Method for producing water absorbent resin particle
    2.
    发明授权
    Method for producing water absorbent resin particle 有权
    吸水性树脂颗粒的制造方法

    公开(公告)号:US09593212B2

    公开(公告)日:2017-03-14

    申请号:US12296808

    申请日:2007-09-28

    IPC分类号: C08J3/12 B29B17/00

    摘要: The present invention provides a method for producing a water absorbent resin particle, in high productivity, not only in a controlled manner of particle size but also enhancing fundamental property (absorption capacity or absorption capacity against pressure) of a water absorbent resin. A method for producing a water absorbent resin particle having the cross-linking polymerization step for an aqueous solution of an unsaturated monomer; the grain refining step for water-swellable, water-containing gel-like cross-linked polymer (a) obtained in the cross-linking polymerization step; the drying step for grain refined gel; and the crushing step for a dried substance, wherein, in the grain refining step for the water-swellable, water-containing gel-like cross-linked polymer (a), water-swellable, water-containing gel-like cross-linked polymer (b), having solid content or centrifuge retention capacity different from solid content or centrifuge retention capacity of the cross-linked polymer (a) by equal to or larger than 1%, is subjected to coexistence.

    摘要翻译: 本发明提供了一种生产吸水性树脂颗粒的方法,不仅以受控的粒度控制,而且提高了吸水性树脂的基本性能(吸收能力或抗吸收能力)。 一种制备具有用于不饱和单体的水溶液的交联聚合步骤的吸水性树脂颗粒的方法; 在交联聚合步骤中获得的水溶胀性含水凝胶状交联聚合物(a)的晶粒细化步骤; 颗粒精制凝胶的干燥步骤; 和干物质的破碎步骤,其中在水溶胀性含水凝胶状交联聚合物(a)的晶粒细化工序中,水溶胀性含水凝胶状交联聚合物 (b)具有不同于交联聚合物(a)的固体含量或离心保留能力等于或大于1%的固体含量或离心保留能力共存。

    Water-absorbing resin and method for manufacturing the same
    3.
    发明授权
    Water-absorbing resin and method for manufacturing the same 有权
    吸水树脂及其制造方法

    公开(公告)号:US09090718B2

    公开(公告)日:2015-07-28

    申请号:US11723822

    申请日:2007-03-22

    摘要: The present invention provides a highly productive method for manufacturing a water-absorbing resin, the amounts of fine powder and dust of which are small, the amount of residual monomer of which is small, and whose absorption rate is high. That is, the method for manufacturing the water-absorbing resin of the present invention is a method for crosslinking and polymerizing an aqueous solution of an acid-group containing unsaturated monomer, and is characterized in that stationary polymerization is carried out in such a manner that a solid matter is added to the monomer aqueous solution, and an initiation temperature of the polymerization is adjusted to 40° C. or more or a maximum temperature of the polymerization is adjusted to 100° C. or more.

    摘要翻译: 本发明提供了一种制造吸水性树脂的高效生产方法,其粉末和粉尘的量少,残留单体的量少,吸收率高。 也就是说,本发明的吸水性树脂的制造方法是使含酸基的不饱和单体的水溶液进行交联和聚合的方法,其特征在于,以下述方式进行固定聚合: 将固体物质加入到单体水溶液中,并将聚合的起始温度调节至40℃以上或将聚合的最高温度调节至100℃以上。

    Method for producing polyacrylic acid (salt) type water absorbent resin powder
    4.
    发明授权
    Method for producing polyacrylic acid (salt) type water absorbent resin powder 有权
    聚丙烯酸(盐)型吸水性树脂粉末的制造方法

    公开(公告)号:US08765906B2

    公开(公告)日:2014-07-01

    申请号:US13643682

    申请日:2011-04-27

    IPC分类号: C08G63/02 C08G63/00

    摘要: A water absorbent resin having less fine powder or powdery dust and a controlled particle size is provided, and the water absorption rate of the water absorbent resin is increased by a simple method at low cost, while maintaining or improving other physical properties such as liquid permeability. Disclosed is a method for producing a polyacrylic acid (salt)-type water absorbent resin powder, which includes, in sequence, a step of polymerizing an aqueous solution of acrylic acid (salt)-type monomer; a step of gel-crushing a gel of a water-containing gel-like crosslinked polymer during polymerization or after polymerization; a step of drying the water-containing gel-like crosslinked polymer; and a step of pulverizing and classifying the dried polymer, wherein water absorbent resin fine particles having a particle size of less than 150 μm or a hydrated-particles thereof is added to a step prior to the drying step, and in the drying step, hot air drying is carried out with a hot air having an average flow velocity of 1.0 to 3.0 [m/s], a dew point of 30° C. to 100° C., and a hot air temperature of 140° C. to 235° C.

