公开(公告)号：US20130136996A1

公开(公告)日：2013-05-30

申请号：US13681560

申请日：2012-11-20

Applicant: Korea Institute of Science and Technology

Inventor： Joong Kee LEE ,  Byung Won CHO ,  Hwa Young LEE ,  Byoung Sung AHN ,  Joo Man WOO ,  Sang Ok KIM ,  Ji Hun PARK ,  Jung Sub KIM ,  Nguyen Si HIEU

IPC: H01M4/38 ,  H01M4/04 ,  H01M4/583

CPC classification number: H01M4/386 ,  B82Y30/00 ,  H01M4/04 ,  H01M4/0428 ,  H01M4/049 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/405 ,  H01M4/583

Abstract: Disclosed are a metallic nano-structure material in which an energy storage capacity based on electrochemical reaction with lithium is improved by 10 times or more compared to a conventional graphite material and power characteristics are excellent, an electrode composed of the metallic nano-structure material, and a lithium ion asymmetric secondary battery including the electrode as an anode. When using the electrode for the lithium ion asymmetric secondary battery, energy larger than with the graphite material can be stored with very thin thickness due to the high-capacity feature of the metallic material and the high-power feature can be achieved by the nano structure, such that energy density can be innovatively improved in the same weight condition when compared to a conventional lithium ion capacitor, and the lithium ion asymmetric secondary battery including the electrode can be used for renewable energy storage, ubiquitous power supply, heavy machinery, vehicle power source, etc.

Abstract translation: 公开了一种金属纳米结构材料，其中与常规石墨材料相比，基于与锂的电化学反应的能量存储容量提高10倍以上，功率特性优异，由金属纳米结构材料构成的电极， 以及包含该电极作为阳极的锂离子不对称二次电池。 当使用电极作为锂离子不对称二次电池时，由于金属材料的高容量特性，能够比石墨材料大的能量可以非常薄的厚度储存，并且可通过纳米结构实现高功率特征 与以往的锂离子电容器相比，能够在与重量相同的条件下进行能量密度的创新改善，并且包含电极的锂离子不对称二次电池可用于可再生能源储存，普遍存在的电力供应，重型机械，车辆动力 来源等

公开(公告)号：US20140349836A1

公开(公告)日：2014-11-27

申请号：US14265989

申请日：2014-04-30

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Dong Ju MOON ,  Jae Sun JUNG ,  Eun Hyeok YANG ,  Sang Woo KIM ,  Jae Suk LEE ,  Bang Hee KIM ,  Jong Tae JUNG ,  Hyun Jin KIM ,  Ga Ram CHOI ,  Byoung Sung AHN

IPC: B01J23/755

CPC classification number: B01J23/755 ,  B01J21/04 ,  B01J23/83 ,  B01J35/002 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0207 ,  B01J37/08 ,  C01B3/04 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1058 ,  C01B2203/1082 ,  Y02P20/52

Abstract: The present invention relates to a method for preparing a nickel-based catalyst for steam carbon dioxide reforming (SCR) of natural gas using steam and carbon dioxide, more particularly to a method for preparing a nickel-based catalyst represented by Ni/η-Al2O3, which is prepared by supporting nickel on a spherical η-alumina support having many acid sites at high density by repeating impregnation and drying tens of times.The catalyst prepared according to the present invention exhibits superior catalytic activity when used in steam carbon dioxide reforming reaction (SCR) even under harsh conditions of high temperature and high pressure and hardly exhibits carbon deposition due to superior durability.

Abstract translation: 本发明涉及一种使用蒸汽和二氧化碳制备天然气蒸汽二氧化碳重整（SCR）的镍基催化剂的方法，更具体地涉及一种由Ni / eegr- Al2O3，其通过重复浸渍和干燥几次而以高密度将镍支撑在具有多个酸性位点的球形和氧化铝载体上来制备。 根据本发明制备的催化剂即使在高温高压的苛刻条件下也用于蒸汽二氧化碳重整反应（SCR）中也显示出优异的催化活性，并且由于耐久性优异，几乎不显示碳沉积。

公开(公告)号：US20140145116A1

公开(公告)日：2014-05-29

申请号：US13909412

申请日：2013-06-04

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Dong Ju MOON ,  Eun Hyeok YANG ,  Jin Hee LEE ,  Hyun Jin KIM ,  Byoung Sung AHN ,  Sang Woo KIM ,  Jae Sun JUNG

IPC: B01J23/83 ,  C01B3/26

CPC classification number: B01J23/83 ,  B01J35/1014 ,  B01J37/0018 ,  B01J37/031 ,  B01J2523/00 ,  C01B3/00 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1241 ,  Y02P20/142 ,  Y02P20/52 ,  Y10S502/525 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/847 ,  B01J2523/842

Abstract: The present invention relates to an Fe-modified perovskite-type catalyst, a method for preparing same and a method for preparing a synthesis gas by a combined reforming reaction using same. More particularly, it relates to a catalyst for a combined natural gas/steam/carbon dioxide reforming reaction having a perovskite structure with La and Sr introduced at the A site and Ni and Fe introduced at the B site with specific molar ratios and a method for producing a synthesis gas for Fischer-Tropsch synthesis or methanol synthesis using the catalyst by the combined reforming reaction. The catalyst of the present invention exhibits higher carbon dioxide conversion rate, significantly reduced catalyst deactivation caused by carbon deposition and improved long-term catalyst stability and activity, as compared to the existing catalyst for reforming reaction prepared by the impregnation method.

