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    PHOTOCURABLE COMPOSITIONS FOR PREPARING ABS-LIKE ARTICLES
    3.
    发明申请
    PHOTOCURABLE COMPOSITIONS FOR PREPARING ABS-LIKE ARTICLES 审中-公开
    用于制备ABS样品的光刻胶组合物

    公开(公告)号：US20100119835A1

    公开(公告)日：2010-05-13

    申请号：US12530899

    申请日：2008-03-07

    申请人： Laurence Messe ,  Loic Messe ,  Carole Chapelat ,  Ranjana Patel

    发明人： Laurence Messe ,  Loic Messe ,  Carole Chapelat ,  Ranjana Patel

    IPC分类号： C08L63/00 ,  G03F7/004 ,  G03F7/20 ,  B32B27/38

    CPC分类号： G03F7/038 ,  B33Y70/00 ,  C08L63/00 ,  G03F7/0037 ,  Y10T428/31515 ,  C08L2666/02

    摘要： The present invention relates to a photocurable composition comprising: (a) 30-80% by weight of an epoxy-containing component (b) 5 to 65% by weight of a compound containing an oxetane ring in its molecule; (c) 1-25% by weight of a polyol having a molecular weight Mw of 2.000 or higher, (d) an antimony-free cationic photoinitiator. wherein the percent by weight is based on the total weight of the photocurable composition. The curable resin composition can be used for photocurable coatings per se and in specific for stereolithography and other such three dimensional printing applications where a 3D object is formed.

    摘要翻译： 本发明涉及一种光固化组合物，其包含：（a）30-80重量％的含环氧基的组分（b）5至65重量％的分子中含有氧杂环丁烷环的化合物; （c）1-25重量％的分子量Mw为2.000以上的多元醇，（d）无锑阳离子光引发剂。 其中所述重量百分数是基于所述可光固化组合物的总重量。 可固化树脂组合物本身可用于光固化涂料，特别用于立体光刻和其它形成3D物体的其它这样的三维印刷应用。

    Production of composites articles composed of thin layers
    4.
    发明申请
    Production of composites articles composed of thin layers 失效
    生产由薄层组成的复合材料制品

    公开(公告)号：US20060035034A1

    公开(公告)日：2006-02-16

    申请号：US10495028

    申请日：2002-11-11

    申请人： Yonetatsu Matsumoto ,  Peggy Studer ,  Yong Zhao ,  Stefan Barny ,  Ranjana Patel

    发明人： Yonetatsu Matsumoto ,  Peggy Studer ,  Yong Zhao ,  Stefan Barny ,  Ranjana Patel

    IPC分类号： C08F2/46

    CPC分类号： B29C67/0059 ,  B29C64/106 ,  B29C64/112 ,  B33Y10/00 ,  B33Y70/00 ,  B42D25/00 ,  B42D25/29 ,  B42D25/324 ,  B42D25/328 ,  B42D25/333 ,  B42D2033/20 ,  B42D2033/24 ,  B42D2033/46

    摘要： A method is described of producing thin layers (below 10 μm in thickness) by directing droplets (preferably by inkjet printing techniques) onto precise locations on a substrate, the liquid of the droplets having a viscosity such that the droplets, on impact with the substrate, spread out to form relics on the substrate that are at least 1.4 times the diameter of the droplets in flight, adjacent droplets merging to form a continuous layer on the substrate. The droplets may have different compositions to form images within the layer. Successive layers may be added to built up a three dimensional structure whose properties can be tailored by the compositions used to build up a composite.

    摘要翻译： 描述了通过将液滴（优选通过喷墨印刷技术）引导到基底上的精确位置上来生产薄层（厚度低于10um）的方法，液滴的液体具有使得液滴在与基底碰撞时的粘度 ，展开以形成至少为飞行中液滴直径的1.4倍的基材上的相邻液滴，从而在基板上形成连续的层。 液滴可以具有不同的组成以在层内形成图像。 可以添加连续的层以构建三维结构，其三维结构的特性可以由用于构建复合材料的组合物来调整。

    Three-dimensional structured printing
    7.
    发明授权
    Three-dimensional structured printing 有权
    三维结构印刷

    公开(公告)号：US07767132B2

    公开(公告)日：2010-08-03

    申请号：US12044269

    申请日：2008-03-07

    申请人： Ranjana Patel ,  Richard J. Peace ,  Yong Zhao ,  Jeremy Powell ,  Michael Rhodes

    发明人： Ranjana Patel ,  Richard J. Peace ,  Yong Zhao ,  Jeremy Powell ,  Michael Rhodes

    IPC分类号： B27N5/00 ,  B29C35/08 ,  B29C41/02

    CPC分类号： B29C64/165 ,  B29K2105/162 ,  B33Y10/00 ,  B33Y30/00 ,  B33Y70/00

    摘要： A process for forming a three-dimensional article in sequential layers in accordance with a digital model of the article. The process comprises the steps of defining a layer of powder material, applying a liquid reagent to the powder layer in a pattern corresponding to the digital model, and repeating these steps to form successive layers. The powder comprises a first reactive component and the liquid includes a second active component capable of reacting with the first reactive component so that the article is built up in layers.

