公开(公告)号：US06617006B1

公开(公告)日：2003-09-09

申请号：US09914997

申请日：2001-09-07

申请人： Koji Kubo ,  Masahiko Kosuge ,  Shunsuke Kubota ,  Kinji Hasegawa ,  Nobuo Minobe ,  Kimihiko Sato

发明人： Koji Kubo ,  Masahiko Kosuge ,  Shunsuke Kubota ,  Kinji Hasegawa ,  Nobuo Minobe ,  Kimihiko Sato

IPC分类号： B32B1508

CPC分类号： B32B27/36 ,  B32B15/08 ,  C08G63/85 ,  Y10S428/91 ,  Y10T428/24355 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/257 ,  Y10T428/258 ,  Y10T428/259 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A biaxially oriented polyester film to be laminated on a metal plate and molded, which comprises an aromatic polyester composition comprising: (A) an aromatic polyester which comprises ethylene terephthalate as the main recurring unit and a titanium compound and a phosphorus compound both of which satisfy at least one of the following expressions (1) and (2): 0.1≦Ti/P≦3.0  (1) 5≦Ti+P≦60  (2) wherein Ti is the amount (mmol %) of elemental titanium of the titanium compound contained in this aromatic polyester and P is the amount (mmol %) of elemental phosphorus of the phosphorus compound contained in the aromatic polyester, and the following expression (3): 2≦Ti≦20  (3) wherein Ti is as defined hereinabove, and which contains alkali metal compounds, germanium compound and antimony compound in a total amount of not more than 3 ppm in terms of the total of elemental alkali metals, elemental germanium and elemental antimony; and (B) 0.05 to 5.0 wt % based on the aromatic polyester composition of inert fine particles having an average particle diameter of 2.5 &mgr;m or less.

摘要翻译： 一种层压在金属板上并成型的双轴取向聚酯膜，其包含芳族聚酯组合物，其包含：（A）包含对苯二甲酸乙二醇酯作为主要重复单元的芳族聚酯和两者都满足的钛化合物和磷化合物 以下表达式（1）和（2）中的至少一个：其中Ti是该芳族聚酯中所含的钛化合物的元素钛的量（mmol％），P是该芳族聚酯中的元素磷的量（mmol％） 包含在芳族聚酯中的磷化合物和以下表达式（3）：其中Ti如上所定义，并且含有碱金属化合物，锗化合物和锑化合物的总量不大于3ppm 的元素碱金属，元素锗和元素锑; 和（B）基于平均粒径为2.5μm以下的惰性微粒的芳香族聚酯组合物为0.05〜5.0重量％。

公开(公告)号：US06086978A

公开(公告)日：2000-07-11

申请号：US101043

申请日：1998-06-29

申请人： Hirofumi Murooka ,  Kinji Hasegawa ,  Koji Kubo

发明人： Hirofumi Murooka ,  Kinji Hasegawa ,  Koji Kubo

IPC分类号： B32B15/08 ,  B32B27/36 ,  B65D25/14 ,  C08J5/18 ,  B32B5/16

CPC分类号： C08J5/18 ,  B32B15/08 ,  B32B27/36 ,  B65D25/14 ,  C08J2367/02 ,  Y10S428/91 ,  Y10T428/24355 ,  Y10T428/25

摘要： A film to be laminated onto a metal plate and molded, which includes a first copolyester including ethylene-2,6-naphthalene dicarboxylate as a main recurring unit or a blend of the first copolyester and a second copolyester including terephthalate as a main recurring unit. Both the first copolyester and the blend contain diethylene glycol in an amount of 0.05 to 8 mol %. This film has a water extraction of 0.5 mg/inch.sup.2 or less and a center line surface roughness (Ra) of 4 to 30 nm.

