Photosensitive resin composition
    1.
    发明授权
    Photosensitive resin composition 有权
    感光树脂组合物

    公开(公告)号:US06280905B1

    公开(公告)日:2001-08-28

    申请号:US09556528

    申请日:2000-04-21

    IPC分类号: G03F7032

    摘要: A photosensitive resin composition which comprises (1) a particulate copolymer comprising 10-99.8% by mole of the unit of (i) an aliphatic conjugated diene monomer, 0.1-30% by mole of the unit of (ii) a monomer having one polymerizable unsaturated group and an amino group, 0.1-20% by mole of the unit of (iii) a monomer having at least two polymerizable unsaturated groups and 0-40% by mole of the unit of (iv) a copolymerizable other monomer having one polymerizable unsaturated group, (2) a photopolymerizable unsaturated monomer and (3) a photopolymerization initiator typically represented by 9-fluorenone or 2-i-propylthioxanthone. A photosensitive resin composition is provided which can be developed by using water, has a low hardness and high resilience, and is excellent in balance of properties.

    摘要翻译: 一种感光性树脂组合物,其包含(1)包含(i)脂肪族共轭二烯单体的单元的10-99.8摩尔%的粒状共聚物,(ii)具有一个可聚合的单体的单元的0.1-30摩尔% 不饱和基团和氨基,0.1-20摩尔%的单元(iii)具有至少两个可聚合不饱和基团的单体和0-40摩尔%的单元(iv)可共聚的其它单体,其具有一个可聚合的 不饱和基团,(2)可光聚合的不饱和单体和(3)通常用9-芴酮或2-异丙基噻吨酮代表的光聚合引发剂。提供一种可通过使用水显影,具有低硬度和高的光敏树脂组合物 弹性,并且性能优越。

    Polymeric material for laser processing and a laminated body for laser processing thereof, flexographic printing plate and the method of producing the same, and a seal material
    2.
    发明申请
    Polymeric material for laser processing and a laminated body for laser processing thereof, flexographic printing plate and the method of producing the same, and a seal material 审中-公开
    激光加工用聚合材料及其激光加工用层叠体,柔性版印刷版及其制造方法,以及密封材料

    公开(公告)号:US20050277061A1

    公开(公告)日:2005-12-15

    申请号:US11158076

    申请日:2005-06-22

    IPC分类号: B41C1/05 B41N1/00 G03F7/00

    CPC分类号: B41C1/05 B41N1/12

    摘要: The object of the present invention is to provide a polymeric material without odors or fuming and with reduced stickiness of the worked surface of material for seals and workability during laser processing, and the flexographic printing plate and sealing material made of the polymeric material having excellent characteristics of laser processing and having sufficient carving depth. The polymeric material of the present invention is characterized in that the polymeric material is made by crosslinking a polymer composition comprising a polymer which contains an ethylene unit as a repeating unit in content of 45% or more by mass and an organic peroxide. Another object of the present invention is to provide a laminated body for laser processing with excellent workability upon laser processing and a flexographic printing plate with excellent printing performance and workability and a method for fabricating the same. The laminated body for laser processing of the present invention comprises a polymer layer for laser processing which is fabricated by crosslinking a polymer composition containing an ethylenic copolymer, and a base layer laminated on one of the surfaces of the polymer layer for laser processing, whereby peeling the polymer layer for laser processing from the base layer at the interface.

    摘要翻译: 本发明的目的是提供一种不含气味或发烟的聚合物材料,并且在激光加工期间用于密封材料的加工表面和可加工性的降低的粘性,以及由具有优异特性的聚合材料制成的柔性版印刷版和密封材料 的激光加工并具有足够的雕刻深度。 本发明的聚合物材料的特征在于,聚合物材料是通过将包含含有作为重量单元的乙烯单元的聚合物的聚合物组合物以45质量%以上的含量和有机过氧化物交联而制成的。 本发明的另一个目的是提供一种激光加工的具有优异的加工性的激光加工用层叠体和具有优异的印刷性能和加工性的柔性版印刷版及其制造方法。 本发明的激光加工用层叠体包括激光加工用聚合物层,该聚合物层通过交联含有乙烯类共聚物的聚合物组合物和层叠在该激光加工用聚合物层的一个表面上的基材层而制成, 用于激光加工的聚合物层,从界面处的基底层。

    Water-developable photosensitive resin composition
    3.
    发明授权
    Water-developable photosensitive resin composition 失效
    水显影感光树脂组合物

    公开(公告)号:US6140017A

    公开(公告)日:2000-10-31

    申请号:US37538

    申请日:1998-03-10

    IPC分类号: G03F7/033 G03C1/73

    摘要: A water-developable photosensitive resin composition which comprises:(1) a particulate copolymer comprising, as recurring units in the copolymer, (a) 10 to 95 mole % of an aliphatic conjugated diene unit, (b) 0.1 to 30 mole % of a monomer unit having at least one polymerizable unsaturated group and at least one functional group selected from the group consisting of carboxyl group, amino group, hydroxyl group, epoxy group, sulfonic acid group and phosphoric acid group, and (c) 0.1 to 20 mole % of a monomer unit having at least two polymerizable unsaturated groups;(2) at least one copolymer selected from the group consisting of (i) a block-like copolymer composed of two or more polymeric segments having a sulfonic acid group in at least one of the polymeric segments, (ii) a block-like copolymer composed of two or more polymeric segments having a polyurethane segment in at least one of the polymeric segments, and (iii) a copolymer of ethylene and an .alpha.-olefin having 3 to 20 carbon atoms;(3) a photopolymerizable unsaturated compound; and(4) a photopolymerization initiator.

