摘要:
Provided are a curable composition including a pigment, a resin, a polymerizable compound, a photopolymerization initiator, and a solvent; a film formed of the curable composition; a structural body; a color filter; a solid-state imaging element; and an image display device. The resin includes a resin A which includes a repeating unit having a graft chain of a poly(meth)acrylate structure and a repeating unit having an acid group, and the graft chain of a poly(meth)acrylate structure includes a repeating unit represented by the following formula. R1 represents a hydrogen atom or a methyl group, and R2 represents a hydrocarbon group having 1 to 20 carbon atoms. However, R1 is a hydrogen atom in a case where R2 is a methyl group, and R2 is a hydrocarbon group having 2 or more carbon atoms in a case where R1 is a methyl group.
摘要:
An aqueous polymer dispersion comprising a vinyl polymer with at least two phases comprising: A) 40 to 90 wt % of a vinyl polymer A having a glass transition temperature in the range of from −50 to 30° C.; and B) 10 to 60 wt % of a vinyl polymer B having a glass transition temperature the range of from 50 to 130° C.; wherein vinyl polymer A comprises 0.1 to 10 wt % of at least one acid-functional olefinically unsaturated monomer, wherein at least 20 wt % of the monomer composition used to form vinyl polymer A and vinyl polymer B is derived from at least one bio-renewable olefinically unsaturated monomer.
摘要:
A process for preparing a composition by free-radical polymerization of a monomer composition comprising: a) at least one ethylenically unsaturated carboxylic acid containing monomer or anhydride thereof; b) optionally at least one ethylenically unsaturated monomer different from a) but copolymerizable therewith; and c) at least one crosslinking monomer containing at least two ethylenically unsaturated groups. The monomer composition is polymerized in an organic medium having a solubilizing effect on one or more of the monomeric ingredients, but substantially none on the resulting polymer. The polymerization is conducted in the presence of a free radical forming catalyst and at least one steric stabilizing polymer polymerized from a vinyl lactam and a copolymerizable monomer selected from a short chain alkyl ester of (meth)acrylic acid, a long chain alkyl ester of (meth)acrylic acid, and combinations thereof.
摘要:
A method for the preparation of a fluoropolymer by means of emulsion polymerization of a reaction mixture in an aqueous medium is disclosed wherein the reaction mixture includes a fluoromonomer having the structure of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring; b) an emulsion stabilizer combination comprising: i) an anionic surfactant; and, ii) a cationic surfactant or a non-ionic surfactant; and, c) a free-radical initiator.
摘要:
A process for producing a polymer by polymerizing at least one fluorinated monomer in the presence of a radical initiator and a surfactant in a polymerization medium containing essentially only carbon dioxide. The surfactant is a functional (per)fluoropolyether having recurring units (R1) and at least one functional group containing a heteroatom other than fluorine, the recurring units containing at least one ether linkage in the main chain and at least one fluorine atom. Molded article containing the polymer obtained from the process.
摘要:
Polymeric compositions of matter are described comprising olefin polymer chains having Mn of about 400 to 75,000, a ratio of vinyl groups to total olefin groups according to the formula vinyl groups olefin groups ≥ [ comonomer mole percentage + 0.1 ] a × 10 a × b ( 1 ) where, a=−0.24 and b=0.8, and where the total number of vinyl groups per 1000 carbon atoms is greater than or equal to 8000÷Mn. The invention includes a method for preparing these polymeric products comprising contacting one or more olefin comonomers with a catalyst system containing a transition metal catalyst compound and an alumoxane wherein the aluminum to transition metal ratio is from 10:1 to less than or equal to 220:1 (Al:Me). The process conditions of the invention permit predictable macromer characteristics of both molecular weight and vinyl unsaturation.
摘要:
The present invention relates to polyol latex compositions, to methods of making such compositions, and to condensation polymers comprising such compositions.
摘要:
A composition including polyalphaolefins that function as drag reducing agents and a process for the preparation of polyalphaolefins that function as drag reducing agents are disclosed. The process includes contacting alpha olefin monomers with a catalyst system, which includes a catalyst and an activator (co-catalyst) in a reactant mixture. The catalyst is a transition metal catalyst, preferably titanium trichloride, and the co-catalyst may include an alkylaluminoxane, alone or in combination, with a dialkylaluminum halide or a halohydrocarbon. The polymerization of the alpha olefin monomers produces a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of at least 10 dL/g. The addition of the alkylaluminoxane during the polymerization process provides for a non-crystalline, ultra-high molecular weight polyalphaolefin and a more uniform molecular weight distribution of the resulting polyalphaolefin, thereby creating a drag reducing agent superior to known drag reducing agents. A process for forming a drag reducing agent comprising a non-crystalline, ultra-high molecular weight polyalphaolefin having an inherent viscosity of about at least 10 dL/g and a process for reducing drag in a conduit are also disclosed.
摘要:
The heterogeneous polymerization of water-insoluble polymer in CO.sub.2 is disclosed. The method comprises providing a heterogeneous reaction mixture comprising CO.sub.2, a monomer, and a surfactant, then polymerizing the monomer to form a water-insoluble polymer.
摘要:
The heterogeneous polymerization of water-insoluble polymer in CO.sub.2 is disclosed. The method comprises providing a heterogeneous reaction mixture comprising CO.sub.2, a monomer, and a surfactant, then polymerizing the monomer to form a water-insoluble polymer.