公开(公告)号：US08397776B2

公开(公告)日：2013-03-19

申请号：US12331735

申请日：2008-12-10

Applicant: Uwe Ernst Frank ,  Andreas Frantzen ,  Claude Schweitzer

Inventor： Uwe Ernst Frank ,  Andreas Frantzen ,  Claude Schweitzer

IPC: B60C5/02

CPC classification number: C08K3/346 ,  B60C1/0008 ,  C08L21/00 ,  C08L23/22 ,  C08L61/06 ,  C08L71/03 ,  C08L2666/22 ,  C08L2666/06 ,  C08L2666/02

Abstract: The present invention is directed to a pneumatic tire comprising a carcass and an innerliner in direct contact with the carcass, the innerliner comprising a rubber composition comprising: at least one elastomer selected from the group consisting of butyl rubber, chlorinated butyl rubber, brominated butyl rubber, synthetic polyisoprene, natural rubber, styrene butadiene rubber, polybutadiene, copolymer of isobutylene and paramethylstyrene, and brominated copolymer of isobutylene and paramethylstyrene; epichlorohydrin rubber; and at least one delaminated talc having a BET surface area according to DIN 66131 of 10-40 m2/g, an average particle size (D50) of 4-8 microns, determined by laser diffraction measurement, and a lamellarity index of 3-15.

Abstract translation: 本发明涉及一种充气轮胎，其包括与胎体直接接触的胎体和内衬层，所述衬里包括橡胶组合物，所述橡胶组合物包含：至少一种选自丁基橡胶，氯化丁基橡胶，溴化丁基橡胶 ，合成聚异戊二烯，天然橡胶，丁苯橡胶，聚丁二烯，异丁烯和对甲基苯乙烯的共聚物，异丁烯和对甲基苯乙烯的溴化共聚物; 表氯醇橡胶; 并且根据DIN 66131具有10-40m 2 / g的BET表面积的至少一种脱层滑石，通过激光衍射测量确定的平均粒径（D50）为4-8微米，层厚指数为3-15 。

公开(公告)号：US20110152434A1

公开(公告)日：2011-06-23

申请号：US12641869

申请日：2009-12-18

Applicant: Claude Schweitzer ,  Uwe Ernst Frank ,  Pascal Patrick Steiner ,  Ralf Mruk ,  Carolin Anna Welter

Inventor： Claude Schweitzer ,  Uwe Ernst Frank ,  Pascal Patrick Steiner ,  Ralf Mruk ,  Carolin Anna Welter

IPC: C08K3/34

CPC classification number: C08L9/06 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08K2201/005 ,  C08K2201/006 ,  C08K2201/014 ,  C08L9/00 ,  C08L21/00 ,  C08L45/02 ,  C08L2666/02

Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition comprising: 100 parts by weight of at least one elastomer; from 10 to 80 parts by weight, per 100 parts by weight of elastomer (phr) of a high structure silica having a CTAB specific surface area (SCTAB) of between 40 and 525 m2/g, a BET specific surface area (SBET) of between 45 and 550 m2/g; and from 10 to 70 phr of a low structure silica having a median particle size of less than 500 nm, a specific area ranging from 15 to 25 m2/g, and a specific gravity of 2.1 to 2.3 g/cm3.

Abstract translation: 本发明涉及一种包括至少一种组分的充气轮胎，所述至少一种组分包括橡胶组合物，其包含：100重量份的至少一种弹性体; 10重量份至80重量份，相对于每100重量份具有40-52m 2 / g CTAB比表面积（SCTAB）的高结构二氧化硅的弹性体（phr），BET比表面积（SBET）为 45至550平方米/克; 和10至70phr的中等颗粒尺寸小于500nm，比表面积为15至25m 2 / g，比重为2.1至2.3g / cm 3的低结构二氧化硅。

