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公开(公告)号：US07956095B2
公开(公告)日：2011-06-07
申请号：US11886466
申请日：2006-03-09
IPC分类号： C08J5/20
CPC分类号： B01D67/002 , B01D67/0027 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/02 , B01D2323/08 , B01D2323/20 , B01D2323/21 , B01D2325/24 , C08J5/2256 , C08J2371/12 , C08J2379/06 , C08L71/00 , C08L81/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a process for the extrusion of thermoplastic polymers having acid ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having acid ionic groups and a plasticizer, in extruding the mixture obtained to form a film, then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.
摘要翻译： 本发明涉及挤出具有酸性离子基团的热塑性聚合物的方法。 该方法包括制备由具有酸性离子基团的热塑性聚合物和增塑剂组成的混合物，挤出获得的混合物以形成膜，然后洗涤在水性介质中获得的膜以除去所述增塑剂。 增塑剂选自相对于聚合物的离子基团稳定的非挥发性化合物，其可溶于水或与水混溶的溶剂中，所述增塑剂选自与离子基团的离子基团反应的化合物 通过形成氢键型的弱键的聚合物，以及通过形成强键与聚合物的离子基团反应的离子键型的化合物。
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公开(公告)号：US20080290022A1
公开(公告)日：2008-11-27
申请号：US12094580
申请日：2006-11-21
申请人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Nadia El Kissi , France Chabert , Jeremie Salomon
发明人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Nadia El Kissi , France Chabert , Jeremie Salomon
IPC分类号： C08F38/00 , B32B5/00 , C07C317/14 , B01D15/36
CPC分类号： H01G9/038 , B01D67/0006 , B01D2323/38 , B01D2323/42 , B01D2325/14 , B01J39/19 , B01J47/12 , C08J3/246 , C08J7/12 , H01G11/56 , H01M10/052 , H01M10/0565 , Y02E60/13
摘要： The invention relates to the preparation of a crosslinked polymeric film bearing ionic groupings.The process consists in extruding a material comprising at least one prepolymer, in polymerizing said material after extrusion, and in subjecting the extruded material to a chemical reaction for grafting ionic groupings. The prepolymer comprises repeating units each comprising at least one aromatic group GA and at least one functional group GF; it bears at least one group GP which is polymerizable thermally at a temperature greater than the extrusion temperature, or photochemically, and also at least one reactive group GR which allows the grafting of ionic groupings.The films are useful as a membrane for fuel cells or electrodialysis, as an electrolyte of a lithium battery, of a supercapacitor or of an electrochromic device, or as an ion exchange membrane.
摘要翻译： 本发明涉及具有离子基团的交联聚合物膜的制备。 该方法包括挤出包含至少一种预聚物的材料，在挤出后使所述材料聚合，以及使挤出的材料经受用于接枝离子组的化学反应。 预聚物包含各自包含至少一个芳族基团GA和至少一个官能团GF的重复单元; 它具有至少一个在大于挤出温度的温度下热可聚合的GP组，或光化学上还有至少一个允许离子组接枝的反应性基团GR。 这些膜可用作燃料电池或电渗析的膜，作为锂电池的电解质，超级电容器或电致变色器件，或作为离子交换膜。
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3.发明授权公开(公告)号：US07973089B2
公开(公告)日：2011-07-05
申请号：US11886467
申请日：2006-03-09
申请人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Manuel Marechal , Nadia El Kissi , Herve Galiano , France Chabert
发明人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Manuel Marechal , Nadia El Kissi , Herve Galiano , France Chabert
IPC分类号： C08J5/20
CPC分类号： B01D67/0025 , B01D67/002 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/12 , B01D2325/32 , C08J5/2256 , C08J2371/12 , C08L71/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a process for the extrusion of thermoplastic polymers having alkaline ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having alkaline ionic groups and a plasticizer, in extruding the mixture obtained to form a film; then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.
