公开(公告)号：US5284563A

公开(公告)日：1994-02-08

申请号：US690832

申请日：1991-04-24

申请人： Masamichi Fujihira ,  Yoshiki Hirata ,  Kosaku Suga ,  Uichi Akiba ,  Yasuo Nakamura

发明人： Masamichi Fujihira ,  Yoshiki Hirata ,  Kosaku Suga ,  Uichi Akiba ,  Yasuo Nakamura

IPC分类号： C01B32/50 ,  B01J31/18 ,  C25B11/04 ,  C25B11/06 ,  H01M4/90

CPC分类号： H01M4/9008 ,  B01J31/182 ,  C25B1/00 ,  C25B11/0447 ,  B01J2531/847 ,  B01J2531/96

摘要： An electrocatalyst for use in electrolytic reduction of carbon dioxide gas in an aqueous solution. The electrocatalyst is formed of nickel alkyl cyclam which is expressed by the general formula: ##STR1## where each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 is selected from the group consisting of hydrogen atom and aliphatic saturated hydrocarbon group expressed by the formula of C.sub.n H.sub.2n+1 ; wherein at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 is the aliphatic saturated hydrocarbon group in which n is a number ranging from 1 to 22. The nickel alkyl cyclam as the electrocatalyst is excellent in stability and energy consumption improving effect while exhibiting a high carbon dioxide gas reduction effect, as compared with conventional nickel cyclam.

摘要翻译： 一种用于在水溶液中电解还原二氧化碳气体的电催化剂。 电催化剂由烷基环烷基镍形成，其由以下通式表示：（*化学结构*）其中R1，R2，R3，R4，R5和R6各自选自氢原子和脂族饱和烃基 由CnH2n + 1的式表示; 其中R 1，R 2，R 3，R 4，R 5和R 6中的至少一个是脂族饱和烃基，其中n为1至22的数。作为电催化剂的烷基环烷基镍具有优异的稳定性和能量消耗改善效果 同时表现出与常规的镍环境相比更高的二氧化碳气体减少效果。

公开(公告)号：US5382332A

公开(公告)日：1995-01-17

申请号：US110017

申请日：1993-08-23

申请人： Masamichi Fujihira ,  Yoshiki Hirata ,  Kosaku Suga ,  Uichi Akiba

发明人： Masamichi Fujihira ,  Yoshiki Hirata ,  Kosaku Suga ,  Uichi Akiba

IPC分类号： C01B32/50 ,  B01J31/18 ,  C25B11/04 ,  C25B11/06 ,  H01M4/90 ,  C25B1/00

CPC分类号： H01M4/9008 ,  B01J31/182 ,  C25B1/00 ,  C25B11/0447 ,  B01J2531/847 ,  B01J2531/96

摘要： An electrocatalyst for use in electrolytic reduction of carbon dioxide gas in an aqueous solution. The electrocatalyst is formed of nickel alkyl cyclam which is expressed by the general formula: ##STR1## where each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 is selected from the group consisting of hydrogen atom and aliphatic saturated hydrocarbon group expressed by the formula of C.sub.n H.sub.2n+1 ; wherein at least one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 is the aliphatic saturated hydrocarbon group in which n is a number ranging from 1 to 22. The nickel alkyl cyclam as the electrocatalyst is excellent in stability and energy consumption improving effect while exhibiting a high carbon dioxide gas reduction effect, as compared with conventional nickel cyclam.

