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    Bound zeolite catalyst and process for using said catalyst
    1.
    发明授权
    Bound zeolite catalyst and process for using said catalyst 失效
    结合沸石催化剂和使用所述催化剂的方法

    公开(公告)号：US4648960A

    公开(公告)日：1987-03-10

    申请号：US837780

    申请日：1986-03-10

    申请人： Kenneth R. Poeppelmeier ,  Walter G. Funk ,  John J. Steger ,  Shun C. Fung ,  Virginia R. Cross ,  Jar-Lin Kao

    发明人： Kenneth R. Poeppelmeier ,  Walter G. Funk ,  John J. Steger ,  Shun C. Fung ,  Virginia R. Cross ,  Jar-Lin Kao

    IPC分类号： B01J29/62 ,  C10G35/06 ,  C10G35/095

    CPC分类号： C10G35/095 ,  B01J29/62 ,  B01J2229/26 ,  B01J2229/42

    摘要： A class of bound catalysts which exhibit superior activity maintenance in dehydrocyclization reactions are defined as a type L zeolite having exchangeable cations of which at least 75% are selected from Group IA and calcium and barium cations and containing well dispersed particles of at least one Group VIII noble metal where at least 90% of the noble metal thereof is dispersed in the form of particles having a diameter less than 7 .ANG.. The catalysts may also be identified as type L zeolites loaded with at least one Group VIII noble metal which have a terminal cracking index (as a measure of production of pentanes versus butanes from hexane) of at least 1.5.

    摘要翻译： 在脱氢环化反应中表现出优异的活性维持性的一类结合的催化剂定义为具有可交换阳离子的L型沸石，其中至少75％选自IA族和钙和钡阳离子，并且含有至少一种VIII族的良好分散的颗粒 贵金属，其中至少90％的贵金属以直径小于7安士的颗粒形式分散。 催化剂也可以被鉴定为负载有至少一种VIII族贵金属的L型沸石，其具有至少1.5的末端裂解指数（作为戊烷与己烷的丁烷的生成量的量度）。

    Bound zeolite catalyst
    2.
    发明授权
    Bound zeolite catalyst 失效
    结合沸石催化剂

    公开(公告)号：US4595668A

    公开(公告)日：1986-06-17

    申请号：US550952

    申请日：1983-11-10

    申请人： Kenneth R. Poeppelmeier ,  Walter G. Funk ,  John J. Steger ,  Shun C. Fung ,  Virginia R. Cross ,  Jar-Lin Kao

    发明人： Kenneth R. Poeppelmeier ,  Walter G. Funk ,  John J. Steger ,  Shun C. Fung ,  Virginia R. Cross ,  Jar-Lin Kao

    IPC分类号： B01J29/62 ,  B01J29/74 ,  C10G35/095 ,  B01J29/30

    CPC分类号： C10G35/095 ,  B01J29/62 ,  B01J2229/26 ,  B01J2229/42

    摘要： A class of bound catalysts which exhibit superior activity maintenance in dehydrocyclization reactions are defined as a type L zeolite having exchangeable cations of which at least 75% are selected from Group IA and calcium and barium cations and containing well dispersed particles of at least one Group VIII noble metal where at least 90% of the noble metal thereof is dispersed in the form of particles having a diameter less than 7 .ANG.. The catalysts may also be identified as type L zeolites loaded with at least one Group VIII noble metal which have a terminal cracking index (as a measure of production of pentanes versus butanes from hexane) of at least 1.5.

