公开(公告)号：US08871567B2

公开(公告)日：2014-10-28

申请号：US13641793

申请日：2011-12-19

申请人： Koichi Hirano ,  Shingo Komatsu ,  Yasuteru Saito ,  Naoki Ike

发明人： Koichi Hirano ,  Shingo Komatsu ,  Yasuteru Saito ,  Naoki Ike

IPC分类号： H01L21/336 ,  H01L29/786 ,  H01L29/66

CPC分类号： H01L29/7869 ,  H01L29/66742 ,  H01L29/66969 ,  H01L29/78693

摘要： The present invention achieves a formation of a metal oxide film of a thin film transistor with a simplified process. The present invention is concerned with a method for manufacturing a field-effect transistor comprising a gate electrode, a source electrode, a drain electrode, a channel layer and a gate insulating layer wherein the channel layer is formed by using a metal salt-containing composition comprising a metal salt, a polyvalent carboxylic acid having a cis-form structure of —C(COOH)═C(COOH)—, an organic solvent and a water wherein a molar ratio of the polyvalent carboxylic acid to the metal salt is in the range of 0.5 to 4.0.

摘要翻译： 本发明通过简化的工艺实现了薄膜晶体管的金属氧化物膜的形成。 本发明涉及一种制造场效应晶体管的方法，该场效应晶体管包括栅电极，源电极，漏电极，沟道层和栅极绝缘层，其中通过使用含金属盐的组合物形成沟道层 包括金属盐，具有-C（COOH）= C（COOH） - 的顺式结构的多元羧酸，有机溶剂和水，其中多价羧酸与金属盐的摩尔比为 范围为0.5至4.0。

公开(公告)号：US20130032797A1

公开(公告)日：2013-02-07

申请号：US13641793

申请日：2011-12-19

申请人： Koichi Hirano ,  Shingo Komatsu ,  Yasuteru Saito ,  Naoki Ike

发明人： Koichi Hirano ,  Shingo Komatsu ,  Yasuteru Saito ,  Naoki Ike

IPC分类号： H01L21/336 ,  H01L29/786

CPC分类号： H01L29/7869 ,  H01L29/66742 ,  H01L29/66969 ,  H01L29/78693

摘要： The present invention achieves a formation of a metal oxide film of a thin film transistor with a simplified process. The present invention is concerned with a method for manufacturing a field-effect transistor comprising a gate electrode, a source electrode, a drain electrode, a channel layer and a gate insulating layer wherein the channel layer is formed by using a metal salt-containing composition comprising a metal salt, a polyvalent carboxylic acid having a cis-form structure of —C(COOH)═C(COOH)—, an organic solvent and a water wherein a molar ratio of the polyvalent carboxylic acid to the metal salt is in the range of 0.5 to 4.0.

摘要翻译： 本发明通过简化的工艺实现了薄膜晶体管的金属氧化物膜的形成。 本发明涉及一种制造场效应晶体管的方法，该场效应晶体管包括栅电极，源电极，漏电极，沟道层和栅极绝缘层，其中通过使用含金属盐的组合物形成沟道层 包括金属盐，具有-C（COOH）= C（COOH） - 的顺式结构的多元羧酸，有机溶剂和水，其中多价羧酸与金属盐的摩尔比为 范围为0.5至4.0。

公开(公告)号：US08999450B2

公开(公告)日：2015-04-07

申请号：US13498563

申请日：2009-09-28

申请人： Yasuteru Saito ,  Naoki Ike

发明人： Yasuteru Saito ,  Naoki Ike

IPC分类号： B05D3/02 ,  C01G25/02 ,  C01G3/00 ,  C01G3/02 ,  C01G9/00 ,  C01G9/02 ,  C01G15/00 ,  C01G19/02 ,  C01G23/04 ,  C01G33/00 ,  C01G37/027 ,  C01G39/02 ,  C01G49/02 ,  C01G53/04 ,  C23C18/12