摘要翻译： 一种用于在水溶液中电解还原二氧化碳气体的电催化剂。 电极催化剂由镍烷基环己烷形成，其由以下通式表示：其中R 1，R 2，R 3，R 4，R 5和R 6各自选自氢原子和脂族饱和烃基 CnH2n + 1的配方; 其中R 1，R 2，R 3，R 4，R 5和R 6中的至少一个是脂族饱和烃基，其中n为1至22的数。作为电催化剂的烷基环烷基镍具有优异的稳定性和能量消耗改善效果 同时表现出与常规的镍环境相比更高的二氧化碳气体减少效果。

公开(公告)号：US06817293B2

公开(公告)日：2004-11-16

申请号：US10108192

申请日：2002-03-27

申请人： Masamichi Fujihira ,  Uichi Akiba ,  Hiroki Okui ,  Shintaro Fujii ,  Masaaki Kurihara

发明人： Masamichi Fujihira ,  Uichi Akiba ,  Hiroki Okui ,  Shintaro Fujii ,  Masaaki Kurihara

IPC分类号： B41N600

CPC分类号： B82Y10/00 ,  B82Y40/00 ,  G03F7/0002 ,  Y10T428/31663

摘要： A patterning method for micro-contact printing involves the steps of: applying a resin on a master having projected patterns, hardening the resin and thereafter removing the hardened resin from the master to make a stamp of the resin; applying a molecular ink including hydrophobic molecules dispersed in a solvent on the stamp; forming micro-contact printed patterns of the hydrophobic molecular layer on a substrate by means of the stamp on which the molecular ink is applied; dipping the substrate with micro-contact printed patterns in a hydrophilic molecule solution dispersed in a solvent to give chemical modification to the areas of the surface of the substrate around the micro-contact printed patterns, the solution including hydrophilic molecules having a chain length shorter than the chain length of hydrophobic molecules included in the molecular ink is used as the hydrophilic molecule solution. According to the method, printed products having micro-contact printed patterns of a molecular level are obtained with a contrast between the micro-contact printed patterns and the area of the surface of the substrate around the micro-contact printed patterns.

摘要翻译： 用于微接触印刷的图案化方法包括以下步骤：将树脂施加在具有突出图案的母版上，硬化树脂，然后从母版中除去硬化树脂以制成树脂的印模; 将包含分散在溶剂中的疏水性分子的分子油墨施加到印模上; 通过施加分子油墨的印模在基材上形成疏水分子层的微接触印刷图案; 将具有微接触印刷图案的基底浸渍在分散在溶剂中的亲水性分子溶液中，以对微接触印刷图案周围的基底表面的区域进行化学改性，该溶液包括链长短于 包含在分子油墨中的疏水性分子的链长用作亲水性分子溶液。 根据该方法，通过微接触印刷图案与微接触印刷图案周围的基板表面的面积之间的对比度获得具有分子水平的微接触印刷图案的印刷产品。

公开(公告)号：US06868786B2

公开(公告)日：2005-03-22

申请号：US10738367

申请日：2003-12-12

申请人： Masamichi Fujihira ,  Uichi Akiba ,  Hiroki Okui ,  Shintaro Fujii ,  Masaaki Kurihara

发明人： Masamichi Fujihira ,  Uichi Akiba ,  Hiroki Okui ,  Shintaro Fujii ,  Masaaki Kurihara

IPC分类号： G03F7/00 ,  B41F1/18

CPC分类号： B82Y10/00 ,  B82Y40/00 ,  G03F7/0002 ,  Y10T428/31663

摘要： A patterning method for micro-contact printing involves the steps of: applying a resin on a master having projected patterns, hardening the resin and thereafter removing the hardened resin from the master to make a stamp of the resin; applying a molecular ink including hydrophobic molecules dispersed in a solvent on the stamp; forming micro-contact printed patterns of the hydrophobic molecular layer on a substrate by means of the stamp on which the molecular ink is applied; dipping the substrate with micro-contact printed patterns in a hydrophilic molecule solution dispersed in a solvent to give chemical modification to the areas of the surface of the substrate around the micro-contact printed patterns, the solution including hydrophilic molecules having a chain length shorter than the chain length of hydrophobic molecules included in the molecular ink is used as the hydrophilic molecule solution. According to the method, printed products having micro-contact printed patterns of a molecular level are obtained with a contrast between the micro-contact printed patterns and the area of the surface of the substrate around the micro-contact printed patterns.

