摘要:
A process for producing a thiophene derivative represented by a general formula (2) involves catalytically reducing a compound represnted by the general formula (1) with hydrogen in a solvent mixture of at least one of alcohol and water in the presence of a palladium catalyst soluble in organic solvents. A thiophene derivative is useful in preparing biotin (Vitamin H).
摘要:
An imidazole derivative of the general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 are each a hydrogen atom or an alkyl, aryl, acyl or aralkyl group, X and Y are each an oxygen or sulfur atom, and Z is a substituted alkyl group is prepared by reducing a thienoimidazole carboxylic acid of the general formula (2): ##STR2## in an alcoholic solvent using a palladium catalyst, adding an adsorbent and an ion exchange resin, chelate resin or polymeric flocculating agent to the reaction mixture, and removing the spent catalyst from the reaction mixture.
摘要:
A process for producing 1-hydroxythienoimidazole carboxylic acid represented by formula (2): ##STR1## wherein R.sup.1 and R.sup.2 are as defined in the specification; wherein said process comprises the steps of: (a) reacting thienoimidazole represented by formula (1) with 1,4-dihalogenodimagnesium butane, in the presence of tetrahydrofuran or a mixed solvent comprising tetrahydrofuran and an aromatic solvent to produce a reaction mixture: ##STR2## wherein R.sup.1 and R.sup.2 are as defined above; (b) adding the reaction mixture obtained in said step (a) and, optionally, carbon dioxide, to: (i) a solution comprising carbon dioxide and tetrahydrofuran, or (ii) a solution comprising carbon dioxide, tetrahydrofuran and an dramatic solvent to give a reaction liquid; and (c) hydrolyzing said reaction liquid.
摘要:
A method of producing methyl methacrylate comprising the following steps: Thermal decomposition step: a hydrocarbon having 3 or more carbon atoms is thermally decomposed to obtain a decomposed gas having a total content of propyne and propadiene of 2 wt % or more, Separation step: mixed liquid rich in propyne and propadiene is separated from the decomposed gas obtained in the thermal decomposition step, Propyne purification step: the mixed liquid rich in propyne and propadiene obtained in the separation step is subjected to extractive distillation, for separation into purified propyne, and crude propadiene containing propadiene as the main component, Isomerization step: the crude propadiene obtained in the propyne purification step is isomerized in the presence of an isomerization catalyst, to obtain crude propyne containing propyne as the main component, and Carbonylation step: the purified propyne obtained in the propyne purification step is reacted with carbon monoxide and methanol in the presence of a group VIII metal catalyst system, to produce methyl methacrylate.
摘要:
Values of multiple tire dynamic element parameters are set for a tire dynamic model constructed using the tire dynamic element parameters for calculating a tire axial force and a self-aligning torque under a given slip ratio. Next, the values of the tire axial force and the self-aligning torque are calculated using the tire dynamic model and output. The tire dynamic model allows a center position of a contact patch thereof against a road surface to move in accordance with a longitudinal force that occurs as the tire axial force when a slip ratio in a braking/driving direction is given so that a position of the contact patch moves in a longitudinal direction due to the longitudinal force. When designing a vehicle or when designing a tire, the tire dynamic model is used.
摘要:
The present invention is directed to a method for purifying pyruvic acid compounds, which method comprises reacting a pyruvic acid compound of general formula (I): wherein R1 is an optionally substituted lower alkyl group, a lower alkenyl group, a lower alkynyl group, a cycloalkyl group, an aryl group, or a heterocyclic group, and R2 is a lower alkyl group, with a bisulfite of general formula (II): MHSO3 (II) wherein M is NH4 or an alkali metal, to give a bisulfite adduct of the pyruvic acid compound and then decomposing the adduct with an acid. According to the present invention, pyruvic acid compounds can be purified by simple and easy procedures without using purification techniques such as distillation or column chromatography, and the above method is advantageous as a process for the production on an industrial scale.
摘要:
A portable video camera of the type having a taking lens and an electronic video imaging device comprises a camera body incorporating the electronic video imaging device therein, a handgrip turnably mounted on one side wall of the camera body, and a view finder, electronic or optical, structurally integral with the handgrip for viewing an image of a subject therethrough. Being changeable in position according to camera angles, the action finder can be brought into alignment with an eye of the operator in any shooting angle.
摘要:
The present invention regards a tire braking characteristic test apparatus which can reflect the dynamic characteristics of a vehicle at the time of braking in order to evaluate the braking characteristics of tires. The test apparatus can also perform a test where a vehicle condition is changed in a manner which influences the braking characteristics of the tires.
摘要:
Values of multiple tire dynamic element parameters are set for a tire dynamic model constructed using the tire dynamic element parameters for calculating a tire axial force and a self-aligning torque under a given slip ratio. Next, the values of the tire axial force and the self-aligning torque are calculated using the tire dynamic model and output. The tire dynamic model allows a center position of a contact patch thereof against a road surface to move in accordance with a longitudinal force that occurs as the tire axial force when a slip ratio in a braking/driving direction is given so that a position of the contact patch moves in a longitudinal direction due to the longitudinal force. When designing a vehicle or when designing a tire, the tire dynamic model is used.
摘要:
A drive transmission device includes a motor pinion gear provided at an output shaft of the driving motor and a-transmission gear engaging the motor pinion gear. In the drive transmission device, a sliding washer and a compression spring are disposed between the transmission-gear and the motor mounting plate. The sliding washer is pressed against a web of the transmission gear by the compression spring.