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1.发明授权Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid 有权丙烯醛的异相催化部分气相氧化成丙烯酸公开(公告)号：US06982347B2
公开(公告)日：2006-01-03
申请号：US10806460
申请日：2004-03-23
IPC分类号： C07C51/235
CPC分类号： C07C51/252 , C07C57/04
摘要： In a process for partially oxidizing acrolein to acrylic acid in the gas phase under heterogeneous catalysis, the starting reaction gas mixture is oxidized at an acrolein loading of ≦145 and ≧70 l (STP) of acrolein/l of fixed catalyst bed·h over a fixed catalyst bed which is accommodated in two successive reaction zones A, B, the highest temperature of the reaction gas mixture within reaction zone A being above the highest temperature of the reaction gas mixture within reaction zone B.
摘要翻译： 在非均相催化下在气相中将丙烯醛部分氧化为丙烯酸的方法中，起始反应气体混合物以丙烯醛负载<= 145和> = 70l（STP）的丙烯醛/ l固定催化剂床进行氧化。 h在固定的催化剂床上，其被容纳在两个连续的反应区A，B中，反应区A内的反应气体混合物的最高温度高于反应区B内的反应气体混合物的最高温度。
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2.发明授权Heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound 有权至少一种有机化合物的异相催化气相部分氧化公开(公告)号：US07115776B2
公开(公告)日：2006-10-03
申请号：US10460153
申请日：2003-06-13
IPC分类号： C07C51/16
CPC分类号： C07C51/252 , B01J8/003 , B01J8/008 , B01J8/067 , B01J23/002 , B01J2208/00707 , B01J2208/00752 , B01J2208/00761 , B01J2523/00 , C07C51/215 , C07C57/04 , B01J2523/12 , B01J2523/13
摘要： A process for the heterogeneously catalyzed gas-phase partial oxidation of an organic compound over a fixed catalyst bed present in a fixed-bed reactor having a plurality of catalyst tubes, in which the reduction of the quality of the catalyst load with increasing duration of operation is restored by a partial catalyst change, is described.
摘要翻译： 存在于具有多个催化剂管的固定床反应器中的固定催化剂床上的有机化合物的非均相催化气相部分氧化的方法，其中随着操作持续时间的延长，催化剂负载的质量降低 被部分催化剂改变所恢复。
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3.发明授权Long-term operation of a heterogeneously catalyzed gas phase partial oxidation of acrolein to acrylic acid 失效长期运行丙烯醛异丙烯醛到丙烯酸的异质催化气相部分氧化公开(公告)号：US07022877B2
公开(公告)日：2006-04-04
申请号：US10962570
申请日：2004-10-13
IPC分类号： C07C51/235
CPC分类号： C07C51/252 , C07C57/04
摘要： A process for the long-term operation of a heterogeneously catalyzed gas phase partial oxidation of acrolein to acrylic acid, in which the temperature of the fixed catalyst bed is increased over time and partial oxidation is interrupted and an oxygen-containing gas is conducted through the fixed catalyst bed before the temperature increase is 8° C.
摘要翻译： 长期运行丙烯醛到丙烯酸的非均相催化气相部分氧化丙烯醛的方法，其中固定催化剂床的温度随时间增加并且部分氧化被中断，并且含氧气体通过 固定催化剂床前温度升高8℃
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4.发明授权Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid 有权将丙烯非均相催化部分气相氧化成丙烯酸公开(公告)号：US07019168B2
公开(公告)日：2006-03-28
申请号：US10465653
申请日：2003-06-20
CPC分类号： C07C51/252 , C07C57/04
摘要： In a process for partially oxidizing propene to acrylic acid in the gas phase under heterogeneous catalysis, a starting reaction gas mixture comprising propene and oxygen and having a specific composition is oxidized in a first reaction stage over a first fixed catalyst bed having a volume-specific activity which is constant or increases in the flow direction and the acrolein-containing product gas mixture of the first reaction stage is subsequently oxidized in a second reaction stage over a second fixed catalyst bed having a volume-specific activity increasing in the flow direction, and the shaped catalyst bodies of both fixed catalyst beds are annular and each have a specific multimetal oxide composition.
