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    Process for producing carbamoyloxy (meth) acrylates and new carbamoyloxy (meth) acrylates
    1.
    发明申请
    Process for producing carbamoyloxy (meth) acrylates and new carbamoyloxy (meth) acrylates 审中-公开
    氨基甲酰氧基（甲基）丙烯酸酯和新的氨基甲酰氧基（甲基）丙烯酸酯的制备方法

    公开(公告)号：US20080167489A1

    公开(公告)日：2008-07-10

    申请号：US11987986

    申请日：2007-12-06

    申请人： Vincent Stone ,  Jurgen Van Holen ,  Hugues Van Den Bergen

    发明人： Vincent Stone ,  Jurgen Van Holen ,  Hugues Van Den Bergen

    IPC分类号： C07C271/10

    CPC分类号： C07C269/06 ,  C07C271/16

    摘要： The invention relates to a process for producing carbamoyloxy(meth)acrylates which comprises transesterification of hydroxyalkyl carbamates with an (meth)acrylate of formula CH2═CR29—COOR30 wherein R29 is hydrogen or methyl and R30 represents an alkyl group comprising from 1 to 8 carbon atoms, in the presence of an organotitanate, an organozirconate catalyst or an organotin catalyst, the carbamoyloxy(meth)acrylates thereby obtained and their use in radiation curable compositions.

    摘要翻译： 本发明涉及一种生产氨基甲酰氧基（甲基）丙烯酸酯的方法，其包括将氨基甲酸羟烷基酯与式CH 2 - （CH 2）2 - > 30其中R 29是氢或甲基，R 30表示含有1至8个碳原子的烷基，在有机钛酸盐存在下， 有机锆酸酯催化剂或有机锡催化剂，由此得到的氨基甲酰氧基（甲基）丙烯酸酯及其在可辐射固化组合物中的用途。

    Process for producing carbamoyloxy (meth) acrylates and new carbamoyloxy (meth)acrylates
    2.
    发明申请
    Process for producing carbamoyloxy (meth) acrylates and new carbamoyloxy (meth)acrylates 失效
    氨基甲酰氧基（甲基）丙烯酸酯和新的氨基甲酰氧基（甲基）丙烯酸酯的制备方法

    公开(公告)号：US20060058549A1

    公开(公告)日：2006-03-16

    申请号：US10536017

    申请日：2003-11-18

    申请人： Vincent Stone ,  Jurgen Van Holen ,  Hugues Van Den Bergen

    发明人： Vincent Stone ,  Jurgen Van Holen ,  Hugues Van Den Bergen

    IPC分类号： C07C271/18

    CPC分类号： C07C269/06 ,  C07C271/16

    摘要： The invention relates to a process for producing carbamoyloxy (meth)acrylates which comprises transesterification of hydroxyalkyl carbamates with an (meth)acrylate of formula CH2═CR29—COOR30 wherein R29 is hydrogen or methyl and R30 represents an alkyl group comprising from 1 to 8 carbon atoms, in the presence of an organotitanate, an organozirconate catalyst or an organotin catalyst, the carbamoyloxy (meth)acrylates thereby obtained and their use in radiation curable compositions.

    摘要翻译： 本发明涉及一种生产氨基甲酰氧基（甲基）丙烯酸酯的方法，其包括将氨基甲酸羟烷基酯与式CH 2 - （CH 2）2 - > 30其中R 29是氢或甲基，R 30表示含有1至8个碳原子的烷基，在有机钛酸盐存在下， 有机锆酸酯催化剂或有机锡催化剂，由此得到的氨基甲酰氧基（甲基）丙烯酸酯及其在可辐射固化组合物中的用途。

    Process for producing carbamoyloxy (meth) acrylates and new carbamoyloxy (meth)acrylates
    3.
    发明授权
    Process for producing carbamoyloxy (meth) acrylates and new carbamoyloxy (meth)acrylates 失效
    氨基甲酰氧基（甲基）丙烯酸酯和新的氨基甲酰氧基（甲基）丙烯酸酯的制备方法

