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公开(公告)号：US5824390A
公开(公告)日：1998-10-20
申请号：US504309
申请日：1995-07-20
申请人： Katsura Ochi , Osamu Tanaka , Masaki Yoshizawa
发明人： Katsura Ochi , Osamu Tanaka , Masaki Yoshizawa
CPC分类号： G02B5/128 , Y10T156/109 , Y10T428/24364 , Y10T428/24372 , Y10T428/24421 , Y10T428/24562 , Y10T428/24876 , Y10T428/252
摘要： The present invention provides a method for producing retroreflective sheeting useful for marking or the like of signs such as road signs and construction signs; number plates of vehicles such as motorcars and motorcycles; materials for safety such as clothes and life jackets; signboards, etc., and the method is a method for producing retroreflective sheeting, which comprises embedding glass beads substantially in a monolayer in a temporary support at least one surface of which is composed of a thermoplastic resin in such a manner that at least part of each bead is embedded in the thermoplastic resin; forming a vapor-deposited metal film on the surface in which the glass beads were embedded; superposing thereon a thermoformable support film; pressing the resultant superposed matter under heating to embed the vapor-deposited metal film portion of each of the glass beads in the support film; and peeling the temporary support from the superposed matter in such a manner that the glass beads remain in the support film, said method being characterized in that a thin film containing a coupling agent is previously formed on the vapor-deposited metal film of the temporary support in which the glass beads are embedded and on which the vapor-deposited metal film is then formed, and then the support film is superposed thereon.
摘要翻译： 本发明提供一种用于生产可用于诸如道路标志和施工标志等标志的标记等的回射片材的方法; 车辆如摩托车和摩托车的车牌; 用于安全的材料，如衣服和救生衣; 招牌等，该方法是制造回射片的方法，其包括将基本上在单层中的玻璃珠嵌入临时支撑体中，其中至少一个表面由热塑性树脂构成，使得至少部分 每个珠子都嵌入热塑性树脂中; 在其中嵌入玻璃珠的表面上形成气相沉积金属膜; 在其上叠加可热成型支撑膜; 在加热下压制所得的叠加物，将每个玻璃珠的蒸镀金属膜部分嵌入支撑膜中; 以及将玻璃珠保持在支撑膜中的方式从重叠物质剥离临时支撑体，其特征在于，在临时支撑体的蒸镀金属膜上预先形成含有偶联剂的薄膜 其中嵌入玻璃珠，然后在其上形成气相沉积的金属膜，然后将载体膜叠加在其上。
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公开(公告)号：US6110574A
公开(公告)日：2000-08-29
申请号：US894064
申请日：1997-08-12
申请人： Katsura Ochi , Osamu Tanaka , Masaki Yoshizawa
发明人： Katsura Ochi , Osamu Tanaka , Masaki Yoshizawa
CPC分类号： G09F13/16 , Y10T428/263 , Y10T428/264 , Y10T428/265 , Y10T428/2891 , Y10T428/3154 , Y10T428/31935
摘要： The present invention provides a retroreflective sheeting comprising:a base retroreflective sheeting having a flat front face layer at the light-incident side, anda fluorine-contained resin film having a total light transmittance of at least 80%, laminated on the flat front face layer of the base retroreflective sheeting via an adhesive layer.This retroreflective sheeting is low in extent of freezing or snow sticking on the surface when used in cold districts, and shows excellent stain removability even for the stain made on the surface by mischief with a paint, an ink or the like.
