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公开(公告)号:US20100130673A1
公开(公告)日:2010-05-27
申请号:US12624558
申请日:2009-11-24
申请人: Kazutoshi ITO , Hiroaki Kizaki , Kunihiro Yamada , Osamu Uchida
发明人: Kazutoshi ITO , Hiroaki Kizaki , Kunihiro Yamada , Osamu Uchida
IPC分类号: C08L83/04
CPC分类号: C10M169/02 , C10M2201/056 , C10M2201/0626 , C10M2229/0415 , C10M2229/0445 , C10M2229/0465 , C10N2220/022 , C10N2220/082 , C10N2230/08 , C10N2230/68 , C10N2250/10 , C10N2270/00
摘要: An invention of a heat-dissipating grease composition characterized by comprising of the following components (A)-(C) is disclosed. Component (A): 100 mass parts of organopolysiloxane wherein a thixotropicity degree α is 1.03-1.50, a viscosity is 100-1,000,000 mPa·s at 25° C.; in this regard, the thixotropicity degree α is η1/η2. Herein, η1 is a measured viscosity at 25° C. measured by a B type rotation viscometer at 6 rpm of a rotor, η2 is a measured viscosity at 25° C. measured by a B type rotation viscometer at 12 rpm of the rotor. Component (B): 5-200 mass parts of hydrolysable organopolysiloxane having three functional groups at one end represented by the following general formula (1); R1 in the formula is an alkyl group having 1-6 carbon atoms, R2 is at least one kind of groups having 1-18 carbon atoms selected from a group consisting of substituted or unsubstituted monovalent hydrocarbon groups, a is an integer of 5-120. Component (C): 200-4,000 mass parts of a thermoconductive inorganic filler having an average particle diameter of 0.1-100 μm and 0.01-50 m2/g of a specific surface.
摘要翻译: 公开了一种散热油脂组合物的发明,其特征在于包括以下组分(A) - (C)。 成分(A):100质量份的触变性α为1.03〜1.50的有机聚硅氧烷,25℃的粘度为100〜100,000mPa·s。 在这方面,触变性α为&eegr; 1 /&eegr; 2。 本文中,1是通过B型旋转粘度计以6rpm的转子测量的25℃下的测量粘度,e是25℃时的测量粘度,通过B型旋转粘度计以12rpm测量 的转子。 组分(B):5-200质量份由下列通式(1)表示的一端具有三个官能团的可水解有机聚硅氧烷; 式中的R1是具有1-6个碳原子的烷基,R2是至少一种选自取代或未取代的一价烃基的具有1-18个碳原子的基团,a是5-120的整数 。 成分(C):200-4,000质量份的平均粒径为0.1-100μm,比表面积为0.01〜50m 2 / g的导热无机填料。
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公开(公告)号:US08383005B2
公开(公告)日:2013-02-26
申请号:US13282797
申请日:2011-10-27
摘要: A thermally conductive silicone grease composition comprising: (A) an organopolysiloxane having at least two alkenyl groups in one molecule and having a kinetic viscosity of 5,000 to 100,000 mm2/s at 25° C.; (B) a hydrolyzable methylpolysiloxane having a trifunctional termination at one end and represented by the following general formula (2): wherein R2 represents an alkyl group having 1 to 6 carbon atoms and b is an integer of 5 to 100; (C) a thermally conductive filler having a thermal conductivity of at least 10 W/m·° C.; (D) an organohydrogenpolysiloxane containing from 2 to 5 hydrogen atoms in one molecule directly bound to silicon atoms (Si—H groups); (E) a bonding aid having a triazine ring and at least one alkenyl group in one molecule; and (F) a catalyst selected from the group consisting of platinum and platinum compounds.
