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    RECONSTITUTED DEHYDROGENATION CATALYST SHOWING SLOWED ACTIVITY LOSS WHEN COMPARED WITH FRESH CATALYST
    1.
    发明申请
    RECONSTITUTED DEHYDROGENATION CATALYST SHOWING SLOWED ACTIVITY LOSS WHEN COMPARED WITH FRESH CATALYST 审中-公开
    与新鲜催化剂比较时，重新发现的脱氢催化剂显示出缓慢的活性损失

    公开(公告)号：US20140371501A1

    公开(公告)日：2014-12-18

    申请号：US14366611

    申请日：2013-02-06

    申请人： Lin Luo ,  Devon C. Rosenfeld ,  Andrzej M. Malek

    发明人： Lin Luo ,  Devon C. Rosenfeld ,  Andrzej M. Malek

    IPC分类号： B01J23/62 ,  C07C5/32

    CPC分类号： B01J23/62 ,  B01J23/96 ,  B01J38/485 ,  C07C5/322 ,  C07C5/3337 ,  C07C2521/12 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/42 ,  C07C2523/62 ,  C07C2527/224 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06

    摘要： A process for dehydrogenating alkane or alkylaromatic compounds comprising contacting the given compound and a dehydrogenation catalyst in a fluidized bed. The dehydrogenation catalyst is prepared from an at least partially deactivated platinum/gallium catalyst on an alumina-based support that is reconstituted by impregnating it with a platinum salt solution, then calcining it at a temperature from 400° C. to 1000° C., under conditions such that it has a platinum content ranging from 1 to 500 ppm, based on weight of catalyst; a gallium content ranging from 0.2 to 2.0 wt %; and a platinum to gallium ratio ranging from 1:20,000 to 1:4. It also has a Pt retention that is equal to or greater than that of a fresh catalyst being used in a same or similar catalytic process.

    摘要翻译： 一种使烷烃或烷基芳族化合物脱氢的方法，包括在流化床中使给定化合物和脱氢催化剂接触。 脱氢催化剂由氧化铝基载体上的至少部分失活的铂/镓催化剂制备，其通过用铂盐溶液浸渍而重新构成，然后在400℃至1000℃的温度下煅烧， 在其基于催化剂重量的铂含量为1至500ppm的条件下进行; 镓含量范围为0.2-2.0重量％; 铂与镓之比为1：20,000至1：4。 它还具有等于或大于在相同或相似催化过程中使用的新鲜催化剂的Pt保留。

    CATALYST COMPOSITION FOR DIRECT CONVERSION OF ETHANOL TO PROPYLENE
    4.
    发明申请
    CATALYST COMPOSITION FOR DIRECT CONVERSION OF ETHANOL TO PROPYLENE 有权
    乙醇直接转化成丙烯的催化剂组合物

    公开(公告)号：US20120330080A1

    公开(公告)日：2012-12-27

    申请号：US13576431

    申请日：2011-03-07

    申请人： Yu Liu ,  Andrzej M. Malek ,  Albert E. Schweizer, JR.

    发明人： Yu Liu ,  Andrzej M. Malek ,  Albert E. Schweizer, JR.

    IPC分类号： C07C1/20 ,  B01J29/48

    CPC分类号： B01J29/48 ,  C07C1/20 ,  C07C2529/48 ,  Y02P20/52 ,  C07C11/06

    摘要： A process to prepare propylene showing desirably increased selectivity comprises contacting, at an elevated temperature, ethanol and a rhenium oxide-modified ZSM-5 zeolite catalyst, under conditions suitable to form propylene. The rhenium oxide-modified ZSM-5 zeolite catalyst may be prepared by impregnating, in an aqueous or organic medium, a ZSM-5 zeolite with a rhenium source, under conditions suitable to form a catalyst precursor, and calcining the catalyst precursor under conditions suitable to form a rhenium oxide-modified ZSM-5 zeolite catalyst.

    摘要翻译： 制备丙烯的方法显示出期望的增加的选择性包括在适于形成丙烯的条件下，在高温下使乙醇和氧化铼改性的ZSM-5沸石催化剂接触。 氧化铼氧化物改性的ZSM-5沸石催化剂可以通过在适合于形成催化剂前体的条件下在含水或有机介质中浸渍具有铼源的ZSM-5沸石并在合适的条件下煅烧催化剂前体来制备 以形成氧化铼氧化物改性的ZSM-5沸石催化剂。

    Fischer-Tropsch catalyst production
    5.
    发明授权
    Fischer-Tropsch catalyst production 有权
    费 - 托催化剂生产

    公开(公告)号：US07361619B2

    公开(公告)日：2008-04-22

    申请号：US10819379

    申请日：2004-04-06

    申请人： Andrzej M. Malek ,  Stephen C. Leviness ,  Horacio M. Trevino ,  Weldon K. Bell ,  David O. Marler

    发明人： Andrzej M. Malek ,  Stephen C. Leviness ,  Horacio M. Trevino ,  Weldon K. Bell ,  David O. Marler

    IPC分类号： B01J20/34 ,  B01J21/20 ,  B01J23/00 ,  B01J25/04 ,  B01J27/28

    CPC分类号： C10G2/33 ,  B01J23/75 ,  B01J23/8896 ,  B01J37/12 ,  B01J37/18

    摘要： Dispersed Active Metal catalyst for hydrogenation reactions is produced by treating a substantially catalytically inactive metal particulate with a solution capable of oxidizing the metal particulate and comprising of at least one compound of a hydrogenation catalyst metal thereby forming a layer of at least one of hydroxides and oxides thereon. The metal particulate is activated by treatment with a hydrogen-containing gas at elevated temperatures to form a porous layer of Dispersed Active Metal catalyst. Preferably, the treated metal particulate is dried prior to activation, and also preferably calcined in an oxidant-containing atmosphere prior to activation. The treatment solution may advantageously contain a compound of at least one promoter metal for the added catalyst metal. The porosity of the layer provides enhanced catalyst activity as well as improved methane selectivity in the Fischer-Tropsch process.