    摘要翻译： 在脱氢环化反应中表现出优异的活性维持性的一类结合的催化剂定义为具有可交换阳离子的L型沸石，其中至少75％选自IA族和钙和钡阳离子，并且含有至少一种VIII族的良好分散的颗粒 贵金属，其中至少90％的贵金属以直径小于7安士的颗粒形式分散。 催化剂也可以被鉴定为负载有至少一种VIII族贵金属的L型沸石，其具有至少1.5的末端裂解指数（作为戊烷与己烷的丁烷的生成量的量度）。

    Process for loading platinum into Zeolite-L
    3.
    发明授权
    Process for loading platinum into Zeolite-L 失效
    将铂载入沸石-L的方法

    公开(公告)号：US4568656A

    公开(公告)日：1986-02-04

    申请号：US679495

    申请日：1984-12-07

    申请人： Kenneth R. Poeppelmeier ,  Theodore D. Trowbridge ,  Jar-Lin Kao

    发明人： Kenneth R. Poeppelmeier ,  Theodore D. Trowbridge ,  Jar-Lin Kao

    IPC分类号： C07C5/41 ,  B01J29/54 ,  B01J29/62 ,  B01J29/74 ,  C07B61/00 ,  C07C1/00 ,  C07C15/04 ,  C07C67/00 ,  B01J29/32 ,  B01J29/12 ,  B01J29/22

    CPC分类号： B01J29/62

    摘要： A process is provided for loading and uniformly distributing platinum onto a Zeolite-L. The Zeolite-L is contacted with an aqueous solution containing a platinum salt and a non-platinum metal salt, wherein the non-platinum metal salt is present in solution in an amount which is critical to preventing the formation of acid sites as well as avoiding an excess of metal ions in the form of a salt which could block the pores of the Zeolite-L. The Zeolite-L is then aged to allow the platinum to migrate and uniformly distribute throughout the Zeolite.

    摘要翻译： 提供了一种用于将铂均匀分布到Zeolite-L上的方法。 将沸石-L与含有铂盐和非铂金属盐的水溶液接触，其中非铂金属盐以对防止酸性位点形成至关重要的量存在于溶液中，以及避免 过量的可能阻挡沸石-L的孔的盐形式的金属离子。 然后将沸石-L老化，以允许铂迁移并均匀分布在整个沸石中。

    Preparation and composition of superconducting copper oxides based on Ga-O layers
    4.
    发明授权
    Preparation and composition of superconducting copper oxides based on Ga-O layers 失效
    基于Ga-O层的超导铜氧化物的制备和组成

    公开(公告)号：US5374611A

    公开(公告)日：1994-12-20

    申请号：US956844

    申请日：1992-10-01

    申请人： Bogdan Dabrowski ,  J. T. Vaughey ,  Kenneth R. Poeppelmeier

    发明人： Bogdan Dabrowski ,  J. T. Vaughey ,  Kenneth R. Poeppelmeier

    IPC分类号： H01L39/12 ,  H01L39/24 ,  H01B1/00 ,  H01B12/00

    CPC分类号： H01L39/2419 ,  H01L39/126 ,  Y10S505/777 ,  Y10S505/778

    摘要： A high temperature superconducting material with the general formula GaSr.sub.2 Ln.sub.1-x MxCu.sub.2 O.sub.7.+-.w wherein Ln is selected from the group consisting of La, Ce, Pt, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Y and M is selected from the group consisting of Ca and Sr, 0.2.ltoreq.x.ltoreq.0.4 and w is a small fraction of one. A method of preparing this high temperature superconducting material is provided which includes heating and cooling a mixture to produce a crystalline material which is subsequently fired, ground and annealed at high pressure and temperature in oxygen to establish superconductivity.

    摘要翻译： 一种具有通式GaSr2Ln1-xMxCu2O7 +/- w的高温超导材料，其中Ln选自La，Ce，Pt，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb和Y， M选自Ca和Sr，0.2≤x≤0.4，w是一小部分。 提供了一种制备这种高温超导材料的方法，其包括加热和冷却混合物以产生结晶材料，随后在氧气中在高压和高温下烧制，研磨和退火以形成超导性。

    Oxygen-deficient, barium-containing perovskites
    7.
    发明授权
    Oxygen-deficient, barium-containing perovskites 失效
    缺氧，含钡钙钛矿