摘要翻译： PCT No.PCT / JP97 / 03870 Sec。 371日期1998年6月29日第 102（e）日期1998年6月29日PCT 1997年10月24日PCT公布。 WO98 / 18851 PCT出版物 日期：1998年5月7日A将要层压在金属板上并成型的薄膜，其包括包括作为主要重复单元的乙烯-2,6-萘二甲酸酯的第一共聚酯或第一共聚酯和包括对苯二甲酸酯的第二共聚酯的共混物 主要单位。 第一共聚酯和共混物均含有0.05至8mol％的二甘醇。 该膜的水提取量为0.5mg / inch2以下，中心线表面粗糙度（Ra）为4〜30nm。

公开(公告)号：US5780158A

公开(公告)日：1998-07-14

申请号：US684935

申请日：1996-07-19

申请人： Takeo Asai ,  Takafumi Kudo ,  Koji Kubo ,  Yukihiko Minamihira ,  Kinji Hasegawa

发明人： Takeo Asai ,  Takafumi Kudo ,  Koji Kubo ,  Yukihiko Minamihira ,  Kinji Hasegawa

IPC分类号： B32B15/08 ,  B32B27/36 ,  C08J5/18

CPC分类号： B32B15/08 ,  Y10T428/31507 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A biaxially oriented film to be laminated on a metal, which is a laminate film comprising (A) a first layer of a polyester comprising ethylene terephthalate as a main recurring unit; and (B) a second layer formed from a composition of a polycarbonate and polyesters, the polycarbonate and the polyesters being each contained in amounts of 20 to 50% by weight and 50 to 80% by weight based on the total thereof; the polyesters consisting essentially of a first polyester comprising ethylene terephthalate as a main recurring unit and having a terminal carboxyl group concentration of more than 5 eq./10.sup.6 g and a second polyester comprising butylene terephthalate as a main recurring unit and having a terminal carboxyl group concentration of less than 20 eq./10.sup.6 g; and the first and second polyesters being each contained in an amount of 10 to 90% by weight based on the total thereof; and in which (C) the plane orientation coefficients of the first layer and second layer are both in the range of 0.05 to 0.10.

摘要翻译： 一种层压在金属上的双轴取向膜，它是层压膜，它包括（A）第一层包含对苯二甲酸乙二醇酯作为主要重复单元的聚酯; 和（B）由聚碳酸酯和聚酯的组合物形成的第二层，聚碳酸酯和聚酯的含量相对于其总量为20〜50重量％和50〜80重量％ 所述聚酯基本上由包含对苯二甲酸乙二醇酯作为主要重复单元并且具有大于5当量/ 10g的末端羧基浓度的第一聚酯和包含对苯二甲酸丁二醇酯作为主要重复单元并具有末端羧基的第二聚酯 浓度小于20当量/ 10 6 g; 所述第一和第二聚酯的含量相对于其总量为10〜90重量％ 并且其中（C）第一层和第二层的平面取向系数都在0.05至0.10的范围内。

公开(公告)号：US6071599A

公开(公告)日：2000-06-06

申请号：US142852

申请日：1998-05-22

申请人： Masahiko Kosuge ,  Manabu Kimura ,  Tetsuo Yoshida ,  Koji Kubo ,  Hirofumi Murooka ,  Tetsuya Hasegawa

发明人： Masahiko Kosuge ,  Manabu Kimura ,  Tetsuo Yoshida ,  Koji Kubo ,  Hirofumi Murooka ,  Tetsuya Hasegawa

IPC分类号： B32B15/08 ,  B32B27/36 ,  C09D167/02 ,  B32B7/02 ,  B32B27/06

CPC分类号： C09D167/02 ,  B32B15/08 ,  B32B27/36 ,  Y10T428/2495

摘要： A laminate polyester film to be laminated onto metal plate and molded comprises the first layer made from copoly(ethylene-terephthalate/isophthalate) having a melting point of 205 to 250.degree. C. and a second layer made from a polyester (i) comprising ester units of an aromatic dicarboxylic acid component, an aliphatic dicarboxylic acid component and aliphatic diol components, (ii) containing a titanium compound soluble in the polyester in an amount of 30 to 200 ppm in terms of elemental titanium and (iii) having one or two melting point(s) in the range of 170 to 245.degree. C., and has the maximum peak temperature of loss elastic modulus of higher than 47.degree. C. and 85.degree. C. or lower. This laminate polyester film is suitably used for application such as metal cans for juice and other refreshing drinks that are handled in a cooled state.