摘要翻译： 在非均相催化下在气相中将丙烯部分氧化为丙烯酸的方法中，包含丙烯和氧并具有特定组成的起始反应气体混合物在第一反应阶段在具有体积特异性的第一固定催化剂床上被氧化 随后在第二反应阶段，在流动方向上具有体积比活度增加的第二固定催化剂床上氧化第一反应段的流动方向恒定或增加的含丙烯醛的产物气体混合物的活性，以及 两个固定催化剂床的成形催化剂体是环状的，并且各自具有特定的多金属氧化物组合物。
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5.发明授权Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid 有权将丙烯非均相催化部分气相氧化成丙烯酸公开(公告)号：US06888024B2
公开(公告)日：2005-05-03
申请号：US10799754
申请日：2004-03-15
CPC分类号： B01J23/002 , B01J23/8876 , B01J23/8877 , B01J35/0006 , B01J37/0221 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/842 , B01J2523/845
摘要： In a process for heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid, the starting reaction gas mixture is oxidized at a propene loading of
摘要翻译： 在将丙烯非均相催化的部分气相氧化成丙烯酸的过程中，起始反应气体混合物在第一反应阶段中以<160l（STP）/ 1h的丙烯负载量在被容纳的固定催化剂床1上被氧化 在两个连续的反应区A，B和第一反应阶段的含丙烯醛的产物气体混合物随后在第二反应阶段中在固定的催化剂床2上氧化，固定的催化剂床2容纳在两个连续的反应区C，D中， 反应区A内的反应气体混合物的最高温度高于反应区B内反应气体混合物的最高温度，反应区C内的反应气体混合物的最高温度高于反应气体混合物的最高温度 区D.
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公开(公告)号：US07015354B2
公开(公告)日：2006-03-21
申请号：US10917414
申请日：2004-08-13
申请人： Jochen Petzoldt , Signe Unverricht , Heiko Arnold , Klaus Joachim Müller-Engel , Martin Dieterle
发明人： Jochen Petzoldt , Signe Unverricht , Heiko Arnold , Klaus Joachim Müller-Engel , Martin Dieterle
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound over a fresh fixed catalyst bed, in which the process is started up at a reduced hourly space velocity of charging gas mixture on the fixed catalyst bed.
摘要翻译： 通过在新鲜的固定催化剂床上的有机前体化合物的非均相催化气相部分氧化制备（甲基）丙烯醛和/或（甲基）丙烯酸的方法，其中该方法以减小的小时空速充电开始 固定催化剂床上的气体混合物。
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7.发明授权Process for removing methacrylic acid from liquid phase comprising acrylic acid as a main constituent and target product, and methacrylic acid as a secondary component 有权从包含丙烯酸作为主要成分和目标产物的液相中除去甲基丙烯酸的方法和甲基丙烯酸作为次要组分公开(公告)号：US07705181B2
公开(公告)日：2010-04-27
申请号：US11354101
申请日：2006-02-15
IPC分类号： C07C51/42
摘要： A process for removing methacrylic acid from liquid phase P comprising acrylic acid as a main constituent and target product, and methacrylic acid as a secondary component in which the removal is effected by crystallization, the acrylic acid accumulating in the crystals formed and the methacrylic acid in the remaining mother liquor.
摘要翻译： 从包含丙烯酸作为主要成分和目标产物的液相P中除去甲基丙烯酸的方法，以及甲基丙烯酸作为其中通过结晶进行除去的次要组分，在形成的晶体中积聚的丙烯酸和形成的晶体中的甲基丙烯酸 剩下的母酒。
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公开(公告)号：US07038082B2
公开(公告)日：2006-05-02
申请号：US10647335
申请日：2003-08-26
IPC分类号： B01J29/06
CPC分类号： C07C51/215 , B01J23/002 , B01J23/31 , B01J23/6525 , B01J23/8877 , B01J27/0576 , B01J35/002 , B01J37/0045 , B01J37/0223 , B01J2523/00 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/824 , B01J2523/845 , B01J2523/54 , B01J2523/44 , B01J2523/17 , B01J2523/847
摘要： A process for preparing a multimetal oxide material which contains the elements Mo, V and Te and/or Sb and at least one of the elements Nb, Ti, W, Ta and Ce and if desired promoters and has a specific X-ray diffraction pattern, in which process the last process step comprises washing with acidic liquids. In addition, a multimetal oxide material obtainable in such a way is used as a catalyst for heterogeneously catalyzed gas-phase partial oxidations and/or ammoxidation of hydrocarbons.