    公开(公告)号：US07329773B2

    公开(公告)日：2008-02-12

    申请号：US10536017

    申请日：2003-11-18

    申请人： Vincent Stone ,  Jurgen Van Holen ,  Hugues Van Den Bergen

    发明人： Vincent Stone ,  Jurgen Van Holen ,  Hugues Van Den Bergen

    IPC分类号： C07C269/00

    CPC分类号： C07C269/06 ,  C07C271/16

    摘要： The invention relates to a process for producing carbamoyloxy (meth)acrylates which comprises transesterification of hydroxyalkyl carbamates with an (meth)acrylate of formula CH2═CR29—COOR30 wherein R29 is hydrogen or methyl and R30 represents an alkyl group comprising from 1 to 8 carbon atoms, in the presence of an organotitanate, an organozirconate catalyst or an organotin catalyst, the carbamoyloxy (meth)acrylates thereby obtained and their use in radiation curable compositions.

    摘要翻译： 本发明涉及一种生产氨基甲酰氧基（甲基）丙烯酸酯的方法，其包括将氨基甲酸羟烷基酯与式CH 2 - （CH 2）2 - > 30其中R 29是氢或甲基，R 30表示含有1至8个碳原子的烷基，在有机钛酸盐存在下， 有机锆酸酯催化剂或有机锡催化剂，由此得到的氨基甲酰氧基（甲基）丙烯酸酯及其在可辐射固化组合物中的用途。

    Process for producing urethane (meth)acrylates and new urethane (meth)acrylates
    4.
    发明申请
    Process for producing urethane (meth)acrylates and new urethane (meth)acrylates 审中-公开
    制备氨基甲酸酯（甲基）丙烯酸酯和新的聚氨酯（甲基）丙烯酸酯的方法

    公开(公告)号：US20070197820A1

    公开(公告)日：2007-08-23

    申请号：US10591230

    申请日：2005-05-02

    申请人： Jurgen Van Holen ,  Vincent Stone ,  Hugues Van Den Bergen

    发明人： Jurgen Van Holen ,  Vincent Stone ,  Hugues Van Den Bergen

    IPC分类号： C07C271/08

    CPC分类号： C07C271/20 ,  C07D295/205

    摘要： The invention relates to urethane(meth)acrylates and to a process for their production which comprises transesterification of hydroxyalkyl carbamates with an (meth)acrylate of formula [CH2═CR29—CO—O—]t—R30 wherein R29 is hydrogen or methyl, and R30 represents an alkyl, optionally substituted by hydroxy, which may contain from 1 to 10 ether bridges group, from 1 to 10 —CO— bridges and/or from 1 to 5 —O—CO— bridges, and at least one carbonate of formula (IX) and/or a diester of formula (X) wherein each R31, each R32, each R33, each R34 is, independently, chosen from the group of alkyl and aryl, and R35 is alkylene, alkenylene or arylene.

    摘要翻译： 本发明涉及氨基甲酸酯（甲基）丙烯酸酯及其制备方法，其包括氨基甲酸羟烷基酯与式[CH 2/2 -CR 29]的（甲基）丙烯酸酯的酯交换反应， -CO-O - ]其中R 29是氢或甲基，R 30表示 任选被羟基取代的烷基，其可以含有1至10个醚桥基，1至10个-CO-桥和/或1至5个-O-CO-桥，以及至少一种式（IX ）和/或式（X）的二酯，其中每个R 31，每个R 32，每个R 33，每个R 30， 34独立地选自烷基和芳基，R 35是亚烷基，亚烯基或亚芳基。

    Radiation curable compositions
    6.
    发明授权
    Radiation curable compositions 有权
    辐射固化组合物