Abstract translation: 本发明涉及Fe改性的钙钛矿型催化剂及其制备方法以及通过使用它们的组合重整反应制备合成气的方法。 更具体地说，本发明涉及一种具有钙钛矿结构的合成天然气/蒸汽/二氧化碳重整反应的催化剂，其中在A位置引入La和Sr，并在B位上引入具有特定摩尔比的Ni和Fe， 使用催化剂通过组合的重整反应生产费 - 托合成或甲醇合成的合成气。 与通过浸渍法制备的用于重整反应的现有催化剂相比，本发明的催化剂显示较高的二氧化碳转化率，显着降低了由碳沉积引起的催化剂失活和改善的长期催化剂稳定性和活性。

公开(公告)号：US20160244419A1

公开(公告)日：2016-08-25

申请号：US15015890

申请日：2016-02-04

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Hyun Joo LEE ,  Byoung Sung AHN ,  Sang Deuk LEE ,  Ji Sik CHOI ,  Hyejeong LEE ,  Hye Jin LEE

IPC: C07D301/02 ,  C07D317/20

CPC classification number: C07D301/02 ,  C07D317/20

Abstract: A method for preparing glycidol using glycerol includes mixing glycerol with urea in the presence of at least one zinc-based catalyst selected from the group consisting of Zn(NO3)2, ZnCl2, ZnO and Zn(OAc)2 under a pressure of 0.5-10 kPa at a temperature of 100-170° C. to obtain glycerol carbonate; filtering the glycerol carbonate mixed with the zinc-based catalyst through an adsorbent including a polymer resin coordinated with amine groups to separate the zinc-based catalyst and glycerol carbonate from each other; and carrying out reaction of the glycerol carbonate separated from the zinc-based catalyst in the presence of an anion alkali metal salt catalyst that is Na, K, Rb, Cs or a mixture thereof containing at least one anion selected from the group consisting of Cl−, Br−, I−, NO3−, NO2− and acetate under a pressure of 0.13-6.67 kPa at a temperature of 140-250° C. to obtain glycidol.

Abstract translation: 使用甘油制备缩水甘油的方法包括在至少一种选自Zn（NO 3）2，ZnCl 2，ZnO和Zn（OAc）2）的锌基催化剂的存在下，在0.5- 在100-170℃的温度下10kPa，得到碳酸甘油酯; 通过包含与胺基配位的聚合物树脂的吸附剂过滤与锌基催化剂混合的甘油碳酸酯，以将锌基催化剂和甘油碳酸酯彼此分离; 在Na，K，Rb，Cs的阴离子碱金属盐催化剂或其含有至少一种选自Cl的阴离子的混合物的存在下进行从锌基催化剂分离的碳酸甘油酯的反应 - ，Br-，I-，NO 3 - ，NO 2 - 和乙酸盐，在温度为140-250℃的温度下，在0.13-6.67kPa的压力下进行，得到缩水甘油。

公开(公告)号：US20190134616A1

公开(公告)日：2019-05-09

申请号：US16043161

申请日：2018-07-24

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Jungho JAE ,  Haryo Pandu Winoto ,  Jeong-Myeong HA ,  Hyun Joo LEE ,  Dong Jin SUH ,  Byoung Sung AHN

IPC: B01J29/70 ,  B01J27/19 ,  B01J21/06 ,  B01J37/02 ,  C07D307/33

CPC classification number: B01J29/7007 ,  B01J21/06 ,  B01J27/19 ,  B01J37/0201 ,  B01J2229/18 ,  C07D307/33

Abstract: Disclosed are a heteropolyacid catalyst for producing gamma-valerolactone, which is supported on M-Beta zeolite (M=Sn, Ti, Zr or Hf), and a method for preparing the same and a method for manufacturing gamma-valerolactone using the catalyst. The catalyst has an effect of producing gamma-valerolactone from biomass-derived furfural at a high yield through a one-pot process.

公开(公告)号：US20150045589A1

公开(公告)日：2015-02-12

申请号：US14059007

申请日：2013-10-21

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Chang Soo KIM ,  Kyesang YOO ,  Byoung Sung AHN ,  Hyun Joo LEE ,  Jeong Myeong HA ,  Hong Gon KIM

IPC: B01J23/44 ,  C07C17/23

CPC classification number: B01J23/44 ,  B01J21/18 ,  B01J31/0284 ,  B01J35/0013 ,  B01J35/0053 ,  B01J35/006 ,  B01J37/035 ,  B82Y30/00 ,  C07C17/354 ,  C07C19/08

Abstract: Provided is a palladium on carbon (Pd/C) catalyst obtained by using an ionic liquid, a method for preparing the same, and a method for hydrogenation of hydrofluorocarbon using the same. More particularly, palladium particles are supported on carbon particles by using an ionic liquid, and the resultant Pd/C catalyst is used for hydrogenation of hydrofluorocarbon. The catalyst includes palladium particles having a smaller particle size and a more uniform shape as compared to the existing Pd/C catalysts, and thus shows high catalytic activity.