摘要翻译： 一种制备包含元素Mo，V和Te和/或Sb以及元素Nb，Ti，W，Ta和Ce中的至少一种的多金属氧化物材料的方法，并且如果需要的话，具有特定的X射线衍射图 ，其中最后的工艺步骤包括用酸性液体洗涤。 此外，可以以这种方式获得的多金属氧化物材料用作烃的非均相催化气相部分氧化和/或氨氧化的催化剂。
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9.发明授权公开(公告)号：US08642826B2
公开(公告)日：2014-02-04
申请号：US11829424
申请日：2007-07-27
申请人： Martin Dieterle , Catharina Klanner , Götz-Peter Schindler , Klaus Joachim Müller-Engel , Jens Scheidel , Christoph Adami
发明人： Martin Dieterle , Catharina Klanner , Götz-Peter Schindler , Klaus Joachim Müller-Engel , Jens Scheidel , Christoph Adami
IPC分类号： C07C5/333
CPC分类号： B01J8/0453 , B01J8/0496 , B01J8/062 , B01J8/067 , B01J19/0033 , B01J2208/00221 , B01J2208/00407 , B01J2208/00415 , B01J2208/00522 , B01J2208/025 , C07C5/3337 , C07C45/33 , C07C45/35 , C07C67/08 , C07C2523/42 , Y02P20/52 , C07C11/02 , C07C11/06 , C07C47/22 , C07C69/54
摘要： A process for long-term operation of a continuous heterogeneously catalyzed partial dehydrogenation of a hydrocarbon to be dehydrogenated, in which a reaction gas mixture stream comprising the hydrocarbon to be dehydrogenated in a molar starting amount KW is conducted through an overall catalyst bed comprising the total amount M of dehydrogenation catalyst and the deactivation of the overall catalyst bed is counteracted in such a way that, with increasing operating time, the contribution to the conversion in the first third of the total amount M of dehydrogenation catalyst in flow direction decreases, the contribution to the conversion in the last third of the total amount M of dehydrogenation catalyst in flow direction increases, and the contribution to the conversion in the second third of the total amount M of dehydrogenation catalyst in flow direction passes through a maximum.
摘要翻译： 一种用于长期运行待脱氢烃的连续不均匀催化的部分脱氢的方法，其中包含待脱氢的烃以摩尔起始量KW的反应气体混合物流通过包含总共的催化剂床 脱氢催化剂的量M和整个催化剂床的失活以这样的方式被抵消：随着操作时间的增加，在流动方向上对脱氢催化剂总量M的前三分之一转化的贡献减小，贡献 到脱氢催化剂流向总量M的最后三分之一的转化率增加，并且对流化方向的脱氢催化剂总量M的第二分之三转化率的影响最大。
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10.发明授权公开(公告)号：US08202814B2
公开(公告)日：2012-06-19
申请号：US12025448
申请日：2008-02-04
IPC分类号： B01J38/04
CPC分类号： B01J23/96 , B01J38/20 , C07C5/48 , C07C51/252 , C07C2521/06 , C07C2521/08 , C07C2523/04 , C07C2523/63 , Y02P20/52 , Y02P20/584 , C07C11/06 , C07C57/04
摘要： A process for regenerating a catalyst bed deactivated in the course of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon, in which a gas comprising molecular oxygen is conducted at elevated temperature through the deactivated catalyst bed and, in the course of the regeneration, the content of molecular oxygen in the regeneration gas is increased repeatedly and the increase in the carbon oxide content of the regeneration gas as it flows through the deactivated catalyst bed is restricted to values of ≦5% by volume.
摘要翻译： 在烃的非均相催化部分脱氢过程中使催化剂床再生失活的方法，其中包含分子氧的气体在高温下通过失活的催化剂床进行，并且在再生过程中， 再生气体中的分子氧反复增加，并且再生气体在流过失活催化剂床时的碳氧化物含量的增加被限制为±10体积％的量。
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