公开(公告)号：US09944731B2

公开(公告)日：2018-04-17

申请号：US15105291

申请日：2014-12-19

申请人： Saudi Basic Industries Corporation ,  Sabic Global Technologies B.V. ,  Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts ,  Gennadii Dimitrievich Bukatov ,  Sergei Andreevich Sergeev ,  Vladimir Aleksandrovich Zakharov

发明人： Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts ,  Gennadii Dimitrievich Bukatov ,  Sergei Andreevich Sergeev ,  Vladimir Aleksandrovich Zakharov

IPC分类号： C08F110/06

CPC分类号： C08F110/06 ,  C08F4/651 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6557 ,  C08F4/6567

摘要： A process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, the procatalyst obtained or obtainable by the process; and a catalyst composition for olefin polymerization comprising the procatalyst. In particular a benzamide can be used as an activator in the preparation of a supported Ziegler-Natta type procatalyst useful for a process for the preparation of polyolefins. The Polyolefins and polypropylene homopolymers are also disclosed.

公开(公告)号：US20160311947A1

公开(公告)日：2016-10-27

申请号：US15105291

申请日：2014-12-19

申请人： Martin Alexander ZUIDEVELD ,  Aurora Alexandra BATINAS-GEURTS ,  Gennadii Dimitrievich BUKATOV ,  Sergei Andreevich SERGEEV ,  Vladimir Aleksandrovich ZAKHAROV ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

发明人： Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts ,  Gennadii Dimitrievich Bukatov ,  Sergei Andreevich Sergeev ,  Vladimir Aleksandrovich Zakharov

IPC分类号： C08F110/06

CPC分类号： C08F110/06 ,  C08F4/651 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6557 ,  C08F4/6567

摘要： A process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, the procatalyst obtained or obtainable by the process; and a catalyst composition for olefin polymerization comprising the procatalyst. In particular a benzamide can be used as an activator in the preparation of a supported Ziegler-Natta type procatalyst useful for a process for the preparation of polyolefins. The Polyolefins and polypropylene homopolymers are also disclosed.

摘要翻译： 一种制备适用于制备烯烃聚合催化剂组合物的前催化剂的方法，该方法获得或可获得的前催化剂; 以及包含前催化剂的烯烃聚合催化剂组合物。 特别地，苯甲酰胺可用作制备用于制备聚烯烃的方法的负载齐格勒 - 纳塔型前催化剂的活化剂。 还公开了聚烯烃和聚丙烯均聚物。

公开(公告)号：US10106632B2

公开(公告)日：2018-10-23

申请号：US15406124

申请日：2017-01-13

申请人： Mansour Taftaf ,  Jaiprakash Brijlal Sainani ,  Vladimir Aleksandrovich Zakharov ,  Gennadii Dimitrievich Bukatov ,  Vimalkumar Mahendrabhai Patel ,  Sergei Andreevich Sergeev ,  Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts

发明人： Mansour Taftaf ,  Jaiprakash Brijlal Sainani ,  Vladimir Aleksandrovich Zakharov ,  Gennadii Dimitrievich Bukatov ,  Vimalkumar Mahendrabhai Patel ,  Sergei Andreevich Sergeev ,  Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts

IPC分类号： C08F4/649 ,  C08F4/654 ,  C08F4/656 ,  C08F10/06 ,  C08F110/06 ,  C07C233/23 ,  C07C233/18 ,  C08F4/655 ,  C07C233/69

摘要： The present invention relates to a process for preparing a catalyst component for polymerization of an olefin comprising the steps of: i) contacting a compound R9zMgX2-z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to given a first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by electron donors and compounds of formula M(OR10)v-w(OR11)w, wherein M can be Ti, Zr, Hf, Al or Si, and M(OR10)v-w(R11)w, wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v being either 3 or 4, and w is smaller than v, to give a second intermediate reaction product; and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, a 1,3-diether as an internal electron donor, and optionally a diester as an additional internal electron donor.

