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    Graft copolymer, composition containing the same and molded object thereof, and process for producing the same
    2.
    发明授权
    Graft copolymer, composition containing the same and molded object thereof, and process for producing the same 有权
    接枝共聚物，含有其的成型物及其成型体的组合物及其制造方法

    公开(公告)号：US07368507B2

    公开(公告)日：2008-05-06

    申请号：US10532799

    申请日：2003-10-23

    申请人： Masumi Takamura ,  Hitoshi Uchida ,  Yoshiki Yamamoto ,  Motoyuki Sugiura

    发明人： Masumi Takamura ,  Hitoshi Uchida ,  Yoshiki Yamamoto ,  Motoyuki Sugiura

    IPC分类号： C08F255/02 ,  C08F255/04 ,  C08F255/06 ,  C08F8/46

    CPC分类号： C08F255/00 ,  C08F255/02 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06

    摘要： A graft copolymer having a structure in which a vinyl copolymer segment formed from a vinyl monomer having an acid is suspended in a molecular chain of a polyolefin resin segment via a β-substituted propylene group is obtained, by reaction of polyolefin resin having β-substituted propenyl group as a pendant and a vinyl monomer having an acid, and further a graft copolymer composition containing the same and a molded product thereof are obtained.The obtained graft copolymer, the composition containing the same and the molded product thereof are excellent in adhesive property to a polar material and scratch resistance.

    摘要翻译： 通过具有β-取代的聚烯烃树脂的反应，得到具有由具有酸的乙烯基单体形成的乙烯基共聚物链段通过β-取代的丙烯基团悬浮在聚烯烃树脂链段的分子链中的结构的接枝共聚物 作为侧基的丙烯基和具有酸的乙烯基单体，并且还得到含有它们的接枝共聚物组合物及其模塑产品。 所得到的接枝共聚物，含有该共聚物的成分及其成型体的极性材料的粘合性优异，耐划伤性优异。

    COMPOSITION FOR COLLOIDAL CRYSTAL
    4.
    发明申请
    COMPOSITION FOR COLLOIDAL CRYSTAL 有权
    胶体晶体组成

    公开(公告)号：US20130171438A1

    公开(公告)日：2013-07-04

    申请号：US13806593

    申请日：2011-06-01

    申请人： Masaki Hayashi ,  Masumi Takamura

    发明人： Masaki Hayashi ,  Masumi Takamura

    IPC分类号： C09D139/04

    CPC分类号： C09D139/04 ,  B05D2401/10 ,  B32B5/14 ,  B32B7/02 ,  C08F2/44 ,  C08F285/00 ,  C08F2220/306 ,  C08F2222/102 ,  G02B1/02 ,  Y10T428/254 ,  Y10T428/2998 ,  C08F220/10

    摘要： A composition for colloidal crystals including core-shell particles and a monomer having a particular structure. The core-shell particles constitute 25% to 65% by weight of the composition, and the monomer constitutes 35% to 75% by weight of the composition. The core has an average particle size from 50 to 900 nm. Each particle includes a core and a shell. The shell is formed of a linear polymer composed of at least one of styrene and a monomer having a particular structure. One end of the linear polymer is covalently bonded to the core. The refractive index of the core (n(core)) satisfies the following formulae: wherein R1 denotes a hydrogen atom or a methyl group, and y is 0 or 1, n(shell)−n(core)≧0.07, n(shell) denoting the refractive index of the shell, and n(B)−n(core)≧0.07, n(B) denoting the refractive index of the monomer (B1) after curing.

    摘要翻译： 包括核 - 壳颗粒和具有特定结构的单体的胶体晶体组合物。 核 - 壳颗粒占组合物重量的25％至65％，单体占组合物重量的35％至75％。 核心的平均粒度为50〜900nm。 每个颗粒包括核和壳。 壳由由苯乙烯和具有特定结构的单体中的至少一种构成的线性聚合物形成。 线性聚合物的一端共价结合到芯上。 核（n（核））的折射率满足下式：其中，R1表示氢原子或甲基，y表示0或1，n（壳）-n（核心）= 0.07，n（ 壳体）表示壳体的折射率，n（B）-n（芯）> = 0.07，n（B）表示固化后的单体（B1）的折射率。

    Composition for colloidal crystal comprising core-shell particles and styrene polymer
    6.
    发明授权
    Composition for colloidal crystal comprising core-shell particles and styrene polymer 有权
    包含核 - 壳颗粒和苯乙烯聚合物的胶体晶体的组合物

    公开(公告)号：US08906505B2

    公开(公告)日：2014-12-09

    申请号：US13806593

    申请日：2011-06-01

    申请人： Masaki Hayashi ,  Masumi Takamura

    发明人： Masaki Hayashi ,  Masumi Takamura

    IPC分类号： B32B5/16 ,  B05D7/00 ,  C09D139/04 ,  B32B5/14 ,  B32B7/02 ,  C08F2/44 ,  C08F285/00 ,  G02B1/02 ,  C08F220/30 ,  C08F222/10

    CPC分类号： C09D139/04 ,  B05D2401/10 ,  B32B5/14 ,  B32B7/02 ,  C08F2/44 ,  C08F285/00 ,  C08F2220/306 ,  C08F2222/102 ,  G02B1/02 ,  Y10T428/254 ,  Y10T428/2998 ,  C08F220/10

    摘要： A composition for colloidal crystals including core-shell particles and a monomer having a particular structure. The core-shell particles constitute 25% to 65% by weight of the composition, and the monomer constitutes 35% to 75% by weight of the composition. The core has an average particle size from 50 to 900 nm. Each particle includes a core and a shell. The shell is formed of a linear polymer composed of at least one of styrene and a monomer having a particular structure. One end of the linear polymer is covalently bonded to the core. The refractive index of the core (n(core)) satisfies the following formulae: wherein R1 denotes a hydrogen atom or a methyl group, and y is 0 or 1, n(shell)−n(core)≧0.07, n(shell) denoting the refractive index of the shell, and n(B)−n(core)≧0.07, n(B) denoting the refractive index of the monomer (B1) after curing.