    摘要翻译： 根据制品的数字模型在连续层中形成三维制品的方法。 该方法包括以下步骤：定义一层粉末材料，以对应于数字模型的图案将液体试剂施加到粉末层，并重复这些步骤以形成连续的层。 粉末包括第一反应性组分，并且液体包括能够与第一反应性组分反应的第二活性组分，使得制品层压成型。

    Photocurable Compositions
    9.
    发明申请
    Photocurable Compositions 有权
    光固化组合物

    公开(公告)号：US20070205528A1

    公开(公告)日：2007-09-06

    申请号：US10593746

    申请日：2005-03-21

    申请人： Ranjana Patel ,  Michael Rhodes ,  Yong Zhao

    发明人： Ranjana Patel ,  Michael Rhodes ,  Yong Zhao

    IPC分类号： A61C13/00

    CPC分类号： G03F7/038 ,  B29C2035/0827 ,  B29K2033/00 ,  B33Y70/00 ,  G03F7/0037

    摘要： An optical moulding process is disclosed comprising the sequential steps of: (a)(y) forming a layer of a photocurable composition; and (bXz) irradiating selected areas of the composition in the layer with radiation from a radiation source, thereby curing the composition in said selected areas and repeating the steps a) and b) on top of an earlier cured layer to form a three dimensional structure, wherein the radiation source used in step b) is a non-coherent source of radiation and wherein the photocurable composition comprises at least two curable components: (i) 45%-95% (and preferably at least 50%, more preferably at least 60%, e.g. at least 70%) by weight of the total curable components in the composition is a first component that is photocurable and that is such that, when cured in the presence of a photocuring initiator by exposure to UV radiation having an energy of 30 mJ/cm2, at least 90% of the component is cured within 50 milliseconds; and (ii) 5% to 55% (and preferably 10-40%, more preferably 15 to 30%, e.g. about 20%) by weight of the total curable components in the composition is a second component that results in the composition, on curing, shrinking, in a linear direction, by less than 3% and preferably that results in the composition having, after cure, a Tg of greater than 50° C., preferably at least 100° C. and more preferably at least 120° C.

    摘要翻译： 公开了一种光学模制方法，其包括以下顺序步骤：（a）（y）形成光固化组合物层; 和（bXz）用来自辐射源的辐射照射该组合物中的组合物的所选区域，从而固化所述选定区域中的组合物，并在较早固化层的顶部重复步骤a）和b），以形成三维结构 其中步骤b）中使用的辐射源是非相干辐射源，并且其中所述可光固化组合物包含至少两种可固化组分：（i）45％-95％（优选至少50％，更优选至少为 组合物中总可固化组分的60重量％，例如至少70重量％）是可光固化的第一组分，并且使得当在光固化引发剂存在下通过暴露于具有 30mJ / cm 2，至少90％的组分在50毫秒内固化; 和（ii）组合物中总可固化组分的5重量％至55重量％（优选10-40重量％，更优选15至30重量％，例如约20重量％）是导致组合物的第二组分， 在线性方向上固化，收缩小于3％，优选地导致组合物在固化后具有大于50℃，优选至少100℃的T g 更优选至少120℃

    Photocurable compositions
    10.
    发明授权
    Photocurable compositions 有权
    可光固化组合物

    公开(公告)号：US08097399B2

    公开(公告)日：2012-01-17

    申请号：US10593746

    申请日：2005-03-21

    申请人： Ranjana Patel ,  Michael Rhodes ,  Yong Zhao

    发明人： Ranjana Patel ,  Michael Rhodes ,  Yong Zhao

    IPC分类号： G03F7/027 ,  B29C67/00

    CPC分类号： G03F7/038 ,  B29C2035/0827 ,  B29K2033/00 ,  B33Y70/00 ,  G03F7/0037

    摘要： An optical moulding process is disclosed comprising the sequential steps of: (a)(y) forming a layer of a photocurable composition; and (bXz) irradiating selected areas of the composition in the layer with radiation from a radiation source, thereby curing the composition in said selected areas and repeating the steps a) and b) on top of an earlier cured layer to form a three dimensional structure, wherein the radiation source used in step b) is a non-coherent source of radiation and wherein the photocurable composition comprises at least two curable components: (i) 45%-95% (and preferably at least 50%, more preferably at least 60%, e.g. at least 70%) by weight of the total curable components in the composition is a first component that is photocurable and that is such that, when cured in the presence of a photocuring initiator by exposure to UV radiation having an energy of 30 mJ/cm2, at least 90% of the component is cured within 50 milliseconds; and (ii) 5% to 55% (and preferably 10-40%, more preferably 15 to 30%, e.g. about 20%) by weight of the total curable components in the composition is a second component that results in the composition, on curing, shrinking, in a linear direction, by less than 3% and preferably that results in the composition having, after cure, a Tg of greater than 50° C., preferably at least 100° C. and more preferably at least 120° C.

    摘要翻译： 公开了一种光学模制方法，其包括以下顺序步骤：（a）（y）形成光固化组合物层; 和（bXz）用来自辐射源的辐射照射该组合物中的组合物的所选区域，从而固化所述选定区域中的组合物，并在较早固化层的顶部重复步骤a）和b），以形成三维结构 其中步骤b）中使用的辐射源是非相干辐射源，并且其中所述可光固化组合物包含至少两种可固化组分：（i）45％-95％（优选至少50％，更优选至少为 组合物中总可固化组分的60重量％，例如至少70重量％）是可光固化的第一组分，并且使得当在光固化引发剂存在下通过暴露于具有 30mJ / cm 2，至少90％的组分在50毫秒内固化; 和（ii）组合物中总可固化组分的5重量％至55重量％（优选10-40重量％，更优选15至30重量％，例如约20重量％）是导致组合物的第二组分， 在线性方向上固化，收缩小于3％，优选地导致组合物在固化后具有大于50℃，优选至少100℃，更优选至少120℃的Tg C。