公开(公告)号：US11753222B2

公开(公告)日：2023-09-12

申请号：US16915883

申请日：2020-06-29

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Yashodhan S. Parulekar

IPC: B65D65/46 ,  B65D30/08 ,  B65D37/00 ,  C08J7/06 ,  C11D17/04 ,  C11D3/50 ,  C08J7/04 ,  B32B27/30 ,  B32B1/02 ,  B32B27/28 ,  B32B27/36 ,  B32B27/42 ,  B32B27/38 ,  C09D1/02 ,  C09D103/02

CPC classification number: B65D65/46 ,  B32B1/02 ,  B32B27/28 ,  B32B27/285 ,  B32B27/286 ,  B32B27/30 ,  B32B27/302 ,  B32B27/306 ,  B32B27/308 ,  B32B27/36 ,  B32B27/38 ,  B32B27/42 ,  B65D31/02 ,  B65D37/00 ,  C08J7/042 ,  C08J7/0423 ,  C08J7/06 ,  C08J7/065 ,  C09D1/02 ,  C09D103/02 ,  C11D3/505 ,  C11D17/042 ,  C11D17/043 ,  C11D17/044 ,  C08J7/0427 ,  C08J2300/14 ,  Y02W90/10 ,  Y10T428/1324 ,  Y10T428/1334 ,  Y10T428/1341 ,  Y10T428/1345 ,  Y10T428/1352 ,  Y10T428/1372 ,  Y10T428/1379

Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.

公开(公告)号：US11745937B2

公开(公告)日：2023-09-05

申请号：US16713710

申请日：2019-12-13

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  David Brian Edwards

IPC: B65D85/808 ,  B65D65/46 ,  B65D75/32 ,  B65D75/40 ,  B65D75/44 ,  B65D77/06 ,  B65D81/20 ,  B65D81/32 ,  B65B9/04 ,  C11D17/04 ,  B65B31/02 ,  B65D75/48 ,  B65D75/52 ,  B65B61/00

CPC classification number: B65D85/808 ,  B65B9/042 ,  B65B31/02 ,  B65D65/46 ,  B65D75/327 ,  B65D75/40 ,  B65D75/44 ,  B65D75/48 ,  B65D75/527 ,  B65D77/06 ,  B65D81/2023 ,  B65D81/2084 ,  B65D81/3261 ,  C11D17/042 ,  B65B61/005

Abstract: A web of cleaning products and a method of manufacturing the same is disclosed. The web includes first and second carrier sheets and a plurality of pouches containing a cleaning composition. Each of the pouches is disposed in a respective depression formed in an upper surface of the first carrier sheet. A first internal atmosphere is enclosed within each of the pouches. The first carrier sheet is sealed to the second carrier sheet such that a second internal atmosphere exists between the second carrier sheet and the plurality of pouches. The second internal atmosphere has a greater absolute pressure than the first internal atmosphere so that the plurality of pouches and at least a portion of the cleaning composition in the plurality of pouches are compressed into the plurality of depressions in the first carrier sheet by the second internal atmosphere.

公开(公告)号：US11168289B2

公开(公告)日：2021-11-09

申请号：US16703105

申请日：2019-12-04

Applicant: MONOSOL, LLC

Inventor： Steven G. Friedrich ,  David M. Lee ,  Regine Labeque ,  Florence Catherine Courchay

IPC: C11D17/04 ,  C08L29/04 ,  C08K5/053 ,  C08L101/14 ,  C08J5/18 ,  C11D3/37

Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) polymer and a combination of at least three plasticizers. The combination of plasticizers includes dipropylene glycol as a first plasticizer, a sugar alcohol such as sorbitol as a second plasticizer, and a polyol such as glycerin as a third plasticizer. When the PVOH polymer and plasticizers are blended in particular proportions and/or selected with regard to various criteria related to physical and chemical film properties, the resulting water-soluble film formed from the PVOH resin blend exhibits beneficial combinations four) of aged tensile strength, aged melting transition delta elevation, aged adhesion value, and/or resistance to seal peeling, which provide strong film seals that retain their water-solubility characteristics.

公开(公告)号：US10696460B2

公开(公告)日：2020-06-30

申请号：US15858644

申请日：2017-12-29

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Yashodhan S. Parulekar

IPC: B32B1/02 ,  B65D65/46 ,  C08J7/04 ,  C08J7/06 ,  B65D30/08 ,  B65D37/00 ,  C11D17/04 ,  C11D3/50 ,  B32B27/30 ,  B32B27/28 ,  B32B27/36 ,  B32B27/42 ,  B32B27/38 ,  C09D1/02 ,  C09D103/02

Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.