    公开(公告)号：US09475959B2

    公开(公告)日：2016-10-25

    申请号：US13991268

    申请日：2011-12-21

    申请人： Jean-Yves Salviato ,  Jurgen Van Holen ,  Michel Tielemans ,  Marc Decaux

    发明人： Jean-Yves Salviato ,  Jurgen Van Holen ,  Michel Tielemans ,  Marc Decaux

    IPC分类号： C09D175/16 ,  C08F283/00 ,  C08G18/08 ,  C08G18/34 ,  C08G18/42 ,  C08G18/66 ,  C08G18/67 ,  C08G18/76 ,  C08L33/00

    CPC分类号： C09D175/16 ,  C08F283/008 ,  C08G18/0823 ,  C08G18/348 ,  C08G18/4238 ,  C08G18/6659 ,  C08G18/6705 ,  C08G18/765 ,  C08L33/00 ,  C08L2666/04

    摘要： The present invention relates to an ethylenically unsaturated hydroxyl-terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and, optionally, at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (B2); (iii) optionally, at least one ethylenically unsaturated compound (C) containing essentially one reactive group capable of reacting with isocyanate groups; with (iv) at least one polyisocyanate (D) selected from a tetramethylxylenediisocyanate. The present invention further relates to dispersions in water containing same, to their production and uses.

    摘要翻译： 本发明涉及通过使（i）至少一种含有至少两个能够与异氰酸酯基反应的反应性基团和至少一个烯属不饱和基团的烯属不饱和化合物（A）反应而获得的烯属不饱和羟基封端的聚氨酯（I） 与（ii）至少一种饱和醇组分（B），其包含：（i）至少一种含有亲水基团的饱和羟基化合物（B1），所述亲水基团能够使所述聚氨酯在水性介质中直接或与中和剂反应， 提供盐，和任选地至少一种选自饱和聚酯多元醇（B21）和/或饱和聚碳酸酯多元醇（B22）的化合物（B2）; 和/或（iib）选自含有化合物（B1）部分的饱和聚酯多元醇（B31）和/或含有化合物（B1）部分的饱和聚碳酸酯多元醇（B32）的至少一种化合物（B3） 和任选的一种或多种化合物（B1）和/或（B2）; （iii）任选的至少一种含有能够与异氰酸酯基团反应的基本上一个反应性基团的烯键式不饱和化合物（C）; 与（iv）至少一种选自四甲基亚甲基二异氰酸酯的多异氰酸酯（D）。 本发明还涉及含有它们的水分散体及其生产和用途。

    RADIATION CURABLE COMPOSITIONS
    7.
    发明申请
    RADIATION CURABLE COMPOSITIONS 有权
    辐射可固化组合物

    公开(公告)号：US20130310513A1

    公开(公告)日：2013-11-21

    申请号：US13991268

    申请日：2011-12-21

    申请人： Jean-Yves Salviato ,  Jurgen Van Holen ,  Michel Tielemans ,  Marc Decaux

    发明人： Jean-Yves Salviato ,  Jurgen Van Holen ,  Michel Tielemans ,  Marc Decaux

    IPC分类号： C09D175/16

    CPC分类号： C09D175/16 ,  C08F283/008 ,  C08G18/0823 ,  C08G18/348 ,  C08G18/4238 ,  C08G18/6659 ,  C08G18/6705 ,  C08G18/765 ,  C08L33/00 ,  C08L2666/04

    摘要： The present invention relates to an ethylenically unsaturated hydroxyl-terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and, optionally, at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (B2); (iii) optionally, at least one ethylenically unsaturated compound (C) containing essentially one reactive group capable of reacting with isocyanate groups; with (iv) at least one polyisocyanate (D) selected from a tetramethylxylenediisocyanate. The present invention further relates to dispersions in water containing same, to their production and uses.