CPC分类号： C01G25/02 ,  C01G3/00 ,  C01G3/02 ,  C01G9/00 ,  C01G9/02 ,  C01G15/00 ,  C01G19/02 ,  C01G23/04 ,  C01G33/00 ,  C01G37/027 ,  C01G39/02 ,  C01G49/02 ,  C01G53/04 ,  C01P2004/03 ,  C01P2006/82 ,  C23C18/1216 ,  C23C18/1283

摘要： An object of the present invention is to provide a method for manufacturing a substrate having a metal complex film on the surface thereof. According to the present invention, a metal salt-containing composition containing a metal salt, a polyvalent carboxylic acid having a cis-form structure, and a solvent, in which: the molar ratio of the polyvalent carboxylic acid to the metal salt is not less than 0.5 and not more than 4.0; the moisture content of the composition is not less than 0.05% by weight is used in an application method to apply on a substrate. Thereafter, a two-step heat treatment is carried out.

摘要翻译： 本发明的目的是提供一种在其表面上具有金属复合膜的基板的制造方法。 根据本发明，含有金属盐，具有顺式结构的多元羧酸和溶剂的含金属盐的组合物，其中：多价羧酸与金属盐的摩尔比不小于 大于0.5且不大于4.0; 组合物的含水量不小于0.05重量％用于施用于基材上的涂布方法。 此后，进行两步热处理。

公开(公告)号：US20120230900A1

公开(公告)日：2012-09-13

申请号：US13498563

申请日：2009-09-28

申请人： Yasuteru Saito ,  Naoki Ike

发明人： Yasuteru Saito ,  Naoki Ike

IPC分类号： C01B13/00 ,  C01F5/00 ,  C01F11/02 ,  C01F17/00 ,  C01G23/04 ,  C01G25/02 ,  C01G27/02 ,  C01G33/00 ,  C01G35/00 ,  C01G37/02 ,  C01G41/02 ,  C01G49/02 ,  C01G53/04 ,  C01G3/02 ,  C01G5/00 ,  C01F7/02 ,  C01G15/00 ,  C01G19/02 ,  C01G30/00 ,  B05D3/02 ,  C23C30/00 ,  C01G9/02

CPC分类号： C01G25/02 ,  C01G3/00 ,  C01G3/02 ,  C01G9/00 ,  C01G9/02 ,  C01G15/00 ,  C01G19/02 ,  C01G23/04 ,  C01G33/00 ,  C01G37/027 ,  C01G39/02 ,  C01G49/02 ,  C01G53/04 ,  C01P2004/03 ,  C01P2006/82 ,  C23C18/1216 ,  C23C18/1283

摘要： An object of the present invention is to provide a metal salt-containing composition which is applicable to many metal source materials, and can be used for forming a compact and uniform metal oxide film comparable to those formed according to a sputtering method, as well as to provide a substrate having a metal complex film on the surface thereof obtained using the metal salt-containing composition, and a substrate having a metal complex film on the surface thereof obtained by further heating the substrate. Moreover, another object of the present invention is to provide a method for manufacturing a substrate having such a metal complex film on the surface thereof.According to the present invention, a metal salt-containing composition containing a metal salt, a polyvalent carboxylic acid having a cis-form structure, and a solvent, in which: the molar ratio of the polyvalent carboxylic acid to the metal salt is not less than 0.5 and not more than 4.0; the moisture content of the composition is not less than 0.05% by weight is used in an application method to apply on a substrate. Thereafter, a two-step heat treatment is carried out.