    摘要翻译: 一种水显影性感光性树脂组合物,其特征在于,含有:(1)作为共聚物中的重复单元的(a)10〜95摩尔%的脂肪族共轭二烯单元,(b)0.1〜30摩尔% 具有至少一个可聚合不饱和基团和至少一个选自羧基,氨基,羟基,环氧基,磺酸基和磷酸基的官能团的单体单元,和(c)0.1-20摩尔% 具有至少两个可聚合不饱和基团的单体单元; (2)至少一种共聚物,其选自(i)由两个或更多个在至少一个聚合物链段中具有磺酸基的聚合物链段组成的嵌段共聚物,(ii)嵌段共聚物 由两个或更多个在至少一个聚合物链段中具有聚氨酯链段的聚合物链段组成,和(iii)乙烯和具有3-20个碳原子的α-烯烃的共聚物; (3)光聚合性不饱和化合物; 和(4)光聚合引发剂。

    Water-developable photosensitive resin composition
    7.
    发明授权
    Water-developable photosensitive resin composition 失效
    水显影感光树脂组合物

    公开(公告)号:US5837421A

    公开(公告)日:1998-11-17

    申请号:US904267

    申请日:1997-07-31

    CPC分类号: G03F7/033

    摘要: A photosensitive resin composition is provided which is excellent in water developability, impact resilience, resin plate strength after exposure, breaking extension, and resin-plate transparency. The composition comprises: (1) a granular copolymer produced by polymerizing a monomer mixture comprising: (i) an aliphatic conjugated diene monomer; (ii) a monomer expressed by the general formula (I): ##STR1## (in which R.sup.1 represents a hydrogen atom or a methyl group, R.sup.2 represents an alkylene group having a carbon number of 3 to 20, and l represents an integer of 1 to 20); (iii) a monomer having at least two addition-polymerizable groups, and (iv) an addition-polymerizable monomer other than (i), (ii) and (iii), if desirable; (2) a photo-polymerizable unsaturated monomer; (3) an amino group-containing compound, and (4) a photo-polymerization initiator.

    摘要翻译: 提供一种感光性树脂组合物,其具有优异的水显影性,冲击弹性,曝光后的树脂板强度,断裂伸长和树脂板透明度。 组合物包括:(1)通过聚合单体混合物制备的颗粒共聚物,其包含:(i)脂族共轭二烯单体; (ii)由通式(I)表示的单体:n原子或甲基,R 2表示碳原子数3〜20的亚烷基,l表示1〜20的整数)表示的单体。 (iii)具有至少两个可加成聚合基团的单体,和(iv)除(i),(ii)和(iii)之外的可加成聚合单体,如果需要; (2)光聚合性不饱和单体; (3)含氨基化合物,(4)光聚合引发剂。

    Water developable photosensitive resin composition
    8.
    发明授权
    Water developable photosensitive resin composition 失效
    水可显影光敏树脂组合物

    公开(公告)号:US5736298A

    公开(公告)日:1998-04-07

    申请号:US536494

    申请日:1995-10-02

    IPC分类号: G03F7/027 G03F7/033 G03C1/73

    CPC分类号: G03F7/027 G03F7/033

    摘要: A photo-sensitive resin composition is provided which contains (1) a particulate polymer of a carboxy-group-containing-diene having a cross-linked structure; (2) a polymer having two or more photo-polymerizable unsaturated groups at its molecular chain terminals, and, optionally, a photo-polymerizable unsaturated group, carboxyl group, hydroxy group, amino group, or epoxy group in side chains, or (2') a non-diene-type polymer having a photo-polymerizable unsaturated group, carboxyl group, hydroxy group, amino group, or epoxy group in side chains, or a low molecular weight linear diene-type polymer; (3) a photo-polymerizable unsaturated monomer; (4) a polymer containing an amino group; and (5) a photo-polymerization initiator. The photo-sensitive resin composition has excellent water-developing capability and shows almost no swelling in water, causing minimal reduction in strength and only minimal dimensional changes during development. Resin plates prepared from the composition possess excellent strength after exposure to light, excellent elongation at break, impact resilience and superb transparency, providing a good characteristic balance of properties.

    摘要翻译: 提供了一种光敏树脂组合物,其包含(1)具有交联结构的含羧基的二烯的颗粒状聚合物; (2)在其分子链末端具有两个以上的光聚合性不饱和基团的聚合物,以及任选的侧链中的光聚合性不饱和基团,羧基,羟基,氨基或环氧基,或(2 ')侧链中具有光聚合性不饱和基团,羧基,羟基,氨基或环氧基的非二烯类聚合物,或低分子线型二烯类聚合物; (3)光聚合性不饱和单体; (4)含有氨基的聚合物; 和(5)光聚合引发剂。 感光树脂组合物具有优异的水显影能力,并且在水中几乎没有溶胀,在显影期间几乎不降低强度并且只有极小的尺寸变化。 由组合物制备的树脂板在曝光后具有优异的强度,优异的断裂伸长率,抗冲击弹性和极好的透明度,提供良好的性能特征平衡。