摘要:
An aliphatic mono-olefin e.g. butene-2, is isomerized in the presence of a catalyst comprising essentially zirconium phosphate and at least one of chromium and thorium to produce the corresponding terminal olefin selectively.
摘要:
An aliphatic mono-olefin e.g. butene-2 is isomerized in the presence of a catalyst comprising zirconium phosphate and zirconium phosphate prepared from an aryl phosphonic acid to produce a corresponding terminal olefin selectively.
摘要:
Complexing reagents are provided which comprise Cu(I) carboxylates or Cu(I) sulfonates and high molecular weight olefins. The invention complexing reagents are useful for separating olefins from mixtures of olefins and paraffins.
摘要:
Aliphatic olefinic hydrocarbons are isomerized in the presence of a catalyst consisting essentially of elemental chromium or a chromium compound and an aluminum phosphate support wherein the phosphorus/aluminum atomic ratio of the support is less than 1.
摘要:
An improved process for removing metals from heavy oils and other hydrocarbon feed streams is disclosed. The process includes adding phosphorus sulfide to the hydrocarbon feed stream under suitable demetallizing conditions. It is believed that phosphorus sulfide reacts with the metals contained in the hydrocarbon containing feed stream to form oil insoluble compounds that can be removed from the hydrocarbon containing feed stream by any conventional method, such as filtration, centrifugation, or decantation.
摘要:
Unsaturated hydrocarbons are hydrogenated using a catalyst comprising nickel on a calcium phosphate support. The catalyst can be used in combination with a promoter selected from at least one of barium and uranium. Aromatic compounds such as benzene can be hydrogenated in this process. The catalytic activity of the described catalyst is sufficiently great as to permit hydrogenation under relatively mild conditions, including liquid phase hydrogenation of aromatics, thus prolonging the active life of the catalyst.
摘要:
A catalyst consisting essentially of nickel, a promoter selected from the group consisting of barium and uranium and a calcium phosphate support having a Ca:P atomic ratio in the range of 1.4:1 to 2.3:1, is formed by impregnating a calcium phosphate gel with suitable compounds of nickel and either barium or uranium. The resulting catalysts are useful for reacting carbon monoxide and steam and in steam reforming processes for producing methane.
摘要:
A method and catalysts for isomerization which involves contacting a feedstream with hydrogen and with various supported catalysts of metallic arsenides and antimonides, with carbon monoxide being optionally introduced into the reaction as a modifier.
摘要:
A carbonaceous material is converted to a fuel gas which is fungible with natural gas by a combination of steps comprising gasifying the carbonaceous material in the presence of air and carbon dioxide, purifying the effluent stream and separating carbon monoxide therefrom, catalytically reacting steam with the separated carbon monoxide and recovering a methane-rich product gas.