公开(公告)号：US07855243B2

公开(公告)日：2010-12-21

申请号：US11845816

申请日：2007-08-28

Applicant: Carlo Kanz ,  Uwe Ernst Frank ,  Wolfgang Albert Leo Loesslein

Inventor： Carlo Kanz ,  Uwe Ernst Frank ,  Wolfgang Albert Leo Loesslein

IPC: C08L95/00 ,  B60C1/00 ,  C08F8/34

CPC classification number: C08L7/00 ,  B60C1/00 ,  B60C1/0016 ,  C08K3/04 ,  C08K5/01 ,  C08L9/06 ,  C08L21/00 ,  C08L95/00 ,  C08L2666/02 ,  C08L2666/08

Abstract: The present invention is directed to a pneumatic tire including at least one component, the at least component including a rubber composition, the rubber composition including 100 parts by weight of a diene based elastomer and from 1 to 20 parts by weight, per 100 parts by weight of elastomer (phr), of a solvent-extracted asphaltene.

Abstract translation: 本发明涉及一种充气轮胎，其包括至少一种组分，所述至少一种组分包括橡胶组合物，所述橡胶组合物包含100重量份的二烯基弹性体和每100重量份1至20重量份 溶剂提取的沥青质的弹性体重量（phr）。

公开(公告)号：US06624214B2

公开(公告)日：2003-09-23

申请号：US09794561

申请日：2001-02-27

Applicant: Rene Jean Zimmer ,  Wolfgang Lauer ,  Marc Weydert ,  Friedrich Visel ,  Uwe Ernst Frank

Inventor： Rene Jean Zimmer ,  Wolfgang Lauer ,  Marc Weydert ,  Friedrich Visel ,  Uwe Ernst Frank

IPC: C08L8300

CPC classification number: B60C1/0016 ,  C08L21/00 ,  C08L2666/14 ,  C08L83/04

Abstract: There is disclosed a rubber composition comprising: (a) 100 parts by weight of at least one rubber containing olefinic unsaturation; and (b) 1 to 150 phr of a precipitated organosilicon particles having a core and a shell, wherein the core is obtained by the condensation of at least one monomer of the formula: R1—Si(OR2)3  I  where R1 is selected from the group consisting of hydrogen, methyl, ethyl, vinyl, alkoxy having from 1 to 4 carbon atoms, and phenyl; R2 is selected from the group consisting of alkyls having from 1 to 4 carbon atoms and phenyl; and wherein said condensation of said monomer is in the presence of a surfactant; and wherein the shell is obtained by the subsequent addition to the core of a monomer of the formula: R3—Si(OR2)3  II  where R3 is selected from the group consisting of —CH═CH2, —CH2—CH═CH2, &Parenopenst;CH2&Parenclosest;nSH and mixtures thereof; and n is an integer of from 2 to 8.

Abstract translation: 公开了一种橡胶组合物，其包含：（a）100重量份的至少一种含有烯属不饱和的橡胶; 和（b）1至150phr具有核和壳的沉淀的有机硅颗粒，其中所述核通过至少一种下式的单体的缩合获得：其中R 1选自氢 ，甲基，乙基，乙烯基，具有1至4个碳原子的烷氧基和苯基; R 2选自具有1至4个碳原子的烷基和苯基; 并且其中所述单体的所述缩合是在表面活性剂存在下进行的; 并且其中壳体通过随后加入下式的单体的核心获得：其中R 3选自-CH = CH 2，-CH 2 -CH = CH 2和Parenopenst; CH 2和Parenclosest; nSH和混合物 的; n为2〜8的整数。

公开(公告)号：US06417286B1

公开(公告)日：2002-07-09

申请号：US09624733

申请日：2000-07-25

Applicant: Giorgio Agostini ,  Mario Corigliano ,  Uwe Ernst Frank

Inventor： Giorgio Agostini ,  Mario Corigliano ,  Uwe Ernst Frank

IPC: C08C1900

CPC classification number: C07D303/22 ,  C07F7/003 ,  C08K5/56 ,  C08L21/00

Abstract: The present invention relates to titanium and zirconium compounds of the formulae (R1—O&Parenclosest;yX&Parenopenst;O—R2—W)z  I wherein each R1 is independently selected from the group consisting of alkyl radicals having from 1 to 8 carbon atoms; R2 is a divalent radical selected from the group consisting of alkylenes having 1 to 15 carbon atoms, arylene and alkyl substituted arylene groups having 6 to 10 carbon atoms; W is an epoxy group; and y is an integer of from 1 to 3, z is an integer of from 1 to 3 and the sum of y and z equals 4; and X is titanium or zirconium.