摘要翻译： 本发明涉及挤出具有碱性离子基团的热塑性聚合物的方法。 该方法包括制备由具有碱性离子基团的热塑性聚合物和增塑剂组成的混合物，挤出获得的混合物以形成膜; 然后洗涤在水介质中获得的膜以除去所述增塑剂。 增塑剂选自相对于聚合物的离子基团稳定的非挥发性化合物，其可溶于水或与水混溶的溶剂中，所述增塑剂选自与离子基团的离子基团反应的化合物 通过形成氢键型的弱键的聚合物，以及通过形成强键与聚合物的离子基团反应的离子键型的化合物。
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4.发明申请公开(公告)号：US20090203805A1
公开(公告)日：2009-08-13
申请号：US11886467
申请日：2006-03-09
申请人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Manuel Marechal , Nadia El Kissi , Herve Galiano , France Chabert
发明人： Jean-Yves Sanchez , Cristina Iojoiu , Regis Mercier , Manuel Marechal , Nadia El Kissi , Herve Galiano , France Chabert
IPC分类号： C08J5/22
CPC分类号： B01D67/0025 , B01D67/002 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/12 , B01D2325/32 , C08J5/2256 , C08J2371/12 , C08L71/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a process for the extrusion of thermoplastic polymers having alkaline ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having alkaline ionic groups and a plasticizer, in extruding the mixture obtained to form a film; then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.
摘要翻译： 本发明涉及挤出具有碱性离子基团的热塑性聚合物的方法。 该方法包括制备由具有碱性离子基团的热塑性聚合物和增塑剂组成的混合物，挤出获得的混合物以形成膜; 然后洗涤在水介质中获得的膜以除去所述增塑剂。 增塑剂选自相对于聚合物的离子基团稳定的非挥发性化合物，其可溶于水或与水混溶的溶剂中，所述增塑剂选自与离子基团的离子基团反应的化合物 通过形成氢键型的弱键的聚合物，以及通过形成强键与聚合物的离子基团反应的离子键型的化合物。
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公开(公告)号：US20090131544A1
公开(公告)日：2009-05-21
申请号：US11886466
申请日：2006-03-09
IPC分类号： C08J5/20
CPC分类号： B01D67/002 , B01D67/0027 , B01D67/003 , B01D71/52 , B01D71/68 , B01D71/82 , B01D2323/02 , B01D2323/08 , B01D2323/20 , B01D2323/21 , B01D2325/24 , C08J5/2256 , C08J2371/12 , C08J2379/06 , C08L71/00 , C08L81/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/1051 , H01M8/1083 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to a process for the extrusion of thermoplastic polymers having acid ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having acid ionic groups and a plasticizer, in extruding the mixture obtained to form a film, then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.
摘要翻译： 本发明涉及挤出具有酸性离子基团的热塑性聚合物的方法。 该方法包括制备由具有酸性离子基团的热塑性聚合物和增塑剂组成的混合物，挤出获得的混合物以形成膜，然后洗涤在水性介质中获得的膜以除去所述增塑剂。 增塑剂选自相对于聚合物的离子基团稳定的非挥发性化合物，其可溶于水或与水混溶的溶剂中，所述增塑剂选自与离子基团的离子基团反应的化合物 通过形成氢键型的弱键的聚合物，以及通过形成强键与聚合物的离子基团反应的离子键型的化合物。
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公开(公告)号：US08376149B2
公开(公告)日：2013-02-19
申请号：US12094580
申请日：2006-11-21
申请人： Jean-Yves Sanchez , Crístina Iojoiu , Régis Mercier , Nadia El Kissi , France Chabert , Jérèmie Salomon
发明人： Jean-Yves Sanchez , Crístina Iojoiu , Régis Mercier , Nadia El Kissi , France Chabert , Jérèmie Salomon
CPC分类号： H01G9/038 , B01D67/0006 , B01D2323/38 , B01D2323/42 , B01D2325/14 , B01J39/19 , B01J47/12 , C08J3/246 , C08J7/12 , H01G11/56 , H01M10/052 , H01M10/0565 , Y02E60/13
摘要： The invention relates to the preparation of a crosslinked polymeric film bearing ionic groupings.The process consists in extruding a material comprising at least one prepolymer, in polymerizing said material after extrusion, and in subjecting the extruded material to a chemical reaction for grafting ionic groupings. The prepolymer comprises repeating units each comprising at least one aromatic group GA and at least one functional group GF; it bears at least one group GP which is polymerizable thermally at a temperature greater than the extrusion temperature, or photochemically, and also at least one reactive group GR which allows the grafting of ionic groupings.The films are useful as a membrane for fuel cells or electrodialysis, as an electrolyte of a lithium battery, of a supercapacitor or of an electrochromic device, or as an ion exchange membrane.
