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公开(公告)号：US06268422B1
公开(公告)日：2001-07-31
申请号：US08566533
申请日：1995-12-04
IPC分类号： C08K504
CPC分类号： C08F36/04 , C08L2666/04 , C09J109/10 , C08F2/44
摘要： An adhesive composition containing a polyvinyl alcohol-stabilized butadiene polymer latex and a methylene donor compound. The butadiene polymer latex is prepared by an emulsion polymerization in the presence of polyvinyl alcohol. The adhesive composition may also contain other optional ingredients such as a supplemental polymeric film-forming component, a nitroso compound crosslinker, a maleimide compound crosslinker, a vulcanizing agent, and an acid-scavenging compound. The polyvinyl alcohol-stabilized butadiene polymer latex and methylene donor compound combine to provide a tightly crosslinked, robust film which provides for excellent adhesion and environmental resistance.
摘要翻译： 一种含有聚乙烯醇稳定的丁二烯聚合物胶乳和亚甲基供体化合物的粘合剂组合物。 丁二烯聚合物胶乳通过聚乙烯醇存在下的乳液聚合制备。 粘合剂组合物还可以含有其它任选的成分，例如补充的聚合物成膜组分，亚硝基化合物交联剂，马来酰亚胺化合物交联剂，硫化剂和除酸化合物。 聚乙烯醇稳定的丁二烯聚合物胶乳和亚甲基给体化合物结合在一起提供了紧密交联的坚固的膜，其提供优异的粘附性和耐环境性。
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公开(公告)号：US5496884A
公开(公告)日：1996-03-05
申请号：US152112
申请日：1993-11-12
IPC分类号： C08F2/22 , C08F2/14 , C08F2/44 , C08F8/00 , C08F36/04 , C08F257/00 , C08F261/04 , C08K5/04 , C09J109/00 , C09J109/10 , C09J111/00 , C09J115/02 , C09J121/00 , C09J147/00 , C09J151/00 , C08L29/04
CPC分类号： C08F36/04 , C09J109/10
摘要： An adhesive composition containing a polyvinyl alcohol-stabilized butadiene polymer latex and a methylene donor compound. The butadiene polymer latex is prepared by an emulsion polymerization in the presence of polyvinyl alcohol. The adhesive composition may also contain other optional ingredients such as a supplemental polymeric film-forming component, a nitroso compound crosslinker, a maleimide compound crosslinker, a vulcanizing agent, and an acid-scavenging compound. The polyvinyl alcohol-stabilized butadiene polymer latex and methylene donor compound combine to provide a tightly crosslinked, robust film which provides for excellent adhesion and environmental resistance.
摘要翻译： 一种含有聚乙烯醇稳定的丁二烯聚合物胶乳和亚甲基供体化合物的粘合剂组合物。 丁二烯聚合物胶乳通过聚乙烯醇存在下的乳液聚合制备。 粘合剂组合物还可以含有其它任选的成分，例如补充的聚合物成膜组分，亚硝基化合物交联剂，马来酰亚胺化合物交联剂，硫化剂和除酸化合物。 聚乙烯醇稳定的丁二烯聚合物胶乳和亚甲基给体化合物结合在一起提供了紧密交联的坚固的膜，其提供优异的粘附性和耐环境性。
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公开(公告)号：US5200459A
公开(公告)日：1993-04-06
申请号：US708973
申请日：1991-05-31
申请人： Mark A. Weih , Helmut W. Kucera
发明人： Mark A. Weih , Helmut W. Kucera
IPC分类号： C08F2/16 , C08F36/04 , C09J109/10
CPC分类号： C09J109/10 , C08F36/04 , C08K5/32
摘要： A butadiene heteropolymer latex is prepared by emulsion polymerizing appropriate monomers in the presence of polyvinyl alcohol and a stabilizing solvent. The butadiene heteropolymer can be a butadiene copolymer or terpolymer prepared from butadiene monomers and comonomers such as .alpha.-haloacrylonitrile and acrylic acid. The butadiene heteropolymer latices can be prepared without problems of coagulation and can be utilized effectively in adhesive compositions without the use of volatile solvents. Adhesive bonds prepared from the butadiene heteropolymer latices also avoid the side effect problems associated with polymers prepared utilizing conventional surfactant-based emulsion polymerization techniques.