    摘要翻译： 包括核 - 壳颗粒和具有特定结构的单体的胶体晶体组合物。 核 - 壳颗粒占组合物重量的25％至65％，单体占组合物重量的35％至75％。 核心的平均粒度为50〜900nm。 每个颗粒包括核和壳。 壳由由苯乙烯和具有特定结构的单体中的至少一种构成的线性聚合物形成。 线性聚合物的一端共价结合到芯上。 核（n（核））的折射率满足下式：其中，R1表示氢原子或甲基，y表示0或1，n（壳）-n（核）≥0.07，n（壳 ）表示壳的折射率，n（B）-n（芯）≥0.07，n（B）表示固化后的单体（B1）的折射率。

    Thermoplastic Resin Composition
    8.
    发明申请
    Thermoplastic Resin Composition 失效
    热塑性树脂组合物

    公开(公告)号：US20110213083A1

    公开(公告)日：2011-09-01

    申请号：US12674672

    申请日：2008-08-26

    申请人： Masumi Takamura ,  Kazuaki Mima

    发明人： Masumi Takamura ,  Kazuaki Mima

    IPC分类号： C08L51/10 ,  C08L67/04 ,  C08L25/06

    CPC分类号： C08K9/04 ,  C08J3/201

    摘要： Disclosed is a thermoplastic resin composition containing a graft material and an organic peroxide group dispersion medium in which the graft material is dispersed. The graft material is obtained by melt-mixing a metal oxide fine particle having an organic peroxide group on the surface and a thermoplastic resin, and has a structure in which the thermoplastic resin is grafted to the metal oxide fine particle. The organic peroxide group on the surface of the metal oxide fine particle is preferably a peroxymonocarbonate group. The organic peroxide group on the surface of the metal oxide fine particle is preferably obtained by reacting a hydroxy group of a silicon oxide fine particle with an amino-modified silane coupling agent, thereby introducing an amino group to the surface of the silicon oxide fine particle, and then reacting the amino group with a compound having an ethylenically unsaturated group and an organic peroxide group.

    摘要翻译： 公开了一种热塑性树脂组合物，其含有接枝材料和其中分散有接枝材料的有机过氧化物基团分散介质。 通过将表面上具有有机过氧化物基团的金属氧化物细颗粒和热塑性树脂熔融混合而获得接枝材料，并且具有将热塑性树脂接枝到金属氧化物细颗粒上的结构。 金属氧化物微粒表面的有机过氧化物基团优选为过氧单碳酸酯基。 金属氧化物微粒表面上的有机过氧化物基团优选通过使氧化硅微粒的羟基与氨基改性的硅烷偶联剂反应而获得，从而将氨基引入氧化硅微粒的表面 然后使氨基与具有烯属不饱和基团和有机过氧化物基团的化合物反应。

    Thermoplastic resin composition
    10.
    发明授权
    Thermoplastic resin composition 失效
    热塑性树脂组合物

    公开(公告)号：US08575268B2

    公开(公告)日：2013-11-05

    申请号：US12674672

    申请日：2008-08-26

    申请人： Masumi Takamura ,  Kazuaki Mima

    发明人： Masumi Takamura ,  Kazuaki Mima

    IPC分类号： C08L25/06 ,  C08L101/00 ,  C08L51/00 ,  C08K9/04

    CPC分类号： C08K9/04 ,  C08J3/201

    摘要： Disclosed is a thermoplastic resin composition containing a graft material and an organic peroxide group dispersion medium in which the graft material is dispersed. The graft material is obtained by melt-mixing a metal oxide fine particle having an organic peroxide group on the surface and a thermoplastic resin, and has a structure in which the thermoplastic resin is grafted to the metal oxide fine particle. The organic peroxide group on the surface of the metal oxide fine particle is preferably a peroxymonocarbonate group. The organic peroxide group on the surface of the metal oxide fine particle is preferably obtained by reacting a hydroxy group of a silicon oxide fine particle with an amino-modified silane coupling agent, thereby introducing an amino group to the surface of the silicon oxide fine particle, and then reacting the amino group with a compound having an ethylenically unsaturated group and an organic peroxide group.

    摘要翻译： 公开了一种热塑性树脂组合物，其含有接枝材料和其中分散有接枝材料的有机过氧化物基团分散介质。 通过将表面上具有有机过氧化物基团的金属氧化物细颗粒和热塑性树脂熔融混合而获得接枝材料，并且具有将热塑性树脂接枝到金属氧化物细颗粒上的结构。 金属氧化物微粒表面的有机过氧化物基团优选为过氧单碳酸酯基。 金属氧化物微粒表面上的有机过氧化物基团优选通过使氧化硅微粒的羟基与氨基改性的硅烷偶联剂反应而获得，从而将氨基引入氧化硅微粒的表面 然后使氨基与具有烯属不饱和基团和有机过氧化物基团的化合物反应。