公开(公告)号：US20060084753A1

公开(公告)日：2006-04-20

申请号：US10518342

申请日：2003-06-17

申请人： Laurent Dumont ,  Alian Pouchelon ,  Marilyne Quemin

发明人： Laurent Dumont ,  Alian Pouchelon ,  Marilyne Quemin

IPC分类号： C08L83/04 ,  C08L83/00

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/20 ,  C08G77/24 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31663 ,  C08L2666/14

摘要： A silicone composition useful especially for the production of varnishes applicable to substrates whose coefficient of friction it is sought to reduce. The object is to provide an anti-friction silicone varnish for textiles coated with silicone elastomers which is economic and adhesive, provides the desired slip, resists soiling and is shiny. This object is achieved by a crosslinkable silicone composition containing two silicones A and B which react with one another in the presence of a catalyst C to allow crosslinking, and a particulate component D selected from the group comprising powdered (co)polyamides—preferably (co)polyamides 6, 12 and 6/12. The (co)polyamide particles are of substantially rounded shape and the mean particle diameter Φmd is between 0.1 and 200 μm, preferably between 5 and 100 μm and particularly preferably between 10 and 50 μm. Also disclosed is a varnishing process and a composite containing the varnished substrate.

摘要翻译： 一种有机硅组合物，其特别用于生产适用于寻求降低摩擦系数的基材的清漆。 目的是为涂有硅氧烷弹性体的纺织品提供一种抗摩擦硅油清漆，这是有经济和粘合性的，提供所需的滑爽，抗污染和有光泽。 该目的是通过一种可交联的硅氧烷组合物实现的，该组合物含有两种在催化剂C存在下相互反应以允许交联的硅氧烷A和B，以及选自粉末状（共）聚酰胺 - 优选（共） ）聚酰胺6,12和6/12。 （共）聚酰胺颗粒基本上为圆形，平均粒径PhiMS为0.1〜200μm，优选为5〜100μm，特别优选为10〜50μm。 还公开了上漆工艺和含有上漆基材的复合材料。

公开(公告)号：US07198854B2

公开(公告)日：2007-04-03

申请号：US10518342

申请日：2003-06-17

申请人： Laurent Dumont ,  Alain Pouchelon ,  Marilyne Quemin

发明人： Laurent Dumont ,  Alain Pouchelon ,  Marilyne Quemin

IPC分类号： C08L83/04

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/20 ,  C08G77/24 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31663 ,  C08L2666/14

摘要： A silicone composition useful especially for the production of varnishes applicable to substrates whose coefficient of friction it is sought to reduce. The object is to provide an anti-friction silicone varnish for textiles coated with silicone elastomers which is economic and adhesive, provides the desired slip, resists soiling and is shiny. This object is achieved by a crosslinkable silicone composition containing two silicones A and B which react with one another in the presence of a catalyst C to allow crosslinking, and a particulate component D selected from the group comprising powdered (co)polyamides—preferably (co)polyamides 6, 12 and 6/12. The (co)polyamide particles are of substantially rounded shape and the mean particle diameter Φmd is between 0.1 and 200 μm, preferably between 5 and 100 μm and particularly preferably between 10 and 50 μm. Also disclosed is a varnishing process and a composite containing the varnished substrate.

摘要翻译： 一种有机硅组合物，其特别用于生产适用于寻求降低摩擦系数的基材的清漆。 目的是为涂有硅氧烷弹性体的纺织品提供一种抗摩擦硅油清漆，这是有经济和粘合性的，提供所需的滑爽，抗污染和有光泽。 该目的是通过一种可交联的硅氧烷组合物实现的，该组合物含有两种在催化剂C存在下相互反应以允许交联的硅氧烷A和B，以及选自粉末状（共）聚酰胺 - 优选（共） ）聚酰胺6,12和6/12。 （共）聚酰胺颗粒基本上为圆形，平均粒径PhiMS为0.1〜200μm，优选为5〜100μm，特别优选为10〜50μm。 还公开了上漆工艺和含有上漆基材的复合材料。

公开(公告)号：US08153206B2

公开(公告)日：2012-04-10

申请号：US12068453

申请日：2008-02-06

申请人： Marilyne Quemin ,  Laurent Dumont ,  Francis Lafaysse

发明人： Marilyne Quemin ,  Laurent Dumont ,  Francis Lafaysse

IPC分类号： C08J7/18

CPC分类号： D06N3/128 ,  C08K5/0091 ,  C09D4/00 ,  C09D183/04 ,  D06M15/3568 ,  D06M15/643 ,  D06N3/183 ,  Y10T428/31663 ,  Y10T442/2279 ,  C08G77/20 ,  C08L2666/52

