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    Iron-air accumulator with lithium mediator
    2.
    发明授权
    Iron-air accumulator with lithium mediator 有权
    带锂介质的铁空气蓄能器

    公开(公告)号：US09136539B2

    公开(公告)日：2015-09-15

    申请号：US12992279

    申请日：2009-11-11

    申请人： Stephane Lascaud ,  Philippe Stevens

    发明人： Stephane Lascaud ,  Philippe Stevens

    IPC分类号： H01M2/16 ,  H01M4/74 ,  H01M4/04 ,  H01M4/24 ,  H01M4/52 ,  H01M12/08

    CPC分类号： H01M4/74 ,  H01M2/1606 ,  H01M2/162 ,  H01M2/1646 ,  H01M2/1686 ,  H01M4/0445 ,  H01M4/049 ,  H01M4/24 ,  H01M4/521 ,  H01M12/08 ,  H01M2300/0014 ,  Y02E60/124 ,  Y02E60/128 ,  Y02P70/54

    摘要： The invention relates to a half-cell including an electrode formed of an electron collector containing one or more transition metals from groups 4 to 12 of the Period Table of the Elements, and of an electrochemically active material present on the surface of the electron collector in the form of a nanostructured conversion film containing nanoparticles having an average diameter of between 1 nm and 1000 nm. The electrochemically active material contains at least one compound of the transition metal or the transition metals present in the electron collector. The invention further includes a continuous film of a lithium-ion conductive, solid electrolyte that is water- and air-impermeable and that is deposited directly onto, covering totally, the surface of the nanostructured active material of the electrode. The continuous film of solid electrolyte having a thickness of between 1 μm and 50 μm.

    摘要翻译： 本发明涉及一种半电池，包括由含有元素周期表第4至12族中的一种或多种过渡金属的电子收集体形成的电极，以及存在于电子收集器表面上的电化学活性材料 包含平均直径在1nm和1000nm之间的纳米颗粒的纳米结构转化膜的形式。 电化学活性材料含有至少一种过渡金属化合物或存在于电子收集器中的过渡金属。 本发明还包括一种锂离子传导性固体电解质的连续膜，其是水不透气且直接沉积在电极的纳米结构的活性材料的表面上。 固体电解质的连续薄膜的厚度为1μm〜50μm。

    INTERPENETRATING NETWORK OF ANION-EXCHANGE POLYMERS, PRODUCTION METHOD THEREOF AND USE OF SAME
    5.
    发明申请
    INTERPENETRATING NETWORK OF ANION-EXCHANGE POLYMERS, PRODUCTION METHOD THEREOF AND USE OF SAME 有权
    阴离子交换聚合物的交联网络及其生产方法及其使用

    公开(公告)号：US20120058413A1

    公开(公告)日：2012-03-08

    申请号：US13318497

    申请日：2010-05-04

    申请人： Philippe Stevens ,  Fouad Ghamous ,  Odile Fichet ,  Christian Sarrazin

    发明人： Philippe Stevens ,  Fouad Ghamous ,  Odile Fichet ,  Christian Sarrazin

    IPC分类号： H01M4/86 ,  H01M8/08 ,  C08J5/22 ,  H01M8/10

    CPC分类号： H01M8/1044 ,  C08J3/246 ,  C08J5/2275 ,  C08J2300/208 ,  C08L71/03 ,  H01M8/083 ,  H01M12/02 ,  H01M12/06 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02E60/50 ,  Y02P70/56 ,  C08L2666/04 ,  C08L2666/06

    摘要： The invention relates to a method for producing an anion-exchange polymer material having an IPN or semi-IPN structure, said method consisting in: (A) preparing a homogeneous reaction solution containing, in a suitable organic solvent, (a) at least one organic polymer bearing reactive halogen groups, (b) at least one tertiary diamine, (c) at least one monomer comprising an ethylenic unsaturation polymerizable by free radical polymerization, (d) optionally at least one cross-linking agent including at least two ethylenic unsaturations polymerizable by free radical polymerization, and e) at least one free radical polymerization initiator; and (B) heating the prepared solution to a temperature and for a duration that are sufficient to allow both a nucleophilic substitution reaction between components (a) and (b) and a free radical copolymerization reaction of components (c) and optionally (d) initiated by component (e). The invention also relates to the resulting IPN or semi-IPN material and to the use thereof in electrochemical devices, in direct contact with an air electrode.

