公开(公告)号：US06423369B1

公开(公告)日：2002-07-23

申请号：US09557085

申请日：2000-04-21

申请人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Masahiro Asano ,  Takahiro Isozaki

发明人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Masahiro Asano ,  Takahiro Isozaki

IPC分类号： B05D100

CPC分类号： C23C24/045 ,  H01F41/026 ,  Y10S428/90 ,  Y10T428/12049

摘要： A molded product having pores in its surface, an inorganic powder, a fat and oil and media are placed into a treating vessel, and a kinetic energy is supplied to the contents of the treating vessel, thereby forcing the inorganic powder into the pores and hardening it in the pores. In another process, a molded product having pores in its surface and an inorganic powder producing material are placed into a treating vessel, and a kinetic energy is supplied to the contents of the treating vessel, thereby forcing an inorganic powder produced from the inorganic powder producing material into the pores and hardening it in the pores. The inorganic powder producing material performs a role of producing an inorganic powder by the collision of pieces of the inorganic powder producing material against one another, against the molded product and against the inner wall of the vessel, and a role as media for forcing the produced inorganic powder into the pores. Thus, a pore sealing effect can be achieved by cooperation of these roles. Therefore, the process according to the present invention can be carried out selectively and simply in a dry manner for the pores in the molded product to exhibit a pore sealing effect. Then, a corrosion-resistant film such as a plated film having dimensional accuracy can be formed on the surface of the molded product in a subsequent step without exertion of an influence to the surface accuracy of the molded product.

摘要翻译： 将其表面具有孔的成型体，无机粉末，油脂和介质放入处理容器中，向处理容器的内容物供给动能，从而迫使无机粉末进入孔中并硬化 它在毛孔中。 在另一方法中，将具有孔表面的成型体和无机粉末生成材料放入处理容器中，并将动能供给到处理容器的内容物中，从而迫使由无机粉末生成的无机粉末 材料进入毛孔并在毛孔中硬化。 无机粉末生成材料通过使无机粉末生成材料的块彼此相对于模制产品和容器的内壁的碰撞而发挥无机粉末的作用，并且作为用于迫使所生产的 无机粉末进入毛孔。 因此，通过这些作用的合作可以实现孔密封效果。 因此，根据本发明的方法可以以干燥方式选择性地和简单地进行，使成型体中的孔呈孔密封效果。 然后，可以在随后的步骤中在模制品的表面上形成具有尺寸精度的镀膜的耐腐蚀膜，而不影响模制产品的表面精度。

公开(公告)号：US06923898B2

公开(公告)日：2005-08-02

申请号：US10028359

申请日：2001-12-28

申请人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Masahiro Asano ,  Takahiro Isozaki

发明人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Masahiro Asano ,  Takahiro Isozaki

IPC分类号： C25D7/00 ,  C25D3/00 ,  C25D7/04 ,  C25D17/12 ,  C25D17/16 ,  C25D21/00 ,  C25D21/10 ,  H01F7/02 ,  H01F41/02 ,  H02K1/17 ,  H02K1/27 ,  H02K15/03 ,  C25D5/02 ,  C25D5/00 ,  H01F7/06

CPC分类号： H01F41/026 ,  C25D7/04 ,  C25D17/12 ,  Y10T29/49075

摘要： An electroplating device including an anode inserted through and disposed in a hole provided in a work and communicating with the outside, and a member for rotating the work about its center axis and supplying a plating electric current to the work. Alternatively, a separate member may supply the plating electric current to the work. A plating solution in the hole in the work may be allowed to flow. Thus, a uniform plated film can be formed on both of the outer and inner surfaces of the work having the communicating with the outside such as a ring-shaped work, of which a ring-shaped bonded magnet is representative, by using the electroplating device.

