摘要:
A binder/release system for the preparation of molded articles, especially lignocellulosic composites, which utilizes in combination with isocyanate-based binders a fatty material as an internal and/or external release agent, the fatty material being at least one polymerized fatty acid and/or at least one polycarboxyl compound containing a polymeric fatty radical(s).
摘要:
A binder/release system for the preparation of molded articles, especially lignocellulosic composites, which utilizes in combination with isocyanate-based binders a fatty material as an internal and/or external release agent, the fatty material being at least one polymerized fatty acid and/or at least one polycarboxyl compound containing a polymeric fatty radical(s).
摘要:
A synthetic board is prepared by a process of contacting lignocellulosic material with a binder and subsequently forming the treated material into a board by the application of heat and pressure, wherein (a) the binder comprises an organic polyisocyanate and a reactive hydrogen-containing component, especially an aromatic polyester polyol, and (b) the lignocellulosic material is additionally contracted with a surfactant.
摘要:
A closed cell, rigid polymer foam which comprises the reaction product of a polyisocyanate and an isocyanate-reactive component in the presence of a catalyst and a hydrogen-containing blowing agent or a mixture of a hydrogen-containing blowing agent and at least one co-blowing agent wherein the isocyanate-reactive component comprises (a) a hydroxy terminated polyester having an equivalent weight greater than about 350, or (b) a mixture of the hydroxy terminated polyester with at least one other isocyanate-reactive compound. Foams prepared with the hydroxy terminated polyester have superior shrinkage resistance, strength and long-term insulating efficiency.
摘要:
A closed cell, rigid polyisocyanurate foam which comprises the reaction product of a polyisocyanate and a polyol in the presence of (a) a hydrogen-containing blowing agent or a mixture of a hydrogen-containing blowing agent and at least one co-blowing agent, and (b) a siloxane oxyalkylene copolymer (i) having a molecular weight below about 7500 and an oxyalkylene portion containing greater than 60 weight percent of oxyethylene units and (ii) being prepared by the reaction of an organohydrogensiloxane with a polyoxyalkylene in an essentially solventless system or in the presence of a high boiling point polar polyol.
摘要:
Rigid, closed cell polyisocyanurate foams are prepared by reacting together a polyisocyanate and a polyester polyol or a mixture of a polyester polyol and at least one other isocyanate-reactive compound in the presence of (a) a hydrogen-containing blowing agent or a mixture of a hydrogen-containing blowing agent and at least one co-blowing agent and (b) a catalyst mixture comprising (i) a carboxylate salt of an alkali metal or an alkaline earth metal or mixtures thereof, (ii) a tertiary amine, and (iii) a quaternary ammonium carboxylate salt, wherein the mole ratio of carboxylate metal salt: tertiary amine is a value less than about 2:1, and the total moles of quaternary ammonium carboxylate salt are less than the combined moles of the carboxylate metal salt and the tertiary amine.
摘要:
An isocyanate-terminated quasi-prepolymer is prepared by reacting an organic polyisocyanate and a polyester polyol which comprises the reaction product of a polycarboxylic acid component and ethylene glycol or a mixture of ethylene glycol and at least one other glycol. The use of the quasi-prepolymer in the preparation of rigid cellular polymers, especially polyisocyanurate foams, enhances the thermal insulating properties of the foams, and helps to reduce their cost and blowing agent usage.
摘要:
Rigid, closed cell polyisocyanurate foams are prepared by reacting together a polyisocyanate and a polyester polyol or a mixture of a polyester polyol and at least one other isocyanate-reactive compound in the presence of (a) a hydrogen-containing blowing agent or a mixture of a hydrogen-containing blowing agent and at least one co-blowing agent and (b) a catalyst mixture comprising (i) a carboxylate salt of an alkali metal or an alkaline earth metal or mixtures thereof, (ii) a quaternary ammonium carboxylate salt, and (iii) optionally a tertiary amine, wherein the mole ratio of carboxylate metal salt: tertiary amine is a value greater than about 2:1, and the total moles of quaternary ammonium carboxylate salt are less than the combined moles of the carboxylate metal salt and the tertiary amine.
摘要:
A closed cell, rigid polyisocyanurate foam which comprises the reaction product of a polyisocyanate and a polyol in the presence of (a) a hydrogen-containing blowing agent or a mixture of a hydrogen-containing blowing agent and at least one co-blowing agent, and (b) a siloxane oxyalkylene copolymer (i) having a molecular weight below about 7500 and an oxyalkylene portion containing greater than 60 weight percent of oxyethylene units and (ii) being prepared by the reaction of an organohydrogensiloxane with a polyoxyalkylene in an essentially solventless system or in the presence of a high boiling point polar polyol.
摘要:
Rigid cellular polymers are made by reacting an isocyanate-terminated quasi-prepolymer with a polyol component comprising a polyester polyol having a free glycol content of less than about 7 percent by weight of the polyester polyol in the presence of a blowing agent. The combined use of the quasi-prepolymer and the polyester polyol enhances the thermal insulating properties of the foams.