摘要翻译： 用于微接触印刷的图案化方法包括以下步骤：将树脂施加在具有突出图案的母版上，硬化树脂，然后从母版中除去硬化树脂以制成树脂的印模; 将包含分散在溶剂中的疏水性分子的分子油墨施加到印模上; 通过施加分子油墨的印模在基材上形成疏水分子层的微接触印刷图案; 将具有微接触印刷图案的基底浸渍在分散在溶剂中的亲水性分子溶液中，以对微接触印刷图案周围的基底表面的区域进行化学改性，该溶液包括链长短于 包含在分子油墨中的疏水性分子的链长用作亲水性分子溶液。 根据该方法，通过微接触印刷图案与微接触印刷图案周围的基板表面的面积之间的对比度获得具有分子水平的微接触印刷图案的印刷产品。

公开(公告)号：US4403022A

公开(公告)日：1983-09-06

申请号：US221977

申请日：1981-01-02

申请人： Tetsuo Osa ,  Masamichi Fujihira

发明人： Tetsuo Osa ,  Masamichi Fujihira

IPC分类号： H01G9/20 ,  H01M14/00 ,  H01M6/36

CPC分类号： H01M14/005 ,  H01G9/2031 ,  Y02E10/542

摘要： A chemically modified photoelectrochemical cell including at least one cathode and a plurality of anodes, at least said plurality of anodes being constituted with a semiconductor, each of said plurality of anodes being formed by fixing through covalent bonds molecules of at least one sensitizer dye on the surface of a light-transmissible flat plate of an n-type semiconductor or a light-transmissible flat plate covered with a thin film of an n-type semiconductor, and said plurality of anodes being disposed parallelly to each other and in the form of layers in an electrolyte solution, together with said at least one cathode. Thus, since this photoelectrochemical cell can convert photoenergy of a longer wavelength to electric energy with a high efficiency by making the use of the dye sensitization effect, sufficient practical utility to the photodevices is obtained.

摘要翻译： 一种化学修饰的光电化学电池，包括至少一个阴极和多个阳极，至少所述多个阳极由半导体构成，所述多个阳极中的每一个阳极通过共价键固定至少一种敏化剂染料的分子 n型半导体的透光平板的表面或覆盖有n型半导体薄膜的透光性平板，并且所述多个阳极彼此平行地设置并且以层的形式 在电解质溶液中，与所述至少一个阴极一起。 因此，由于该光电化学电池可以通过利用染料敏化效果将高波长的光能高效率地转换成电能，因此获得了对光器件的实用效用。

公开(公告)号：US20090036698A1

公开(公告)日：2009-02-05

申请号：US11886725

申请日：2006-03-17

申请人： Masamichi Fujihira ,  Fumie Sato ,  Yuuki Takayama ,  Go Ono

发明人： Masamichi Fujihira ,  Fumie Sato ,  Yuuki Takayama ,  Go Ono

IPC分类号： C07F1/12 ,  C07C327/36 ,  C07F1/08 ,  C07F15/02 ,  C07F3/10 ,  C07F1/10

CPC分类号： H01B1/125 ,  C07C327/22 ,  C07F7/0805

摘要： Enediyne compounds of the formula: (1) characterized in that the structure thereof is very simple and the production process is easy, and that the molecular length thereof is shorter than those of compounds having been proposed. Consequently, electrode assemblies comprising any of these enediyne compounds are highly promising in the application to nanomolecular wiring (nanomolecular wire) whose production has been difficult.