摘要翻译： PCT No.PCT / JP97 / 03285。 371日期：1998年5月22日 102（e）日期1998年5月22日PCT 1997年9月17日PCT公布。 第WO98 / 12049号公报 1998年3月26日将层压在金属板上并成型的层压聚酯膜包括由熔点为205-250℃的共聚（对苯二甲酸乙二醇酯/间苯二甲酸酯）制成的第一层和由聚酯制成的第二层 （i）包含芳族二羧酸组分的酯单元，脂肪族二羧酸组分和脂肪族二醇组分，（ii）以元素钛计，含有以聚氨酯为基准的30-200ppm的钛化合物，（iii） ）具有170-245℃范围内的一个或两个熔点，并且具有高于47℃和85℃或更低的损耗弹性模量的最大峰值温度。 这种层压聚酯薄膜适合用于诸如用于果汁的金属罐和在冷却状态下处理的其它清凉饮料。

公开(公告)号：US06472046B1

公开(公告)日：2002-10-29

申请号：US09367593

申请日：1999-08-18

申请人： Koji Kubo ,  Hirofumi Murooka ,  Masahiko Kosuge ,  Hideshi Kurihara

发明人： Koji Kubo ,  Hirofumi Murooka ,  Masahiko Kosuge ,  Hideshi Kurihara

IPC分类号： B32B516

CPC分类号： B32B15/09 ,  B29C55/12 ,  B32B15/08 ,  B32B27/20 ,  B32B27/36 ,  B32B38/12 ,  B32B2307/518 ,  B32B2367/00 ,  B32B2439/66 ,  C08J5/18 ,  C08J2367/02 ,  Y10S428/91 ,  Y10T156/1036 ,  Y10T156/1038 ,  Y10T156/1043 ,  Y10T156/1048 ,  Y10T428/24355 ,  Y10T428/249981 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A biaxially oriented polyester film to be laminated onto a metal plate and molded, (A) which comprises a copolyester comprising (a) terephthalic acid in an amount of 82 to 100 mol % and 2,6-naphthalenedicarboxylic acid or a combination of 2,6-naphthalenedicarboxylic acid and other dicarboxylic acid in an amount of 0 to 18 mol % of the total of all dicarboxylic acid components and (b) ethylene glycol in an amount of 82 to 100 mol % and cyclohexanedimethanol or a combination of cyclohexanedimethanol and other diol in an amount of 0 to 18 mol % of the total of all diol components, having (c) a glass transition temperature of 78° C. or more and (d) a melting point of 210 to 250° C., and containing (e) porous silica particles with a pore volume of 0.5 to 2.0 ml/g which are agglomerates of primary particles having an average particle diameter of 0.001 to 0.1 &mgr;m; and (B) which has the following relationship between the highest peak temperature (Te, °C.) of loss elastic modulus and the glass transition temperature (Tg, °C.): Te−Tg≦30. This film has improved taste-and-flavor retainabilities, particularly taste and flavor retainabilities after a retort treatment, without losing the excellent moldability, heat resistance, impact resistance and retort resistance of a copolyester film.

