Copolymers comprising low surface tension (meth) acrylates

    公开(公告)号:US20050119409A1

    公开(公告)日:2005-06-02

    申请号:US11009424

    申请日:2004-12-10

    IPC分类号: C08F220/10 C08L53/00

    CPC分类号: C08F220/10

    摘要: The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.

    Compositions containing copolymers of olefinic monomers
    6.
    发明申请
    Compositions containing copolymers of olefinic monomers 失效
    含有烯属单体共聚物的组合物

    公开(公告)号:US20050250911A1

    公开(公告)日:2005-11-10

    申请号:US11116706

    申请日:2005-04-28

    摘要: A composition that includes a non-gelled copolymer that contains residues having structural units (I): where n is an integer from 1 to 10,000; R1 is linear or branched C1 to C4 alkyl; R2 is selected from the group consisting of methyl, linear, cyclic or branched C2 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl, and R3 is a group resulting from a post polymerization reaction selected from transesterification, transamidification and hydrolysis with a compound selected from hydroxy functional compounds and amine functional compounds. The composition may contain co-reactive functional groups and may be a thermosetting composition. A substrate may be coated with the thermosetting composition singly or as part of a multi-layer composite coating that includes a base coat layer and a substantially pigment free top coat layer.

    摘要翻译: 包含含有具有结构单元(I)的残基的非胶凝共聚物的组合物:其中n为1至10,000的整数; R 1是直链或支链C 1至C 4烷基; R 2选自甲基,直链,环状或支链C 2至C 20烷基,烯基,芳基,烷芳基和 芳烷基和R 3是由选自酯交换反应,酰胺化反应和用选自羟基官能化合物和胺官能化合物的化合物水解的后聚合反应得到的基团。 组合物可以含有共反应性官能团并且可以是热固性组合物。 基材可以单独地涂覆有热固性组合物,或者作为多层复合涂层的一部分,其包括底涂层和基本上不含颜料的顶涂层。

    Etherified carbamate functional copolymers of isobutylene type monomers, and their use in curable compositions
    7.
    发明申请
    Etherified carbamate functional copolymers of isobutylene type monomers, and their use in curable compositions 审中-公开
    异丁烯型单体的醚化氨基甲酸酯官能共聚物及其在可固化组合物中的用途

    公开(公告)号:US20050032978A1

    公开(公告)日:2005-02-10

    申请号:US10635796

    申请日:2003-08-06

    CPC分类号: C08F8/30 C08F8/28 C08F210/14

    摘要: A reaction product is provided, of reactants comprising: a) at least one copolymer comprising at least 30 mol % of residues having the following alternating structural units: -[DM-AM]-  wherein DM represents a residue from a donor monomer, AM represents a residue from an acceptor monomer, the copolymer containing pendant carbamate groups or groups that can be converted to carbamate groups; b) at least one aldehyde; and c) at least one monohydric alcohol; wherein when the copolymer (a) contains groups that can be converted to carbamate groups, the reactants further comprise: d) at least one material that will convert said groups into carbamate groups. The reaction product is suitable for use in a variety of curable compositions, which are also provided.

    摘要翻译: 提供反应产物,反应物包括:a)至少一种包含至少30mol%具有以下交替结构单元的残基的共聚物: - [DM-AM] - 其中DM表示来自供体单体的残基,AM表示 来自受主单体的残基,含有氨基甲酸酯侧基的共聚物或可转化为氨基甲酸酯基团的基团; b)至少一种醛; 和c)至少一种一元醇; 其中当所述共聚物(a)含有可转化为氨基甲酸酯基团的基团时,所述反应物还包含:d)至少一种将所述基团转化为氨基甲酸酯基团的物质。 反应产物适用于各种可固化组合物,其也可提供。

    Coatings comprising the reaction product of a terpene, an acrylic monomer and a phenolic compound
    8.
    发明授权
    Coatings comprising the reaction product of a terpene, an acrylic monomer and a phenolic compound 有权
    包含萜烯,丙烯酸类单体和酚类化合物的反应产物的涂料

    公开(公告)号:US07608676B2

    公开(公告)日:2009-10-27

    申请号:US11564552

    申请日:2006-11-29

    IPC分类号: C09D4/00 C08G59/02 C08G59/16

    CPC分类号: C09D4/00

    摘要: Coatings comprising the reaction product of a terpene, an acrylic monomer and a phenolic compound containing at least one unsubstituted carbon atom ortho or para to a phenolic group and/or the reaction product of a phenolic compound containing at least one unsubstituted carbon atom ortho or para to a phenolic group and a compound containing a phenolic reactive group and an epoxy group are disclosed.

    摘要翻译: 包含萜烯,丙烯酸类单体和含有酚基的至少一个未取代的碳原子或酚基的对位的酚化合物的反应产物和/或含有至少一个未取代的碳原子的酚类化合物的反应产物邻位或对位 涉及酚基和含有酚类反应性基团和环氧基团的化合物。

    Copolymers comprising low surface tension (meth) acrylates
    10.
    发明授权
    Copolymers comprising low surface tension (meth) acrylates 失效
    包含低表面张力(甲基)丙烯酸酯的共聚物

    公开(公告)号:US06841641B2

    公开(公告)日:2005-01-11

    申请号:US10237357

    申请日:2002-09-09

    CPC分类号: C08F220/10

    摘要: The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.

    摘要翻译: 本发明涉及包含第一自由基聚合性低表面张力(甲基)丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体的共聚物。 共聚物的多分散指数小于2.5。 本发明还包括制备上述低表面张力共聚物的受控自由基聚合方法。 该方法包括将第一自由基聚合性低表面张力(甲基)丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体加入到含有合适的原子转移自由基聚合(ATRP)引发剂的溶液中的步骤。