摘要翻译： 具有下式的恩二炔化合物：（1）其特征在于其结构非常简单，制备方法容易，其分子长度短于已提出的化合物的分子长度。 因此，包含任何这些烯化合物的电极组件在其难以生产的纳米分子布线（纳米分子线）的应用中是非常有希望的。

公开(公告)号：US5654131A

公开(公告)日：1997-08-05

申请号：US595097

申请日：1996-02-01

申请人： Masamichi Fujihira ,  Hiroshi Muramatsu ,  Norio Chiba ,  Tatsuaki Ataka

发明人： Masamichi Fujihira ,  Hiroshi Muramatsu ,  Norio Chiba ,  Tatsuaki Ataka

IPC分类号： G01Q20/02 ,  G01Q20/04 ,  G01Q60/26 ,  G11B7/12 ,  G11B7/135 ,  G11B7/244 ,  G11B7/253 ,  G11B9/00 ,  G11B11/00 ,  G11B7/24

CPC分类号： G11B7/12 ,  B82Y10/00 ,  G11B11/007 ,  G11B7/1384 ,  G11B7/244 ,  G11B7/2531 ,  G11B9/1463 ,  G01Q80/00 ,  Y10S430/146 ,  Y10S430/163

摘要： There is provided an optical memory medium comprising a flat plate modified on the surface thereof by a photolytic residual group, an optical recording apparatus comprising an optical probe having a microscopic aperture on the leading end thereof, a light source, X-Y-Z position control means, and a controller for controlling the apparatus as whole and an apparatus for reading the optical memory medium comprising the optical memory medium, a friction detecting probe, an X-Y-Z position control means and a controller for controlling the apparatus as a whole. Further, information is written and read with high density less than the wavelength of light using an apparatus for writing to and reading from an optical memory piezoelectric medium comprising the optical memory piezoelectric medium constituted by a piezoelectric element modified on the surface thereof by a photolytic residual group, an optical probe having a microscopic aperture on the leading end thereof, a light source, an X-Y-Z position control means, a means for measuring the resonance characteristics of the piezoelectric element and a controller for controlling the apparatus as a whole.

摘要翻译： 提供了一种光学存储介质，其包括通过光解残留组在其表面上改性的平板，光学记录装置，包括在其前端具有微小孔的光学探针，光源，XYZ位置控制装置和 用于整体控制装置的控制器和用于读取包括光学存储介质的光学存储介质的装置，摩擦检测探针，XYZ位置控制装置和用于整体控制装置的控制器。 此外，使用用于写入和读取由光学存储器压电介质构成的光学存储器压电介质的装置，以比光的波长高的密度来写入和读取信息，该光存储器压电介质由其表面上由光解残留物修饰的压电元件构成 组，在其前端具有微小孔的光学探针，光源，XYZ位置控制装置，用于测量压电元件的谐振特性的装置和用于整体控制装置的控制器。

公开(公告)号：US07507957B2

公开(公告)日：2009-03-24

申请号：US11216389

申请日：2005-08-31

申请人： Masamichi Fujihira ,  Masatoshi Yasutake ,  Tatsuaki Ataka

发明人： Masamichi Fujihira ,  Masatoshi Yasutake ,  Tatsuaki Ataka

IPC分类号： G01N23/00

CPC分类号： G01Q30/14 ,  G01Q10/06 ,  Y10S977/853 ,  Y10S977/86 ,  Y10S977/862 ,  Y10S977/869 ,  Y10S977/871

摘要： A problem to be resolved by the invention resides in providing a multifunction analyzing apparatus for detecting a shape with high resolution and physical property information capable of not only successively reading a base arrangement from end to end but also specifying a position hybridized by known RNA with regard to a single piece of DNA elongated in one direction on a board. A microscope system of the invention is provided with a fluorescence microscope, a scanning near field microscope and a scanning probe microscope as a detecting system, the microscopes are fixed to a switching mechanism and can be moved to a position at which the various microscopes can observe the same portion of a sample by switching operation of the mechanism. The microscope system of the invention is provided with a function capable of directly detecting a shape and physical property information of one piece of DNA by the scanning probe microscope by multifunction scanning.