摘要翻译: 一种导热硅脂组合物,其包含:(A)在一个分子中具有至少两个烯基的有机聚硅氧烷,其在25℃下的动力学粘度为5,000至100,000mm 2 / s; (B)在一端具有三官能终止并由以下通式(2)表示的可水解甲基聚硅氧烷:其中R2表示碳原子数1〜6的烷基,b为5〜100的整数。 (C)具有至少10W / m·℃的导热率的导热填料; (D)在一个直接与硅原子结合的分子(Si-H基)中含有2至5个氢原子的有机氢聚硅氧烷; (E)在一个分子中具有三嗪环和至少一个烯基的键合助剂; 和(F)选自铂和铂化合物的催化剂。
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3.
公开(公告)号:US20070042533A1
公开(公告)日:2007-02-22
申请号:US11505435
申请日:2006-08-17
申请人: Akihiro Endo , Kunihiro Yamada , Hiroaki Kizaki , Kei Miyoshi
发明人: Akihiro Endo , Kunihiro Yamada , Hiroaki Kizaki , Kei Miyoshi
CPC分类号: H01L23/3737 , C10M169/04 , C10M2201/041 , C10M2201/05 , C10M2201/053 , C10M2201/061 , C10M2229/041 , C10M2229/0415 , C10M2229/044 , C10M2229/046 , C10N2210/01 , C10N2210/03 , C10N2210/07 , C10N2210/08 , C10N2220/082 , C10N2230/02 , H01L2224/32245 , Y10T428/31663
摘要: Provided is a heat conductive silicone grease composition including (A) 100 parts by mass of an organopolysiloxane containing 2 or more alkenyl groups bonded to silicon atoms within each molecule, (B) an organohydrogenpolysiloxane containing 2 or more hydrogen atoms bonded to silicon atoms within each molecule, in sufficient quantity to provide from 0.1 to 5.0 hydrogen atoms bonded to silicon atoms within the component (B) for each alkenyl group within the component (A), (C) 100 to 2,200 parts by mass of a heat conductive filler, (D) an effective quantity of a platinum-based catalyst, and (E) an effective quantity of an addition reaction retarder, in which the component (C) includes more than 90% by mass and no more than 100% by mass of an indium powder with an average particle size of 0.1 to 100 μm. Also provided is a heat conductive silicone cured product obtained by curing the above composition by heating at a temperature equal to, or greater than, the melting point of the indium powder. Further provided is an electronic device including an electronic component, a heat radiating member, and a heat conductive member including the above cured product disposed between the electronic component and the heat radiating member. Still further provided is a method of curing the above composition. Even further provided is a method of forming a heat conductive member between an electronic component and a heat radiating member. The above heat conductive silicone grease composition generates a suitably thin cured product with excellent thermal conductivity that prevents problems such as the contamination of components other than the coated component, and the leakage of oily materials from the product if used over extended periods.
摘要翻译: 本发明提供一种导热性硅氧烷润滑脂组合物,其包含(A)100质量份在每个分子内含有2个以上与硅原子键合的烯基的有机聚硅氧烷,(B)含有2个以上与各原子中的硅原子键合的氢原子的有机氢聚硅氧烷 分子,提供组分(A),(C)中每个链烯基组分(B)内与硅原子键合的0.1至5.0个氢原子,100至2200质量份的导热填料( D)有效量的铂系催化剂和(E)有效量的加成反应缓凝剂,其中组分(C)包含大于90质量%且不大于100质量%的铟 平均粒径为0.1〜100μm的粉末。 还提供了通过在等于或大于铟粉末的熔点的温度下加热固化上述组合物而获得的导热硅酮固化产物。 还提供了一种电子设备,包括电子部件,散热构件和导热构件,其包括设置在电子部件和散热构件之间的上述固化物。 还提供了固化上述组合物的方法。 进一步提供一种在电子部件和散热部件之间形成导热部件的方法。 上述导热硅脂组合物产生具有优异导热性的合适薄的固化产物,其防止诸如涂层组分之外的组分的污染等问题,以及如果长时间使用则油品从产品中泄漏。