摘要翻译： 本发明涉及具有离子基团的交联聚合物膜的制备。 该方法包括挤出包含至少一种预聚物的材料，在挤出后使所述材料聚合，以及使挤出的材料经受用于接枝离子组的化学反应。 预聚物包含各自包含至少一个芳族基团GA和至少一个官能团GF的重复单元; 它具有至少一个在大于挤出温度的温度下热可聚合的GP组，或光化学上还有至少一个允许离子组接枝的反应性基团GR。 这些膜可用作燃料电池或电渗析的膜，作为锂电池的电解质，超级电容器或电致变色器件，或作为离子交换膜。
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7.发明授权公开(公告)号：US08853448B2
公开(公告)日：2014-10-07
申请号：US12309462
申请日：2007-07-17
申请人： Jean-Yves Sanchez , Bernard Langlois , Maurice Medebielle , Fabien Toulgoat , Fannie Alloin , Elie Paillard , Cristina Iojoiu
发明人： Jean-Yves Sanchez , Bernard Langlois , Maurice Medebielle , Fabien Toulgoat , Fannie Alloin , Elie Paillard , Cristina Iojoiu
IPC分类号： C07C303/00 , C07F7/08 , H01M10/0525 , C07C317/14 , H01M6/16 , H01M6/18 , C07C323/67 , H01G11/62 , H01G9/022 , H01M10/0565 , H01M10/0566 , H01M6/06
CPC分类号： C07C323/67 , C07C317/14 , C07F7/081 , H01G9/038 , H01G11/62 , H01M6/06 , H01M6/166 , H01M6/181 , H01M6/183 , H01M6/188 , H01M10/0525 , H01M10/0565 , H01M10/0566 , Y02E60/122 , Y02E60/13
摘要： The invention relates to a process for preparing aromatic sulfonylimides, to the sulfonylimides obtained, and to the use thereof as salt of an electrolyte. The sulfonylimides correspond to the formula [R—SO2—N—SO2R′]rM (I). R′ is an ArZL- group. R′ is a perfluoroalkyl group or an ArZL- group. Z is an S, SO or SO2 group. L is a —(CF2)n—CFRf— group. n is 0 or 1; Rf represents F or a C1 to C8 perfluoroalkyl group; Ar is an aromatic group. M represents H, an alkali metal cation, an alkaline earth metal cation, a trivalent or tetravalent metal cation, or an organic cation. The process consists in preparing a compound RSO2N(R′)SO2R′ from RSO2F, and in replacing the group R′ by nucleophilic substitution reaction so as to obtain the compound (I), R′ being a benzyl or trimethylsilyl group.
摘要翻译： 本发明涉及制备芳族磺酰亚胺，所得磺酰亚胺及其作为电解质盐的用途的方法。 磺酰亚胺对应于式[R-SO 2 -N-SO 2 R'] r M（I）。 R'是一个ArZL-组。 R'是全氟烷基或ArZL-基团。 Z是S，SO或SO2基团。 L是 - （CF2）n-CFRf-基团。 n为0或1; Rf表示F或C1〜C8全氟烷基; Ar是芳族基团。 M表示H，碱金属阳离子，碱土金属阳离子，三价或四价金属阳离子或有机阳离子。 该方法包括从RSO2F制备化合物RSO2N（R'）SO2R'，并通过亲核取代反应代替基团R'，得到化合物（I），R'为苄基或三甲基甲硅烷基。
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8.发明授权Copolymer of propylene or ethylene oxide and of an oxirane bearing an ionic group 有权丙烯或环氧乙烷和带有离子基团的环氧乙烷的共聚物公开(公告)号：US08216487B2
公开(公告)日：2012-07-10
申请号：US11884476
申请日：2006-02-09
IPC分类号： H01G9/02
CPC分类号： C08G65/321 , C08G18/0828 , C08G18/5072
摘要： The invention relates to a copolymer of ethylene oxide or propylene oxide and at least one substituted oxirane bearing an ionic group.The copolymer is characterized in that its chain comprises repeat units —O—CH2—CH(—CH2—O—SO3−Li+)—, repeat units —O—CH2—CHR— in which R is H or CH3, optionally, repeat units —O—CH2—CH(—CH2R′)— in which R′ is a functional group. x Uses: electrolyte in electrochemical, selective-membrane and reference-membrane devices.
