Manufacture of polyisocyanate prepolymers using ethylene glycol and
cellular foams therefrom
    7.
    发明授权
    Manufacture of polyisocyanate prepolymers using ethylene glycol and cellular foams therefrom 失效
    使用乙二醇和泡沫塑料制造多异氰酸酯预聚物

    公开(公告)号:US5164422A

    公开(公告)日:1992-11-17

    申请号:US796956

    申请日:1991-11-25

    IPC分类号: C08G18/10 C08G18/42

    摘要: An isocyanate-terminated quasi-prepolymer is prepared by reacting an organic polyisocyanate and a polyester polyol which comprises the reaction product of a polycarboxylic acid component and ethylene glycol or a mixture of ethylene glycol and at least one other glycol. The use of the quasi-prepolymer in the preparation of rigid cellular polymers, especially polyisocyanurate foams, enhances the thermal insulating properties of the foams, and helps to reduce their cost and blowing agent usage.

    摘要翻译: 异氰酸酯封端的准预聚物是通过使有机多异氰酸酯和聚酯多元醇反应来制备的,所述聚酯多元醇包括多元羧酸组分与乙二醇的反应产物或乙二醇与至少一种其它二醇的混合物。 在制备刚性多孔聚合物,特别是聚异氰脲酸酯泡沫体中使用准预聚物可增强泡沫的隔热性能,有助于降低其成本和发泡剂用量。

    Catalyst for polyisocyanurate foams made with alternative blowing agents
    8.
    发明授权
    Catalyst for polyisocyanurate foams made with alternative blowing agents 失效
    用替代发泡剂制备的聚异氰脲酸酯泡沫的催化剂

    公开(公告)号:US5563180A

    公开(公告)日:1996-10-08

    申请号:US500287

    申请日:1995-07-10

    摘要: Rigid, closed cell polyisocyanurate foams are prepared by reacting together a polyisocyanate and a polyester polyol or a mixture of a polyester polyol and at least one other isocyanate-reactive compound in the presence of (a) a hydrogen-containing blowing agent or a mixture of a hydrogen-containing blowing agent and at least one co-blowing agent and (b) a catalyst mixture comprising (i) a carboxylate salt of an alkali metal or an alkaline earth metal or mixtures thereof, (ii) a quaternary ammonium carboxylate salt, and (iii) optionally a tertiary amine, wherein the mole ratio of carboxylate metal salt: tertiary amine is a value greater than about 2:1, and the total moles of quaternary ammonium carboxylate salt are less than the combined moles of the carboxylate metal salt and the tertiary amine.

    摘要翻译: 通过在(a)含氢发泡剂或其混合物的存在下使多异氰酸酯和聚酯多元醇或聚酯多元醇与至少一种其它异氰酸酯反应性化合物的混合物反应,制备刚性的闭孔聚异氰脲酸酯泡沫体, 含氢发泡剂和至少一种共发泡剂,和(b)催化剂混合物,其包含(i)碱金属或碱土金属的羧酸盐或其混合物,(ii)季铵羧酸盐, 和(iii)任选的叔胺,其中羧酸金属盐:叔胺的摩尔比是大于约2:1的值,并且羧酸季铵盐的总摩尔数小于羧酸盐金属盐的组合摩尔数 和叔胺。