摘要:
A process for preparing a tetrafluoroethylene/fluoro(alkyl vinyl ether) copolymer comprising polymerizing tetrafluoroethylene and fluoro(alkyl vinyl ether) in an aqueous suspension system which comprises a mixed medium of water and a fluorohydrocarbon or a chlorofluorohydrocarbon in a volume ratio of from 1:1 to 10:1 at a temperature of from 0.degree. to 25.degree. C. in the presence of a polymerization initiator of the formula:[Cl(CF.sub.2).sub.n --COO].sub.2 (I)wherein n is an integer of 1 to 10, the copolymer obtained by the process having a small number of unstable terminal groups and excellent flex life.
摘要:
A copolymer comprising monomeric units derived from ethylene, tetrafluoroethylene and a fluorine-containing vinyl monomer which provides the copolymer with side chains having at least one carbon atom, wherein the molar ratio of tetrafluoroethylene and ethylene is from 62:38 to 90:10 and the content of the fluorine-containing vinyl monomer is from 0.1 to 10% by mole based on the total number of mole of ethylene and tetrafluoroethylene, which has improved flexibility and better flame retardance.
摘要:
A laminated rubber stopper comprising a head portion and a leg portion which is to be inserted in an opening of a vessel, wherein at least a leg portion is laminated with a film of a copolymer of tetrafluoroethylene, ethylene and at least one fluorine-containing vinyl monomer copolymerizable with tetrafluoroethylene and ethylene, a molar ratio of tetrafluoroethylene and ethylene being from 62:38 to 90:10 and the amount of the fluorine-containing vinyl monomer being from 0.1 to 10% by mole based on the total number of mole of tetrafluoroethylene and ethylene, which has improved fitting with an opening of a vessel and sealing properties and can be produced with low failure rate.
摘要:
A copolymer of tetrafluoroethylene and a perfluoro(alkyl vinyl ether) having the formula (I):CF.sub.2 .dbd.CF--O--Rf (I)wherein Rf is a perfluoroalkyl group having 3 or 4 carbon atoms; and said copolymer having 1 to 10% by weight of the perfluoro(alkyl vinyl ether) units, having 7 to 20, per 10.sup.6 carbon atoms, of terminal groups --CONH.sub.2, having substantially no --CH.sub.2 OH and no --COF, and having a melt viscosity at 380.degree. C. of 0.1.times.10.sup.4 to 100.times.10.sup.4 poise and a preparation process thereof. The tetrafluoroethylene copolymer is thermally stable and has excellent powder properties. Molded articles thereform have a few bubbles and excellent dimensional stability on heating.
摘要:
A method for producing a fluorine-containing olefin represented by formula (I):Ch.sub.2 .dbd.CFR.sub.f (I)wherein R.sub.f represents a perfluoroalkyl group or a fluoroalkyl group comprising the step of contacting, at a high temperature, hydrogen gas with a 1,1-dihydro-2,2-difluoro alcohol represented by formula (II):HOCH.sub.2 CF.sub.2 R.sub.f (II)wherein R.sub.f represents a perfluoroalkyl group or a fluoroalkyl group.
摘要:
An optical material comprising a copolymer of:(1) ethylene,(2) at least one of tetrafluoroethylene and chlorotrifluoroethylene and(3) olefin having at least one fluoroalkyl group,and a cladding material as used in assembling an optical fiber which comprises the copolymer as defined in above.
摘要:
A copolymer comprising monomeric units of tetrafluoroethylene, ethylene and at least one monomeric compound selected from the group consisting of 2-trifluoromethylpropylene and 2-methyl-1,1,3,3,3-pentafluoropropylene, which has a improved crack resistance at a high temperature.
摘要:
The fine powder of high molecular weight fluorine containing resins having melt viscosities of 106 to 1013 poise, apparent density of 0.4 to 1.5 g/cc, and specific surface area of 2 m2/g or less, mold goods of the fine powder and these production methods. By utilizing the fine powder of high molecular weight flourine containing fused resins that have previously not been employed, the mold goods obtained from the fine powder have fewer liquated particles and have become the most suitable especially for manufacturing semiconductors. The powder's products have greater resistance to flex fatigue, abrasion, resistance, etc.
摘要:
A process for preparing low molecular weight polytetrafluoroethylene having a melting point of 250.degree. C. to 325.degree. C. comprising polymerizing tetrafluoroethylene in at least one polymerization solvent selected from the group consisting of hydrochlorofluorocarbons, hydrofluorocarbons and perfluorocarbons which have boiling points in the range between -10.degree. C. and 70.degree. C. under constant pressure by the supplement of tetrafluoroethylene. According to this process, the low molecular weight polytetrafluoroethylene which is useful as an additive to various materials is produced in the solvent which has a low ozone destruction factor or does not destroy the ozone, under economically advantageous low pressure which can be controlled safely.
摘要:
A copolymer comprising chlorotrifluoroethylene and 0.01 to 1% by mole of perfluoro(alkyl vinyl ether) of the formula:R.sub.f --O--CF.dbd.CF.sub.2 (I)wherein R.sub.f is a C.sub.3 -C.sub.6 perfluoroalkyl group, and having a melt flow rate of 0.01 to 200.times.10.sup.-3 cc/sec., which has good mechanical strength and sufficiently high melting point.