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    Graft copolymer, composition containing the same and molded object thereof, and process for producing the same
    1.
    发明授权
    Graft copolymer, composition containing the same and molded object thereof, and process for producing the same 有权
    接枝共聚物，含有其的成型物及其成型体的组合物及其制造方法

    公开(公告)号：US07368507B2

    公开(公告)日：2008-05-06

    申请号：US10532799

    申请日：2003-10-23

    申请人： Masumi Takamura ,  Hitoshi Uchida ,  Yoshiki Yamamoto ,  Motoyuki Sugiura

    发明人： Masumi Takamura ,  Hitoshi Uchida ,  Yoshiki Yamamoto ,  Motoyuki Sugiura

    IPC分类号： C08F255/02 ,  C08F255/04 ,  C08F255/06 ,  C08F8/46

    CPC分类号： C08F255/00 ,  C08F255/02 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06

    摘要： A graft copolymer having a structure in which a vinyl copolymer segment formed from a vinyl monomer having an acid is suspended in a molecular chain of a polyolefin resin segment via a β-substituted propylene group is obtained, by reaction of polyolefin resin having β-substituted propenyl group as a pendant and a vinyl monomer having an acid, and further a graft copolymer composition containing the same and a molded product thereof are obtained.The obtained graft copolymer, the composition containing the same and the molded product thereof are excellent in adhesive property to a polar material and scratch resistance.

    摘要翻译： 通过具有β-取代的聚烯烃树脂的反应，得到具有由具有酸的乙烯基单体形成的乙烯基共聚物链段通过β-取代的丙烯基团悬浮在聚烯烃树脂链段的分子链中的结构的接枝共聚物 作为侧基的丙烯基和具有酸的乙烯基单体，并且还得到含有它们的接枝共聚物组合物及其模塑产品。 所得到的接枝共聚物，含有该共聚物的成分及其成型体的极性材料的粘合性优异，耐划伤性优异。

    Olefinic thermoplastic elastomer and moldings thereof
    5.
    发明申请
    Olefinic thermoplastic elastomer and moldings thereof 有权
    烯烃类热塑性弹性体及其成型品

    公开(公告)号：US20050288434A1

    公开(公告)日：2005-12-29

    申请号：US10509421

    申请日：2003-03-27

    申请人： Motoyuki Sugiura ,  Toru Tamura ,  Takamitsu Kano ,  Toru Kato

    发明人： Motoyuki Sugiura ,  Toru Tamura ,  Takamitsu Kano ,  Toru Kato

    IPC分类号： C08F285/00 ,  C08L51/06 ,  C08L51/00

    CPC分类号： C08L51/06 ,  C08F285/00 ,  C08L2666/04 ,  C08L2666/02

    摘要： An olefinic thermoplastic elastomer with improved properties can be obtained by melting and kneading a graft copolymer, acrylic rubber, a crosslinking agent, and a co-crosslinking agent. The graft copolymer is composed of an olefin polymer segment formed from a nonpolar α-olefin monomer and a vinyl polymer segment formed from a vinyl monomer, with particles of one segment being dispersed in the other segment. The particle diameter is 0.01 to 1 μm. The acrylic rubber can be obtained by polymerizing a monomer mixture containing methoxyethyl acrylate.

    摘要翻译： 通过熔融和捏合接枝共聚物，丙烯酸橡胶，交联剂和共交联剂，可以获得具有改进性能的烯属热塑性弹性体。 接枝共聚物由由非极性α-烯烃单体形成的烯烃聚合物链段和由乙烯基单体形成的乙烯基聚合物链段组成，一个链段的颗粒分散在另一个链段中。 粒径为0.01〜1μm。 丙烯酸橡胶可以通过聚合含有甲氧基乙基丙烯酸酯的单体混合物获得。

    Olefinic thermoplastic elastomer and moldings thereof
    6.
    发明授权
    Olefinic thermoplastic elastomer and moldings thereof 有权
    烯烃类热塑性弹性体及其成型品

    公开(公告)号：US07723434B2

    公开(公告)日：2010-05-25

    申请号：US10509421

    申请日：2003-03-27

    申请人： Motoyuki Sugiura ,  Toru Tamura ,  Takamitsu Kano ,  Toru Kato

    发明人： Motoyuki Sugiura ,  Toru Tamura ,  Takamitsu Kano ,  Toru Kato

    IPC分类号： C08L51/00 ,  C08L51/06 ,  C08L53/00

    CPC分类号： C08L51/06 ,  C08F285/00 ,  C08L2666/04 ,  C08L2666/02

    摘要： An olefinic thermoplastic elastomer with improved properties can be obtained by melting and kneading a graft copolymer, acrylic rubber, a crosslinking agent, and a co-crosslinking agent. The graft copolymer is composed of an olefin polymer segment formed from a nonpolar α-olefin monomer and a vinyl polymer segment formed from a vinyl monomer, with particles of one segment being dispersed in the other segment. The particle diameter is 0.01 to 1 μm. The acrylic rubber can be obtained by polymerizing a monomer mixture containing methoxyethyl acrylate.