摘要翻译： 通过在聚乙烯醇和稳定溶剂的存在下将适当的单体乳液聚合制备丁二烯杂聚物胶乳。 丁二烯杂聚物可以是由丁二烯单体和共聚单体如α-卤代丙烯腈和丙烯酸制备的丁二烯共聚物或三元共聚物。 可以制备丁二烯杂聚物胶乳而没有凝结的问题，并且可以在不使用挥发性溶剂的情况下有效地用于粘合剂组合物。 从丁二烯杂聚物胶乳制备的粘合剂粘合剂也避免了与使用常规的基于表面活性剂的乳液聚合技术制备的聚合物相关的副作用问题。
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公开(公告)号：US5128403A
公开(公告)日：1992-07-07
申请号：US683219
申请日：1991-04-10
申请人： Patrick A. Warren , Mark A. Weih , Karen M. Bond
发明人： Patrick A. Warren , Mark A. Weih , Karen M. Bond
IPC分类号： C09J147/00 , C08C19/18 , C08F279/02 , C08K5/13 , C09J115/02 , C09J127/24 , C09J151/04
CPC分类号： C09J115/02 , C08C19/18 , C09J151/04
摘要： A one-coat adhesive composition which utilizes environmentally acceptable ingredients and which can withstand high temperature conditions such as those experienced during injection molding processes. The adhesive contains a Diels-Alder adduct of a perhalogenated cyclic conjugated diene and an olefinically unsaturated dienophile having a vinyl content in excess of 50 percent, a phenolic resin, an aromatic hydroxy compound, a formaldehyde donor, a heat-activated unsaturated elastomer crosslinker, a vulcanizing agent, and a metal oxide. An adhesive bond prepared with the adhesive is resistant to high temperature fluids and corrosive agents.
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5.发明授权Adhesive with polyesterurethane, halogenated polyolefin and Diels-Alder adduct 失效与聚氨酯，卤化聚烯烃和Diels-Alder加合物的粘合剂
公开(公告)号：US5310796A
公开(公告)日：1994-05-10
申请号：US36122
申请日：1993-03-23
IPC分类号： C08G18/10 , C09J123/28 , C09J151/00 , C09J153/02 , C09J175/06 , C08L9/00 , C08L23/28 , C08L53/02 , C08L75/06
CPC分类号： C09J153/025 , C08G18/10 , C09J123/28 , C09J151/006 , C09J175/06
摘要： An adhesive composition containing a linear polyester polyurethane, a halogenated polyolefin, an epoxy/silane adduct, a Diels-Alder adduct of a halogenated cyclic conjugated diene and a block copolymer of styrene and butadiene and a crosslinking compound for the linear polyester polyurethane. The adhesive composition is preferably utilized as a two-component adhesive for bonding vinyl polymers such as polyvinyl chloride to various substrates such as glass. The adhesive composition exhibits substantial resistance to environmental conditions without the requirements of a pre-heating step.
摘要翻译： 含有线性聚酯聚氨酯，卤化聚烯烃，环氧/硅烷加成物，卤代环状共轭二烯的狄尔斯 - 阿尔德加成物和苯乙烯和丁二烯的嵌段共聚物以及直链聚酯聚氨酯的交联化合物的粘合剂组合物。 粘合剂组合物优选用作将乙烯基聚合物如聚氯乙烯粘合到各种基材如玻璃上的双组分粘合剂。 粘合剂组合物在没有预热步骤的要求的情况下显示出对环境条件的显着抵抗性。
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公开(公告)号：US5717031A
公开(公告)日：1998-02-10
申请号：US492939
申请日：1995-06-21
申请人： James B. Degen , Patrick A. Warren , Mark A. Weih
发明人： James B. Degen , Patrick A. Warren , Mark A. Weih
IPC分类号： B32B25/04 , C08J5/12 , C09J123/28 , C09J175/00 , C08L27/00 , C08L75/04
CPC分类号： C08J5/127 , Y10T428/3154 , Y10T428/31551 , Y10T428/31569
摘要： An aqueous adhesive composition includes a water-dispersible polyisocyanate; an aqueous dispersion of a halogenated polyolefin elastomer; and a curing agent. The aqueous adhesive composition exhibits low VOC emissions and can be used to bond vulcanizable rubbers to a variety of substrates.
摘要翻译： 水性粘合剂组合物包括水分散性多异氰酸酯; 卤化聚烯烃弹性体的水分散体; 和固化剂。 水性粘合剂组合物表现出低的VOC排放，可用于将可硫化的橡胶粘合到各种基材上。
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公开(公告)号：US5102937A
公开(公告)日：1992-04-07
申请号：US587275
申请日：1990-09-24
IPC分类号： C03C27/10 , C03C17/32 , C08G18/10 , C08L23/26 , C08L23/28 , C09J123/28 , C09J127/04 , C09J127/24 , C09J175/00 , C09J175/06
CPC分类号： C09J175/06 , C03C17/32 , C08G18/10 , Y10T428/3158
摘要： A chemical formulation useful as a coating, primer or adhesive including a linear polyester polyurethane, a halogenated polyolefin, an alkoxy silane compound, and a cross-linker. The formulation is preferably utilized as a two-component adhesive for bonding vinyl polymers such as polyvinyl chloride to various substrates such as glass.