公开(公告)号：US20170226298A1

公开(公告)日：2017-08-10

申请号：US15519032

申请日：2015-10-13

Applicant: MONOSOL, LLC

Inventor： Steven G. Friedrich ,  David M. Lee ,  Thomas J. Yogan ,  Regine Labaeque

IPC: C08J5/18 ,  C11D3/37 ,  C11D17/04

Abstract: Disclosed herein are water-soluble films including a polyvinyl alcohol (PVOH) resin blend and optionally one or more additional components such as plasticizers, fillers, surfactants, and other additives. Also disclosed herein are articles including the water-soluble film and containing a composition such as a household care composition. The PVOH resin blend includes a PVOH copolymer including one or more types of anionic monomer units such as a PVOH terpolymer and a PVOH polymer such as a partially or completely hydrolyzed PVOH homopolymer. When the PVOH copolymer and PVOH polymer are blended in particular proportions and/or selected with regard to various criteria related to the 4% solution viscosity of one or both of the PVOH polymer(s) and PVOH copolymer(s), the resulting water-soluble film formed from the PVOH resin blend exhibits substantially improved aqueous dissolution properties.

公开(公告)号：US20160326325A1

公开(公告)日：2016-11-10

申请号：US15214197

申请日：2016-07-19

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Yashodhan S. Parulekar

IPC: C08J7/04 ,  C11D17/04 ,  C09D103/02 ,  B65D65/46 ,  C09D1/02

CPC classification number: B65D65/46 ,  B65D31/02 ,  B65D37/00 ,  C08J7/04 ,  C08J7/042 ,  C08J7/045 ,  C08J7/047 ,  C08J7/06 ,  C08J7/065 ,  C08J2300/14 ,  C09D1/02 ,  C09D103/02 ,  C11D3/505 ,  C11D17/042 ,  C11D17/043 ,  C11D17/044 ,  Y02W90/13 ,  Y10T428/1324 ,  Y10T428/1334 ,  Y10T428/1341 ,  Y10T428/1345 ,  Y10T428/1352 ,  Y10T428/1372 ,  Y10T428/1379

Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.

公开(公告)号：US09394092B2

公开(公告)日：2016-07-19

申请号：US13828299

申请日：2013-03-14

Applicant: Monosol, LLC.

Inventor： David M. Lee ,  Yashodhan S. Parulekar

IPC: B65D65/46 ,  B65D30/08 ,  C08J7/04 ,  C08J7/06 ,  C11D17/04 ,  C11D3/50

CPC classification number: B65D65/46 ,  B65D31/02 ,  B65D37/00 ,  C08J7/04 ,  C08J7/042 ,  C08J7/045 ,  C08J7/047 ,  C08J7/06 ,  C08J7/065 ,  C08J2300/14 ,  C09D1/02 ,  C09D103/02 ,  C11D3/505 ,  C11D17/042 ,  C11D17/043 ,  C11D17/044 ,  Y02W90/13 ,  Y10T428/1324 ,  Y10T428/1334 ,  Y10T428/1341 ,  Y10T428/1345 ,  Y10T428/1352 ,  Y10T428/1372 ,  Y10T428/1379

Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.

Abstract translation: 本文公开了水溶性薄膜和所得到的包装，其包括由粉末涂覆的水溶性薄膜，其中所述粉末包括粉末状润滑剂和活性剂的混合物。 任选地，可以包封活性剂。 通过包括但不限于机械破裂，熔体，消融，溶解，扩散，生物降解或pH控制释放的机制来微囊化以释放活性剂。 描述的活性成分包括酶，油，香料，着色剂，气味吸收剂，香料，农药，肥料，活化剂，酸催化剂，金属催化剂，离子清除剂，漂白剂，漂白组分，织物柔软剂及其组合。 包装填充的实例包括衣物洗涤剂，漂白剂和洗衣添加剂，织物护理，洗碗，硬表面清洁，美容护理，护肤，其他个人护理和食品。

公开(公告)号：US20140199460A1

公开(公告)日：2014-07-17

申请号：US13740053

申请日：2013-01-11

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Jennifer L. Childers

IPC: C08L1/28 ,  A23L1/236

Abstract: Disclosed herein are water-soluble films and resulting packets including a water soluble film, wherein the water-soluble film includes a water-soluble mixture of polyvinyl alcohol, a compatibilizing agent, and a sugar alcohol plasticizer that is a solid at room temperature, wherein the water-soluble film is substantially transparent.