摘要： Silicone compositions, particularly for the production of anti-fouling varnishes which may be applied to flexible or bulk supports to provide an anti-fouling silicone varnish for textiles coated with elastomeric silicones which is economical, adhesive, low-slip and glossy; these are crosslinked silicone compositions comprising: A. at least one alkenylsilane, B. at least one catalytic system which comprises: B/1 at least one organometallic condensation catalyst, B/2 at least one metal M chelate and/or one metal alkoxide of general formula M(OJ)n, wherein n=valence of M and J=linear or branched C1-C8 alkyl radical, M being selected from among: Ti, Zr, Ge and Al, C. at least one ultrafine filler, D. optionally, at least one arylsilane other than A. E. optionally, at least one other silane other than A. and other than D., F. optionally, at least one thickening agent and G. optionally, at least one functional additive.

摘要翻译： 硅酮组合物，特别是用于生产防污清漆，其可应用于柔性或大体积的支持物，以提供用于涂覆有弹性体硅酮的纺织品的防污硅氧烷清漆，其具有经济性，粘合性，低滑爽和光滑; 这些是交联硅氧烷组合物，其包含：A.至少一种烯基硅烷，B.至少一种催化体系，其包含：B / 1至少一种有机金属缩合催化剂，B / 2至少一种金属M螯合物和/或一种金属醇盐 通式M（OJ）n，其中n = M的价数，J =直链或支链的C 1 -C 8烷基，M选自：Ti，Zr，Ge和Al，C至少一种超细填料D. 任选地，至少一种除了AE之外的至少一种芳基硅烷任选地至少一种除了D.而不是D.，F之外的至少一种其它硅烷。任选地，至少一种增稠剂和G.任选的至少一种功能添加剂。

公开(公告)号：US20060019106A1

公开(公告)日：2006-01-26

申请号：US11166218

申请日：2005-06-27

申请人： Marilyne Quemin ,  Laurent Dumont ,  Francis Lafaysse

发明人： Marilyne Quemin ,  Laurent Dumont ,  Francis Lafaysse

IPC分类号： B32B25/20 ,  B32B9/04

CPC分类号： D06N3/128 ,  C08K5/0091 ,  C09D4/00 ,  C09D183/04 ,  D06M15/3568 ,  D06M15/643 ,  D06N3/183 ,  Y10T428/31663 ,  Y10T442/2279 ,  C08G77/20 ,  C08L2666/52

摘要： Silicone compositions, particularly for the production of anti-fouling varnishes which may be applied to flexible or bulk supports to provide an anti-fouling silicone varnish for textiles coated with elastomeric silicones which is economical, adhesive, low-slip and glossy; these are crosslinked silicone compositions comprising: A. at least one alkenylsilane, B. at least one catalytic system which comprises: B/1 at least one organometallic condensation catalyst, B/2 at least one metal M chelate and/or one metal alkoxide of general formula M(OJ)n, wherein n=valence of M and J=linear or branched C1-C8 alkyl radical, M being selected from among: Ti, Zr, Ge and Al, C. at least one ultrafine filler, D. optionally, at least one arylsilane other than A. E. optionally, at least one other silane other than A. and other than D., F. optionally, at least one thickening agent and G. optionally, at least one functional additive.

摘要翻译： 硅酮组合物，特别是用于生产防污清漆，其可应用于柔性或大体积的支持物，以提供用于涂覆有弹性体硅酮的纺织品的防污硅氧烷清漆，其具有经济性，粘合性，低滑爽和光泽; 这些是交联硅氧烷组合物，其包含：A.至少一种烯基硅烷，B.至少一种催化体系，其包含：B / 1至少一种有机金属缩合催化剂，B / 2至少一种金属M螯合物和/或一种金属醇盐 通式M（OJ）n N，其中n = M的价数，J =直链或支链C 1 -C 8烷基，M 选自Ti，Zr，Ge和Al，C.至少一种超细填料，D.任选地，除AE之外的至少一种芳族硅烷任选地除了除D.之外的至少一种其它硅烷，而不是D.，F 任选地，至少一种增稠剂和G.任选的至少一种功能添加剂。

