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公开(公告)号：US09985309B2
公开(公告)日：2018-05-29
申请号：US14394012
申请日：2012-11-21
IPC分类号： H01M8/10 , H01M8/1032 , C08G75/24 , C08J5/22
CPC分类号： H01M8/1032 , C08G75/24 , C08J5/2256 , H01M2300/0082
摘要： The present invention aims to provide a hydrocarbon-based polymer electrolyte which is excellent in processability and proton conductivity, especially proton conductivity at low water content, and a membrane thereof. The polymer electrolyte contains, in its main chain, a repeating unit represented by the following formula (1): wherein Ar represents a benzene or naphthalene ring, or a derivative thereof in which one or more of the ring-forming carbon atoms is replaced by a hetero atom; X represents a proton or a cation; a and b are each an integer of 0 to 4, and the sum of a's and b's is 1 or greater; m represents an integer of 1 or greater; and n represents an integer of 0 or greater.
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公开(公告)号：US20150064601A1
公开(公告)日：2015-03-05
申请号：US14394012
申请日：2012-11-21
CPC分类号： H01M8/1032 , C08G75/24 , C08J5/2256 , H01M2300/0082
摘要： The present invention aims to provide a hydrocarbon-based polymer electrolyte which is excellent in processability and proton conductivity, especially proton conductivity at low water content, and a membrane thereof. The polymer electrolyte contains, in its main chain, a repeating unit represented by the following formula (1): wherein Ar represents a benzene or naphthalene ring, or a derivative thereof in which one or more of the ring-forming carbon atoms is replaced by a hetero atom; X represents a proton or a cation; a and b are each an integer of 0 to 4, and the sum of a's and b's is 1 or greater; m represents an integer of 1 or greater; and n represents an integer of 0 or greater.
摘要翻译： 本发明的目的在于提供加工性和质子传导性优异的烃类聚合物电解质，特别是低含水量下的质子传导性及其膜。 聚合物电解质在其主链中含有由下式（1）表示的重复单元：其中Ar表示苯或萘环，或其衍生物，其中一个或多个成环碳原子被 杂原子 X表示质子或阳离子; a和b各自为0〜4的整数，a和b的和为1以上; m表示1或更大的整数; n表示0以上的整数。
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公开(公告)号：US10566645B2
公开(公告)日：2020-02-18
申请号：US15156853
申请日：2016-05-17
发明人： Masahiro Watanabe
IPC分类号： H01M8/0202 , H01M8/2465 , H01M8/0258 , H01M8/0267
摘要： Separators of multiple types capable of supplying and diffusing fluids such as an anode gas, cathode gas and coolant uniformly are prepared and combined to construct a fuel cell stack. Such a cell stack (20) for fuel cells includes separators of at least two types (types CA, C, A, C, CW and AW) for anode gas and cathode gas. Each separator is such that a corrosion-resistance layer is formed on at least one face of a metal plate (30) and a fluid supply and diffusion layer for the corresponding gas is formed by an electrically conductive porous layer on the corrosion-resistant layer. The at least two separators are stacked so as to face each other with at least an electrolyte membrane and catalyst layers on both sides of the membrane (a new membrane electrode assembly N-MEA) being sandwiched between the fluid supply and diffusion layers of the separators.
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公开(公告)号：US09931624B2
公开(公告)日：2018-04-03
申请号：US15126910
申请日：2015-02-28
发明人： Naoki Yokota , Manai Shimada , Kenji Miyatake , Masahiro Watanabe , Junpei Miyake , Eriko Nishino , Koichiro Asazawa
IPC分类号： B01J41/13 , B01J41/04 , B01J47/12 , C08G61/12 , H01B1/12 , H01M8/1067 , H01M4/86 , H01M8/1018
CPC分类号： B01J41/13 , B01J41/04 , B01J47/12 , C08G61/12 , C08G2261/146 , C08G2261/312 , C08G2261/3142 , C08G2261/3444 , C08G2261/516 , C08J5/2256 , H01B1/06 , H01B1/122 , H01M4/8668 , H01M8/102 , H01M8/1067 , H01M2008/1095 , Y02P70/56
摘要： An anion exchange resin having a hydrophobic unit with divalent hydrophobic groups bonded to each other via an ether bond, the divalent hydrophobic groups being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are bonded to each other via a divalent hydrocarbon group, carbon-carbon bond or the like; and a hydrophilic unit having divalent hydrophilic groups bonded to each other via carbon-carbon bond, the divalent hydrophilic groups being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are bonded to each other via a divalent hydrocarbon group or carbon-carbon bond, the aromatic ring or at least one of the aromatic rings having an anion exchange group are bonded via carbon-carbon bond.