摘要翻译： 将层压在金属板上并成型的双轴取向聚酯膜（A），其包含共聚酯，该共聚酯包含（a）82〜100摩尔％的对苯二甲酸和2,6-萘二羧酸或2〜 （b）82〜100摩尔％的乙二醇和环己烷二甲醇或环己烷二甲醇与其他二醇的组合的量为0〜18摩尔％的二羧酸和6-萘二羧酸 （c）玻璃化转变温度为78℃以上，（d）熔点为210〜250℃，含有（ e）孔体积为0.5〜2.0ml / g的多孔二氧化硅粒子，其为平均粒径为0.001〜0.1μm的一次粒子的凝聚体; 和（B），其在损耗弹性模量的最高峰值温度（Te，℃）与玻璃化转变温度（Tg，℃）之间具有以下关系：Te-Tg <= 30。 该膜具有改善的口味和味道保留性，特别是在蒸煮处理后的味道和风味保持性，而不失去共聚聚酯薄膜的优异成型性，耐热性，耐冲击性和耐蒸煮性。

公开(公告)号：US6086989A

公开(公告)日：2000-07-11

申请号：US91190

申请日：1998-06-10

申请人： Koji Kubo ,  Hirofumi Murooka ,  Masahiko Kosuge ,  Manabu Kimura

发明人： Koji Kubo ,  Hirofumi Murooka ,  Masahiko Kosuge ,  Manabu Kimura

IPC分类号： B32B15/08 ,  B32B27/36 ,  C08J5/18 ,  B32B31/04

CPC分类号： C08J5/18 ,  B32B15/08 ,  B32B27/36 ,  C08J2367/02 ,  Y10S428/91 ,  Y10T428/264 ,  Y10T428/269

摘要： A biaxially oriented polyester film to be laminated onto a metal plate and molded, which comprises a copolyester, said copolyester comprising (a) terephthalic acid in an amount of 82 to 100 mol % and 2,6-naphthalenedicarboxylic acid or a combination of 2,6-naphthalenedicarboxylic acid and other dicarboxylic acids in an amount of 0 to 18 mol % of the total of all dicarboxylic acid components and (b) ethylene glycol in an amount of 82 to 100 mol % and cyclohexanedimethanol or a combination of cyclohexanedimethanol and other diols in an amount of 0 to 18 mol % of the total of all diol components, and having (c) a glass transition temperature of 78.degree. C. or higher and (d) a melting point of 210 to 250.degree. C. The said film has the following relationship between the highest peak temperature (Te, .degree. C.) of loss elastic modulus and the glass transition temperature (Tg, .degree. C.): Te-Tg.ltoreq.30, or its content of a free dicarboxylic acid diol ester is 50 ppm or less. The said film has improved flavor retention properties for its contents taste, particularly taste and flavor retention properties after a retort treatment, while retaining excellent moldability, heat resistance, impact resistance.

摘要翻译： PCT No.PCT / JP97 / 03643 Sec。 371日期：1998年6月10日 102（e）1998年6月10日PCT 1997年10月9日PCT PCT。 公开号WO98 / 16573 日期：1998年4月23日将双轴取向聚酯薄膜层叠在金属板上并成型为包含共聚酯的共聚酯，所述共聚酯包含（a）82至100摩尔％的对苯二甲酸和2,6-萘二羧酸，或 2,6-萘二羧酸和其它二羧酸的组合，其量为所有二羧酸组分总量的0至18摩尔％，和（b）82至100摩尔％的乙二醇和环己烷二甲醇或其组合 的环己烷二甲醇和其它二醇的量为所有二醇组分总量的0至18摩尔％，并且（c）玻璃化转变温度为78℃或更高，（d）熔点为210至250℃ C.所述膜在损耗弹性模量的最高峰值温度（Te，℃）和玻璃化转变温度（Tg，℃）之间具有以下关系：Te-Tg = 30或其含量 游离二羧酸二醇酯的含量为50ppm以下。 所述薄膜在蒸煮处理后具有改善其含量味道，特别是味道和香味保留性能的风味保持性，同时保持优异的成型性，耐热性，耐冲击性。