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公开(公告)号:US20050084691A1
公开(公告)日:2005-04-21
申请号:US10958251
申请日:2004-10-06
申请人: Akihiro Endo , Kunihiko Mita , Akio Nakano , Kunihiro Yamada , Hiroaki Kizaki , Hiroaki Tetsuka
发明人: Akihiro Endo , Kunihiko Mita , Akio Nakano , Kunihiro Yamada , Hiroaki Kizaki , Hiroaki Tetsuka
IPC分类号: C08L83/07 , C08K3/08 , C08K5/5419 , C08L83/04 , C08L83/05 , C09K5/14 , H01L23/36 , H01L23/373 , H01L21/60
CPC分类号: H01L23/3737 , C08G77/12 , C08G77/18 , C08G77/20 , C08K3/08 , C08K5/5419 , C08L83/04 , C08L2205/02 , C08L2205/03 , C09K5/14 , H01L2224/16 , H01L2224/73253 , Y10T428/31663 , C08L83/00
摘要: Provided is a curable organopolysiloxane composition which includes (A) an organopolysiloxane containing at least 2 alkenyl groups bonded to silicon atoms within each molecule, (B) an organohydrogenpolysiloxane containing at least 2 hydrogen atoms bonded to silicon atoms within each molecule, (C) gallium and/or an alloy thereof, with a melting point within a range from 0 to 70° C., optionally (D) a heat conductive filler with an average particle size within a range from 0.1 to 100 μm, (E) a platinum based catalyst, and (F) an addition reaction control agent. The composition is useful as a material capable of forming a layer with excellent thermal conductivity that is sandwiched between a heat generating electronic component and a heat radiating member.
摘要翻译: 提供了一种可固化的有机基聚硅氧烷组合物,其包含(A)在每个分子内含有至少2个与硅原子键合的烯基的有机聚硅氧烷,(B)含有与每个分子内的硅原子键合的至少2个氢原子的有机氢聚硅氧烷,(C)镓 和/或其合金,熔点在0-70℃的范围内,任选地(D)平均粒径在0.1-100μm范围内的导热填料,(E)铂基 催化剂,(F)加成反应控制剂。 该组合物可用作能够形成具有优异导热性的层的材料,其夹在发热电子部件和散热构件之间。
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公开(公告)号:US20150001439A1
公开(公告)日:2015-01-01
申请号:US14241652
申请日:2012-05-11
IPC分类号: C09K5/14
CPC分类号: C09K5/14 , C10M169/02 , C10M169/044 , C10M2201/05 , C10M2201/0603 , C10M2201/0606 , C10M2201/0623 , C10M2201/0626 , C10M2203/024 , C10M2203/06 , C10M2215/222 , C10M2229/043 , C10M2229/044 , C10M2229/046 , C10N2210/07 , C10N2220/022 , C10N2230/02 , C10N2230/08 , C10N2240/20 , C10N2240/202 , C10N2250/10
摘要: The present invention provides a thermally conductive grease composition which scarcely increases in hardness during high-temperature heating and has a minimized reduction in growth, containing: (A) an organopolysiloxane including at least two alkenyl groups per molecule, the 25° C. kinetic viscosity being 5,000 to 100,000 mm2/s; (B) a hydrolysable methyl polysiloxane, trifunctional at one terminus, represented by general formula (1) (R1 is a C1-6 alkyl group, and a is an integer 5 to 100); (C) a thermally conductive filler having a thermal conductivity of 10 W/m·° C. or greater; (D) an organohydrogenpolysiloxane containing two to five hydrogen atoms directly bonded to a silicon atom (Si—H group) per molecule; (E) an adhesion promoter having a triazine ring and at least one alkenyl group per molecule; and (F) a catalyst selected from the group consisting of platinum and platinum compounds.