摘要翻译： 本发明的目的是提供一种适用于许多金属源材料的含金属盐的组合物，可用于形成与根据溅射法形成的那些相当的紧凑且均匀的金属氧化物膜，以及 提供一种使用含金属盐的组合物在其表面上具有金属络合物膜的基板，以及在其表面上具有通过进一步加热基板而获得的金属络合物膜的基板。 此外，本发明的另一个目的是提供一种在其表面上制造具有这种金属络合物膜的基板的方法。 根据本发明，含有金属盐，具有顺式结构的多元羧酸和溶剂的含金属盐的组合物，其中：多价羧酸与金属盐的摩尔比不小于 大于0.5且不大于4.0; 组合物的含水量不小于0.05重量％用于施用于基材上的涂布方法。 此后，进行两步热处理。

公开(公告)号：US20130291943A1

公开(公告)日：2013-11-07

申请号：US13979200

申请日：2012-01-11

申请人： Yasuteru Saito

发明人： Yasuteru Saito

IPC分类号： H01G9/20

CPC分类号： H01G9/2013 ,  H01G9/2018 ,  H01G9/2031 ,  H01G9/2059 ,  Y02E10/52 ,  Y02E10/542

摘要： Disclosed is a photoelectric conversion element which includes a semiconductor electrode, an opposite electrode, and an electrolyte layer held between the semiconductor electrode and the opposite electrode, and which is a photoelectric conversion element of high practical use using a redox couple which has high transparency and ease of enclosure and exhibits high performance compared to an iodine redox couple. An electrolyte layer includes a redox couple formed of compounds represented by General Formula (1) and Formula (2), and ionic liquid having bis(fluorosulfonyl)imide anion represented by Formula (3).

摘要翻译： 公开了一种光电转换元件，其包括半导体电极，相对电极和保持在半导体电极和相对电极之间的电解质层，并且是使用具有高透明度的氧化还原对的高实用性的光电转换元件， 与碘氧化还原对相比，易于封闭并表现出高性能。 电解质层包括由通式（1）和式（2）表示的化合物形成的氧化还原对，和由式（3）表示的具有双（氟磺酰基）酰亚胺阴离子的离子液体。

公开(公告)号：US20110000527A1

公开(公告)日：2011-01-06

申请号：US12677071

申请日：2008-09-10

申请人： Yasuteru Saito ,  Masashi Nakayama

发明人： Yasuteru Saito ,  Masashi Nakayama

IPC分类号： H01L31/0224 ,  B05D5/12

CPC分类号： H01G9/2004 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/91 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0037 ,  H01L2251/306 ,  Y02E10/542 ,  Y02E60/13 ,  Y02P70/521

摘要： A method for producing an electroconductive polymer electrode that is excellent in electroconductivity and catalyst capability, is easily patterned, is high in use efficiency of a coating solution, and can produce conveniently with good reproducibility and productivity, and a dye-sensitized solar cell with an excellent conversion efficiency obtained by using the same are provided. Specifically, such a method is employed that a solution containing a monomer of an electroconductive polymer, a pyrrolidone compound represented by the following general formula (1) as a polymerization controlling agent and an oxidizing agent is coated on an electrode substrate, and then the monomer is polymerized by oxidation polymerization to form an electroconductive polymer electrode. wherein in the formula (1), R1 represents an alkyl group or an aryl group.

摘要翻译： 制造导电性和催化剂性能优异的导电性聚合物电极的方法容易图案化，涂布液的使用效率高，能够以良好的再现性和生产率方便地制造，并且具有染料敏化太阳能电池 提供了通过使用它们获得的优异的转换效率。 具体而言，采用这样的方法，将包含导电聚合物的单体，由以下通式（1）表示的吡咯烷酮化合物作为聚合控制剂和氧化剂的溶液涂布在电极基材上，然后将单体 通过氧化聚合聚合以形成导电聚合物电极。 式（1）中，R 1表示烷基或芳基。

公开(公告)号：US08377504B2

公开(公告)日：2013-02-19

申请号：US12677071

申请日：2008-09-10

申请人： Yasuteru Saito ,  Masashi Nakayama

发明人： Yasuteru Saito ,  Masashi Nakayama

IPC分类号： B05D5/12 ,  H01L31/18 ,  H01L31/042

CPC分类号： H01G9/2004 ,  C08G2261/3223 ,  C08G2261/43 ,  C08G2261/91 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0037 ,  H01L2251/306 ,  Y02E10/542 ,  Y02E60/13 ,  Y02P70/521