公开(公告)号：US20100006150A1

公开(公告)日：2010-01-14

申请号：US12373027

申请日：2006-07-13

申请人： Rei Nishio ,  Koji Kubo ,  Shinya Komura ,  Takanori Miyoshi

发明人： Rei Nishio ,  Koji Kubo ,  Shinya Komura ,  Takanori Miyoshi

IPC分类号： H01L31/0216

CPC分类号： H01G9/2031 ,  H01G9/2059 ,  H01G9/2095 ,  H01M14/005 ,  Y02E10/542

摘要： A laminated film comprising a porous semiconductor layer, a transparent conductive layer and a transparent plastic film, wherein the porous semiconductor layer comprises crystalline titanium oxide fibers and crystalline titanium oxide fine particles, the crystalline titanium oxide fibers and the crystalline titanium oxide fine particles are substantially composed of an anatase phase and a rutile phase, the anatase phase content ratio calculated from the integral intensity ratio of X-ray diffraction is between 1.00 and 0.32, and the laminated film is used in an electrode for dye-sensitized solar cells, and the electrode and a dye-sensitized solar cell comprising the same.

摘要翻译： 一种层叠膜，包括多孔半导体层，透明导电层和透明塑料膜，其中所述多孔半导体层包含结晶氧化钛纤维和结晶二氧化钛细颗粒，所述结晶氧化钛纤维和所述结晶氧化钛微粒基本上 由锐钛矿相和金红石相组成，由X射线衍射的积分强度比计算出的锐钛矿相含量比为1.00〜0.32，层叠膜用于染料敏化太阳能电池用电极， 电极和包含该电极的染料敏化太阳能电池。

公开(公告)号：US07211309B2

公开(公告)日：2007-05-01

申请号：US10541234

申请日：2004-03-24

申请人： Satoshi Kitazawa ,  Koji Kubo ,  Takeshi Asada ,  Shigeyuki Watamabe

发明人： Satoshi Kitazawa ,  Koji Kubo ,  Takeshi Asada ,  Shigeyuki Watamabe

IPC分类号： B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/30 ,  B32B27/36

CPC分类号： C08J7/047 ,  C08J2367/02 ,  C08J2433/00 ,  C09K3/16 ,  Y10S428/91 ,  Y10T428/14 ,  Y10T428/1471 ,  Y10T428/24355 ,  Y10T428/24802 ,  Y10T428/25 ,  Y10T428/266 ,  Y10T428/269 ,  Y10T428/28 ,  Y10T428/31786 ,  Y10T428/31797 ,  Y10T428/31935

摘要： An antistatic film having an antistatic coating film on at least one surface of a polyester film, the antistatic coating film comprising a polymer having a polymerized unit represented by the following formula (1): wherein R1 and R2 each independently represent a hydrogen atom or a methyl group, R3 represents an alkylene group having 2 to 10 carbon atoms, R4 and R5 each independently represent an alkyl group having 1 to 5 carbon atoms, R6 represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or a hydroxyalkyl group having 2 to 10 carbon atoms, and Y− represents a halogen ion, a halogenated alkyl ion, a nitrate ion, a sulfate ion, an alkyl sulfate ion, a sulfonate ion or an alkyl sulfonate ion. The film is used in such applications requiring an antistatic property such as a protective film for a liquid crystal polarizing plate.

摘要翻译： 一种在聚酯薄膜的至少一个表面上具有抗静电涂膜的抗静电薄膜，所述抗静电涂膜包含具有由下式（1）表示的聚合单元的聚合物：其中R 1和R 2 各自独立地表示氢原子或甲基，R 3表示具有2〜10个碳原子的亚烷基，R 4和R 4 各自独立地表示具有1至5个碳原子的烷基，R 6表示氢原子，具有1至5个碳原子的烷基或具有2个碳原子的羟烷基 至10个碳原子，Y - 表示卤素离子，卤代烷基离子，硝酸根离子，硫酸根离子，烷基硫酸根离子，磺酸根离子或烷基磺酸根离子。 该膜用于需要抗静电性能的应用，例如液晶偏振片用保护膜。