摘要翻译: 本发明提供了一种导热油脂组合物,其在高温加热期间几乎不增加硬度,并且生长最小化,其包含:(A)每分子包含至少两个烯基的有机聚硅氧烷,25℃动力粘度 为5000〜100,000mm2 / s; (B)由通式(1)表示的一端三官能的可水解甲基聚硅氧烷(R 1为C 1-6烷基,a为5〜100的整数)。 (C)导热性为10W / m·℃以上的导热性填料, (D)每分子含有与硅原子(Si-H基)直接键合的2〜5个氢原子的有机氢聚硅氧烷; (E)每分子具有三嗪环和至少一个烯基的粘合促进剂; 和(F)选自铂和铂化合物的催化剂。
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公开(公告)号:US20070149834A1
公开(公告)日:2007-06-28
申请号:US11616185
申请日:2006-12-26
申请人: Akihiro Endo , Kei Miyoshi , Kunihiro Yamada , Hiroaki Kizaki
发明人: Akihiro Endo , Kei Miyoshi , Kunihiro Yamada , Hiroaki Kizaki
CPC分类号: C10M169/02 , C08G77/14 , C08G77/18 , C08G77/20 , C08K3/013 , C08K5/5419 , C08L83/04 , C10M111/04 , C10M2201/0416 , C10M2201/0606 , C10M2201/0616 , C10M2201/0626 , C10M2201/1013 , C10M2203/0213 , C10M2203/102 , C10M2227/04 , C10M2227/045 , C10M2229/0415 , C10M2229/0425 , C10M2229/0435 , C10M2229/0445 , C10M2229/0455 , C10M2229/0465 , C10M2229/0485 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/08 , C10N2220/022 , C10N2220/082 , C10N2230/08 , C10N2240/20 , C10N2240/201 , C10N2240/202 , C10N2250/10 , H01L23/3737 , H01L2924/0002 , C08L2666/44 , C08L2666/54 , H01L2924/00
摘要: Provided is a heat conductive silicone grease composition, including: (A) 100 parts by volume of an organopolysiloxane with a specific structure and with a kinematic viscosity at 25° C. of 10 to 10,000 mm2/s, (B) 0.1 to 50 parts by volume of an alkoxysilane with a specific structure, and (C) 100 to 2,500 parts by volume of a heat conductive filler. The composition exhibits high thermal conductivity, retains excellent fluidity meaning the composition exhibits favorable workability, and is capable of filling fine indentations, thereby reducing contact resistance and providing excellent heat radiation performance. Also, the durability, under conditions of high temperature and high humidity, of the composition is improved, thereby improving the reliability of the composition during actual use. Heat generated by a heat-generating body can be dissipated into a heat-radiating body by sandwiching the composition between the heat-generating body and the heat-radiating body.
摘要翻译: 提供一种导热硅脂组合物,其包括:(A)100体积%的具有特定结构并且在25℃下的运动粘度为10至10,000mm 2的有机聚硅氧烷 ,(B)0.1〜50体积份的具有特定结构的烷氧基硅烷,(C)100〜2,500体积份的导热性填料。 该组合物显示出高导热性,保持了优异的流动性,这意味着组合物表现出良好的加工性,并且能够填充细小的凹痕,从而降低接触电阻并提供优异的散热性能。 此外,在高温高湿条件下的组合物的耐久性得到改善,从而提高了实际使用中组合物的可靠性。 由发热体产生的热量可以通过将组合物夹在发热体和散热体之间而散发到散热体中。
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公开(公告)号:US09321950B2
公开(公告)日:2016-04-26
申请号:US14241652
申请日:2012-05-11
IPC分类号: C09K5/14 , C10M169/02 , C10M169/04
CPC分类号: C09K5/14 , C10M169/02 , C10M169/044 , C10M2201/05 , C10M2201/0603 , C10M2201/0606 , C10M2201/0623 , C10M2201/0626 , C10M2203/024 , C10M2203/06 , C10M2215/222 , C10M2229/043 , C10M2229/044 , C10M2229/046 , C10N2210/07 , C10N2220/022 , C10N2230/02 , C10N2230/08 , C10N2240/20 , C10N2240/202 , C10N2250/10
摘要: The present invention provides a thermally conductive grease composition which scarcely increases in hardness during high-temperature heating and has a minimized reduction in growth, containing: (A) an organopolysiloxane including at least two alkenyl groups per molecule, the 25° C. kinetic viscosity being 5,000 to 100,000 mm2/s; (B) a hydrolysable methyl polysiloxane, trifunctional at one terminus, represented by general formula (1) (R1 is a C1-6 alkyl group, and a is an integer 5 to 100); (C) a thermally conductive filler having a thermal conductivity of 10 W/m·° C. or greater; (D) an organohydrogenpolysiloxane containing two to five hydrogen atoms directly bonded to a silicon atom (Si—H group) per molecule; (E) an adhesion promoter having a triazine ring and at least one alkenyl group per molecule; and (F) a catalyst selected from the group consisting of platinum and platinum compounds.
