摘要:
A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of at least one organic compound over a catalyst bed, in which, in order to counteract the deactivation of the catalyst bed, the working pressure in the gas phase is increased during the operating time of the catalyst bed.
摘要:
A process for preparing acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas oxidation of propylene, in which the starting reaction gas mixture has the following contents: from 6 to 9% by volume of propylene, from 8 to 18% by volume of molecular oxygen, from 6 to 30% by volume of propane and from 32 to 72% by volume of molecular nitrogen.
摘要:
A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of at least one organic compound over a catalyst bed, in which, in order to counteract the deactivation of the catalyst bed, the working pressure in the gas phase is increased during the operating time of the catalyst bed.
摘要:
A shell which encloses an interior and has at least one first orifice for feeding at least one gas stream into the interior and at least one second orifice for withdrawing a gas stream fed to the interior beforehand via the at least one first orifice from the interior, the surface of the shell, on its side in contact with the interior, being manufactured at least partly, in a layer thickness of at least 1 mm, from a steel which has a specific elemental composition, and in the interior, a process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated is carried out in a reactor which is manufactured from the steel on its side in contact with the reaction gas.
摘要:
Emissions treatment systems and methods for treating an engine exhaust gas stream containing NOx and particulate matter are disclosed including a particulate filter comprising a first SCR catalyst for NOx conversion a second SCR catalyst for NOx conversion on a substrate disposed downstream of the particulate filter. The system NOx conversion and the system back pressure increase lie within a targeted operational window.
摘要:
A process for preparing an organic target compound by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound with molecular oxygen in two oxidation reactor lines operated in parallel and removal of the target compound from the mixture of the product gas streams in a workup line, wherein the catalysts charge of one of the oxidation lines comprises a portion of catalyst over which the heterogeneously catalyzed gas phase partial oxidation has already been carried out for longer than over the portions of catalyst of the catalyst charge of the other oxidation reactor line.
摘要:
Disclosed are processes for the preparation of copper containing molecular sieves with the CHA structure having a silica to alumina mole ratio greater than about 10, wherein the copper exchange step is conducted via wet state exchanged and prior to the coating step and wherein in the copper exchange step a liquid copper solution is used wherein the concentration of copper is in the range of about 0.001 to about 0.25 molar using copper acetate and/or an ammoniacal solution of copper ions as copper source. Catalysts made by the processes, catalyst systems and methods of treating exhaust gas with the molecular sieves and catalysts are also disclosed.
摘要:
Disclosed are processes for the preparation of copper containing molecular sieves with the CHA structure wherein the copper is exchanged into the Na+-form of the Chabazite, using a liquid copper solution wherein the concentration of copper is in the range of about 0.001 to about 0.4 molar. Also described are copper containing molecular sieves with the CHA structure, catalysts incorporating molecular sieves, systems and methods for their use.
摘要:
A process for heterogeneously catalyzed partial gas phase oxidation of propylene to acrylic acid, in which the starting reaction gas mixture comprises cyclopropane as an impurity and the acrylic acid, after conversion from the product gas mixture into the condensed phase, is removed with the aid of a crystallative removal.
摘要:
A process for preparing acrolein or acrylic acid or a mixture thereof as the target product from propane, in which propane is partially dehydrogenated under heterogeneous catalysis in a reaction zone A, molecular hydrogen formed is at least partly combusted to water, any water present in the product gas A formed in reaction zone A is removed therefrom and product gas A is otherwise used to charge a reaction zone B in which propylene formed in reaction zone A is partially oxidized in the presence of remaining propane to give the target product. The target product is removed from the product gas B formed in reaction zone B and propane present in the remaining residual gas is absorbed therefrom into a solvent and, after release from the absorbate, recycled into reaction zone A.