Additives and method for controlling clathrate hydrates in fluid systems
    7.
    发明授权
    Additives and method for controlling clathrate hydrates in fluid systems 失效
    用于控制流体系统中的笼形水合物的添加剂和方法

    公开(公告)号:US5639925A

    公开(公告)日:1997-06-17

    申请号:US358140

    申请日:1994-12-15

    摘要: Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Also, polymers having an amide on which a C.sub.1 -C.sub.4 group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

    摘要翻译: 讨论的是防止笼形水合物质量不利地阻碍易于包合的水合物形成的流体的可能流动的过程。 这个过程在天然气和石油生产,运输和加工业中特别有用,天然气水合物形成可能会导致严重的问题。 添加剂优选含有一个或多个五元件,六元件和/或七件循环化学品分组。 添加剂包括具有内酰胺环的聚合物。 添加剂还可以含有被认为通过空间阻碍和/或电荷排斥改善聚合物添加剂一致性的聚电解质。 此外,可以单独使用其上具有C1-C4基团的氨基和/或酰胺的羰基碳上的酰胺的聚合物,或与含环聚合物组合使用以提高有效性。 具有至少一些代表聚合至少一种恶唑啉,N-取代的丙烯酰胺和N-乙烯基烷基酰胺的重复单元的聚合物是优选的。