    摘要翻译： 通过熔融和捏合接枝共聚物，丙烯酸橡胶，交联剂和共交联剂，可以获得具有改进性能的烯属热塑性弹性体。 接枝共聚物由由非极性α-烯烃单体形成的烯烃聚合物链段和由乙烯基单体形成的乙烯基聚合物链段组成，一个链段的颗粒分散在另一个链段中。 粒径为0.01〜1μm。 丙烯酸橡胶可以通过聚合含有甲氧基乙基丙烯酸酯的单体混合物获得。

    GAP-FILLING MEMBER FOR VEHICLES, AND PLATE-LIKE BODY FOR VEHICLE WINDOWS PROVIDED WITH GAP-FILLING MEMBER USING THE SAME
    7.
    发明申请
    GAP-FILLING MEMBER FOR VEHICLES, AND PLATE-LIKE BODY FOR VEHICLE WINDOWS PROVIDED WITH GAP-FILLING MEMBER USING THE SAME 审中-公开
    用于车辆的GAP填充会员，以及使用其的GAP填充会员提供的用于车窗的类似车身的身体

    公开(公告)号：US20090005507A1

    公开(公告)日：2009-01-01

    申请号：US12203495

    申请日：2008-09-03

    申请人： Yuuji MASAKI ,  Toshihiro Atsumi ,  Satoshi Usami ,  Toru Tamura ,  Motoyuki Sugiura

    发明人： Yuuji MASAKI ,  Toshihiro Atsumi ,  Satoshi Usami ,  Toru Tamura ,  Motoyuki Sugiura

    IPC分类号： C08L51/04

    CPC分类号： B60J10/70

    摘要： To provide a gap-filling member for vehicles using an olefinic thermoplastic elastomer, which has a wide range for regulating a gloss value representing gloss, can provide a high initial gloss value and is excellent also in mechanical properties such as scratch resistance, chemical resistance and adhesion, and recycling properties.A gap-filling member for vehicles to be mounted on a peripheral portion of a plate-like body for vehicle windows, to fill a gap between the plate-like body for vehicle windows and an opening of a vehicle body, said gap-filling member being made of an olefinic thermoplastic elastomer which comprises: an olefinic graft copolymer comprising an olefinic polymer or olefinic copolymer segment formed from an α-olefin monomer, and a vinyl copolymer segment, wherein particles of one segment are dispersed in the other segment, and the particles have an average diameter of from 0.01 to 1 μm; and an acrylic rubber obtained by copolymerizing a monomer mixture comprising, as the main components, methoxyethyl acrylate, an alkyl acrylate, acrylonitrile and allyl methacrylate.

    摘要翻译： 为了提供用于调节表现光泽度的光泽值的宽范围的烯烃类热塑性弹性体的车辆的间隙填充部件，能够提供高的初始光泽值，并且在耐刮擦性，耐化学性等机械性能方面优异， 附着力和回收性能。 一种车辆用间隙填充部件，其安装在车窗用板状体的周缘部，填充车辆用窗板状体和车体开口部之间的间隙，所述间隙填充部件 由烯属热塑性弹性体制成，其包括：包含由α-烯烃单体形成的烯属聚合物或烯烃共聚物链段的烯属接枝共聚物和乙烯基共聚物链段，其中一个链段的颗粒分散在另一个链段中，并且 颗粒的平均直径为0.01-1μm; 和通过共聚单体混合物获得的丙烯酸橡胶，其包含作为主要组分的丙烯酸甲氧基乙酯，丙烯酸烷基酯，丙烯腈和甲基丙烯酸烯丙酯。

    Thermoplastic Elastomer Composition
    8.
    发明申请
    Thermoplastic Elastomer Composition 有权
    热塑性弹性体组合物

    公开(公告)号：US20080221270A1

    公开(公告)日：2008-09-11

    申请号：US11917968

    申请日：2006-08-08

    申请人： Takamitsu Kano ,  Toru Tamura ,  Motoyuki Sugiura

    发明人： Takamitsu Kano ,  Toru Tamura ,  Motoyuki Sugiura

    IPC分类号： C08L51/08

    CPC分类号： C08L51/06 ,  C08F255/00 ,  C08F255/02 ,  C08K5/092 ,  C08L33/04 ,  C08L33/06 ,  C08L51/003 ,  C08L67/00 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

    摘要： Disclosed is a thermoplastic elastomer composition obtained by dynamically crosslinking a composition composed of a component (A), a component (B) and a component (C) with 0.05 to 5 parts by mass of a crosslinking agent per 100 parts by mass of the component (A). The component (A) is 50 to 85 parts by mass of an acrylic rubber prepared by copolymerizing a monomer mixture mainly containing an alkyl acrylate and also containing 0.5 to 15% by mass of an epoxy group-containing monomer. The component (B) is 15 to 50 parts by mass of a thermoplastic polyester resin. The component (C) is 1 to 35 parts by mass of a graft copolymer or a precursor thereof per 100 parts by mass of the total of the components (A) and (B), and the graft copolymer is composed of an olefin polymer segment and a vinyl copolymer segment.