摘要翻译： 本发明涉及环氧乙烷或环氧丙烷与至少一个带有离子基团的取代的环氧乙烷的共聚物。 共聚物的特征在于其链包含重复单元-O-CH 2 -CH（-CH 2 -O-SO 3 -Li +） - ，其中R是H或CH 3的重复单元-O-CH 2 -CHR-，任选地，重复单元 -O-CH 2 -CH（-CH 2 R'） - 其中R'是官能团。 x用途：电化学，选择膜和参比膜装置中的电解质。
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9.发明申请AROMATIC SULPHONYLIMIDES, PREPARATION THEREOF AND USE THEREOF AS ELECTROLYTE 有权芳香磺酰胺，其制备方法及其作为电解质的用途公开(公告)号：US20100174113A1
公开(公告)日：2010-07-08
申请号：US12309462
申请日：2007-07-17
申请人： Jean-Yves Sanchez , Bernard Langlois , Maurice Medebielle , Fabien Toulgoat , Fannie Alloin , Elie Paillard , Cristina Iojoiu
发明人： Jean-Yves Sanchez , Bernard Langlois , Maurice Medebielle , Fabien Toulgoat , Fannie Alloin , Elie Paillard , Cristina Iojoiu
IPC分类号： C07C303/00 , C07D233/54 , C07C307/06 , C07C315/00 , C07C303/34
CPC分类号： C07C323/67 , C07C317/14 , C07F7/081 , H01G9/038 , H01G11/62 , H01M6/06 , H01M6/166 , H01M6/181 , H01M6/183 , H01M6/188 , H01M10/0525 , H01M10/0565 , H01M10/0566 , Y02E60/122 , Y02E60/13
摘要： The invention relates to a process for preparing aromatic sulphonylimides, to the sulphonylimides obtained, and to the use thereof as salt of an electrolyte. The sulphonylimides correspond to the formula [R—SO2—N—SO2R′]rM (I). R′ is an ArZL- group. R′ is a perfluoroalkyl group or an ArZL- group. Z is an S, SO or SO2 group. L is a —(CF2)n—CFRf— group. n is 0 or 1; Rf represents F or a C1 to C8 perfluoroalkyl group; Ar is an aromatic group. M represents H, an alkali metal cation, an alkaline earth metal cation, a trivalent or tetravalent metal cation, or an organic cation. The process consists in preparing a compound RSO2N(R′)SO2R′ from RSO2F, and in replacing the group R′ by nucleophilic substitution reaction so as to obtain the compound (I), R′ being a benzyl or trimethylsilyl group.
摘要翻译： 本发明涉及一种制备芳族磺酰亚胺，所得磺酰亚胺及其作为电解质盐的用途的方法。 磺酰亚胺对应于式[R-SO 2 -N-SO 2 R'] r M（I）。 R'是一个ArZL-组。 R'是全氟烷基或ArZL-基团。 Z是S，SO或SO2基团。 L是 - （CF2）n-CFRf-基团。 n为0或1; Rf表示F或C1〜C8全氟烷基; Ar是芳族基团。 M表示H，碱金属阳离子，碱土金属阳离子，三价或四价金属阳离子或有机阳离子。 该方法包括从RSO2F制备化合物RSO2N（R'）SO2R'，并通过亲核取代反应代替基团R'，得到化合物（I），R'为苄基或三甲基甲硅烷基。
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10.发明申请COPOLYMER OF PROPYLENE OR ETHYLENE OXIDE AND OF AN OXIRANE BEARING AN IONIC GROUP 有权丙烯或乙烯氧化物的共聚物和含有离子基团的氧化物公开(公告)号：US20090176161A1
公开(公告)日：2009-07-09
申请号：US11884476
申请日：2006-02-09
CPC分类号： C08G65/321 , C08G18/0828 , C08G18/5072
摘要： The invention relates to a copolymer of ethylene oxide or propylene oxide and at least one substituted oxirane bearing an ionic group.The copolymer is characterized in that its chain comprises repeat units —O—CH2—CH(—CH2—O—SO3−Li+)—, repeat units —O—CH2—CHR— in which R is H or CH3, optionally, repeat units —O—CH2—CH(—CH2R′)— in which R′ is a functional group.×Uses: electrolyte in electrochemical, selective-membrane and reference-membrane devices.
摘要翻译： 本发明涉及环氧乙烷或环氧丙烷与至少一个带有离子基团的取代的环氧乙烷的共聚物。 共聚物的特征在于其链包含重复单元-O-CH 2 -CH（-CH 2 -O-SO 3 -Li +） - ，其中R是H或CH 3的重复单元-O-CH 2 -CHR-，任选地，重复单元 -O-CH2-CH（-CH2R'） - 其中R'是官能团。用途：电化学，选择性膜和参比膜装置中的电解质。
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