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    Rubber compositions containing preciptated organosilicon particles having a core and a shell
    4.
    发明授权
    Rubber compositions containing preciptated organosilicon particles having a core and a shell 失效
    含有具有核心和壳体的精细有机硅颗粒的橡胶组合物

    公开(公告)号：US06624214B2

    公开(公告)日：2003-09-23

    申请号：US09794561

    申请日：2001-02-27

    申请人： Rene Jean Zimmer ,  Wolfgang Lauer ,  Marc Weydert ,  Friedrich Visel ,  Uwe Ernst Frank

    发明人： Rene Jean Zimmer ,  Wolfgang Lauer ,  Marc Weydert ,  Friedrich Visel ,  Uwe Ernst Frank

    IPC分类号： C08L8300

    CPC分类号： B60C1/0016 ,  C08L21/00 ,  C08L2666/14 ,  C08L83/04

    摘要： There is disclosed a rubber composition comprising: (a) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (b) 1 to 150 phr of a precipitated organosilicon particles having a core and a shell, wherein the core is obtained by the condensation of at least one monomer of the formula: R1—Si(OR2)3  I  where R1 is selected from the group consisting of hydrogen, methyl, ethyl, vinyl, alkoxy having from 1 to 4 carbon atoms, and phenyl; R2 is selected from the group consisting of alkyls having from 1 to 4 carbon atoms and phenyl; and wherein said condensation of said monomer is in the presence of a surfactant; and wherein the shell is obtained by the subsequent addition to the core of a monomer of the formula: R3—Si(OR2)3  II  where R3 is selected from the group consisting of —CH═CH2, —CH2—CH═CH2, &Parenopenst;CH2&Parenclosest;nSH and mixtures thereof; and n is an integer of from 2 to 8.

    摘要翻译： 公开了一种橡胶组合物，其包含：（a）100重量份的至少一种含有烯属不饱和的橡胶; 和（b）1至150phr具有核和壳的沉淀的有机硅颗粒，其中所述核通过至少一种下式的单体的缩合获得：其中R 1选自氢 ，甲基，乙基，乙烯基，具有1至4个碳原子的烷氧基和苯基; R 2选自具有1至4个碳原子的烷基和苯基; 并且其中所述单体的所述缩合是在表面活性剂存在下进行的; 并且其中壳体通过随后加入下式的单体的核心获得：其中R 3选自-CH = CH 2，-CH 2 -CH = CH 2和Parenopenst; CH 2和Parenclosest; nSH和混合物 的; n为2〜8的整数。

    Preparation of elastomer reinforced with in situ formed silica and tire having component thereof
    6.
    发明授权
    Preparation of elastomer reinforced with in situ formed silica and tire having component thereof 失效
    用原位形成的二氧化硅和具有其组分的轮胎增强的弹性体的制备

    公开(公告)号：US06359034B1

    公开(公告)日：2002-03-19

    申请号：US09521796

    申请日：2000-03-09

    申请人： Friedrich Visel ,  Wolfgang Lauer ,  Uwe Ernst Frank ,  Rene Jean Zimmer

    发明人： Friedrich Visel ,  Wolfgang Lauer ,  Uwe Ernst Frank ,  Rene Jean Zimmer

    IPC分类号： C08K9063

    CPC分类号： C08J3/215 ,  C08J2309/00 ,  C08K3/36 ,  C08K5/54 ,  C08L21/00

    摘要： This invention relates to preparation of an elastomer which contains a dispersion of silica reinforcement by forming a silica reinforcement in situ within an unvulcanized elastomer host, the resulting elastomer/filler composite and tire having component which contains such reinforced elastomer. The invention includes a rubber composition of at least two elastomers wherein one of said elastomers is a pre-formed composite of elastomer/in situ formed silica reinforcement. A tire having a component of such rubber composition, particularly a tire tread, is specifically contemplated.

    摘要翻译： 本发明涉及通过在未硫化弹性体主体内原位形成二氧化硅增强剂，所得弹性体/填料复合材料和具有含有这种增强弹性体的组分的轮胎的轮胎制备含有二氧化硅增强剂的分散体。 本发明包括至少两种弹性体的橡胶组合物，其中所述弹性体之一是弹性体/原位形成的二氧化硅增强物的预成型复合材料。 特别考虑了具有这种橡胶组合物的组分，特别是轮胎胎面的轮胎。

    Method for the preparation of a diene polymer interpenetrated with a polysiloxane
    9.
    发明授权
    Method for the preparation of a diene polymer interpenetrated with a polysiloxane 失效
    用聚硅氧烷渗透的二烯聚合物的制备方法

    公开(公告)号：US06524716B2

    公开(公告)日：2003-02-25

    申请号：US09904596

    申请日：2001-07-13

    申请人： Friedrich Visel ,  Wolfgang Lauer ,  Marc Weydert

    发明人： Friedrich Visel ,  Wolfgang Lauer ,  Marc Weydert

    IPC分类号： B32B904

    CPC分类号： C08G77/442 ,  C08F283/12 ,  C08L21/00 ,  C08L51/085 ,  C08L55/02 ,  Y10S525/903 ,  Y10T428/31663 ,  C08F236/00 ,  C08L2666/24

    摘要： There is disclosed a method for the preparation of a diene polymer interpenetrated with a polysiloxane comprising the polymerization of (A) at least one silane monomer of the formula: (B) at least one silane monomer of the formula: (C) at least one diene monomer, said polymerization being conducted in the presence of an anionic base, an inert solvent and a polymerization initiator, wherein each R1 is independently selected from the group consisting of alkyl radicals having from 1 to 4 carbon atoms and aryl radicals having 6 carbon atoms and R2 is selected from the group consisting of where x is an integer of from 1 to 8.

    摘要翻译： 公开了一种用聚硅氧烷渗透的二烯聚合物的制备方法，包括（A）至少一种下式的硅烷单体的聚合：（B）至少一种下式的硅烷单体：（C）至少一种 所述聚合在阴离子碱，惰性溶剂和聚合引发剂的存在下进行，其中每个R 1独立地选自具有1至4个碳原子的烷基和具有6个碳原子的芳基 并且R 2选自其中x是1至8的整数。