摘要翻译： 本发明要解决的问题在于提供一种用于检测具有高分辨率和物理属性信息的形状的多功能分析装置，其不仅能够从一端到另一端连续读取基本排列，而且还指定与已知RNA杂交的位置 到在板上沿一个方向伸长的单个DNA。 本发明的显微镜系统设置有荧光显微镜，扫描型近场显微镜和扫描探针显微镜作为检测系统，将显微镜固定在切换机构上，并可移动到各种显微镜可以观察到的位置 通过切换机构的操作来获取样品的相同部分。 本发明的显微镜系统具有能够通过扫描探针显微镜通过多功能扫描直接检测一片DNA的形状和物理性质信息的功能。

公开(公告)号：US20060060778A1

公开(公告)日：2006-03-23

申请号：US11216389

申请日：2005-08-31

申请人： Masamichi Fujihira ,  Masatoshi Yasutake ,  Tatsuaki Ataka

发明人： Masamichi Fujihira ,  Masatoshi Yasutake ,  Tatsuaki Ataka

IPC分类号： G21K7/00

CPC分类号： G01Q30/14 ,  G01Q10/06 ,  Y10S977/853 ,  Y10S977/86 ,  Y10S977/862 ,  Y10S977/869 ,  Y10S977/871

摘要： A problem to be resolved by the invention resides in providing a multifunction analyzing apparatus for detecting a shape with high resolution and physical property information capable of not only successively reading a base arrangement from end to end but also specifying a position hybridized by known RNA with regard to a single piece of DNA elongated in one direction on a board. A microscope system of the invention is provided with a fluorescence microscope, a scanning near field microscope and a scanning probe microscope as a detecting system, the microscopes are fixed to a switching mechanism and can be moved to a position at which the various microscopes can observe the same portion of a sample by switching operation of the mechanism. The microscope system of the invention is provided with a function capable of directly detecting a shape and physical property information of one piece of DNA by the scanning probe microscope by multifunction scanning.

公开(公告)号：US06215121B1

公开(公告)日：2001-04-10

申请号：US09124128

申请日：1998-07-29

申请人： Masamichi Fujihira ,  Masatoshi Yasutake ,  Tatsuya Miyatani ,  Toshihiko Sakuhara ,  Kazutoshi Watanabe

发明人： Masamichi Fujihira ,  Masatoshi Yasutake ,  Tatsuya Miyatani ,  Toshihiko Sakuhara ,  Kazutoshi Watanabe

IPC分类号： G01N1316

CPC分类号： G01Q60/32 ,  Y10S977/851

摘要： A signal having a resonant frequency of a cantilever is output by a first oscillator, and supplied to a vibrating element and a control unit to oscillate a probe. A low frequency signal having a large amplitude is output by a second oscillator and supplied to a piezoelectric scanning apparatus. The probe is periodically and relatively moved with respect to the sample between a position where the sample surface is penetrated by the probe and another position where the probe does not penetrate the sample surface and is outside the range of atomic forces caused by the sample. During this movement, the probe movement may be analyzed to obtain a plurality of physical characteristics about the sample, e.g., hardness information of the sample, surface shape information, information related to an adsorption layer of the sample, and information related to physical qualities (for example, electromagnetic field, adsorption force, surface reaction force, electric double layer force in fluid) irradiated from the sample surface along a depth direction.

摘要翻译： 具有悬臂的共振频率的信号由第一振荡器输出，并被提供给振动元件和控制单元以使探头振荡。 具有大振幅的低频信号由第二振荡器输出并提供给压电扫描装置。 探针在样品表面被探针穿透的位置与探针不穿透样品表面的另一个位置之间相对于样品周期性地相对移动并且处于由样品引起的原子力范围之外。 在该移动期间，可以分析探针运动以获得关于样品的多个物理特性，例如样品的硬度信息，表面形状信息，与样品的吸附层相关的信息，以及与物理性质相关的信息（ 例如从样品表面沿着深度方向照射的电磁场，吸附力，表面反作用力，流体中的双电层力）。