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公开(公告)号：US06262217B1
公开(公告)日：2001-07-17
申请号：US08990399
申请日：1997-12-15
IPC分类号： C08G1862
CPC分类号： C09J175/14 , C08G18/12 , C08G18/69 , Y10S528/905 , C08G18/3868 , C08G18/3814
摘要： Polyurethane compositions including the reaction product of a polyurethane prepolymer component including (a) at least one isocyanate-terminated polyalkadiene prepared by capping hydroxy-terminated polyalkadiene having a molecular weight from about 1500 to about 5000 grams per mol (g/mol) with isocyanate; and (b) at least one additional isocyanate-terminated polyalkadiene prepared by capping hydroxy-terminated polyalkadiene having a molecular weight from about 500 to about 1500 g/mol with isocyanate with a curative component. The compositions exhibit numerous useful properties, such as low glass transition temperature (Tg) high temperature stability, low viscosity at room and elevated temperatures, flexibility and flat dynamic mechanical properties versus temperature.
摘要翻译： 聚氨酯组合物包括聚氨酯预聚物组分的反应产物，其包含（a）通过将分子量为约1500至约5000克/ mol（g / mol）的羟基封端的聚链烷二醇与异氰酸酯封端而制备的至少一种异氰酸酯封端的聚链二烯; 和（b）通过用具有固化组分的异氰酸酯封端具有约500至约1500g / mol的分子量的羟基封端的聚链二烯制备的至少一种另外的异氰酸酯封端的聚链二烯。 组合物显示出许多有用的性质，例如低玻璃化转变温度（Tg）高温稳定性，室温下的低粘度和高温，柔韧性和平坦的动态力学性能对温度。
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公开(公告)号：US06973949B1
公开(公告)日：2005-12-13
申请号：US09711567
申请日：2000-11-13
申请人： Edward F. Tokas , Ken C. Caster , Mark A. Weih
发明人： Edward F. Tokas , Ken C. Caster , Mark A. Weih
CPC分类号： C08J5/12 , B60C1/00 , C09J5/04 , C09J2400/163 , C09J2421/006 , Y10S156/91
摘要： A method for bonding a material to a first substrate surface that includes providing a catalyst at the first substrate surface and then contacting that surface with a material that undergoes a metathesis reaction to bond the material to the first substrate surface. There are two embodiments of this method—a coating process and an adhesive process. In the coating embodiment, the metathesizable material is contacted with the catalyst on the substrate surface so that it undergoes metathesis polymerization to form the coating. The adhesive process includes (a) providing a catalyst at the first substrate surface, (b) providing a metathesizable material between the first substrate surface and the second substrate surface, and (c) contacting the catalyst on the first substrate surface with the metathesizable material so that the metathesizable material undergoes a metathesis reaction and bonds the first substrate surface to the second substrate surface.
摘要翻译： 一种用于将材料粘合到第一衬底表面的方法，包括在第一衬底表面处提供催化剂，然后使该表面与经历复分解反应的材料接触以将材料粘合到第一衬底表面。 该方法有两个实施方案 - 涂覆方法和粘合方法。 在涂布实施例中，可复分解材料与衬底表面上的催化剂接触，使得其进行易位聚合以形成涂层。 粘合方法包括（a）在第一基材表面提供催化剂，（b）在第一基材表面和第二基材表面之间提供可复分解材料，和（c）使第一基材表面上的催化剂与可复分解材料 使得可复分解材料经历复分解反应并将第一基材表面结合到第二基材表面。
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公开(公告)号：US06960272B1
公开(公告)日：2005-11-01
申请号：US09711692
申请日：2000-11-13
申请人： Edward F. Tokas , Ken C. Caster , Mark A. Weih
发明人： Edward F. Tokas , Ken C. Caster , Mark A. Weih
CPC分类号： C08J5/12 , B60C1/00 , C09J5/04 , C09J2400/163 , C09J2421/006 , Y10S156/91
摘要： A method for bonding a material to a first substrate surface that includes providing a catalyst at the first substrate surface and then contacting that surface with a material that undergoes a metathesis reaction to bond the material to the first substrate surface. There are two embodiments of this method—a coating process and an adhesive process. In the coating embodiment, the metathesizable material is contacted with the catalyst on the substrate surface so that it undergoes metathesis polymerization to form the coating. The adhesive process includes (a) providing a catalyst at the first substrate surface, (b) providing a metathesizable material between the first substrate surface and the second substrate surface, and (c) contacting the catalyst on the first substrate surface with the metathesizable material so that the metathesizable material undergoes a metathesis reaction and bonds the first substrate surface to the second substrate surface.
摘要翻译： 一种用于将材料粘合到第一衬底表面的方法，包括在第一衬底表面处提供催化剂，然后使该表面与经历复分解反应的材料接触以将材料粘合到第一衬底表面。 该方法有两个实施方案 - 涂覆方法和粘合方法。 在涂布实施例中，可复分解材料与衬底表面上的催化剂接触，使得其进行易位聚合以形成涂层。 粘合方法包括（a）在第一基材表面提供催化剂，（b）在第一基材表面和第二基材表面之间提供可复分解材料，和（c）使第一基材表面上的催化剂与可复分解材料 使得可复分解材料经历复分解反应并将第一基材表面结合到第二基材表面。
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