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    Polystyrene nanocomposites for blow molding applications
    3.
    发明授权
    Polystyrene nanocomposites for blow molding applications 有权
    用于吹塑应用的聚苯乙烯纳米复合材料

    公开(公告)号：US08697208B2

    公开(公告)日：2014-04-15

    申请号：US12508598

    申请日：2009-07-24

    申请人： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Theodore Harris

    发明人： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Theodore Harris

    IPC分类号： B32B1/02 ,  C08K3/34

    CPC分类号： C08K9/04 ,  B29C49/0005 ,  B29C49/06 ,  B29D22/003 ,  B29K2025/00 ,  B29K2105/162 ,  Y10T428/1352 ,  Y10T428/1397

    摘要： Disclosed is a polystyrene based polymer/layered compound nanocomposite for injection blow molding or injection stretch blow molding of articles. The nanocomposite can reduce shrinkage and warpage to the preform during the reheating process compared to neat polystyrene. The incorporation of layered compounds can increase the processability of PS preforms, help improve heating efficiency, and improve bottle mechanical properties. The layered compound can be treated with chemicals or compounds having an affinity with the styrene monomer or polystyrene, thus producing a treated layered compound having an affinity with the styrene monomer or polystyrene. The monomer and the layered compound can be combined prior to polymerization. The polymer and layered compound can be combined by solution mixing in a solvent. The layered compound can also be incorporated into the mixture by compounding a polymer product with the layered compound, or the combination of any of the above three approaches.

    摘要翻译： 公开了用于注射吹塑或注射拉伸吹塑成型的聚苯乙烯基聚合物/层状复合纳米复合材料。 与纯聚苯乙烯相比，纳米复合材料可以在再加热过程中减少预成型件的收缩和翘曲。 结合层状化合物可以增加PS预制件的加工性能，有助于提高加热效率，并提高瓶子的机械性能。 层状化合物可以用与苯乙烯单体或聚苯乙烯具有亲和性的化学品或化合物处理，从而产生与苯乙烯单体或聚苯乙烯具有亲和性的经处理的层状化合物。 单体和层状化合物可以在聚合之前进行组合。 聚合物和层状化合物可以通过在溶剂中的溶液混合来组合。 层叠的化合物也可以通过将聚合物产物与层状化合物混合，或通过上述三种方法中的任一种的组合将其掺入混合物中。

    Polystyrene Nanocomposites for Blow Molding Applications
    4.
    发明申请
    Polystyrene Nanocomposites for Blow Molding Applications 有权
    聚苯乙烯纳米复合材料的吹塑应用

    公开(公告)号：US20110020571A1

    公开(公告)日：2011-01-27

    申请号：US12508598

    申请日：2009-07-24

    申请人： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Ted Harris

    发明人： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Ted Harris

    IPC分类号： B32B1/00 ,  B29C49/06

    CPC分类号： C08K9/04 ,  B29C49/0005 ,  B29C49/06 ,  B29D22/003 ,  B29K2025/00 ,  B29K2105/162 ,  Y10T428/1352 ,  Y10T428/1397

    摘要： Disclosed is a polystyrene based polymer/layered compound nanocomposite for injection blow molding or injection stretch blow molding of articles. The nanocomposite can reduce shrinkage and warpage to the preform during the reheating process compared to neat polystyrene. The incorporation of layered compounds can increase the processability of PS preforms, help improve heating efficiency, and improve bottle mechanical properties. The layered compound can be treated with chemicals or compounds having an affinity with the styrene monomer or polystyrene, thus producing a treated layered compound having an affinity with the styrene monomer or polystyrene. The monomer and the layered compound can be combined prior to polymerization. The polymer and layered compound can be combined by solution mixing in a solvent. The layered compound can also be incorporated into the mixture by compounding a polymer product with the layered compound, or the combination of any of the above three approaches

    摘要翻译： 公开了用于注射吹塑或注射拉伸吹塑成型的聚苯乙烯基聚合物/层状复合纳米复合材料。 与纯聚苯乙烯相比，纳米复合材料可以在再加热过程中减少预成型件的收缩和翘曲。 结合层状化合物可以增加PS预制件的加工性能，有助于提高加热效率，并提高瓶子的机械性能。 层状化合物可以用与苯乙烯单体或聚苯乙烯具有亲和性的化学品或化合物处理，从而产生与苯乙烯单体或聚苯乙烯具有亲和性的经处理的层状化合物。 单体和层状化合物可以在聚合之前进行组合。 聚合物和层状化合物可以通过在溶剂中的溶液混合来组合。 也可以通过将聚合物与层状化合物混合，或者将上述三种方法中的任一种