    摘要翻译： 本发明涉及通过使（i）至少一种含有至少两个能够与异氰酸酯基反应的反应性基团和至少一个烯属不饱和基团的烯属不饱和化合物（A）反应而获得的烯属不饱和羟基封端的聚氨酯（I） 与（ii）至少一种饱和醇组分（B），其包含：（i）至少一种含有亲水基团的饱和羟基化合物（B1），所述亲水基团能够使所述聚氨酯在水性介质中直接或与中和剂反应， 提供盐，和任选地至少一种选自饱和聚酯多元醇（B21）和/或饱和聚碳酸酯多元醇（B22）的化合物（B2）; 和/或（iib）选自含有化合物（B1）部分的饱和聚酯多元醇（B31）和/或含有化合物（B1）部分的饱和聚碳酸酯多元醇（B32）的至少一种化合物（B3） 和任选的一种或多种化合物（B1）和/或（B2）; （iii）任选的至少一种含有能够与异氰酸酯基团反应的基本上一个反应性基团的烯键式不饱和化合物（C）; 与（iv）至少一种选自四甲基亚甲基二异氰酸酯的多异氰酸酯（D）。 本发明还涉及含有它们的水分散体及其生产和用途。

    Radiation curable compositions
    9.
    发明授权
    Radiation curable compositions 有权
    辐射固化组合物

    公开(公告)号：US09540477B2

    公开(公告)日：2017-01-10

    申请号：US13991974

    申请日：2011-12-16

    申请人： Michel Tielemans ,  Jurgen Van Holen ,  Marc Decaux ,  Jean-Yves Salviato

    发明人： Michel Tielemans ,  Jurgen Van Holen ,  Marc Decaux ,  Jean-Yves Salviato

    IPC分类号： C08G18/00 ,  C08F290/06 ,  C08G18/08 ,  C08G18/66 ,  C08G18/67 ,  C09D175/14 ,  C09D4/00

    CPC分类号： C08G18/003 ,  C08F290/067 ,  C08G18/0823 ,  C08G18/0866 ,  C08G18/6659 ,  C08G18/675 ,  C09D4/00 ,  C09D175/14

    摘要： The present invention provides for an ethylenically unsaturated hydroxyl-terminated polyurethane (I) obtained by reacting (i) at least one ethylenically unsaturated compound (A) containing at least two reactive groups capable of reacting with isocyanate groups and at least one ethylenically unsaturated group; with (ii) at least one saturated alcohol component (B) comprising: (iia) at least one saturated hydroxylated compound (B1) containing hydrophilic groups capable of rendering the polyurethane dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, and at least one compound (B2) that is selected from saturated polyester polyols (B21) and/or from saturated polycarbonate polyols (B22); and/or (iib) at least one compound (B3) that is selected from saturated polyester polyols (B31) containing compound (B1) moieties and/or from saturated polycarbonate polyols (B32) containing compound (B1) moieties; and, optionally, one or more of compounds (B1) and/or (B2); (iii) optionally, at least one ethylenically unsaturated compound (C) containing essentially one reactive group capable of reacting with isocyanate groups; and with (iv) at least one polyisocyanate (D). The present invention further relates to radiation curable coating compositions comprising same, to their preparation process and their uses.

    摘要翻译： 本发明提供了通过使（i）至少一种含至少两个能够与异氰酸酯基团反应的反应性基团和至少一个烯属不饱和基团的烯键式不饱和化合物（A）反应而获得的烯属不饱和羟基封端的聚氨酯（I） 与（ii）至少一种饱和醇组分（B），其包含：（i）至少一种含有亲水基团的饱和羟基化合物（B1），所述亲水基团能够使所述聚氨酯在水性介质中直接或与中和剂反应， 提供盐和至少一种选自饱和聚酯多元醇（B21）和/或饱和聚碳酸酯多元醇（B22）的化合物（B2）; 和/或（iib）选自含有化合物（B1）部分的饱和聚酯多元醇（B31）和/或含有化合物（B1）部分的饱和聚碳酸酯多元醇（B32）的至少一种化合物（B3） 和任选的一种或多种化合物（B1）和/或（B2）; （iii）任选的至少一种含有能够与异氰酸酯基团反应的基本上一个反应性基团的烯键式不饱和化合物（C）; 和（iv）至少一种多异氰酸酯（D）。 本发明还涉及包含它们的可辐射固化涂料组合物，其制备方法及其用途。