摘要翻译： PCT No.PCT / JP95 / 02538 Sec。 371日期：1997年8月12日 102（e）日期1997年8月12日PCT提交1995年12月12日PCT公布。 公开号WO97 / 22098 日期：1996年6月19日本发明提供一种逆反射片，其特征在于，包括：在所述光入射侧具有平坦的正面层的底座回射片和全透光率为80％以上的含氟树脂膜， 通过粘合剂层在底座后向反光片的平坦的前表面层上。 当在冷区中使用时，这种回射片材在表面上的冻结或积雪程度低，并且甚至对于通过涂料，油墨等的恶作剧在表面上产生的污渍也显示出优异的除污性。
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公开(公告)号：US5812316A
公开(公告)日：1998-09-22
申请号：US424362
申请日：1995-04-21
申请人： Katsura Ochi , Masaki Yoshizawa , Osamu Tanaka
发明人： Katsura Ochi , Masaki Yoshizawa , Osamu Tanaka
IPC分类号： B32B7/14 , B32B27/00 , B32B27/14 , B60R13/10 , C09D5/00 , E01F9/015 , E01F9/04 , G02B5/124 , G02B5/128 , G09F13/16
摘要： A method for making retroreflective sheeting comprising the steps of placing a light-transmittable protective film on glass beads in a support sheet which consists of a binder layer and a reinforcing layer, and which is provided with retroreflective glass beads embedded in the binder layer, and thermoforming parts of the support sheet under heating and pressure so as to partially bond the binder layer of the support sheet to the protective film, which is characterized in that the reinforcing layer of the support sheet consists of a crosslinkable resin having shearing stress S in the range of 6.times.10.sup.6 -1.2.times.10.sup.7 dyne/cm.sup.2 before the thermoforming. A retroreflective sheeting made by this method has a high uniformity of the joint portions of the support sheet and protective film. Even when this retroreflective sheeting is used outdoors for a long period of time, troubles including peeling-off of the protective film do not substantially occur. This retroreflective sheeting can be utilized extensively as a road sign board, a license plate for a vehicle, a sign board for construction work and an advertisement board.
摘要翻译： PCT No.PCT / JP92 / 01407 Sec。 371日期1995年04月21日 102（e）日期1995年4月21日PCT提交1992年10月30日PCT公布。 出版物WO94 / 10591 日期1994年5月11日一种制造逆反射片材的方法，包括以下步骤：将玻璃珠上的透光保护膜放置在由粘合剂层和增强层组成的支撑片中，并且设置有嵌入在该反射片中的回射玻璃珠 粘合剂层和支撑片材的热成形部分，以便将支撑片材的粘合剂层部分地粘合到保护膜上，其特征在于支撑片材的增强层由具有剪切力的可交联树脂 在热成型之前，应力S在6×10 6 -1.2×10 7达因/ cm 2的范围内。 通过该方法制造的回射片材具有支撑片和保护膜的接合部分的高均匀性。 即使在长时间使用这种逆反射片材的情况下，基本上不发生包括剥离保护膜的麻烦。 这种逆反射片材可广泛用于道路标志牌，车辆牌照，建筑工程标牌和广告牌。
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公开(公告)号：US5601915A
公开(公告)日：1997-02-11
申请号：US404608
申请日：1995-03-15
申请人： Katsura Ochi , Masaki Yoshizawa , Osamu Tanaka
发明人： Katsura Ochi , Masaki Yoshizawa , Osamu Tanaka
CPC分类号： G02B5/128 , Y10T428/234 , Y10T428/25 , Y10T428/252 , Y10T428/254 , Y10T428/2996 , Y10T428/2998 , Y10T428/31504 , Y10T428/3188
摘要： Retroreflective sheeting having excellent weatherability under prolonged outdoor use, which comprises a support sheet in one side of which retroreflective glass beads are embedded as substantially a monolayer in such a manner that at least their non-reflective portions are exposed on said sheet; and a light-transmittable protective film provided on the glass beads on said support sheet, said protective film being partially fixed onto the support sheet; in which at least the surface layer of the support sheet in which the glass beads are embedded is formed of a resin composition comprising (a) thermofusible resin(s) having a glass transition temperature not higher than 50.degree. C. and (a) cellulose derivative(s) having a glass transition temperature not lower than 90.degree. C.
摘要翻译： 在长时间的户外使用下具有优异的耐候性的回射片材，其包括在其一侧的支撑片，其中回射玻璃珠基本上以单层的形式被嵌入，使得至少其非反射部分暴露在所述片材上; 以及设置在所述支撑片上的所述玻璃珠上的透光保护膜，所述保护膜部分地固定在所述支撑片上; 其中至少包含玻璃珠的支撑片的表面层由包含（a）玻璃化转变温度不高于50℃的热熔性树脂的树脂组合物形成，和（a）纤维素 衍生物的玻璃化转变温度不低于90℃
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公开(公告)号：US5601911A
公开(公告)日：1997-02-11
申请号：US587760
申请日：1995-11-22
申请人： Katsura Ochi , Osamu Tanaka , Manabu Ogawa
发明人： Katsura Ochi , Osamu Tanaka , Manabu Ogawa
CPC分类号： G02B5/124 , G02B5/128 , Y10S428/913 , Y10T428/249953 , Y10T428/249958 , Y10T428/249961 , Y10T428/31504 , Y10T428/31663 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31942
摘要： This invention provides a capsule type retroreflective sheeting excelling in strength and longterm weatherability, the connecting walls, which partially connect the light-transmitting protective film and support film while retaining the spaces between the two films, being free of internal flaws such as deficiently filled portions and having uniform structure and shape. The capsule type retroreflective sheeting in which the connecting walls are formed by partially thermofusing and thermoforming the support film is characterized in that the support film is composed of a resin composition which contains a thermofusible rein and a crosslinking agent, said thermofusible resin having a shearing stress at 180.degree. C. within a range of 9.times.10.sup.3 .times.1.times.10.sup.5 dyne/cm.sup.2, and which can form a non-fusible crosslinked resin having a shearing stress at 180.degree. C. of at least 1.times.10.sup.6 dyne/cm.sup.2 after the crosslinkage.