    摘要翻译： 本发明涉及一种具有IPN或半IPN结构的阴离子交换聚合物材料的制备方法，所述方法包括：（A）制备均匀的反应溶液，该溶液含有在合适的有机溶剂中，（a）至少一种 带有反应性卤素基团的有机聚合物，（b）至少一种叔胺，（c）至少一种包含通过自由基聚合可聚合的烯属不饱和度的单体，（d）任选至少一种包含至少两个烯属不饱和键的交联剂 可通过自由基聚合反应，和e）至少一种自由基聚合引发剂; 和（B）将制备的溶液加热到足以允许组分（a）和（b）之间的亲核取代反应和组分（c）和任选（d）的自由基共聚反应的温度和持续时间， 由组件（e）启动。 本发明还涉及所得到的IPN或半IPN材料及其在与空气电极直接接触的电化学装置中的用途。

    Method for preparing metal oxide layers
    6.
    发明申请
    Method for preparing metal oxide layers 审中-公开
    制备金属氧化物层的方法

    公开(公告)号：US20070098905A1

    公开(公告)日：2007-05-03

    申请号：US10561581

    申请日：2004-06-17

    申请人： Manuel Gaudon ,  Christel Laberty-Robert ,  Florence Ansart ,  Philippe Stevens

    发明人： Manuel Gaudon ,  Christel Laberty-Robert ,  Florence Ansart ,  Philippe Stevens

    IPC分类号： B01J23/10 ,  B05D1/18 ,  B05D1/12 ,  B05D3/02

    CPC分类号： C23C18/1283 ,  C23C18/1216 ,  C23C18/1241 ,  C23C18/1245 ,  H01M4/9066

    摘要： Method of preparing a metal oxide layer on a substrate, in which the following successive steps are carried out: a) a metal oxide powder is dispersed in a liquid medium comprising a dispersion solvent and a dispersant, the said liquid medium containing neither plasticizer nor binder, by means of which a suspension A of the said metal oxide powder in the said liquid medium is obtained; b) a solution of at least one polymer in a solvent is added to the said suspension A, by means of which a suspension B is obtained; c) suspension B is deposited on the substrate by a dip coating method, by means of which a green layer is obtained; d) the green layer obtained in step c) is dried; and e) the dried layer obtained in step d) is calcined.

    摘要翻译： 在基材上制备金属氧化物层的方法，其中进行以下连续步骤：a）将金属氧化物粉末分散在包含分散溶剂和分散剂的液体介质中，所述液体介质既不含增塑剂也不含粘合剂 通过其获得所述液体介质中的所述金属氧化物粉末的悬浮液A; b）将至少一种聚合物在溶剂中的溶液加入到所述悬浮液A中，借此获得悬浮液B. c）通过浸涂法将悬浮液B沉积在基底上，通过该方法获得绿色层; d）将步骤c）中获得的生坯层干燥; 和e）将步骤d）中获得的干燥层煅烧。

    Interpenetrating network of anion-exchange polymers, production method thereof and use of same
    8.
    发明授权
    Interpenetrating network of anion-exchange polymers, production method thereof and use of same 有权
    阴离子交换聚合物的互穿网络及其制备方法及用途

    公开(公告)号：US09136550B2

    公开(公告)日：2015-09-15

    申请号：US13318497

    申请日：2010-05-04

    申请人： Philippe Stevens ,  Fouad Ghamouss ,  Odile Fichet ,  Christian Sarrazin

    发明人： Philippe Stevens ,  Fouad Ghamouss ,  Odile Fichet ,  Christian Sarrazin

    IPC分类号： H01M4/86 ,  H01M8/08 ,  C08J3/24 ,  C08J5/22 ,  C08L71/03 ,  H01M12/06

    CPC分类号： H01M8/1044 ,  C08J3/246 ,  C08J5/2275 ,  C08J2300/208 ,  C08L71/03 ,  H01M8/083 ,  H01M12/02 ,  H01M12/06 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02E60/50 ,  Y02P70/56 ,  C08L2666/04 ,  C08L2666/06

    摘要： The invention relates to a method for producing an anion-exchange polymer material having an IPN or semi-IPN structure, said method consisting in: (A) preparing a homogeneous reaction solution containing, in a suitable organic solvent, (a) at least one organic polymer bearing reactive halogen groups, (b) at least one tertiary diamine, (c) at least one monomer comprising an ethylenic unsaturation polymerizable by free radical polymerization, (d) optionally at least one cross-linking agent including at least two ethylenic unsaturations polymerizable by free radical polymerization, and e) at least one free radical polymerization initiator; and (B) heating the prepared solution to a temperature and for a duration that are sufficient to allow both a nucleophilic substitution reaction between components (a) and (b) and a free radical copolymerization reaction of components (c) and optionally (d) initiated by component (e). The invention also relates to the resulting IPN or semi-IPN material and to the use thereof in electrochemical devices, in direct contact with an air electrode.

    摘要翻译： 本发明涉及一种具有IPN或半IPN结构的阴离子交换聚合物材料的制备方法，所述方法包括：（A）制备均匀的反应溶液，该溶液含有在合适的有机溶剂中，（a）至少一种 带有反应性卤素基团的有机聚合物，（b）至少一种叔胺，（c）至少一种包含通过自由基聚合可聚合的烯属不饱和度的单体，（d）任选的至少一种包含至少两个烯属不饱和键的交联剂 可通过自由基聚合反应，和e）至少一种自由基聚合引发剂; 和（B）将制备的溶液加热到足以允许组分（a）和（b）之间的亲核取代反应和组分（c）和任选（d）的自由基共聚反应的温度和持续时间， 由组件（e）启动。 本发明还涉及所得到的IPN或半IPN材料及其在与空气电极直接接触的电化学装置中的用途。