Abstract translation: 提供通过使用离子液体获得的钯/碳（Pd / C）催化剂，其制备方法和使用其的氢氟烃的氢化方法。 更具体地，钯颗粒通过使用离子液体负载在碳颗粒上，所得的Pd / C催化剂用于氢氟烃的氢化。 该催化剂包括与现有Pd / C催化剂相比具有较小粒度和更均匀形状的钯颗粒，因此显示出高催化活性。

公开(公告)号：US20140135512A1

公开(公告)日：2014-05-15

申请号：US13759692

申请日：2013-02-05

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Hyun Joo LEE ,  Sang Deuk LEE ,  Byoung Sung AHN ,  Chang Soo KIM ,  Ji Sik CHOI

IPC: C07D301/02

CPC classification number: C07D301/02

Abstract: Disclosed is a method for producing glycidol by decarboxylation of glycerol carbonate. In the method, an ionic liquid catalyst is added for the reaction. According to the method glycidol can be produced in high yield and selectivity. The method enables the production of glycidol in an easy, simple and environmentally friendly way.

Abstract translation: 公开了通过碳酸甘油脱羧制备缩水甘油的方法。 在该方法中，为反应添加离子液体催化剂。 根据方法，可以高产率和选择性生产缩水甘油。 该方法能够以简单，简单和环保的方式生产缩水甘油。

公开(公告)号：US20170218322A1

公开(公告)日：2017-08-03

申请号：US15329399

申请日：2015-09-21

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Young Soon UM ,  Hong Gon KIM ,  Byoung Sung AHN ,  Sang Deuk LEE ,  Chang Soo KIM ,  Dong Jin SUH ,  Kyung Min LEE

IPC: C12M1/00 ,  C12M1/02 ,  C12M1/34

CPC classification number: C12M45/06 ,  C12M23/34 ,  C12M27/00 ,  C12M29/18 ,  C12M41/12 ,  C12M41/28

Abstract: The apparatus includes: a pretreatment tank where biomass and a first acid solution are stirred to extract sugar components from the biomass; a hydrolysis tank where water is added to the pretreated mixture transferred from the pretreatment tank such that the concentration of the acid is reduced and the sugar components are hydrolyzed to produce an acid hydrolyzate; a first sugar-acid separation tank where the acid hydrolyzate is separated into a second acid solution and a first hydrolyzate; a second sugar-acid separation tank where the first hydrolyzate is separated into a third acid solution and a second hydrolyzate; a fermentation tank where the second hydrolyzate is fermented to produce bioenergy; and an acid solution concentration tank where a mixture of the second acid solution transferred from the first sugar-acid separation tank and the third acid solution transferred from the second sugar-acid separation tank is concentrated to a higher level for reuse.

公开(公告)号：US20150239858A1

公开(公告)日：2015-08-27

申请号：US14313153

申请日：2014-06-24

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Hyun Joo LEE ,  Byoung Sung AHN ,  Sang Deuk LEE ,  Jungho JAE ,  Ji Sik CHOI

IPC: C07D301/02 ,  C07D317/36

CPC classification number: C07D301/02 ,  C07D303/14 ,  C07D317/36

Abstract: Disclosed is a method for producing glycidol by successive catalytic reactions. The method includes a series of reactions for the preparation of glycerol carbonate from glycerol and the decarboxylation of the glycerol carbonate. Specifically, the method includes i) reacting glycerol with a dialkyl carbonate to prepare glycerol carbonate, and ii) subjecting the glycerol carbonate to decarboxylation wherein a base is added as a catalyst in step i) and is allowed to react with an acid to form a metal salt after step i), and the salt is used as a catalyst in step ii). According to the method, inexpensive and easy-to-purchase acid and base catalysts can be used to produce glycidol from glycerol, a by-product of biodiesel production, as a starting material in high yield with high selectivity in a convenient, simple, and environmentally friendly way. In addition, the method eliminates the need to separate the base catalyst.

Abstract translation: 公开了通过连续催化反应制备缩水甘油的方法。 该方法包括从甘油制备甘油碳酸酯和碳酸甘油酯脱羧的一系列反应。 具体地说，该方法包括：i）使甘油与碳酸二烷基酯反应以制备甘油碳酸酯，和ii）使甘油碳酸酯脱羧，其中在步骤i）中加入碱作为催化剂，并使其与酸反应形成 步骤i）后的金属盐，并且该盐在步骤ii）中用作催化剂。 根据该方法，可以使用廉价且易于购买的酸和碱催化剂，以生产生物柴油的副产物甘油作为起始原料，以方便，简单和高效的方式以高选择性产生缩水甘油 环保的方式。 此外，该方法不需要分离碱催化剂。