摘要翻译: 本发明提供了一种导热油脂组合物,其在高温加热期间几乎不增加硬度,并且生长最小化,其含有:(A)每分子包含至少两个烯基的有机聚硅氧烷,25℃动粘度 为5000〜100,000mm2 / s; (B)由通式(1)表示的一端三官能的可水解甲基聚硅氧烷(R 1为C 1-6烷基,a为5〜100的整数)。 (C)导热性为10W / m·℃以上的导热性填料, (D)每分子含有与硅原子(Si-H基)直接键合的2〜5个氢原子的有机氢聚硅氧烷; (E)每分子具有三嗪环和至少一个烯基的粘合促进剂; 和(F)选自铂和铂化合物的催化剂。
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公开(公告)号:US08017684B2
公开(公告)日:2011-09-13
申请号:US11616185
申请日:2006-12-26
申请人: Akihiro Endo , Kei Miyoshi , Kunihiro Yamada , Hiroaki Kizaki
发明人: Akihiro Endo , Kei Miyoshi , Kunihiro Yamada , Hiroaki Kizaki
CPC分类号: C10M169/02 , C08G77/14 , C08G77/18 , C08G77/20 , C08K3/013 , C08K5/5419 , C08L83/04 , C10M111/04 , C10M2201/0416 , C10M2201/0606 , C10M2201/0616 , C10M2201/0626 , C10M2201/1013 , C10M2203/0213 , C10M2203/102 , C10M2227/04 , C10M2227/045 , C10M2229/0415 , C10M2229/0425 , C10M2229/0435 , C10M2229/0445 , C10M2229/0455 , C10M2229/0465 , C10M2229/0485 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/04 , C10N2210/08 , C10N2220/022 , C10N2220/082 , C10N2230/08 , C10N2240/20 , C10N2240/201 , C10N2240/202 , C10N2250/10 , H01L23/3737 , H01L2924/0002 , C08L2666/44 , C08L2666/54 , H01L2924/00
摘要: Provided is a heat conductive silicone grease composition, including: (A) 100 parts by volume of an organopolysiloxane with a specific structure and with a kinematic viscosity at 25° C. of 10 to 10,000 mm2/s, (B) 0.1 to 50 parts by volume of an alkoxysilane with a specific structure, and (C) 100 to 2,500 parts by volume of a heat conductive filler. The composition exhibits high thermal conductivity, retains excellent fluidity meaning the composition exhibits favorable workability, and is capable of filling fine indentations, thereby reducing contact resistance and providing excellent heat radiation performance. Also, the durability, under conditions of high temperature and high humidity, of the composition is improved, thereby improving the reliability of the composition during actual use. Heat generated by a heat-generating body can be dissipated into a heat-radiating body by sandwiching the composition between the heat-generating body and the heat-radiating body.
