Abstract:
A composition and method of construction and use therefor in chemical-mechanical polishing (nullCMPnull) of one or more substrate assemblies is described. More particularly, a polishing solution comprising etchant, abrasive particles, and surfactant and methods of mixing to form and to dispense the polishing solution are described. One or more of the etchant, abrasive particles, and/or surfactant may comprise a liquid medium. Etchant, surfactant or abrasive particles may be premixed, mixed in-situ (nullpoint of use mixingnull), or any combination thereof. The surfactant may be ionic or nonionic. In particular, a polyoxyethylene may be used, and more particularly, a polyoxyethylene ester or ether may be used.
Abstract:
An etching method for use in integrated circuit fabrication includes providing a metal nitride layer on a substrate assembly, providing regions of cobalt silicide on first portions of the metal nitride layer, and providing regions of cobalt on second portions of the metal nitride layer. The regions of cobalt and the second portions of the metal nitride layer are removed with at least one solution including a mineral acid and a peroxide. The mineral acid may be selected from the group including HCl, H2SO4, H3PO4, HNO3, and dilute HF (preferably the mineral acid is HCl) and the peroxide may be hydrogen peroxide. Further, the removal of the regions of cobalt and the second portions of the metal nitride layer may include a one step process or a two step process. In the one step process, the regions of cobalt and the second portions of the metal nitride layer are removed with a single solution including the mineral acid and the peroxide. In the two step process, the regions of cobalt are removed with a first solution containing a mineral acid and a peroxide and the second portions of the metal nitride layer are removed with a second solution containing a peroxide. An etching composition including a mineral acid and a peroxide, preferably, HCl and hydrogen peroxide, is also described. The etching methods and compositions may be used in forming structures such as word lines, gate electrodes, local interconnects, etc.
Abstract:
An etching method for use in integrated circuit fabrication includes providing a metal nitride layer on a substrate assembly, providing regions of cobalt silicide on first portions of the metal nitride layer, and providing regions of cobalt on second portions of the metal nitride layer. The regions of cobalt and the second portions of the metal nitride layer are removed with at least one solution including a mineral acid and a peroxide. The mineral acid may be selected from the group including HCl, H2SO4, H3PO4, HNO3, and dilute HF (preferably the mineral acid is HCl) and the peroxide may be hydrogen peroxide. Further, the removal of the regions of cobalt and the second portions of the metal nitride layer may include a one step process or a two step process. In the one step process, the regions of cobalt and the second portions of the metal nitride layer are removed with a single solution including the mineral acid and the peroxide. In the two step process, the regions of cobalt are removed with a first solution containing a mineral acid and a peroxide and the second portions of the metal nitride layer are removed with a second solution containing a peroxide. An etching composition including a mineral acid and a peroxide, preferably, HCl and hydrogen peroxide, is also described. The etching methods and compositions may be used in forming structures such as word lines, gate electrodes, local interconnects, etc.
Abstract translation:用于集成电路制造的蚀刻方法包括在衬底组件上提供金属氮化物层,在金属氮化物层的第一部分上提供钴硅化物的区域,以及在金属氮化物层的第二部分上提供钴区域。 用至少一种包含无机酸和过氧化物的溶液除去钴的区域和金属氮化物层的第二部分。 无机酸可以选自HCl,H 2 SO 4,H 3 PO 4,HNO 3和稀HF(优选无机酸是HCl),并且过氧化物可以是过氧化氢。 此外,去除钴的区域和金属氮化物层的第二部分可以包括一步法或两步法。 在一步法中,用包含无机酸和过氧化物的单一溶液除去钴的区域和金属氮化物层的第二部分。 在两步法中,用含有无机酸和过氧化物的第一溶液除去钴的区域,并用含有过氧化物的第二溶液除去金属氮化物层的第二部分。 还描述了包含无机酸和过氧化物,优选HCl和过氧化氢的蚀刻组合物。 蚀刻方法和组合物可以用于形成诸如字线,栅电极,局部互连等的结构。
Abstract:
A silicon etching method includes providing a substrate assembly including an exposed silicon region and an exposed oxide region. An etch composition including an ammonium fluoride component, an inorganic acid component, and an oxidizing agent is also provided. The etch composition has a pH in the range of about 7.0 to about 8.0. The substrate assembly is exposed to the etch composition. Exposing the substrate assembly to the etch composition may result in etching the exposed silicon region at an etching rate that is greater than about 3 times the etching rate of the exposed oxide region and/or etching the silicon region at an etch rate greater than about 9 null/minute. The etching method may be used in forming isolation structures. Further, etch compositions for performing the desired etch are provided.
Abstract:
Capacitor structures and capacitors with edge zones that are substantially free of hemispherical grain silicon along the upper edges of the capacitor structures are disclosed. The resulting recessed hemispherical grain silicon layers reduce or prevent separation of particles from the hemispherical grain silicon layer during subsequent manufacturing processes, thereby reducing defects and increasing throughput. Also disclosed are methods of forming the capacitor structures and capacitors in which the silicon layer used to form the hemispherical grain silicon is selectively removed to provide an edge zone that is substantially free of hemispherical grain silicon.
Abstract:
A method and an apparatus for electrochemically removing a metal from a substrate surface with an electrolyte and an electrode that has a surface defining a shape suitable to cause substantially uniform removal of a metal-containing surface.