摘要翻译： 一种电镀装置，包括插入并设置在设置在工件中并与外部连通的孔中的阳极以及用于使工件围绕其中心轴线旋转并向工件供应电镀电流的构件。 或者，单独的构件可以向工件提供电镀电流。 可以允许工作孔中的电镀液流动。 因此，通过使用电镀装置，可以在具有与外部连通的工件的外表面和内表面上形成均匀的镀膜，例如环形粘合磁体代表的环形工件 。

公开(公告)号：US06348138B1

公开(公告)日：2002-02-19

申请号：US09605866

申请日：2000-06-29

申请人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Masahiro Asano ,  Takahiro Isozaki

发明人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Masahiro Asano ,  Takahiro Isozaki

IPC分类号： C25D1700

CPC分类号： H01F41/026 ,  C25D7/04 ,  C25D17/12 ,  Y10T29/49075

摘要： The present invention provides an electroplating device including an anode inserted through and disposed in a hole provided in a work and communicating with the outside, and a member for rotating the work about its center axis and supplying a plating electric current to the work. Thus, a uniform plated film can be formed on both of the outer and inner surfaces of the work having the hole communicating with the outside such as a ring-shaped work, of which a ring-shaped bonded magnet is representative, by using the electroplating device.

摘要翻译： 本发明提供一种电镀装置，其具有插入并设置在工件中并与外部连通的孔中的阳极，以及用于使工件绕其中心轴旋转并向工件供给电镀电流的构件。 因此，可以在具有与外部连通的孔的工件的外表面和内表面上形成均匀的镀膜，例如环形粘结磁体代表的环形工件，通过使用电镀 设备。

公开(公告)号：US06355313B1

公开(公告)日：2002-03-12

申请号：US09512655

申请日：2000-02-24

申请人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui

发明人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui

IPC分类号： B29C3508

CPC分类号： H01F41/026 ,  C23C10/02 ,  C23C10/34 ,  Y10T428/12063 ,  Y10T428/12465

摘要： A hollow work having a hole communicating with the outside and a fine metal powder producing material are placed into a treating vessel, where the fine metal powder producing material is brought into flowing contact with the surface of the work, thereby adhering a fine metal powder produced from the fine metal powder producing material to the surface of the work. The hollow work may be a ring-shaped bonded magnet. Thus, a film having an excellent corrosion resistance can be formed without use of a third component such as a resin and a coupling agent by providing an electric conductivity to the entire surface of the magnet, i.e., not only to the outer surface (including end faces) but also to the inner surface of the magnet and subjecting the magnet to an electroplating treatment.

摘要翻译： 将具有与外部连通的孔的中空工件和精细的金属粉末生成材料放置在处理容器中，使金属粉末生成材料与工件的表面流动接触，从而粘附生产的细金属粉末 从精细的金属粉末生产材料到工作的表面。 中空的工件可以是环形粘结磁体。 因此，通过向磁体的整个表面提供导电性，即不仅可以形成具有优异耐腐蚀性的膜，而且不需要使用诸如树脂和偶联剂的第三组分， 面），而且还与磁体的内表面并对磁体进行电镀处理。

公开(公告)号：US06281774B1

公开(公告)日：2001-08-28

申请号：US09554013

申请日：2000-05-09

申请人： Takeshi Nishiuchi ,  Kohshi Yoshimura ,  Fumiaki Kikui

发明人： Takeshi Nishiuchi ,  Kohshi Yoshimura ,  Fumiaki Kikui

IPC分类号： H01F702

CPC分类号： H01F41/026 ,  Y10S428/90 ,  Y10T428/256 ,  Y10T428/265

摘要： The present invention provides an Fe—B—R based permanent magnet, which has a chemical conversion coating film formed on its surface with an aluminum film interposed therebetween, the chemical conversion coating film containing at least one of titanium and zirconium, phosphorus, oxygen and fluorine as constituting elements, and a process for producing such an Fe—B—R based permanent magnet. In the permanent magnet, the chemical conversion coating film is adhered firmly to the magnet with the aluminum film interposed therebetween and hence, the magnet is excellent in corrosion resistance. Even if the magnet is left to stand for a long time under high-temperature and high-humidity conditions of a temperature of 80° C. and a relative humidity of 90%, the magnet exhibits a stable high magnetic characteristic which cannot deteriorate. Moreover, the film is free from hexa-valent chromium.

