHOTOCHROMIC CURABLE COMPOSITION
    9.
    发明申请
    PHOTOCHROMIC CURABLE COMPOSITION 有权
    光敏可固化组合物

    公开(公告)号:US20130015416A1

    公开(公告)日:2013-01-17

    申请号:US13638101

    申请日:2011-03-28

    IPC分类号: G02B5/23

    摘要: A photochromic curable composition comprising 100 parts by mass of polymerizable monomers which include 70 to 100 mass % of polymerizable monomers having two to four (meth)acrylic groups and 0 to 30 mass % of a polymerizable monomer having one (meth)acrylic group and 0.01 to 20 parts by mass of a photochromic compound, wherein the number of moles of the methacrylic group existent in the polymerizable monomer composition is 3 to 7 times the number of moles of the acrylic group. This composition can provide a lens having a photochromic coating which exhibits excellent photochromic properties, comprises a hard coat layer having sufficiently high adhesion and scratch resistance and has no delay in fading and has excellent storage stability.

    摘要翻译: 一种光致变色固化性组合物,其包含100质量份的可聚合单体,其包含70至100质量%的具有2-4个(甲基)丙烯酸基团的可聚合单体和0至30质量%的具有一个(甲基)丙烯酸基团的可聚合单体和0.01 至20质量份的光致变色化合物,其中存在于可聚合单体组合物中的甲基丙烯酸基团的摩尔数为丙烯酸类的摩尔数的3至7倍。 该组合物可以提供具有优异的光致变色特性的光致变色涂层的透镜,包括具有足够高的粘附性和耐划伤性的硬涂层,并且没有褪色的延迟并且具有优异的储存稳定性。