摘要:
To present a carbon material which provides an electrical storage device not only ensuring a high energy density but also realizing a high output and an excellent low temperature performance.A negative electrode active material for an electrical storage device employing an aprotic organic solvent electrolyte solution containing a lithium salt as an electrolytes characterized in that it is made of a carbon material having a specific surface area of from 0.01 to 50 m2/g and a total mesopore volume of from 0.005 to 1.0 cc/g, wherein volumes of mesopores having pore diameters of from 100 to 400 Å occupy at least 25% of the total mesopore volume.
摘要:
To present a carbon material which provides an electrical storage device not only ensuring a high energy density but also realizing a high output and an excellent low temperature performance.A negative electrode active material for an electrical storage device employing an aprotic organic solvent electrolyte solution containing a lithium salt as an electrolytes characterized in that it is made of a carbon material having a specific surface area of from 0.01 to 50 m2/g and a total mesopore volume of from 0.005 to 1.0 cc/g, wherein volumes of mesopores having pore diameters of from 100 to 400 Å occupy at least 25% of the total mesopore volume.
摘要:
An organic electrolyte capacitor. The organic capacitor is made up of a positive electrode, a negative electrode, and an electrolyte capable of transporting lithium ions. The organic capacitor exhibits a small change in internal resistance during charge and discharge, a high energy and a high output power, and allows lithium ions to move with ease. This is achieved by having a positive electrode that is able to support lithium ions and anions reversibly, a negative electrode that is able to support lithium ions reversibly, and controlling the ratio of positive electrode active material to negative electrode active material within an optimized range.
摘要:
Discharge at a high current density has been difficult because of problems that an electrolytic solution has low conductivity and absorption and desorption reaction of lithium ions are slow in the negative electrode. However, let a (mAh) be a cell capacity when the organic electrolyte capacitor in a charged state is discharged to half the charging voltage over 1±0.25 hours, and b (mAh) be a negative electrode capacity when the negative electrode in the charged state is discharged to 1.5 V (Li/Li+), then, by controlling a ratio of a positive electrode active material and a negative electrode active material to satisfy 0.05≦a/b≦0.30, it is possible to achieve a high-performance organic electrolyte capacitor having a small internal resistance and a small change in internal resistance during charging and discharging as well a high output density, in which lithium ions are allowed to move with ease.
摘要翻译:由于电解液的导电性低,锂离子的吸附和解吸反应在负极中缓慢的问题,所以难以进行高电流密度的放电。 然而,当充电状态下的有机电解电容器在1±0.25小时内放电至充电电压的一半时,使(mAh)为电池容量,当充电状态下的负极为负极时,将(mAh)设为负极容量 放电至1.5V(Li / Li +),然后通过控制正极活性物质和负极活性物质的比例满足0.05 <= a /b≤0.30的范围, 具有小的内部电阻和充放电期间的内部电阻变化小的高性能的有机电解电容器,以及允许锂离子容易地移动的高输出密度。
摘要:
There is provided an organic electrolyte capacitor having electrodes on current collectors that have holes penetrating the front and rear surfaces, in which electrode materials formed an the through-holes of the current collectors seldom fall off and high energy density and high power density can be obtained. The organic electrolyte capacitor includes positive electrodes, negative electrodes and an electrolyte capable of transferring lithium ions, in which the positive electrodes contain a substance capable of carrying lithium ions and/or anions reversibly as a positive electrode active material, the negative electrodes contain a substance capable of carrying lithium ions as a negative electrode active material, the positive and negative electrodes possess the positive or negative electrode active material layers on an electrode substrate that has conductive layers made of conductive materials on current collectors, which have through-holes, and the negative electrodes carry lithium electrochemically.
摘要:
There is provided an organic electrolyte capacitor having electrodes on current collectors that have holes penetrating the front and rear surfaces, in which electrode materials formed on the through-holes of the current collectors seldom fall off and high energy density and high power density can be obtained. The organic electrolyte capacitor includes positive electrodes, negative electrodes and an electrolyte capable of transferring lithium ions, in which the positive electrodes contain a substance capable of carrying lithium ions and/or anions reversibly as a positive electrode active material, the negative electrodes contain a substance capable of carrying lithium ions as a negative electrode active material, the positive and negative electrodes possess the positive or negative electrode active material layers on an electrode substrate that has conductive layers made of conductive materials on current collectors, which have through-holes, and the negative electrodes carry lithium electrochemically.
摘要:
An organic electrolyte capacitor is provided with a high energy density, a high power and a high capacitance even at −20°. The organic electrolyte capacitor has a high discharge capacity even at a temperature as low as −20° C., while having a high voltage and a high energy density. The structure of the organic electrolyte capacitor includes a positive electrode, a negative electrode, and an electrolyte capable of transporting lithium ions. The positive electrode can reversibly support lithium ions and anions, and the negative electrode can reversibly support the lithium ions by using a mesopored carbon material having a pore volume of 0.10 ml/g or more for a pore diameter of 3 nm or larger.
摘要:
An organic electrolyte capacitor having a high energy density and a high power and having a high capacitance even at −20° C. is provided.According to the organic electrolyte capacitor of the present invention, an organic electrolyte capacitor having a high discharge capacity even at a low temperature state as low as −20° C. while having a high voltage and a high energy density can be attained in an organic electrolyte capacitor having a positive electrode, a negative electrode, and an electrolyte capable of transporting lithium ions, in which the positive electrode can reversibly support lithium ions and anions, and the negative electrode can reversibly support the lithium ions by using a mesopored carbon material having a pore volume of 0.10 ml/g or more for pore diameter of 3 nm or larger.
摘要:
An electrical storage device of the present invention is characterized in that a positive electrode, a negative electrode, a lithium electrode, and an electrolyte capable of transferring lithium ion is included, the lithium electrode is arranged to be out of direct contact with the negative electrode, and lithium ion can be supplied to the negative electrode by flowing a current between the lithium electrode and the negative electrode through an external circuit. With the above characteristic, problems such as non-uniform carrying of lithium ion to the negative electrode, shape-change of a cell, and temperature increase of an electrolytic solution under incomplete sealing of a cell and the like can be easily solved. A using method of the electrical storage device is characterized in that, by using the lithium electrode as a reference electrode, the positive electrode potential and negative electrode potential can be measured, and the potential of the positive or negative electrode can be controlled when the electrical storage device is charged or discharged. Therefore, the potentials of the positive electrode and negative electrode can be monitored, thereby it can be easily determined whether deterioration of the electrical storage device is caused by the positive electrode or the negative electrode. Also, it is possible to control the device with the potential difference between the negative electrode and reference electrode, that is, the negative potential. In addition, when characteristics deteriorate such as the internal resistance increase, an appropriate amount of lithium ion can be supplied to the negative electrode and/or positive electrode by the lithium electrode.
摘要:
An electrical storage device having a positive electrode, a negative electrode, a lithium electrode, and an electrolyte capable of transferring lithium ion, the lithium electrode is out of direct contact with the negative electrode, and lithium ion is supplied to the negative electrode by flowing a current between the lithium and negative electrode through an external circuit. A method of using the electrical storage device includes using the lithium electrode as a reference electrode, the positive electrode potential and negative electrode potential is measured, and the potential of the positive or negative electrode is controlled during charging or discharging. The potentials of the positive electrode and negative electrode are monitored to easily determine whether deterioration of the electrical storage device is caused by the positive or negative electrode. It is possible to control the device with the potential difference between the negative electrode and reference electrode, using the negative potential.