Abstract translation: 本发明涉及下式的钛和锆化合物，其中R 1独立地选自具有1至8个碳原子的烷基; R2是选自具有1至15个碳原子的亚烷基，亚芳基和具有6至10个碳原子的烷基取代亚芳基的二价基团; W是环氧基; y为1〜3的整数，z为1〜3的整数，y与z的和为4。 X为钛或锆。

公开(公告)号：US6121346A

公开(公告)日：2000-09-19

申请号：US033491

申请日：1998-03-02

Applicant: Friedrich Visel ,  Uwe Ernst Frank ,  Rene Jean Zimmer ,  Thierry Florent Edme Materne ,  Giorgio Agostini

Inventor： Friedrich Visel ,  Uwe Ernst Frank ,  Rene Jean Zimmer ,  Thierry Florent Edme Materne ,  Giorgio Agostini

IPC: B60C1/00 ,  C08K3/00 ,  C08K3/04 ,  C08K3/22 ,  C08K3/34 ,  C08K3/36 ,  C08K9/00 ,  C08K9/02 ,  C08L21/00 ,  F16G1/06 ,  F16L11/04

CPC classification number: C08K3/36 ,  B60C1/00 ,  C08K3/0033 ,  C08K9/02

Abstract: A rubber composition containing a filler having individual aggregates containing both large and small particles, where the small particles are grafted onto the surface of the large particles. The small particles range from 1 to 30 weight percent of the overall weight of the filler. The large particles range from 70 to 99 weight percent of the overall weight of the filler. The small particles range in size of from 1 to 16 nanometers in diameter and the large particles range in size of from 17 to 500 nanometers in diameter.

Abstract translation: 一种橡胶组合物，其含有具有含有大粒子和小粒子的单个聚集体的填料，其中小颗粒接枝到大颗粒的表面上。 小颗粒占填料总重量的1至30重量％。 大颗粒占填料总重量的70〜99重量％。 该小颗粒的直径范围为1至16纳米，大颗粒的直径范围为17至500纳米。

公开(公告)号：US6068694A

公开(公告)日：2000-05-30

申请号：US032938

申请日：1998-03-02

Applicant: Yvon Andre Bernard ,  Uwe Ernst Frank ,  Wolfgang Lauer ,  Thierry Florent Edme Materne ,  Friedrich Visel ,  Rene Jean Zimmer

Inventor： Yvon Andre Bernard ,  Uwe Ernst Frank ,  Wolfgang Lauer ,  Thierry Florent Edme Materne ,  Friedrich Visel ,  Rene Jean Zimmer

IPC: B60C1/00 ,  C08K3/22 ,  C08K3/36 ,  C08K9/02 ,  C09C3/00 ,  C01B33/12 ,  C01B33/18 ,  C01B33/20

CPC classification number: C09C3/006 ,  B60C1/0016 ,  C08K3/22 ,  C08K3/36 ,  C08K9/02 ,  C01P2004/04 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/60 ,  C01P2004/80 ,  C01P2006/10 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17

Abstract: This invention relates to aggregates comprised of particles which contain silicon dioxide and to elastomers reinforced therewith. The invention also relates to tires having treads composed of such reinforced elastomers.