公开(公告)号：US07022388B2

公开(公告)日：2006-04-04

申请号：US10491921

申请日：2003-06-02

申请人： Katsuyuki Hashimoto ,  Makoto Handa ,  Shinji Yano ,  Koji Kubo

发明人： Katsuyuki Hashimoto ,  Makoto Handa ,  Shinji Yano ,  Koji Kubo

IPC分类号： B32B7/02 ,  B32B27/08 ,  B32B27/18 ,  B32B27/30 ,  B32B27/36

CPC分类号： C08J7/047 ,  C08J7/04 ,  C08J2367/02 ,  Y10S428/91 ,  Y10T428/1328 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/24355 ,  Y10T428/24942 ,  Y10T428/31681 ,  Y10T428/31786 ,  Y10T428/31797

摘要： There is provided a laminated polyester film which is improved in lubricity, transparency, dimensional stability, shock resistance and adhesion, and which comprises a polyester base film comprising polyester and to at least one direction, and a coating layer provided on at least one surface of the base film, wherein said coating layer contains polymer binder and inert particles, the refractive index of the inert particles being substantially same as that of the polymer binder, and wherein the laminated polyester film has a haze of 1.5% or less, a total light transmittance of 85% or more, 50% destructing energy per 100 μm film thickness of 0.3 J or more, and a thermal shrinkage at 230° C. for 30 minutes of 4% or less.

摘要翻译： 提供了一种提高了润滑性，透明性，尺寸稳定性，抗冲击性和粘附性的层压聚酯膜，并且包括聚酯基膜，其包含聚酯和至少一个方向，并且涂层设置在至少一个表面上 所述基膜，其中所述涂层含有聚合物粘合剂和惰性颗粒，所述惰性颗粒的折射率基本上与所述聚合物粘合剂的折射率相同，并且其中所述层压聚酯膜的雾度为1.5％以下，总光 透光率为85％以上，每100μm薄膜厚度为30％以上的破坏能量为50％，230℃下30分钟的热收缩率为4％以下。

公开(公告)号：US08835755B2

公开(公告)日：2014-09-16

申请号：US12373027

申请日：2006-07-13

申请人： Rei Nishio ,  Koji Kubo ,  Shinya Komura ,  Takanori Miyoshi

发明人： Rei Nishio ,  Koji Kubo ,  Shinya Komura ,  Takanori Miyoshi

IPC分类号： H01L31/00 ,  H01G9/20 ,  H01M14/00

CPC分类号： H01G9/2031 ,  H01G9/2059 ,  H01G9/2095 ,  H01M14/005 ,  Y02E10/542

摘要： A laminated film comprising a porous semiconductor layer, a transparent conductive layer and a transparent plastic film, wherein the porous semiconductor layer comprises crystalline titanium oxide fibers and crystalline titanium oxide fine particles, the crystalline titanium oxide fibers and the crystalline titanium oxide fine particles are substantially composed of an anatase phase and a rutile phase, the anatase phase content ratio calculated from the integral intensity ratio of X-ray diffraction is between 1.00 and 0.32, and the laminated film is used in an electrode for dye-sensitized solar cells, and the electrode and a dye-sensitized solar cell comprising the same.

摘要翻译： 一种层叠膜，包括多孔半导体层，透明导电层和透明塑料膜，其中所述多孔半导体层包含结晶氧化钛纤维和结晶二氧化钛细颗粒，所述结晶氧化钛纤维和所述结晶氧化钛微粒基本上 由锐钛矿相和金红石相组成，由X射线衍射的积分强度比计算出的锐钛矿相含量比为1.00〜0.32，层叠膜用于染料敏化太阳能电池用电极， 电极和包含该电极的染料敏化太阳能电池。