Abstract translation: 本文公开了水溶性薄膜和包含水溶性薄膜的所得包装，其中所述水溶性薄膜包括在室温下为固体的聚乙烯醇，相容剂和糖醇增塑剂的水溶性混合物，其中 水溶性薄膜基本上是透明的。

公开(公告)号：US20130273277A1

公开(公告)日：2013-10-17

申请号：US13828299

申请日：2013-03-14

Applicant: MONOSOL, LLC.

Inventor： David M. Lee ,  Yashodhan S. Parulekar

IPC: B65D30/08

CPC classification number: B65D65/46 ,  B65D31/02 ,  B65D37/00 ,  C08J7/04 ,  C08J7/042 ,  C08J7/045 ,  C08J7/047 ,  C08J7/06 ,  C08J7/065 ,  C08J2300/14 ,  C09D1/02 ,  C09D103/02 ,  C11D3/505 ,  C11D17/042 ,  C11D17/043 ,  C11D17/044 ,  Y02W90/13 ,  Y10T428/1324 ,  Y10T428/1334 ,  Y10T428/1341 ,  Y10T428/1345 ,  Y10T428/1352 ,  Y10T428/1372 ,  Y10T428/1379

Abstract: Disclosed herein are water-soluble films and resulting packets including a water-soluble film coated by a powder, wherein the powder includes a mixture of a powdered lubricant and an active agent. Optionally, the active agent may be encapsulated, e.g. microencapsulated, for release of the active agent through mechanisms including, but not limited to, mechanical rupture, melt, ablation, dissolution, diffusion, biodegradation, or pH-controlled release. Active ingredients described include enzymes, oils, flavors, colorants, odor absorbers, fragrances, pesticides, fertilizers, activators, acid catalysts, metal catalysts, ion scavengers, bleaches, bleach components, fabric softeners and combinations thereof. Examples of packet fills include laundry detergents, bleach and laundry additives, fabric care, dishwashing, hard surface cleaning, beauty care, skin care, other personal care, and foodstuffs.

Abstract translation: 本文公开了水溶性薄膜和所得到的包装，其包括由粉末涂覆的水溶性薄膜，其中所述粉末包括粉末状润滑剂和活性剂的混合物。 任选地，可以包封活性剂。 通过包括但不限于机械破裂，熔体，消融，溶解，扩散，生物降解或pH控制释放的机制来微囊化以释放活性剂。 描述的活性成分包括酶，油，香料，着色剂，气味吸收剂，香料，农药，肥料，活化剂，酸催化剂，金属催化剂，离子清除剂，漂白剂，漂白组分，织物柔软剂及其组合。 包装填充的实例包括衣物洗涤剂，漂白剂和洗衣添加剂，织物护理，洗碗，硬表面清洁，美容护理，护肤，其他个人护理和食品。

公开(公告)号：US11884467B2

公开(公告)日：2024-01-30

申请号：US17390005

申请日：2021-07-30

Applicant: MONOSOL, LLC

Inventor： David M. Lee ,  Jennifer L. Childers ,  Lee K. Yeung ,  Ken Jenke ,  Jonathon Knight ,  Nicholas Zeese ,  P. Scott Bening ,  Yashodhan S. Parulekar ,  Sumeet Kumar

IPC: B65D65/46 ,  C08J5/18 ,  C08K3/012 ,  C08K3/014 ,  A45F5/00 ,  B65D65/40 ,  B65D75/30 ,  C08K5/00 ,  C08K9/10 ,  B65D5/46

CPC classification number: B65D5/46 ,  A45F5/00 ,  B65D65/40 ,  B65D75/30 ,  C08J5/18 ,  C08K3/012 ,  C08K3/014 ,  C08K5/005 ,  C08K5/0033 ,  C08K9/10 ,  A45F2005/006 ,  C08J2300/14 ,  C08J2329/00

Abstract: A water-soluble film, comprising a first water-soluble film, wherein the first water soluble film disintegrates in water within less than about 24 hours and dissolves in water within less than about 48 hours as measured by the MSTM-205 at 20° C. The disclosure provides a water-soluble film comprising a first water-soluble film that disintegrates in water within less than 24 hours and dissolves in water within less than 48 hours as measured by MSTM-205 at 20° C. The first water-soluble film optionally may be further characterized in that it does not disintegrate in water for at least about 1 hour and does not dissolve in water for at least about 1 hour as measured by MSTM-205 at 20° C. The disclosure further provides a water-soluble film comprising a first water-soluble film characterized in that the degradation and/or dissolution of the first water-soluble film is adapted to be activated by consumer handling.