    摘要翻译: 提供具有较少粉末或粉末粉尘和受控粒度的吸水性树脂,并且通过简单的方法以低成本提高吸水性树脂的吸水率,同时保持或改善其它物理性质如液体渗透性 。 公开了一种聚丙烯酸(盐)型吸水性树脂粉末的制造方法,其中,依次包括使丙烯酸(盐)型单体的水溶液聚合的工序; 在聚合过程中或聚合后凝胶化凝胶状凝胶状交联聚合物凝胶的步骤; 干燥含水凝胶状交联聚合物的工序; 将干燥聚合物粉碎并分级的步骤,其中在干燥步骤之前的步骤中加入粒径小于150μm的吸水性树脂微粒或其水合颗粒,并且在干燥步骤中,热 使用平均流速为1.0〜3.0 [m / s],露点为30℃〜100℃,热风温度为140℃〜235℃的热风进行空气干燥 C。

    POLYACRYLIC ACID (SALT), POLYACRYLIC ACID (SALT)-BASED WATER-ABSORBING RESIN, AND PROCESS FOR PRODUCING SAME
    5.
    发明申请
    POLYACRYLIC ACID (SALT), POLYACRYLIC ACID (SALT)-BASED WATER-ABSORBING RESIN, AND PROCESS FOR PRODUCING SAME 审中-公开
    聚丙烯酸(盐),聚丙烯酸(盐) - 水吸收树脂及其生产方法

    公开(公告)号:US20130037708A1

    公开(公告)日:2013-02-14

    申请号:US13643498

    申请日:2011-04-26

    IPC分类号: C08L33/02 H01J49/26

    摘要: Disclosed are a polyacrylate (salt) and a polyacrylate (salt) water-absorbent resin containing a tracer which can be verified back to the manufacturing process of the water-absorbent resin when dealing with various problems with the water-absorbent resin which can occur from the manufacturing process of the water-resistant resin, during the use thereof by a consumer, up until the disposal thereof. The disclosed polyacrylate (salt) and the polyacrylate (salt) water-absorbent resin have a carbon stable isotope ratio (δ13C) of at least −20% when measured by accelerator mass spectrometry.

    摘要翻译: 公开了含有示踪剂的聚丙烯酸酯(盐)和聚丙烯酸酯(盐)吸水性树脂,当遇到吸水性树脂的各种问题时,该吸水性树脂可以回溯到吸水性树脂的制造过程, 防水树脂在消费者使用期间的制造过程直至其处理。 当通过加速器质谱法测量时,所公开的聚丙烯酸酯(盐)和聚丙烯酸酯(盐)吸水性树脂具有至少-20%的碳稳定同位素比(δ13C)。

    WATER-ABSORBABLE POLYACRYLIC ACID RESIN POWDER, AND PROCESS FOR PRODUCTION THEREOF
    8.
    发明申请
    WATER-ABSORBABLE POLYACRYLIC ACID RESIN POWDER, AND PROCESS FOR PRODUCTION THEREOF 有权
    水可吸收聚丙烯酸树脂粉及其生产方法

    公开(公告)号:US20120258851A1

    公开(公告)日:2012-10-11

    申请号:US13518438

    申请日:2010-12-23

    IPC分类号: B01J20/26 B01J20/32 B01J20/30

    摘要: A process according to the present invention for production of water-absorbable polyacrylic acid resin powder, including: (a) polymerizing an acrylic acid-based monomer aqueous solution containing bubbles, and (b) drying a hydrogel crosslinked polymer thus obtained in the step of polymerizing, further includes (c) lowering solubility of dissolved gas in a monomer aqueous solution in the presence of a surfactant and/or a dispersing agent, so as to generate the bubbles in the acrylic acid-based monomer aqueous solution. With this arrangement, it is possible to provide white water-absorbable resin with better water absorbing rate, keeping or without significantly losing the other properties (permeability potential, bulk specific gravity, surface tension, absorbency against pressure, impact resistance, etc.)

    摘要翻译: 根据本发明的用于制造吸水性聚丙烯酸树脂粉末的方法,包括:(a)使含有气泡的丙烯酸类单体水溶液聚合,和(b)将由此得到的水凝胶交联聚合物干燥, 聚合,还包括(c)在表面活性剂和/或分散剂存在下降低溶解气体在单体水溶液中的溶解度,以便在丙烯酸类单体水溶液中产生气泡。 通过这种布置,可以提供具有更好吸水率的白色吸水性树脂,保持或不显着损失其它性能(渗透性潜力,体积比重,表面张力,抗压力,耐冲击性等)

    Absorbent article with water-absorbing agent or agents
    9.
    发明授权
    Absorbent article with water-absorbing agent or agents 有权
    具有吸水剂或制剂的吸收制品

    公开(公告)号:US08076530B2

    公开(公告)日:2011-12-13

    申请号:US12324164

    申请日:2008-11-26

    IPC分类号: A61F13/15 A61F13/20

    CPC分类号: A61L15/26 C08L71/02

    摘要: An absorbent article comprising an absorbent core, which comprises a primary water-absorbing agent that can serve as a acquisition and preferably temporarily storage material for fluids, such as urine, and that has a CRC of up to 20 g/g and that comprises a compound that includes a constitutional unit derived from polyalkyleneglycol and that is other than an unsaturated monomer and that comprises a polyvalent metal salt. The absorbent article is preferably an infant (toddler, baby) diaper, including training pant, or adult incontinent article (e.g. a pad, diaper).

    摘要翻译: 一种吸收制品,其包括吸收芯,其包含主要吸水剂,其可以用作收集物,并且优选地临时储存用于诸如尿液的流体,并且具有高达20g / g的CRC,并且其包含 化合物,其包含衍生自聚亚烷基二醇的结构单元,并且不是不饱和单体并且包含多价金属盐。 吸收性物品优选为婴儿(幼儿,婴儿)尿布,包括训练裤,或成人失禁用品(例如衬垫,尿布)。