摘要翻译: 本发明提供一种导热硅脂组合物,其包括:(A)100体积%的具有特定结构且25℃下的运动粘度为10〜10,000mm 2 / s的有机聚硅氧烷,(B)为0.1〜50份 体积的具有特定结构的烷氧基硅烷,(C)100-2,500体积份的导热填料。 该组合物显示出高导热性,保持了优异的流动性,这意味着组合物表现出良好的加工性,并且能够填充细小的凹痕,从而降低接触电阻并提供优异的散热性能。 此外,在高温高湿条件下的组合物的耐久性得到改善,从而提高了实际使用中组合物的可靠性。 由发热体产生的热量可以通过将组合物夹在发热体和散热体之间而散发到散热体中。
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公开(公告)号:US20120119137A1
公开(公告)日:2012-05-17
申请号:US13282797
申请日:2011-10-27
IPC分类号: C09K5/10
摘要: A thermally conductive silicone grease composition comprising: (A) an organopolysiloxane having at least two alkenyl groups in one molecule and having a kinetic viscosity of 5,000 to 100,000 mm2/s at 25° C.; (B) a hydrolyzable methylpolysiloxane having a trifunctional termination at one end and represented by the following general formula (2): wherein R2 represents an alkyl group having 1 to 6 carbon atoms and b is an integer of 5 to 100; (C) a thermally conductive filler having a thermal conductivity of at least 10 W/m·° C.; (D) an organohydrogenpolysiloxane containing from 2 to 5 hydrogen atoms in one molecule directly bound to silicon atoms (Si—H groups); (E) a bonding aid having a triazine ring and at least one alkenyl group in one molecule; and (F) a catalyst selected from the group consisting of platinum and platinum compounds.
摘要翻译: 一种导热硅脂组合物,其包含:(A)在一个分子中具有至少两个烯基的有机聚硅氧烷,其在25℃下的动力学粘度为5,000至100,000mm 2 / s; (B)在一端具有三官能终止并由以下通式(2)表示的可水解甲基聚硅氧烷:其中R2表示碳原子数1〜6的烷基,b为5〜100的整数。 (C)具有至少10W / m·℃的导热率的导热填料; (D)在一个直接与硅原子结合的分子(Si-H基)中含有2至5个氢原子的有机氢聚硅氧烷; (E)在一个分子中具有三嗪环和至少一个烯基的键合助剂; 和(F)选自铂和铂化合物的催化剂。
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公开(公告)号:US07141273B2
公开(公告)日:2006-11-28
申请号:US10958251
申请日:2004-10-06
申请人: Akihiro Endo , Kunihiko Mita , Akio Nakano , Kunihiro Yamada , Hiroaki Kizaki , Hiroaki Tetsuka
发明人: Akihiro Endo , Kunihiko Mita , Akio Nakano , Kunihiro Yamada , Hiroaki Kizaki , Hiroaki Tetsuka
IPC分类号: B05D3/02
CPC分类号: H01L23/3737 , C08G77/12 , C08G77/18 , C08G77/20 , C08K3/08 , C08K5/5419 , C08L83/04 , C08L2205/02 , C08L2205/03 , C09K5/14 , H01L2224/16 , H01L2224/73253 , Y10T428/31663 , C08L83/00
摘要: Provided is a curable organopolysiloxane composition which includes (A) an organopolysiloxane containing at least 2 alkenyl groups bonded to silicon atoms within each molecule, (B) an organohydrogenpolysiloxane containing at least 2 hydrogen atoms bonded to silicon atoms within each molecule, (C) gallium and/or an alloy thereof, with a melting point within a range from 0 to 70° C., optionally (D) a heat conductive filler with an average particle size within a range from 0.1 to 100 μm, (E) a platinum based catalyst, and (F) an addition reaction control agent. The composition is useful as a material capable of forming a layer with excellent thermal conductivity that is sandwiched between a heat generating electronic component and a heat radiating member.
摘要翻译: 提供了一种可固化的有机基聚硅氧烷组合物,其包含(A)在每个分子内含有至少2个与硅原子键合的烯基的有机聚硅氧烷,(B)含有与每个分子内的硅原子键合的至少2个氢原子的有机氢聚硅氧烷,(C)镓 和/或其合金,熔点在0-70℃的范围内,任选地(D)平均粒径在0.1-100μm范围内的导热填料,(E)铂基 催化剂,(F)加成反应控制剂。 该组合物可用作能够形成具有优异导热性的层的材料,其夹在发热电子部件和散热构件之间。
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