公开(公告)号：US20080311810A1

公开(公告)日：2008-12-18

申请号：US12068453

申请日：2008-02-06

申请人： Marilyne Quemin ,  Laurent Dumont ,  Francis Lafaysse

发明人： Marilyne Quemin ,  Laurent Dumont ,  Francis Lafaysse

IPC分类号： B32B27/04 ,  C09D143/04 ,  C09D4/00

CPC分类号： D06N3/128 ,  C08K5/0091 ,  C09D4/00 ,  C09D183/04 ,  D06M15/3568 ,  D06M15/643 ,  D06N3/183 ,  Y10T428/31663 ,  Y10T442/2279 ,  C08G77/20 ,  C08L2666/52

摘要： Silicone compositions, particularly for the production of anti-fouling varnishes which may be applied to flexible or bulk supports to provide an anti-fouling silicone varnish for textiles coated with elastomeric silicones which is economical, adhesive, low-slip and glossy; these are crosslinked silicone compositions comprising: A. at least one alkenylsilane, B. at least one catalytic system which comprises: B/1 at least one organometallic condensation catalyst, B/2 at least one metal M chelate and/or one metal alkoxide of general formula M(OJ)n, wherein n=valence of M and J=linear or branched C1-C8 alkyl radical, M being selected from among: Ti, Zr, Ge and Al, C. at least one ultrafine filler, D. optionally, at least one arylsilane other than A. E. optionally, at least one other silane other than A. and other than D., F. optionally, at least one thickening agent and G. optionally, at least one functional additive.

摘要翻译： 硅酮组合物，特别是用于生产防污清漆，其可应用于柔性或大体积的支持物，以提供用于涂覆有弹性体硅酮的纺织品的防污硅氧烷清漆，其具有经济性，粘合性，低滑爽和光泽; 这些是交联硅氧烷组合物，其包含：A.至少一种烯基硅烷，B.至少一种催化体系，其包含：B / 1至少一种有机金属缩合催化剂，B / 2至少一种金属M螯合物和/或一种金属醇盐 通式M（OJ）n，其中n = M的价数，J =直链或支链的C 1 -C 8烷基，M选自：Ti，Zr，Ge和Al，C至少一种超细填料D. 任选地，至少一种除了AE之外的至少一种芳基硅烷任选地至少一种除了D.而不是D.，F之外的至少一种其它硅烷。任选地，至少一种增稠剂和G.任选的至少一种功能添加剂。

公开(公告)号：US07868056B2

公开(公告)日：2011-01-11

申请号：US12318843

申请日：2009-01-09

申请人： Francis Lafaysse ,  Pierre Luciani ,  Didier Dhaler ,  Laurent Dumont ,  Jean-Marc Frances

发明人： Francis Lafaysse ,  Pierre Luciani ,  Didier Dhaler ,  Laurent Dumont ,  Jean-Marc Frances

IPC分类号： C09J4/00 ,  C09J201/10

CPC分类号： C09D163/00 ,  C08G59/306 ,  C08K5/151 ,  C08K5/5435 ,  C08K5/55 ,  C09D183/06 ,  Y10T428/2962 ,  Y10T428/31663 ,  Y10T442/2525 ,  C08L2666/46

摘要： Silicone compositions particularly useful for the production of anti-fouling varnishes for application to support substrates, these providing an anti-fouling varnish for textiles covered with silicone elastomers which is economical, adhesive, non-slip and glossy; the subject varnishes comprise a crosslinkable silicone composition containing, per 100 parts by weight: 1, at least 80 parts by weight of: (1.1), 2., 0.1 to 10 parts of weight of: (1.2), 3., 0 to 10 parts by weight of at least one polydimethylisiloxane (PDMS) acrylate or epoxide, 4., 0 to 10 parts by weight of at least one silylated compound which includes at least one ultrafine filler, 7., 0 to 10 parts by weight of at least one thickener, and 8., 0 to 10 parts by weigh of at least one additional functional additive.

摘要翻译： 硅胶组合物特别可用于生产用于支撑基材的防污清漆，这些提供了用于经济，粘合，防滑和有光泽的硅氧烷弹性体覆盖的织物的防污清漆; 所述清漆包含每100重量份的交联性硅氧烷组合物：1，至少80重量份：（1.1），2.，0.1至10重量份：（1.2），3.，0至 10重量份的至少一种聚二甲基硅氧烷（PDMS）丙烯酸酯或环氧化物，4. 0至10重量份的至少一种甲硅烷基化合物，其包括至少一种超细填料，7. 0至10重量份的 至少一种增稠剂和8.,0至10份重量的至少一种其它功能添加剂。

