Abstract:
A polymer electrolyte membrane having improved chemical or mechanical durability is provided. The present disclosure relates to a polymer electrolyte membrane, and the polymer electrolyte membrane according to the present disclosure comprises a porous support and a composite layer containing a first ionomer filled in the porous support, wherein the polymer electrolyte membrane comprises a first segment having a first durability and a second segment having a second durability, and the first durability is higher than the second durability.
Abstract:
The present disclosure relates to a method for manufacturing a polymer electrolyte membrane, the method comprising the steps of (a) preparing a porous support containing a plurality of pores, (b) preparing an ion conductor dispersion solution by dispersing an ion conductor in a dispersion medium, (c) contacting the dispersion medium with the porous support to wet the dispersion medium on the porous support, and (d) introducing the ion conductor to at least one surface of the porous support by applying the ion conductor dispersion solution to the porous support wetted with the dispersion medium, and a polymer electrolyte membrane manufactured thereby.
Abstract:
The present invention relates to a polymer electrolyte membrane, a manufacturing method therefor, and a membrane electrode assembly comprising same, the polymer electrolyte membrane comprising: a first porous support having first pores filled with a first ion conductor; and a second porous support having at least one second pore filled with the first ion conductor and third pores filled with a second ion conductor, wherein the first and second porous supports are in contact with each other. The polymer electrolyte membrane has enhanced performance through the improvement of impregnation properties and enhanced mechanical and chemical durability through the minimization of hydrogen permeability and dimensional change. Furthermore, an interface between the ion conductor and the support in the polymer electrolyte membrane can be stably maintained for a long time.
Abstract:
Provided are a polymer electrolyte membrane used in fuel cells, and a method for producing the same, the method including a step of filling a crosslinkable ion conductor in the pores of a porous nanoweb support; and a step of crosslinking the ion conductor filled in the pores of the porous nanoweb support. The method for producing a polymer electrolyte membrane uses a relatively smaller amount of an organic solvent, can ameliorate defects of the support caused by solvent evaporation, and can enhance the impregnability of the ion conductor to the support and the convenience of the process.
Abstract:
Disclosed are: a reinforced composite membrane-type polymer electrolyte membrane which can prevent the loss of an ion conductor even when the ion conductor is chemically deteriorated due to long-term use, and thus has remarkably enhanced mechanical and chemical durability; a method for manufacturing same; and an electrochemical device comprising same. The polymer electrolyte membrane of the present invention comprises: a non-crosslinked ion conductor; and a porous support having a plurality of pores filled with the ion conductor, wherein the porous support comprises a polymer having at least one crosslinking functional group, and the crosslinking functional group is a functional group which, when the ion conductor is deteriorated, can cause crosslinking of the ion conductor by binding to the deteriorated ion conductor.
Abstract:
The present invention relates to an ion exchanging membrane, a method for manufacturing the same, and an energy storage system comprising the same. The ion exchanging membrane includes a porous support including a plurality of pores, a first ion conducting material located on one surface of the porous support, and a second ion conducting material located on the other surface of the porous support, in which the first ion conducting material and the second ion conducting material are polymers including hydrophilic repeating units and hydrophobic repeating units, and the first ion conducting material and the second ion conducting material have different molar ratios of the hydrophilic repeating units and the hydrophobic repeating units.According to the ion exchanging membrane, it is possible to improve overall efficiency of the energy storage system by improving both performance efficiency and voltage efficiency of the energy storage system due to excellent ion-conductivity performance and reduced membrane resistance and ensure durability of the energy storage system by having excellent morphological stability and reducing a crossover of vanadium ions.
Abstract:
The present invention relates to an ion conductor, a method for producing the same, and an ion exchange membrane, a polymer electrolyte membrane and a fuel cell including the same. The ion conductor includes a repeat unit represented by the following Formula 1, and a repeat unit represented by the following Formula 2 or a repeat unit represented by the following Formula 5. Formulae 1, 2 and 3 are described as in the Detailed Description of the Invention.The ion conductor contains a hydrocarbon-based block copolymer which has an easily changeable structure because it includes a hydrophilic region and a hydrophobic region, wherein characteristics of the block copolymer and the ion conductor can be easily regulated through control over the structure of the hydrophilic region and the hydrophobic region, and ion conductivity and durability of the ion conductor are improved within the whole humidity range through micro-phase separation between the hydrophilic region and the hydrophobic region which are structurally controlled.
Abstract:
Provided are a polymer electrode membrane including a porous support including a web of nanofibers of a first hydrocarbon-based ion conductor that are arranged irregularly and discontinuously; and a second hydrocarbon-based ion conductor filling the pores of the porous support, the first hydrocarbon-based ion conductor being a product obtained by eliminating at least a portion of the protective groups (Y) in a precursor of the first hydrocarbon-based ion conductor represented by Formula (1), a method for producing the polymer electrolyte membrane, and a membrane electrode assembly including the polymer electrolyte membrane: wherein m, p, q, M, M′, X and Y respectively have the same meanings as defined in the specification.
Abstract:
The present disclosure relates to a reinforced composite membrane for a fuel cell, comprising a porous support and a hydrogen ion-conductive polymer; a manufacturing method therefor; and a membrane-electrode assembly comprising same, the reinforced composite membrane having the hydrogen ion-conductive polymer impregnated into the porous support, or comprising, on at least one surface of the porous support, an electrolyte layer comprising the hydrogen ion-conductive polymer, wherein the porous support further comprises a compound capable of trapping metal ions.
Abstract:
Disclosed are: an ionomer dispersion having high dispersion stability while also containing high content of ionomer solids, thus optimizing the ionomer morphology in a polymer electrolyte membrane to allow both the ion conductivity and durability of the polymer electrolyte membrane to be improved; a method for producing the ionomer dispersion; and a polymer electrolyte membrane produced using the method.