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公开(公告)号：US09522391B2
公开(公告)日：2016-12-20
申请号：US14425589
申请日：2013-08-26
发明人： Toshihiro Miyao , Kazutoshi Higashiyama , Weihua Shen , Hisao Yamashita , Noboru Hashimoto , Shigehito Deki , Masahiro Watanabe
IPC分类号： B01J21/00 , B01J21/04 , B01J23/00 , B01J23/02 , B01J23/08 , B01J23/10 , B01J23/40 , B01J23/42 , B01J23/56 , B01J23/70 , B01J23/72 , B01J23/74 , B01J29/76 , B01J23/755 , B01J23/78 , C01B37/02 , C01B3/58 , C10L3/08 , B01J37/03 , B01J23/847 , B01J29/03 , B01J35/00 , B01J21/08 , B01J35/10 , H01M8/06 , B01J35/04 , B01J21/06 , B01J37/04
CPC分类号： B01J29/76 , B01J21/063 , B01J21/08 , B01J23/755 , B01J23/78 , B01J23/8472 , B01J29/0308 , B01J29/0333 , B01J35/0006 , B01J35/04 , B01J35/1014 , B01J35/1061 , B01J37/03 , B01J37/04 , C01B3/586 , C01B37/02 , C01B2203/0233 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/1258 , C10L3/08 , H01M8/0612 , H01M8/0668 , Y02E60/50
摘要： The first object is to increase the life of a selective CO methanation catalyst, and the second object is to enhance the CO removal rate of a selective CO methanation catalyst to reduce the outlet CO concentration in a wide temperature range. Provided a selective CO methanation catalyst including a supported metal catalyst which selectively methanizes CO in a hydrogen-rich gas containing CO and CO2 and a coating layer which covers a surface of the supported metal catalyst, has many pores, and is configured to reduce a CO concentration on the surface of the supported metal catalyst.
摘要翻译： 第一个目的是增加选择性CO甲烷化催化剂的寿命，第二个目的是提高选择性CO甲烷化催化剂的CO去除速率，以便在宽温度范围内降低出口CO浓度。 提供一种选择性CO甲烷化催化剂，其包括负载金属催化剂，其选择性地使含CO和CO 2的富氢气体中的CO甲烷化，并且覆盖所述负载型金属催化剂的表面的涂层具有许多孔，并且被配置为减少CO 负载金属催化剂表面的浓度。
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6.发明申请PRODUCTION METHOD FOR FINE METAL PARTICLES, PRODUCTION METHOD FOR FUEL CELL ELECTRODE CATALYST, SUPPORTED FINE METAL PARTICLE CATALYST, AND FUEL CELL ELECTRODE CATALYST 审中-公开精细金属颗粒的生产方法，燃料电池催化剂的生产方法，支持的精细金属颗粒催化剂和燃料电池电极催化剂公开(公告)号：US20160087285A1
公开(公告)日：2016-03-24
申请号：US14787196
申请日：2014-04-16
摘要： Provided is a method for efficiently manufacturing fine metal particles applicable as a fuel cell electrode catalyst. Provided is a method of manufacturing fine metal particles, including the step of: a hydrogen bubbling step to perform bubbling to a reaction solution, wherein: the reaction solution is prepared by allowing seeds of fine metal particles in a dispersed state and a water soluble noble metal precursor to co-exist in a water-containing solvent; and the bubbling is performed with a reaction gas containing a hydrogen gas, is provided.
摘要翻译： 提供一种有效地制造可用作燃料电池电极催化剂的金属微粒的方法。 本发明提供一种金属微粒的制造方法，其特征在于，包括以下步骤：向反应溶液进行鼓泡的氢气鼓泡步骤，其中：通过使分散状态的金属微粒的种子和水溶性贵金属 金属前体共存于含水溶剂中; 并且提供用含有氢气的反应气体进行鼓泡。
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公开(公告)号：US10693146B2
公开(公告)日：2020-06-23
申请号：US14787196
申请日：2014-04-16
摘要： Provided is a method for efficiently manufacturing fine metal particles applicable as a fuel cell electrode catalyst. Provided is a method of manufacturing fine metal particles, including the step of: a hydrogen bubbling step to perform bubbling to a reaction solution, wherein: the reaction solution is prepared by allowing seeds of fine metal particles in a dispersed state and a water soluble noble metal precursor to co-exist in a water-containing solvent; and the bubbling is performed with a reaction gas containing a hydrogen gas, is provided.