公开(公告)号：US20090186224A1

公开(公告)日：2009-07-23

申请号：US12318843

申请日：2009-01-09

申请人： Francis Lafaysse ,  Pierre Luciani ,  Didier Dhaler ,  Laurent Dumont ,  Jean-Marc Frances

发明人： Francis Lafaysse ,  Pierre Luciani ,  Didier Dhaler ,  Laurent Dumont ,  Jean-Marc Frances

IPC分类号： B32B9/00 ,  B32B17/02 ,  B32B18/00

CPC分类号： C09D163/00 ,  C08G59/306 ,  C08K5/151 ,  C08K5/5435 ,  C08K5/55 ,  C09D183/06 ,  Y10T428/2962 ,  Y10T428/31663 ,  Y10T442/2525 ,  C08L2666/46

摘要： Silicone compositions particularly useful for the production of anti-fouling varnishes for application to support substrates, these providing an anti-fouling varnish for textiles covered with silicone elastomers which is economical, adhesive, non-slip and glossy; the subject varnishes comprise a crosslinkable silicone composition containing, per 100 parts by weight: 1, at least 80 parts by weight of: (1.1), 2., 0.1 to 10 parts of weight of: (1.2), 3., 0 to 10 parts by weight of at least one polydimethylisiloxane (PDMS) acrylate or epoxide, 4., 0 to 10 parts by weight of at least one silylated compound which includes at least one ultrafine filler, 7., 0 to 10 parts by weight of at least one thickener, and 8., 0 to 10 parts by weigh of at least one additional functional additive.

摘要翻译： 硅胶组合物特别可用于生产用于支撑基材的防污清漆，这些提供了用于经济，粘合，防滑和有光泽的硅氧烷弹性体覆盖的织物的防污清漆; 所述清漆包含每100重量份的交联性硅氧烷组合物：1，至少80重量份：（1.1），2.，0.1至10重量份：（1.2），3.，0至 10重量份的至少一种聚二甲基硅氧烷（PDMS）丙烯酸酯或环氧化物，4. 0至10重量份的至少一种甲硅烷基化合物，其包括至少一种超细填料，7. 0至10重量份的 至少一种增稠剂和8.,0至10份重量的至少一种其它功能添加剂。

公开(公告)号：US20060157453A1

公开(公告)日：2006-07-20

申请号：US10518344

申请日：2003-06-17

申请人： Laurent Dumont ,  Alain Pouchelon

发明人： Laurent Dumont ,  Alain Pouchelon

IPC分类号： B23K9/00

CPC分类号： C08J5/124 ,  B29C59/005 ,  B29C59/14 ,  B29C2059/145 ,  B29K2083/00 ,  C08J7/123 ,  C08J2383/04 ,  C09J5/02

摘要： A process for increasing the surface tension (“wettability”) of a silicone element crosslinked by polyaddition from a liquid composition containing one or more α, ω-dimethylvinylpolydimethylsiloxanes (PDMS), one or more poly(dimethyl) (methylhydrogenosiloxy)-α,ω-dimethylhydrogenosiloxanes, and a platinum crosslinking catalyst. The silicone surface is treated with a homogeneous atmospheric plasma using a plasma spraying apparatus having a rotating head with one or more plasma nozzles that are offset relative to the axis of rotation, each one being capable of generating a plasma jet whose axis is parallel to said axis of rotation. The articles to which the invention relate include composites of flexible substrate (e.g. textile)/silicone coating. Application: adhesive bonding of silicone surfaces crosslinked by ≡Si—H/≡Si-vinyl polyaddition.

摘要翻译： 通过加聚从含有一种或多种α，ω-二甲基乙烯基聚二甲基硅氧烷（PDMS），一种或多种聚（二甲基）（甲基氢甲硅烷氧基）-α，ω，ω-二甲基乙烯基聚二甲基硅氧烷的液体组合物的组合物交联的硅氧烷元素的表面张力（“润湿性” 二甲基氢硅氧烷和铂交联催化剂。 使用具有旋转头的等离子体喷涂装置处理硅树脂表面，所述等离子喷涂装置具有相对于旋转轴线偏移的一个或多个等离子体喷嘴，每个等离子体喷嘴能够产生其轴线平行于所述 旋转轴。 本发明涉及的制品包括柔性基底（例如织物）/硅氧烷涂层的复合材料。 应用：通过≡Si-H /≡Si-乙烯基加聚交联的硅氧烷表面的粘合剂。