    摘要翻译： 用于氢化反应的分散活性金属催化剂通过用能够氧化金属颗粒并且包含至少一种氢化催化剂金属的化合物的溶液处理基本上催化惰性的金属颗粒而产生，从而形成氢氧化物和氧化物中的至少一种的层 上。 通过在高温下用含氢气体处理来活化金属颗粒以形成分散活性金属催化剂的多孔层。 优选地，处理的金属颗粒在活化之前被干燥，并且还优选在活化之前在含氧化剂的气氛中煅烧。 处理溶液可以有利地含有用于加入的催化剂金属的至少一种助催化剂金属的化合物。 该层的孔隙率提高了催化剂活性以及在费 - 托工艺中提高的甲烷选择性。

    Fischer-Tropsch catalyst production
    7.
    发明授权
    Fischer-Tropsch catalyst production 有权
    费 - 托催化剂生产

    公开(公告)号：US07419928B2

    公开(公告)日：2008-09-02

    申请号：US10819378

    申请日：2004-04-06

    申请人： Andrzej M. Malek ,  Stephen C. Leviness ,  Horacio M. Trevino ,  Weldon K. Bell ,  David O. Marler

    发明人： Andrzej M. Malek ,  Stephen C. Leviness ,  Horacio M. Trevino ,  Weldon K. Bell ,  David O. Marler

    IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00 ,  B01J27/00 ,  B01J29/00

    CPC分类号： C10G2/332 ,  B01J23/75 ,  B01J23/8896 ,  B01J25/00 ,  B01J37/12 ,  B01J37/14 ,  B01J37/18 ,  C10G2/333

    摘要： A process for enhancing the activity of a catalyst metal particulate for hydrogenation reactions comprising calcining the particulate in an oxidant-containing atmosphere to partially oxidize it thereby forming a porous layer of oxides thereon, treating with an solution capable of oxidizing the calcined metal particulate and comprising a compound of a hydrogenation catalyst metal to where said metal particulate has absorbed a volume of solution equal to at least about 10% of its calculated pore volume and activating it by treatment with a hydrogen-containing gas at elevated temperatures thereby forming a dispersed active metal catalyst. Preferably, the treated particulate is calcined a second time under the same conditions as the first before final activation with a hydrogen-containing gas. The metal particulate is preferably sized after each calcination and any agglomerates larger than 250 microns are comminuted to a desired size.

    摘要翻译： 一种用于增强用于氢化反应的催化剂金属颗粒的活性的方法，包括在含氧化剂的气氛中煅烧颗粒以部分氧化，从而在其上形成多孔氧化物层，用能够氧化煅烧金属颗粒的溶液进行处理并包含 氢化催化剂金属的化合物，其中所述金属颗粒吸收了等于其计算孔体积的至少约10％的溶液体积，并通过在高温下用含氢气体处理使其活化，由此形成分散的活性金属 催化剂。 优选地，处理的颗粒在与含氢气体最终活化之前的第一次相同的条件下煅烧第二次。 优选在每次煅烧之后将金属颗粒定形，并将大于250微米的任何附聚物粉碎至所需尺寸。

    Catalyst composition for direct conversion of ethanol to propylene
    9.
    发明授权
    Catalyst composition for direct conversion of ethanol to propylene 有权
    用于将乙醇直接转化成丙烯的催化剂组合物

    公开(公告)号：US08598399B2

    公开(公告)日：2013-12-03

    申请号：US13576431

    申请日：2011-03-07

    申请人： Yu Liu ,  Andrzej M. Malek ,  Albert E. Schweizer, Jr.

    发明人： Yu Liu ,  Andrzej M. Malek ,  Albert E. Schweizer, Jr.

    IPC分类号： C07C1/00

    CPC分类号： B01J29/48 ,  C07C1/20 ,  C07C2529/48 ,  Y02P20/52 ,  C07C11/06

    摘要： A process to prepare propylene showing desirably increased selectivity comprises contacting, at an elevated temperature, ethanol and a rhenium oxide-modified ZSM-5 zeolite catalyst, under conditions suitable to form propylene. The rhenium oxide-modified ZSM-5 zeolite catalyst may be prepared by impregnating, in an aqueous or organic medium, a ZSM-5 zeolite with a rhenium source, under conditions suitable to form a catalyst precursor, and calcining the catalyst precursor under conditions suitable to form a rhenium oxide-modified ZSM-5 zeolite catalyst.

    摘要翻译： 制备丙烯的方法显示出期望的增加的选择性包括在适于形成丙烯的条件下，在高温下使乙醇和氧化铼改性的ZSM-5沸石催化剂接触。 氧化铼氧化物改性的ZSM-5沸石催化剂可以通过在适合于形成催化剂前体的条件下在含水或有机介质中浸渍具有铼源的ZSM-5沸石并在合适的条件下煅烧催化剂前体来制备 以形成氧化铼氧化物改性的ZSM-5沸石催化剂。