Abstract translation: 本发明涉及由含有二氧化硅的颗粒和由其增强的弹性体组成的聚集体。 本发明还涉及具有由这种增强弹性体构成的胎面的轮胎。

公开(公告)号：US5798405A

公开(公告)日：1998-08-25

申请号：US941180

申请日：1997-09-30

Applicant: Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Thierry Florent Edme Materne ,  Giorgio Agostini

Inventor： Rene Jean Zimmer ,  Friedrich Visel ,  Uwe Ernst Frank ,  Thierry Florent Edme Materne ,  Giorgio Agostini

IPC: C08K3/04 ,  C08K3/00

CPC classification number: C08K3/04 ,  C08K2201/014

Abstract: The invention relates to a tire with a tread composed of a rubber composition containing carbon black reinforcement as significant quantities two different carbon blacks and without quantitative amounts of silica reinforcement.

Abstract translation: 本发明涉及具有胎面的轮胎，该胎面由含有大量两种不同炭黑并且没有定量量的二氧化硅增强物的含碳黑增强剂的橡胶组合物组成。

公开(公告)号：US5674932A

公开(公告)日：1997-10-07

申请号：US758869

申请日：1996-12-02

Applicant: Giorgio Agostini ,  Uwe Ernst Frank ,  Thierry Florent Edme Materne ,  Friedrich Visel ,  Rene Jean Zimmer

Inventor： Giorgio Agostini ,  Uwe Ernst Frank ,  Thierry Florent Edme Materne ,  Friedrich Visel ,  Rene Jean Zimmer

IPC: C08J3/24 ,  B29C35/02 ,  B29K21/00 ,  B29L30/00 ,  B60C1/00 ,  C08J3/20 ,  C08K3/00 ,  C08K3/04 ,  C08K3/06 ,  C08K3/18 ,  C08K3/22 ,  C08K3/30 ,  C08K3/34 ,  C08K3/36 ,  C08K5/00 ,  C08K5/36 ,  C08K5/548 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00

CPC classification number: B60C1/0016 ,  C08J3/20 ,  C08K5/548 ,  C08J2321/00

Abstract: The invention relates to a process for preparation of a rubber composition containing silica reinforcement through the utilization of a high purity organosilane disulfide/trisulfide. Pneumatic tires having treads prepared by such process are provided.

Abstract translation: 本发明涉及通过利用高纯度有机硅烷二硫化物/三硫化物制备含有二氧化硅增强剂的橡胶组合物的方法。 提供了具有通过这种方法制备的踏面的气动轮胎。

公开(公告)号：US20120123018A1

公开(公告)日：2012-05-17

申请号：US12948120

申请日：2010-11-17

Applicant: Carlo Kanz ,  Christian Jean-Marie Kaes ,  Olivio Jean-Baptiste Pagliarini ,  Marc Weydert ,  Uwe Ernst Frank

Inventor： Carlo Kanz ,  Christian Jean-Marie Kaes ,  Olivio Jean-Baptiste Pagliarini ,  Marc Weydert ,  Uwe Ernst Frank

IPC: C08J5/14

CPC classification number: B60C1/00 ,  B60C1/0016 ,  C08C19/44 ,  C08K3/36 ,  C08L15/00 ,  C08L21/00 ,  C08L45/00 ,  C08L9/00

Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising: from 70 to 90 phr of a styrene-butadiene rubber functionalized with an alkoxysilane group and at least one of a primary amine group and thiol group; from 10 to 30 phr of at least one additional diene based elastomer; from 60 to 100 phr of precipitated silica; from 1 to 10 phr of a polyoctenamer; from 5 to 25 phr of a starch/plasticizer composite; and from 10 to 20 phr of a tackifying resin.

Abstract translation: 本发明涉及一种充气轮胎，其包括至少一种组分，所述至少一种组分包含橡胶组合物，所述橡胶组合物包含：70至90phr用烷氧基硅烷基官能化的苯乙烯 - 丁二烯橡胶和至少一种 的伯胺基和硫醇基; 10至30phr的至少一种另外的二烯基弹性体; 60至100phr沉淀二氧化硅; 1〜10phr的聚辛烯; 5至25phr淀粉/增塑剂复合材料; 和10〜20phr的增粘树脂。