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    CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN
    3.
    发明申请
    CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN 审中-公开
    用于烯烃聚合的催化剂体系

    公开(公告)号：US20160333121A1

    公开(公告)日：2016-11-17

    申请号：US15105873

    申请日：2014-12-19

    申请人： Aurora Alexandra BATINAS-GEURTS ,  Martin Alexander ZUIDEVELD ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V

    发明人： Aurora Alexandra Batinas-Geurts ,  Martin Alexander Zuideveld

    IPC分类号： C08F10/06

    CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F210/16 ,  C08F2410/01 ,  C08F2500/12 ,  C08F4/6565 ,  C08F4/6465 ,  C08F210/06

    摘要： The present invention relates to a process for the preparation of a catalyst system suitable for olefin polymerization wherein the external electron donor is n-propyltriethoxysilane, and a catalyst system obtained or obtainable by said process. The invention also relates to a process for preparing a polyolefin using said catalyst system. The invention further relates to a polyolefin, in particular polyprolyene, obtainable by such a process, and shaped articles manufactured from such a polymer. The polymers produced using the catalyst system exhibit low volatiles and therefore have a reduced environmental and health impact.

    摘要翻译： 本发明涉及一种制备适用于烯烃聚合的催化剂体系的方法，其中外电子给体是正丙基三乙氧基硅烷，以及通过所述方法获得或可获得的催化剂体系。 本发明还涉及使用所述催化剂体系制备聚烯烃的方法。 本发明还涉及通过这种方法获得的聚烯烃，特别是聚丙烯烯，以及由这种聚合物制成的成型制品。 使用催化剂体系制备的聚合物表现出低挥发性，因此具有降低的环境和健康影响。

    CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN
    7.
    发明申请
    CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 有权
    用于聚合烯烃的催化剂体系

    公开(公告)号：US20160176998A1

    公开(公告)日：2016-06-23

    申请号：US14911028

    申请日：2014-08-11

    申请人： Martin Alexander ZUIDEVELD ,  Jaiprakash Brijlal SAINANI ,  Mahendrabhai Patel VIMALKUMAR ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

    发明人： Martin Alexander Zuideveld ,  Jaiprakash Brijlal Sainani ,  Vimalkumar Mahendrabhai Patel

    IPC分类号： C08F210/16 ,  C07F7/02

    CPC分类号： C08F210/06 ,  C07F7/025 ,  C08F210/16 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/15

    摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4-n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by (Formula II), wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 7 of the IUPAC Periodic Table of the Elements.

    摘要翻译： 本发明涉及包含前催化剂，助催化剂和外电子给体的催化剂体系，其中外电子给体包括具有式I结构的化合物：Si（L）n（OR 11）4-n（ 式I），其中Si是价态为4+的硅原子; O是具有2-价的氧原子，O经由硅 - 氧键与Si键合; n为1,2,3或4; R11选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; L是由式（II）表示的基团，其中L通过氮 - 硅键与硅原子键合; L在氮原子上具有单个取代基，其中该单取代基是亚胺碳原子; X和Y独立地选自氢原子; 选自IUPAC元素周期表的第13,14,15,16或17族的杂原子; 含有至多20个碳原子的直链，支链和环状烷基，任选地含有选自元素周期表IUPAC元素周期表第13,14,15,16或17族的杂原子和具有6至20个碳原子的芳族取代和未取代的烃基 原子，任选地含有选自IUPAC元素周期表的第13,14,15,16或7族的杂原子。

    CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN
    8.
    发明申请
    CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 审中-公开

    公开(公告)号：US20170283531A1

    公开(公告)日：2017-10-05

    申请号：US15625679

    申请日：2017-06-16

    申请人： SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

    发明人： Martin Alexander Zuideveld ,  Jaiprakash Brijlal Sainani ,  Vimalkumar Mahendrabhai Patel

    IPC分类号： C08F210/06 ,  C08F210/16 ,  C07F7/02

    CPC分类号： C08F210/06 ,  C07F7/025 ,  C08F210/16 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/15

    摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4−n  (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by Formula II wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements.

    Catalyst system for polymerisation of an OLEFIN
    9.
    发明授权
    Catalyst system for polymerisation of an OLEFIN 有权

    公开(公告)号：US09701773B2

    公开(公告)日：2017-07-11

    申请号：US14911028

    申请日：2014-08-11

    申请人： SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

    发明人： Martin Alexander Zuideveld ,  Jaiprakash Brijlal Sainani ,  Vimalkumar Mahendrabhai Patel

    IPC分类号： C08F210/16 ,  C07F7/02

    CPC分类号： C08F210/06 ,  C07F7/025 ,  C08F210/16 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/15

    摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4-n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by (Formula II), wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 7 of the IUPAC Periodic Table of the Elements.