公开(公告)号：US07423234B2

公开(公告)日：2008-09-09

申请号：US10518344

申请日：2003-06-17

申请人： Laurent Dumont ,  Alain Pouchelon

发明人： Laurent Dumont ,  Alain Pouchelon

IPC分类号： B23K10/00

CPC分类号： C08J5/124 ,  B29C59/005 ,  B29C59/14 ,  B29C2059/145 ,  B29K2083/00 ,  C08J7/123 ,  C08J2383/04 ,  C09J5/02

摘要： A process for increasing the surface tension (“wettability”) of a silicone element crosslinked by polyaddition from a liquid composition containing one or more α,ω-dimethylvinylpolydimethylsiloxanes (PDMS), one or more poly(dimethyl)(methylhydrogenosiloxy)-α,ω-dimethylhydrogenosiloxanes, and a platinum crosslinking catalyst. The silicone surface is treated with a homogeneous atmospheric plasma using a plasma spraying apparatus having a rotating head with one or more plasma nozzles that are offset relative to the axis of rotation, each one being capable of generating a plasma jet whose axis is parallel to said axis of rotation. The articles to which the invention relate include composites of flexible substrate (e.g. textile)/silicone coating. Application: adhesive bonding of silicone surfaces crosslinked by ≡Si—H/≡Si-vinyl polyaddition.

摘要翻译： 通过加聚从含有一种或多种α，ω-二甲基乙烯基聚二甲基硅氧烷（PDMS），一种或多种聚（二甲基）（甲基氢甲硅烷氧基）-α，ω，ω-二甲基乙烯基聚二甲基硅氧烷的液体组合物的组合物交联的硅氧烷元素的表面张力（“润湿性” 二甲基氢硅氧烷和铂交联催化剂。 使用具有旋转头部的等离子体喷涂装置处理硅树脂表面，所述等离子体喷涂装置具有相对于旋转轴线偏移的一个或多个等离子体喷嘴，每个等离子体喷嘴能够产生其轴线平行于所述 旋转轴。 本发明涉及的制品包括柔性基底（例如织物）/硅氧烷涂层的复合材料。 应用：通过≡Si-H /≡Si-乙烯基加聚交联的硅氧烷表面的粘合剂。

公开(公告)号：US20060122323A1

公开(公告)日：2006-06-08

申请号：US10518401

申请日：2003-06-17

申请人： Laurent Dumont ,  Michel Feder ,  Francis Layfaysse ,  Sylvie Robelin

发明人： Laurent Dumont ,  Michel Feder ,  Francis Layfaysse ,  Sylvie Robelin

IPC分类号： C08L83/04 ,  B01F3/08 ,  B32B27/04

CPC分类号： D06N3/128 ,  C03C25/40 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/20 ,  C08G77/26 ,  C08G77/70 ,  C08L83/04 ,  D06M15/643 ,  Y10T428/31663 ,  C08L83/00

摘要： An aqueous polyorganosiloxane (POS) emulsion which can easily be deposited on/applied to a fibrous substrate at high speed and at limited deposition rates, for example less than 40 g/m2. The emulsion contains (A) a POS with ≡Si-vinyl units, (B) a POS with ≡SiH units, (C) an adhesion promoter, (D) a catalyst, (E) at least one surfactant, (F) optionally a POS resin with ≡Si-vinyl units, (G) optionally a crosslinking inhibitor, (H) optionally a pH fixing agent, (I) optionally a formulating additive, (J) optionally a filler, and (K) water. Adhesion promoter (C) is selected from protective hydrocolloids, hydroxylated silanes and/or POS carrying at least one hydroxyl group and at least one salified amino group per molecule, and mixtures thereof, and is present in the range from 0.005 to 10% by weight, based on the silicone phase. Also disclosed is the corresponding coating process and the coated substrate.

摘要翻译： 一种水溶性聚有机硅氧烷（POS）乳液，其可以容易地以高速和有限的沉积速率沉积在/施加到纤维基材上，例如小于40g / m 2。 乳液含有（A）具有≡Si-乙烯基单元的POS，（B）具有≡SiH单元的POS，（C）粘合促进剂，（D）催化剂，（E）至少一种表面活性剂，（F） 具有≡Si-乙烯基单元的POS树脂，（G）任选的交联抑制剂，（H）任选的pH固定剂，（I）任选的配制添加剂，（J）任选的填料和（K）水。 粘合促进剂（C）选自保护性水胶体，羟基化硅烷和/或POS，每个分子具有至少一个羟基和至少一个成盐氨基，以及它们的混合物，并且其含量范围为0.005-10重量％ ，基于有机硅相。 还公开了相应的涂覆工艺和涂覆的基材。