摘要:
The invention relates to a novel impact-resistance modifier, constructed from a core-shell 1 and a shell 2, whereby the core is plastically deformable. The invention is characterised by excellent mechanical properties obtained by a low content of impact-resistance modifier.
摘要:
The invention describes a novel impact modifier, built up from core-shell1- and shell 2, the core being capable of plastic deformation. Good mechanical properties were achieved using a small amount of impact modifier.
摘要:
The invention describes a novel impact modifier, built up from core-shell1- and shell 2, the core being capable of plastic deformation. Good mechanical properties were achieved using a small amount of impact modifier.
摘要:
The present invention relates to a process for preparing aqueous dispersions. The invention also relates to the formation of core-shell particles in aqueous dispersions. The core-shell particles are useful as impact-modifiers for poly(meth)acrylate moulding compositions.
摘要:
The present invention relates to a process for preparing aqueous dispersions. The invention also relates to the formation of core-shell particles in aqueous dispersions. The core-shell particles are useful as impact-modifiers for poly(meth)acrylate moulding compositions.
摘要:
The present invention relates to a process for preparing an aqueous dispersion, by a) forming an initial charge from water and emulsifier, b) adding from 25.0 to 45.0 parts by weight of a first composition comprising A) from 50.0 to 99.9 parts by weight of alkyl methacrylates, B) from 0.0 to 40.0 parts by weight of alkyl acrylates, C) from 0.1 to 10.0 parts by weight of crosslinking monomers and D) from 0.0 to 8.0 parts by weight of styrenic monomers and polymerizing, c) adding from 35.0 to 55.0 parts by weight of a second composition comprising E) from 80.0 to 100.0 parts by weight of (meth) acrylates F) from 0.05 to 10.0 parts by weight of crosslinking monomers and G) from 0.0 to 20.0 parts by weight of styrenic monomers, and polymerizing, d) adding from 10.0 to 30.0 parts by weight of a third composition comprising H) from 50.0 to 100.0 parts by weight of alkyl methacrylates, I) from 0.0 to 40.0 parts by weight of alkyl acrylates and J) from 0.0 to 10.0 parts by weight of styrenic monomers and polymerizing. Features of the process are that e) each polymerization is carried out at a temperature in the range from >60 to
摘要:
Thermoplastically processable polymer mixtures with high solvent resistance. The polymer mixtures are made up ofA) 2-98 wt. % of a polymer that is composed of at least 80 wt. % of monomer units of CH.sub.2 .dbd.CF.sub.2, andB) 98-2 wt. % of a polymer that consists of (.alpha.) 20-90 wt. % of monomer units of Formula I ##STR1## in which R stands for an alkyl group with 1 to 3 carbon atoms and X stands for a ##STR2## and of (.beta.) 80-10 wt. % of a chemically crosslinked polymer with a glass transition temperature below 0.degree. C., that is bonded to at least 5 wt. % of the polymer formed from the monomer of Formula (I).
摘要:
An emulsion polymer having at least three phases, adaptable as an agent for modifying the impact resistance of rigid thermoplastic synthetic resins such as polymethyl methacrylate, and consisting ofA) a rigid core phase of a crosslinked homo- or copolymer,B) an elastomer phase, prepared in the presence of the core material and having a glass transition temperature not above -10.degree. C., comprising a crosslinked resin which includes an arylalkyl acrylate or arylalkyl methacrylate, andC) a rigid shell phase, prepared in the presence of the elastomer phase, having a glass transition temperature of at least 50.degree. C.
摘要:
The invention relates to core-shell structured silicone rubber graft polymers that comprise a core a) from a silicium-organic polymer that corresponds to the general formula (R2SiO2/2)x.(RSiO3/2)y.(SiO4/2)z, wherein x=0 to 99.5 mole %, y=0.5 to 100 mole %, z=0 to 50 mole %, wherein R is the same or different and represents alkyl or alkenyl groups having 1 to 6 C atoms, aryl groups or substituted hydrocarbon groups and at last one shell c) from an organic polymer. The silicone rubber graft copolymers are obtained by producing the organic shell c) by radical polymerization at a temperature of not more than 65° C. and adding the initiator in at least two portions to the reaction vessel, with a further addition at least 2 minutes after start of the polymerization.
摘要:
The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.