公开(公告)号：US20170129974A1

公开(公告)日：2017-05-11

申请号：US15406124

申请日：2017-01-13

申请人： Mansour TAFTAF ,  Jaiprakash Brijlal SAINANI ,  Vladimir Aleksandrovich ZAKHAROV ,  Gennadii Dimitrievich BUKATOV ,  Vimalkumar Mahendrabhai PATEL ,  Sergei Andreevich SERGEEV ,  Martin Alexander Zuideveld ,  Aurora Alexandra BATINAS-GEURTS

发明人： Mansour TAFTAF ,  Jaiprakash Brijlal SAINANI ,  Vladimir Aleksandrovich ZAKHAROV ,  Gennadii Dimitrievich BUKATOV ,  Vimalkumar Mahendrabhai PATEL ,  Sergei Andreevich SERGEEV ,  Martin Alexander Zuideveld ,  Aurora Alexandra BATINAS-GEURTS

IPC分类号： C08F110/06

CPC分类号： C08F110/06 ,  C07C233/18 ,  C07C233/23 ,  C07C233/69 ,  C07C2601/14 ,  C08F4/649 ,  C08F4/6546 ,  C08F4/655 ,  C08F10/06 ,  C08F10/00 ,  C08F4/6565 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/24

摘要： The present invention relates to a process for preparing a catalyst component for polymerization of an olefin comprising the steps of: i) contacting a compound R9zMgXz2-z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloky-containing silane compound pound to given first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by electron donors and compounds of formula M(OR10)v-w(OR11)w, wherein M can be Ti, Zr, HI, Al or Si, and M(OR10)v-w(R11)w, wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v being either 3 or 4, and w is smaller than v, to give a second intermediate reaction product; and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, a 1,3-diether as an internal electron donor, and optionally a diester as an additional internal electron donor.

公开(公告)号：US20170198072A1

公开(公告)日：2017-07-13

申请号：US15314966

申请日：2015-06-01

申请人： Jaiprakash Brijlal SAINANI ,  Abhyankan SHIRISH ,  Gennadii Dimitrievich BUKATOV ,  Martin Alexander ZUIDEVELD ,  Mansour TAFTAF ,  Aurora Alexandra BATINAS-GEURTS ,  SABIC Global Technologies B.V.

发明人： Jaiprakash Brijlal Sainani ,  Abhyankar Shirish ,  Gennadii Dimitrievich Bukatov ,  Martin Alexander Zuideveld ,  Mansour Taftaf ,  Aurora Alexandra Batinas-Geurts

IPC分类号： C08F110/06

CPC分类号： C08F110/06 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6565

摘要： The present invention relates to a procatalyst comprising the compound represented by Formula (A), preferably the Fischer projection of formula (A) as an internal electron donor. The invention also relates to a process for preparing said procatalyst. Furthermore, the invention is directed to a catalyst system for polymerization of olefins comprising the said procatalyst, a co-catalyst and optionally an external electron donor; a process of making polyolefins by contacting at least one olefin with said catalyst system and to polyolefins obtainable by said process. The invention also relates to the use of said procatalyst in the polymerization of olefins. Moreover, the present invention relates to polymers obtained by polymerization using said procatalyst and to the shaped articles of said polymers.

公开(公告)号：US10160816B2

公开(公告)日：2018-12-25

申请号：US15314966

申请日：2015-06-01

申请人： SABIC GLOBAL TECHNOLOGIES B.V. ,  Jaiprakash Brijlal Sainani ,  Abhyankan Shirish ,  Gennadii Dimitrievich Bukatov ,  Martin Alexander Zuideveld ,  Mansour Taftaf ,  Aurora Alexandra Batinas-Geurts

发明人： Jaiprakash Brijlal Sainani ,  Shirish Shrikant Abhyankar ,  Gennadii Dimitrievich Bukatov ,  Martin Alexander Zuideveld ,  Mansour Taftaf ,  Aurora Alexandra Batinas-Geurts

IPC分类号： C08F110/06

摘要： The present invention relates to a procatalyst comprising the compound represented by Formula (A), preferably the Fischer projection of formula (A) as an internal electron donor. The invention also relates to a process for preparing said procatalyst. Furthermore, the invention is directed to a catalyst system for polymerization of olefins comprising the said procatalyst, a co-catalyst and optionally an external electron donor; a process of making polyolefins by contacting at least one olefin with said catalyst system and to polyolefins obtainable by said process. The invention also relates to the use of said procatalyst in the polymerization of olefins. Moreover, the present invention relates to polymers obtained by polymerization using said procatalyst and to the shaped articles of said polymers.

公开(公告)号：US20160333121A1

公开(公告)日：2016-11-17

申请号：US15105873

申请日：2014-12-19

申请人： Aurora Alexandra BATINAS-GEURTS ,  Martin Alexander ZUIDEVELD ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V

发明人： Aurora Alexandra Batinas-Geurts ,  Martin Alexander Zuideveld

IPC分类号： C08F10/06

CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F210/16 ,  C08F2410/01 ,  C08F2500/12 ,  C08F4/6565 ,  C08F4/6465 ,  C08F210/06

摘要： The present invention relates to a process for the preparation of a catalyst system suitable for olefin polymerization wherein the external electron donor is n-propyltriethoxysilane, and a catalyst system obtained or obtainable by said process. The invention also relates to a process for preparing a polyolefin using said catalyst system. The invention further relates to a polyolefin, in particular polyprolyene, obtainable by such a process, and shaped articles manufactured from such a polymer. The polymers produced using the catalyst system exhibit low volatiles and therefore have a reduced environmental and health impact.