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公开(公告)号：US10287409B2
公开(公告)日：2019-05-14
申请号：US15505606
申请日：2015-08-22
发明人： Manai Shimada , Naoki Yokota , Kenji Miyatake , Masahiro Watanabe , Junpei Miyake , Hideaki Ono , Eriko Nishino , Koichiro Asazawa
IPC分类号： C08J5/22 , C08G61/10 , C08G61/12 , C08G65/40 , H01M8/1025 , H01M8/1032 , H01M8/1034 , H01M8/1037 , C08G75/02 , H01M8/06 , H01B1/12 , H01M4/86 , H01M4/90 , H01M8/1067 , H01M8/1023 , H01M8/103 , H01M4/02
摘要： The present invention provides an anion exchange resin capable of producing an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a battery electrode catalyst layer. The anion exchange resin of the present invention has a hydrophobic unit, a hydrophilic unit and divalent fluorine-containing groups. The hydrophobic unit has divalent hydrophobic groups composed of one aromatic ring or a plurality of aromatic rings that are repeated via carbon-carbon bond. The hydrophilic unit has divalent hydrophilic groups composed of one aromatic ring or a plurality of aromatic rings, at least one of which has an anion exchange group, that are repeated via carbon-carbon bond. The divalent fluorine-containing groups have a specific structure and are bonded via carbon-carbon bond to the hydrophobic unit and/or the hydrophilic unit and/or a moiety other than these units.
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公开(公告)号：US10011912B2
公开(公告)日：2018-07-03
申请号：US14909871
申请日：2014-08-05
发明人： Masahiro Watanabe
IPC分类号： C25B1/04 , C25B9/08 , C25B1/00 , C25B9/00 , C25B9/18 , C25B1/10 , B01D53/22 , H01M8/0662 , H01M8/04082 , B01D63/08 , C25B1/02 , C25B13/04 , H01M8/0612
CPC分类号： C25B9/18 , B01D53/22 , B01D63/082 , B01D2256/16 , C25B1/02 , C25B13/04 , H01M8/04201 , H01M8/0618 , H01M8/0681 , Y02E60/366
摘要： Provided is a hydrogen refining pressure-boosting device which is durable even in a high-pressure environment. This hydrogen refining pressure-boosting device produces, from a hydrogen-containing gas, a refined hydrogen gas having higher pressure and higher purity than the hydrogen-containing gas. The hydrogen refining pressure-boosting device is equipped with multiple stacked cell structures, and a pressing structure that applies tightening stress in the direction in which the cell structures are stacked. In this hydrogen refining pressure-boosting device the flow path surface of a cathode-side separator is sized so as to be contained on the inside of the flow path surface of an anode-side separator, in the direction of a plane parallel to a solid polymer electrolyte membrane.
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公开(公告)号：US20150246347A1
公开(公告)日：2015-09-03
申请号：US14425589
申请日：2013-08-26
发明人： Toshihiro Miyao , Kazutoshi Higashiyama , Weihua Shen , Hisao Yamashita , Noboru Hashimoto , Shigehito Deki , Masahiro Watanabe
IPC分类号： B01J29/76 , B01J23/847 , B01J35/04 , B01J35/00
CPC分类号： B01J29/76 , B01J21/063 , B01J21/08 , B01J23/755 , B01J23/78 , B01J23/8472 , B01J29/0308 , B01J29/0333 , B01J35/0006 , B01J35/04 , B01J35/1014 , B01J35/1061 , B01J37/03 , B01J37/04 , C01B3/586 , C01B37/02 , C01B2203/0233 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/1258 , C10L3/08 , H01M8/0612 , H01M8/0668 , Y02E60/50
摘要： The first object is to increase the life of a selective CO methanation catalyst, and the second object is to enhance the CO removal rate of a selective CO methanation catalyst to reduce the outlet CO concentration in a wide temperature range. Provided a selective CO methanation catalyst including a supported metal catalyst which selectively methanizes CO in a hydrogen-rich gas containing CO and CO2 and a coating layer which covers a surface of the supported metal catalyst, has many pores, and is configured to reduce a CO concentration on the surface of the supported metal catalyst.
摘要翻译： 第一个目的是增加选择性CO甲烷化催化剂的寿命，第二个目的是提高选择性CO甲烷化催化剂的CO去除速率，以便在宽温度范围内降低出口CO浓度。 提供一种选择性CO甲烷化催化剂，其包括负载金属催化剂，其选择性地使含CO和CO 2的富氢气体中的CO甲烷化，并且覆盖所述负载型金属催化剂的表面的涂层具有许多孔，并且被配置为减少CO 负载金属催化剂表面的浓度。
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