    摘要翻译： 公开了一种热塑性弹性体组合物，其通过将组分（A），组分（B）和组分（C）组成的组合物相对于每100质量份的组分 （一个）。 组分（A）是通过使主要含有丙烯酸烷基酯的单体混合物和含有0.5〜15质量％的含环氧基的单体共聚制备的丙烯酸橡胶为50〜85质量份。 组分（B）的热塑性聚酯树脂为15〜50质量份。 组分（C）每100质量份（A）和（B）组分的总量为1〜35质量份的接枝共聚物或其前体，接枝共聚物由烯烃聚合物链段 和乙烯基共聚物片段。

    Thermoplastic elastomer composition
    9.
    发明授权
    Thermoplastic elastomer composition 有权
    热塑性弹性体组合物

    公开(公告)号：US07842754B2

    公开(公告)日：2010-11-30

    申请号：US11917968

    申请日：2006-08-08

    申请人： Takamitsu Kano ,  Toru Tamura ,  Motoyuki Sugiura

    发明人： Takamitsu Kano ,  Toru Tamura ,  Motoyuki Sugiura

    IPC分类号： C08L51/06 ,  C08L67/00

    CPC分类号： C08L51/06 ,  C08F255/00 ,  C08F255/02 ,  C08K5/092 ,  C08L33/04 ,  C08L33/06 ,  C08L51/003 ,  C08L67/00 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

    摘要： Disclosed is a thermoplastic elastomer composition obtained by dynamically crosslinking a composition composed of a component (A), a component (B) and a component (C) with 0.05 to 5 parts by mass of a crosslinking agent per 100 parts by mass of the component (A). The component (A) is 50 to 85 parts by mass of an acrylic rubber prepared by copolymerizing a monomer mixture mainly containing an alkyl acrylate and also containing 0.5 to 15% by mass of an epoxy group-containing monomer. The component (B) is 15 to 50 parts by mass of a thermoplastic polyester resin. The component (C) is 1 to 35 parts by mass of a graft copolymer or a precursor thereof per 100 parts by mass of the total of the components (A) and (B), and the graft copolymer is composed of an olefin polymer segment and a vinyl copolymer segment.

    摘要翻译： 公开了一种热塑性弹性体组合物，其通过将组分（A），组分（B）和组分（C）组成的组合物相对于每100质量份的组分 （一个）。 组分（A）是通过使主要含有丙烯酸烷基酯的单体混合物和含有0.5〜15质量％的含环氧基的单体共聚制备的丙烯酸橡胶为50〜85质量份。 组分（B）的热塑性聚酯树脂为15〜50质量份。 组分（C）每100质量份（A）和（B）组分的总量为1〜35质量份的接枝共聚物或其前体，接枝共聚物由烯烃聚合物链段 和乙烯基共聚物片段。

    Thermoplastic resin compositions
    10.
    发明授权
    Thermoplastic resin compositions 失效
    热塑性树脂组合物

    公开(公告)号：US5674930A

    公开(公告)日：1997-10-07

    申请号：US582739

    申请日：1996-01-04

    申请人： Motoyuki Sugiura ,  Kazumine Ohara

    发明人： Motoyuki Sugiura ,  Kazumine Ohara

    IPC分类号： C08L23/10 ,  C08L23/16 ,  C08L51/06 ,  C08K3/38

    CPC分类号： C08L23/10 ,  C08L51/06 ,  C08L23/16

    摘要： A thermoplastic resin composition having excellent characteristics such as impact resistance and coatability is described. The thermoplastic resin composition contains a propylene based polymer and a graft copolymer having an olefin homo/co-polymer portion forming its main chain and a vinyl copolymer portion forming its branched portion. In the graft copolymer, the proportion of the olefin homo/co-polymer portion is 5 to 95% by weight, and the vinyl copolymer portion occupies the remaining weight. The vinyl copolymer portion of the graft copolymer has a hydroxyl group as a functional group. One of the olefin homo/co-polymer portion and the vinyl copolymer portion forms a dispersed phase in the other with a particle size of 0.001 to 10 .mu.m. Consequently, the graft copolymer assumes a multi-phase structure. The thermoplastic resin composition optionally further contains a thermoplastic elastomer.

    摘要翻译： 对耐冲击性，涂布性等优异的热塑性树脂组合物进行说明。 热塑性树脂组合物含有丙烯类聚合物和形成其主链的烯烃均聚物/共聚物部分和形成其支链部分的乙烯基共聚物部分的接枝共聚物。 在接枝共聚物中，烯烃均聚物/共聚物部分的比例为5〜95重量％，乙烯基共聚物部分占剩余重量。 接枝共聚物的乙烯基共聚物部分具有羟基作为官能团。 烯烃均聚物/共聚物部分和乙烯基共聚物部分之一在另外具有0.001〜10μm的粒径的分散相。 因此，接枝共聚物呈现多相结构。 热塑性树脂组合物任选地还含有热塑性弹性体。