摘要翻译： 本发明涉及一种制备适用于烯烃聚合的催化剂体系的方法，其中外电子给体是正丙基三乙氧基硅烷，以及通过所述方法获得或可获得的催化剂体系。 本发明还涉及使用所述催化剂体系制备聚烯烃的方法。 本发明还涉及通过这种方法获得的聚烯烃，特别是聚丙烯烯，以及由这种聚合物制成的成型制品。 使用催化剂体系制备的聚合物表现出低挥发性，因此具有降低的环境和健康影响。

公开(公告)号：US09944734B2

公开(公告)日：2018-04-17

申请号：US15105028

申请日：2014-12-19

申请人： Saudi Basic Industries Corporation ,  Sabic Global Technologies B.V. ,  Aurora Alexandra Batinas-Geurts ,  Martin Alexander Zuideveld ,  Bobby Johannes Henricus Hubertus Smeets

发明人： Aurora Alexandra Batinas-Geurts ,  Martin Alexander Zuideveld ,  Bobby Johannes Henricus Hubertus Smeets

IPC分类号： C08F210/06 ,  C08F210/16 ,  C08F10/06

CPC分类号： C08F210/06 ,  C08F10/06 ,  C08F210/16 ,  C08F4/6495 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12

摘要： The invention relates to a process for preparing a catalyst system suitable for olefin polymerization. The present invention further relates to a catalyst system obtainable by such process. In addition, the invention relates to a polyolefin. The invention also relates to ashaped article. The catalyst system comprises a procatalyst, a co-catalyst and optionally at least one external electron donor.

公开(公告)号：US20160326280A1

公开(公告)日：2016-11-10

申请号：US15105028

申请日：2014-12-19

申请人： Aurora Alexandra BATINAS-GEURTS ,  Martin Alexander ZUIDEVELD ,  Bobby Johannes Henricus Hubertus SMEETS ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

发明人： Aurora Alexandra Batinas-Geurts ,  Martin Alexander Zuideveld ,  Bobby Johannes Henricus Hubertus Smeets

IPC分类号： C08F210/06 ,  C08F210/16

CPC分类号： C08F210/06 ,  C08F10/06 ,  C08F210/16 ,  C08F4/6495 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12

摘要： The invention relates to a process for preparing a catalyst system suitable for olefin polymerization. The present invention further relates to a catalyst system obtainable by such process. In addition, the invention relates to a polyolefm. The invention also relates to ashaped article. The catalyst system comprises a procatalyst, a co-catalyst and optionally at least one external electron donor.

摘要翻译： 本发明涉及一种制备适用于烯烃聚合的催化剂体系的方法。 本发明还涉及可通过这种方法获得的催化剂体系。 另外，本发明涉及聚烯烃。 本发明还涉及成型制品。 催化剂体系包括前催化剂，助催化剂和任选的至少一种外电子给体。

公开(公告)号：US20160355615A1

公开(公告)日：2016-12-08

申请号：US15105055

申请日：2014-12-19

申请人： Martin Alexander Zuideveld ,  Erik Zuidema ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

发明人： Martin Alexander Zuideveld ,  Erik Zuidema

IPC分类号： C08F10/06

CPC分类号： C08F10/06 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F2410/00 ,  C08F2500/15 ,  C08F2500/12 ,  C08F4/6565 ,  C08F4/6465 ,  C08F4/6495 ,  C08F210/06

摘要： A catalyst system including a procatalyst, a co-catalyst and an external electron donor of Formula I′: Si(L)n(OR11)4-n-m(R12)m  Formula I′ wherein, Si has a valency 4+; O has a valency 2− and O is bonded to Si via a silicon-oxygen bond; n is 1-4; m is 0-3; n+m≦4; each R11 and R12 group is independently an alkyl or aromatic substituted or unsubstituted hydrocarbyl; each L group is independently of Formula II: wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently a hydrogen atom; a heteroatom of Groups 13-17; an alkyl, optionally containing a heteroatom of Groups 13-17 or an aromatic substituted and unsubstituted hydrocarbyl, optionally containing a heteroatom of Groups 13-17.