摘要： A method for producing an electroconductive polymer electrode that is excellent in electroconductivity and catalyst capability, is easily patterned, is high in use efficiency of a coating solution, and can produce conveniently with good reproducibility and productivity, and a dye-sensitized solar cell with an excellent conversion efficiency obtained by using the same are provided. Specifically, such a method is employed that a solution containing a monomer of an electroconductive polymer, a pyrrolidone compound represented by the following general formula (1) as a polymerization controlling agent and an oxidizing agent is coated on an electrode substrate, and then the monomer is polymerized by oxidation polymerization to form an electroconductive polymer electrode. wherein in the formula (1), R1 represents an alkyl group or an aryl group.

摘要翻译： 制造导电性和催化剂性能优异的导电性聚合物电极的方法容易图案化，涂布液的使用效率高，能够以良好的再现性和生产率方便地制造，并且具有染料敏化太阳能电池 提供了通过使用它们获得的优异的转换效率。 具体而言，采用这样的方法，将包含导电聚合物的单体，由以下通式（1）表示的吡咯烷酮化合物作为聚合控制剂和氧化剂的溶液涂覆在电极基材上，然后将单体 通过氧化聚合聚合以形成导电聚合物电极。 式（1）中，R 1表示烷基或芳基。

公开(公告)号：US20080041438A1

公开(公告)日：2008-02-21

申请号：US11810903

申请日：2007-06-07

申请人： Yasuteru Saito ,  Manabu Kikuta ,  Michiyuki Kono

发明人： Yasuteru Saito ,  Manabu Kikuta ,  Michiyuki Kono

IPC分类号： H01L31/042

CPC分类号： H01G9/2031 ,  H01G9/2018 ,  H01G9/2059 ,  Y02E10/542

摘要： Provided is an inexpensive and high-performance photoelectric conversion device of high practicability. The device comprises a semiconductor electrode, a counter electrode and an electrolyte layer held between the two electrodes, in which the electrolyte layer contains a compound of the following general formula (1) as an oxidation-reduction pair therein: (wherein M+represents an organic or inorganic cation; A represents an aromatic, non-aromatic, heteroaromatic or hetero-non-aromatic cyclic compound).

摘要翻译： 提供了一种实用性高的廉价且高性能的光电转换装置。 该装置包括半导体电极，对电极和保持在两个电极之间的电解质层，其中电解质层包含下列通式（1）的化合物作为氧化还原对：（其中M < +表示有机或无机阳离子; A表示芳族，非芳族，杂芳族或杂 - 非芳族环状化合物）。

公开(公告)号：US08907209B2

公开(公告)日：2014-12-09

申请号：US13979200

申请日：2012-01-11

申请人： Yasuteru Saito

发明人： Yasuteru Saito

IPC分类号： H01L51/46 ,  H01G9/20

CPC分类号： H01G9/2013 ,  H01G9/2018 ,  H01G9/2031 ,  H01G9/2059 ,  Y02E10/52 ,  Y02E10/542

摘要： Disclosed is a photoelectric conversion element which includes a semiconductor electrode, an opposite electrode, and an electrolyte layer held between the semiconductor electrode and the opposite electrode, and which is a photoelectric conversion element of high practical use using a redox couple which has high transparency and ease of enclosure and exhibits high performance compared to an iodine redox couple. An electrolyte layer includes a redox couple formed of compounds represented by General Formula (1) and Formula (2), and ionic liquid having bis(fluorosulfonyl)imide anion represented by Formula (3).

摘要翻译： 公开了一种光电转换元件，其包括半导体电极，相对电极和保持在半导体电极和相对电极之间的电解质层，并且是使用具有高透明度的氧化还原对的高实用性的光电转换元件， 与碘氧化还原对相比，易于封闭并表现出高性能。 电解质层包括由通式（1）和式（2）表示的化合物形成的氧化还原对，和由式（3）表示的双（氟磺酰基）酰亚胺阴离子的离子液体。