    Breathable films
    7.
    发明申请
    Breathable films 有权
    透气膜

    公开(公告)号：US20070123650A1

    公开(公告)日：2007-05-31

    申请号：US11288631

    申请日：2005-11-28

    申请人： Juan Aguirre ,  Mark Miller ,  David Turner

    发明人： Juan Aguirre ,  Mark Miller ,  David Turner

    IPC分类号： C08L53/00

    CPC分类号： C08L23/10 ,  C08L23/16 ,  C08L53/02 ,  C08L2666/02

    摘要： A polymeric composition having a MFR of less than 2 g/10 min. which when formed into a film has an oxygen transmission rate of equal to or greater than 300 cc/100 in2/24 h at 73° F. and 0% relative humidity per ASTM D 3895 and a water vapor transmission rate of equal to or greater than 0.5 g/100 in2/24 hrs at 100° F. and 100% relative humidity per ASTM F 1249. A polymeric film having a 2% secant modulus in the machine direction of 300 MPa to 700 MPa; an oxygen transmission rate of greater than 300 cc/100 in2/24 h at 100° F., a water vapor transmission rate of greater than 0.5 g/100 in2/24 hrs at 100° F. and 100% relative humidity; an Elmendorf tear strength in the MD of from 50 g to 400 g; an Elmendorf tear strength in the transverse direction of from 150 g to 400 g, a dart drop strength of from 200 g to about 500 g, a haze of from 0% to 85% and, gloss at 45° of from 5% to 70%.

    摘要翻译： MFR小于2g / 10min的聚合物组合物。 当形成膜时，在73°F和0％相对湿度下，根据ASTM D 3895和0℃的水，在32℃/ 24小时内具有等于或大于300cc / 100的氧气透过率 蒸汽透过率在100°F和100％相对湿度/ ASTM F1249下在0.2℃/ 24小时内等于或大于0.5g / 100。一种具有2％割线模量的聚合物膜 机器方向为300MPa至700MPa; 在100°F的2小时/ 24小时内的透氧率大于300cc / 100，在2℃下的水蒸汽透过率大于0.5g / 在100°F和100％相对湿度下24小时; 埃尔门多夫MD的撕裂强度从50克到400克; 在150克至400克横向方向的埃尔曼多夫撕裂强度，落镖从0％，在45℃的5％下降为200g的强度至约500克，的雾度为85％并将，光泽度至70 ％。

    Heat shrinkable film using a blend of polypropylene impact copolymer, syndiotactic polypropylene and/or polypropylene random copolymer
    8.
    发明申请
    Heat shrinkable film using a blend of polypropylene impact copolymer, syndiotactic polypropylene and/or polypropylene random copolymer 审中-公开
    使用聚丙烯抗冲共聚物，间同立构聚丙烯和/或聚丙烯无规共聚物的共混物的热收缩膜

    公开(公告)号：US20060008666A1

    公开(公告)日：2006-01-12

    申请号：US10885439

    申请日：2004-07-06

    申请人： Mark Miller ,  Juan Aguirre

    发明人： Mark Miller ,  Juan Aguirre

    IPC分类号： B32B27/32 ,  C08L23/00

    CPC分类号： C08L23/10 ,  B32B27/32 ,  C08J5/18 ,  C08J2323/08 ,  C08J2323/10 ,  C08J2323/16 ,  C08K3/013 ,  C08L23/0807 ,  C08L23/16 ,  Y10T428/31938 ,  C08L2666/06

    摘要： It has been discovered that the properties of heat shrinkable sheet or film materials of ethylene/propylene rubber impact-modified heterophasic copolymer (ICP) can be improved by blending the ICP with a second polyolefin. The second polyolefin may be a syndiotactic polypropylene (sPP), a random copolymer (RCP) of propylene and a comonomer (e.g. ethylene and/or butene) made using a Ziegler-Natta or metallocene catalyst. A cavitating agent may be optionally included. The heat shrinkable sheet or film materials may also be biaxially oriented. Property differences in films made with the inclusion of the second polyolefin and possibly the cavitating agent include, but are not necessarily limited to, reduction in yield stress, increased density, decreased cavitation, increased light transmittance, increased shrinkage, among other physical and mechanical properties.

    摘要翻译： 已经发现，通过将ICP与第二聚烯烃混合，可以提高乙烯/丙烯橡胶冲击改性的异相共聚物（ICP）的热收缩性薄片或薄膜材料的性能。 第二聚烯烃可以是间同立构聚丙烯（sPP），丙烯和使用齐格勒 - 纳塔或茂金属催化剂制备的共聚单体（例如乙烯和/或丁烯）的无规共聚物（RCP）。 可以任选地包括空化剂。 热收缩性片材或薄膜材料也可以是双轴取向的。 包含第二聚烯烃和可能的空化剂制成的薄膜的性能差异包括但不一定限于屈服应力的降低，增加的密度，降低的空化，增加的透光率，增加的收缩以及其它物理和机械性能 。