    公开(公告)号：US4482644A

    公开(公告)日：1984-11-13

    申请号：US485708

    申请日：1983-04-18

    申请人： Robert A. Beyerlein ,  Allan J. Jacobson ,  Kenneth R. Poeppelmeier

    发明人： Robert A. Beyerlein ,  Allan J. Jacobson ,  Kenneth R. Poeppelmeier

    IPC分类号： B01J23/18 ,  B01J23/84 ,  C01B13/18 ,  C01F17/00 ,  C01G29/00 ,  C01G30/00 ,  C01G49/00 ,  C01G53/00 ,  C07C1/00 ,  C07C2/76 ,  C07C15/02 ,  C07C67/00 ,  B01J23/02 ,  B01J23/10

    CPC分类号： C01B13/185 ,  C01F17/0018 ,  C01G29/00 ,  C01G29/006 ,  C01G49/009 ,  C01G53/006 ,  C01P2002/34 ,  C01P2002/72 ,  C01P2002/88 ,  Y10S502/525

    摘要： A class of oxygen-deficient, barium-containing compounds having a perovskite-type structure may be prepared which are of the formula:Ba.sub.2 M.sub.a M'.sub.2-a O.sub.5+yif M is a trivalent cation, orBa.sub.3 M.sub.a M'.sub.3-a O[7.5-(a/2)+y]if M is a divalent cation, wherein M is Mg, Ca, Sr, Ba, Sc, Y, La, the lanthanides of atomic number 58 or greater, Ni, Fe, Cu,Al, Ga, In, Zn, Cd, Hg, Bi, Tl or a mixture thereof, M' is Sb or Bi, a is equal to or greater than O but less than or equal to 1, and if M is trivalent, y is equal to or greater than 0 but less than 1, and if M is divalent, y is equal to or greater than O but less than (3+a)/2.Preferably, the compounds herein are of the formula:Ba.sub.2 M.sub.a M'.sub.2-a O.sub.5+ywhere M is La or Sc, a is equal to or greater than O but less than or equal to 1 and y is equal to or greater than O but less than 1.This class of compounds are readily reoxidized and therefore are useful in oxidative dehydrogenation reactions.

    摘要翻译： 或者BaMaM'3-aO [7.5-（... m为Mg，Ca，Sr，Ba，Sc，Y，La为原子数为58以上的镧系元素，Ni，Fe，Cu，Al，Ga， In，Zn，Cd，Hg，Bi，Tl或它们的混合物，M'是Sb或Bi，a等于或大于O但小于或等于1，如果M是三价，y等于或 大于0但小于1，如果M是二价的，y等于或大于O但小于（3 + a）/ 2。 优选地，本文的化合物具有下式：Ba2MaM'2-aO5 + y，其中M是La或Sc，a等于或大于O但小于或等于1，y等于或大于O但少于 该类化合物容易被再氧化，因此可用于氧化脱氢反应。

    Oxygen deficient manganese perovskites
    10.
    发明授权
    Oxygen deficient manganese perovskites 失效
    缺氧锰钙钛矿

    公开(公告)号：US4388294A

    公开(公告)日：1983-06-14

    申请号：US288996

    申请日：1981-07-31

    申请人： Kenneth R. Poeppelmeier ,  John M. Longo

    发明人： Kenneth R. Poeppelmeier ,  John M. Longo

    IPC分类号： B01J23/34 ,  C01G45/12

    CPC分类号： B01J23/34

    摘要： Oxygen deficient manganese compounds of the formula CaMnO.sub.2.5 and Ca.sub.2 MnO.sub.3.5 have been prepared by the relatively low temperature reduction of precursors having the formula CaMnO.sub.3 and Ca.sub.2 MnO.sub.4, respectively. These compounds have a perovskite-type structure and are useful in processes requiring solid oxidizing agents, such as oxidative dehydrogenation processes.

    摘要翻译： 通过分别具有式CaMnO 3和Ca 2 MnO 4的前体的相对低的温度降低来制备式CaMnO2.5和Ca2MnO3.5的缺氧锰化合物。 这些化合物具有钙钛矿型结构，并且可用于需要固体氧化剂的方法，例如氧化脱氢方法。