摘要翻译： 本发明提供一种Fe-BR系永久磁铁，其特征在于，具有在其表面形成有铝膜的化学转化膜，所述化学转化膜含有钛，锆，磷，氧，氟中的至少一种，作为 构成元素，以及这种Fe-BR类永久磁铁的制造方法。 在永久磁铁中，化学转化膜与铝磁性膜牢固地粘附在磁铁上，因此，磁铁的耐腐蚀性优异。 即使磁铁在温度80℃，相对湿度90％的高温高湿条件下长时间放置，磁铁表现出稳定的高磁特性，不会劣化。 此外，该膜不含六价铬。

公开(公告)号：US06251196B1

公开(公告)日：2001-06-26

申请号：US09383274

申请日：1999-08-26

申请人： Takeshi Nishiuchi ,  Kohshi Yoshimura ,  Fumiaki Kikui

发明人： Takeshi Nishiuchi ,  Kohshi Yoshimura ,  Fumiaki Kikui

IPC分类号： C23C880

CPC分类号： H01F41/026 ,  Y10T428/12465 ,  Y10T428/12611

摘要： An Fe—B—R based permanent magnet and metal pieces are placed into a treating vessel, where they are vibrated and/or agitated, whereby a metal film is formed on the surface of the magnet. A sol solution produced by the hydrolytic reaction and the polymerizing reaction of a metal compound which is a starting material for a metal oxide film is applied to the metal film and subjected to a heat treatment to form a metal oxide film. Therefore, it is possible to form, on the surface of the magnet, a corrosion-resistant film which can be produced easily and at a low cost without carrying-out of a plating treatment or a treatment using hexa-valent chromium and which has an excellent adhesion to the surface of the magnet and can exhibit a stable high magnetic characteristic which cannot be degraded even if the magnet is left to stand for a long period of time under high-temperature and high-humidity conditions of a temperature of 80° C. and a relative humidity of 90%. Thus, it is possible to provide an Fe—B—R based permanent magnet having an excellent corrosion resistance.

摘要翻译： 将Fe-B-R基永磁体和金属片放置在处理容器中，在其中它们被振动和/或搅动，由此在磁体的表面上形成金属膜。 将作为金属氧化物膜的原料的金属化合物的水解反应和聚合反应产生的溶胶溶液施加到金属膜上，进行热处理，形成金属氧化物膜。 因此，可以在磁体的表面形成耐腐蚀性膜，其可以容易且低成本地生产，而不会进行电镀处理或使用六价铬的处理，并且具有 对磁体表面的附着力优异，能够呈现稳定的高磁特性，即使在80℃以上的高温高湿条件下长时间放置磁体也不会降低 相对湿度为90％。 因此，可以提供耐腐蚀性优异的Fe-B-R系永久磁铁。

公开(公告)号：US07053745B2

公开(公告)日：2006-05-30

申请号：US10068970

申请日：2002-02-11

申请人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui

发明人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui

IPC分类号： H01F7/02

CPC分类号： H01F41/026

摘要： A rare earth metal-based permanent magnet has a film layer formed substantially of only a fine metal powder on a metal forming the surface of the magnet. The rare earth metal-based permanent magnet having the film layer on its surface is produced in the following manner: A rare earth metal-based permanent magnet and a fine metal powder forming material are placed into a treating vessel, where both of them are vibrated and/or agitated, whereby a film layer made of a fine metal powder produced from the fine metal powder producing material is formed on a metal forming the surface of the magnet. Thus, the formation of a corrosion-resistant film such as plated film can be achieved at a high thickness accuracy by forming an electrically conductive layer uniformly and firmly on the entire surface of the magnet without use of a third component such as a resin and a coupling agent.

公开(公告)号：US06444328B1

公开(公告)日：2002-09-03

申请号：US09382588

申请日：1999-08-25

申请人： Takeshi Nishiuchi ,  Fumiaki Kikui ,  Kohshi Yoshimura

发明人： Takeshi Nishiuchi ,  Fumiaki Kikui ,  Kohshi Yoshimura

IPC分类号： B32B1504

CPC分类号： H01F41/026 ,  Y10T428/12465 ,  Y10T428/12611

摘要： An Fe—B—R based permanent magnet has a metal oxide film having a thickness of 0.01 &mgr;m to 1 &mgr;m on its surface with a metal film interposed therebetween. Thus, the film is excellent in adhesion to the surface of the magnet. Even if the permanent magnet is left to stand under. high-temperature and high-humidity of a temperature of 80° C. and a relative humidity of 90% for a long period of time, the magnetic characteristic of the magnet cannot be degraded. The magnet has a thermal shock resistance enough to resist even a heat cycle for a long period of time in a temperature range of −40° C. to 85° C., and can exhibit a stable high magnetic characteristic. Therefore, it is possible to produce an Fe—B—R based permanent magnet having a corrosion-resistant film free from hexa-valent chromium.