摘要翻译： 本发明提供一种具有强度和长期耐候性的胶囊型逆反射片，连接壁部分地连接透光保护膜和支撑膜，同时保持两个膜之间的间隔，没有内部缺陷，例如不充分的部分 并具有均匀的结构和形状。 其中通过部分热熔和热成型支撑膜形成连接壁的胶囊型定向反光片的特征在于，支撑膜由含有热熔性树脂和交联剂的树脂组合物构成，所述热熔性树脂具有剪切应力 在180℃下在9×10 3×1×10 5达因/ cm 2的范围内，并且可以在交联后形成在180℃下具有至少1×10 6达因/ cm 2的剪切应力的不熔融交联树脂。
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6.发明授权
公开(公告)号：US5988821A
公开(公告)日：1999-11-23
申请号：US52
申请日：1998-01-16
申请人： Osamu Tanaka , Kiyohito Hiromitsu , Kunihiro Takao , Katsura Ochi
发明人： Osamu Tanaka , Kiyohito Hiromitsu , Kunihiro Takao , Katsura Ochi
IPC分类号： G02B5/128
CPC分类号： G02B5/128 , Y10S359/90
摘要： This invention relates to lens type functional retroreflective sheeting having retroreflective regions and visual functionality presenting regions, the retroreflective sheeting comprising:a base sheet consisting of a support comprising a functional resin layer containing a functional pigment having light-storing or fluorescent properties, microspherical lens-embedding regions in which microspherical lenses are densely distributed on the surface of the functional resin layer of the support so as to form a mono-layer, and microspherical lens-free regions in which substantially no microspherical lens is embedded and the functional resin layer is exposed;a transparent protective film disposed above the microspherical lens-bearing surface of the base sheet; andbonds at which said base sheet and said transparent protective film are partly bonded together. This lens type functional retroreflective sheeting not only afford good visibility to viewers positioned in the direction of the light source (e.g., automobile drivers), but also afford good visibility at night to drivers and pedestrians positioned in directions different from the that of the light source.
摘要翻译： PCT No.PCT / JP97 / 01649 Sec。 371日期1998年1月16日 102（e）日期1998年1月16日PCT提交1997年5月16日PCT公布。 公开号WO97 / 43670 日期1997年11月20日本发明涉及具有回射区域和视觉功能呈现区域的透镜型功能性反光片材，该回射片材包括：由包含功能性树脂层的载体构成的基片，所述功能性树脂层含有具有光存储或荧光 性质，微球透镜嵌入区域，其中微球透镜密集地分布在支撑体的功能性树脂层的表面上以形成单层，以及微球状透镜区域，其中基本上不嵌入微球透镜， 功能性树脂层露出; 设置在基片的微球透镜支承面上方的透明保护膜; 以及所述基片和所述透明保护膜部分结合在一起的粘合。 这种透镜式功能性反光片不仅能够对位于光源方向（例如，汽车驾驶员）的观看者提供良好的可视性，而且还能够在晚上向位于与光源不同的方向的驾驶员和行人提供良好的可见性 。
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公开(公告)号：US5984479A
公开(公告)日：1999-11-16
申请号：US917286
申请日：1997-08-25
申请人： Katsura Ochi , Osamu Tanaka , Makoto Takeda
发明人： Katsura Ochi , Osamu Tanaka , Makoto Takeda
IPC分类号： G02B5/128
CPC分类号： G02B5/128
摘要： The present invention discloses lens-type retroreflective sheeting excellent in appearance and having constant thickness and desired retroreflective performance, wherein the transparent microspheres in the retroreflective layer are composed of transparent microspherical lenses (A) having a refractive index of 1.8 or more and transparent microspherical fillers (B) having a refractive index different by at least 5% from the refractive index of the lenses (A).