摘要翻译： Fe-B-R系永久磁铁的表面的金属氧化物膜的厚度为0.01〜1μm，金属膜插入其间。 因此，该膜对于磁体的表面的附着性优异。 即使将永久磁铁置于下方。 温度高达80℃，相对湿度90％的高温高湿度，磁铁的磁特性不会降低。 该磁体具有足够的耐热冲击性，能够在-40℃至85℃的温度范围内长时间抵抗甚至热循环，并且可呈现稳定的高磁特性。 因此，可以制造具有不含六价铬的耐腐蚀性膜的Fe-B-R系永久磁铁。

公开(公告)号：US06365224B1

公开(公告)日：2002-04-02

申请号：US09558162

申请日：2000-04-26

申请人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Shuji Tsujimoto

发明人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Shuji Tsujimoto

IPC分类号： B05D112

CPC分类号： C23C10/34 ,  C23C10/02 ,  Y10T428/12569 ,  Y10T428/24413 ,  Y10T428/24909 ,  Y10T428/31678 ,  Y10T428/31681

摘要： A resin molded product and a fine metal powder producing material are placed into a treating vessel. The fine metal powder producing material is brought into flowing contact with the surface of the resin molded product, thereby producing a fine metal powder, and forming a metal layer of the fine metal powder directly on the surface of the resin molded product. In this process, the metal layer of the fine metal powder can be formed firmly and at high density on the surface of the resin molded product. The metal layer exhibits a function as an electrically conductive layer. Therefore, a metal film having an excellent thickness accuracy, an excellent surface smoothness and a high peel strength can be formed in a simple manner on the metal layer by carrying out an electroplating treatment. In addition, it is possible for the metal layer itself to exhibit functions or properties such as an ornamentality.

摘要翻译： 树脂成型体和金属粉末生成材料配置在处理容器内。 细金属粉末生成材料与树脂成型体的表面流动接触，从而制造细小的金属粉末，并且在树脂模制品的表面上直接形成金属细粉末的金属层。 在该工序中，金属粉末的金属层能够在树脂成型体的表面上牢固且高密度地形成。 金属层表现出作为导电层的功能。 因此，可以通过进行电镀处理，以简单的方式在金属层上形成具有优异的厚度精度，优异的表面光滑度和高剥离强度的金属膜。 此外，金属层本身可以表现出诸如装饰性的功能或性质。

公开(公告)号：US06863986B2

公开(公告)日：2005-03-08

申请号：US10044986

申请日：2002-01-15

申请人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Shuji Tsujimoto

发明人： Kohshi Yoshimura ,  Takeshi Nishiuchi ,  Fumiaki Kikui ,  Shuji Tsujimoto

IPC分类号： C23C24/04 ,  B32B9/00

CPC分类号： C23C10/34 ,  C23C10/02 ,  Y10T428/12569 ,  Y10T428/24413 ,  Y10T428/24909 ,  Y10T428/31678 ,  Y10T428/31681

摘要： A resin molded product and a fine metal powder producing material are placed into a treating vessel. The fine metal powder producing material is brought into flowing contact with the surface of the resin molded product, thereby producing a fine metal powder, and forming a metal layer of the fine metal powder on the surface of the resin molded product. In this process, the metal layer of the fine metal powder can be formed firmly and at high density on the surface of the resin molded product. The metal layer exhibits a function as an electrically conductive layer. Therefore, a metal film having an excellent thickness accuracy, an excellent surface smoothness and a high peel strength can be formed in a simple manner on the metal layer by carrying out an electroplating treatment. In addition, it is possible for the metal layer itself to exhibit functions or properties such as an ornamentality.

摘要翻译： 树脂成型体和金属粉末生成材料配置在处理容器内。 使细金属粉末生成材料与树脂成型体的表面流动接触，由此生成细金属粉末，并在树脂成型体的表面上形成金属细粉末的金属层。 在该工序中，金属粉末的金属层能够在树脂成型体的表面上牢固且高密度地形成。 金属层表现出作为导电层的功能。 因此，可以通过进行电镀处理，以简单的方式在金属层上形成具有优异的厚度精度，优异的表面光滑度和高剥离强度的金属膜。 此外，金属层本身可以表现出诸如装饰性的功能或性质。