摘要翻译： 本发明公开了外观优异且具有恒定厚度和期望的反光性能的透镜型定向反光片，其中回射层中的透明微球由折射率为1.8以上的透明微球透镜（A）和透明微珠填料 （B）具有与透镜（A）的折射率相差至少5％的折射率。
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公开(公告)号：US5726803A
公开(公告)日：1998-03-10
申请号：US536458
申请日：1995-09-25
申请人： Katsura Ochi , Osamu Tanaka , Makoto Takeda
发明人： Katsura Ochi , Osamu Tanaka , Makoto Takeda
CPC分类号： G02B5/128
摘要： The present invention comprises lens-type retroreflective sheeting which is excellent in appearance and having constant thickness and desired retroreflective performance, wherein the transparent microspheres in the retroreflective layer are composed of transparent microspherical lenses (A) having a refractive index of 1.8 or more and transparent microspherical fillers (B) having a refractive index different by at least 5% from the refractive index of the lenses (A).
摘要翻译： 本发明包括外观优异且具有恒定厚度和期望的反光性能的透镜型回射片，其中回射层中的透明微球由折射率为1.8以上的透明微球透镜（A）和透明微透镜 具有与透镜（A）的折射率相差至少5％的折射率的微球填料（B）。
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公开(公告)号：US20140099229A1
公开(公告)日：2014-04-10
申请号：US14119379
申请日：2012-03-09
申请人： Manabu Watanabe , Masao Yoshida , Osamu Tanaka
发明人： Manabu Watanabe , Masao Yoshida , Osamu Tanaka
IPC分类号： H01M4/38
CPC分类号： H01M4/386 , C22C13/00 , C22C27/025 , C22C28/00 , C22C30/00 , C22C30/04 , H01G11/06 , H01G11/50 , H01M4/0426 , H01M4/134 , H01M4/1395 , H01M4/387 , H01M10/0525 , H01M2220/20 , Y02E60/122 , Y02E60/13 , Y02T10/7022
摘要： A negative electrode active material for an electric device includes an alloy containing Si in a range of greater than or equal to 27% by mass and less than 100% by mass, Sn in a range of greater than 0% by mass and less than or equal to 73% by mass, V in a range of greater than 0% by mass and less than or equal to 73% by mass, and inevitable impurities as a residue. The negative electrode active material can be obtained with, for example, a multi DC magnetron sputtering apparatus by use of Si, Sn, and V as targets. An electric device using the negative electrode active material can achieve long cycle life and ensure a high capacity and cycle durability.
摘要翻译： 用于电子器件的负极活性物质包括含量在大于或等于27质量％且小于100质量％范围内的Si的合金，Sn在大于0质量％的范围内，小于或等于 等于73质量％，V在大于0质量％且小于等于73质量％的范围内，以及不可避免的杂质作为残留物。 负极活性物质可以通过例如使用Si，Sn和V作为靶的多直流磁控溅射装置来获得。 使用负极活性物质的电子装置可以实现长的循环寿命，并确保高容量和循环耐久性。
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10.发明申请公开(公告)号：US20130240800A1
公开(公告)日：2013-09-19
申请号：US13989260
申请日：2011-09-27
申请人： Manabu Watanabe , Osamu Tanaka , Masao Yoshida
发明人： Manabu Watanabe , Osamu Tanaka , Masao Yoshida
IPC分类号： H01M4/38
CPC分类号： H01M4/386 , H01B1/04 , H01M4/0426 , H01M4/134 , H01M4/1395 , H01M4/38 , H01M10/052 , H01M10/0525 , Y02E60/122 , Y02T10/7011
摘要： Disclosed is a negative electrode active material for electrical devices, comprising an alloy having a composition represented by the formula: SixCyAlz. In the composition formula: SixCyAlz, x, y and z represent mass percent values and satisfy the following conditions: x+y+z=100; 36≦x
摘要翻译： 公开了一种电气器件用负极活性物质，其包含具有由下式表示的组成的合金：SixCyAlz。 在组成式中：SixCyAlz，x，y和z表示质量百分数值，满足以下条件：x + y + z = 100; 36 @ x <100; 0
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