Silver halide photographic element, photographic coating composition and
process to prepare an aqueous dispersion of a hydrophobic compound
    3.
    发明授权
    Silver halide photographic element, photographic coating composition and process to prepare an aqueous dispersion of a hydrophobic compound 失效
    卤化银照相元件,照相涂料组合物和制备疏水化合物的水分散体的方法

    公开(公告)号:US4990435A

    公开(公告)日:1991-02-05

    申请号:US940903

    申请日:1986-12-10

    CPC分类号: G03C7/3882

    摘要: A polymeric latex to load photographically useful compounds into photographic elements comprises, as a dispersed phase, fine particles of a hydrophobic polymer which, for at least 70% of its weight, comprises:(a) repeating units derived from an ethylenic monomer containing a sulfonic or sulfonate group which monomer is capable of forming hydrophilic homopolymers, said units comprising 0.5 to 1.5% by weight of said hydrophobic polymer,(b) repeating units derived from an N-3-oxo-alkyl-substituted acrylamide, said units comprising from 5 to 25% by weight of said hydrophobic polymer, and(c) repeating units derived from acrylic acid ester monomers having a TG lower than 0.degree. C., said units comprising at least 43.5% by weight of said hydrophobic polymer,the remaining polymer weight percentage, from zero to 30%, being formed by repeating units derived from inert monomers and/or cross-linking monomers.Such polymeric latex can be loaded with hydrophobic compounds to obtain stable coating compositions which are suitable for a uniform dispersion in a hydrophilic layer of a photographic material.

    摘要翻译: 将摄影有用的化合物加载到照相元件中的聚合物胶乳包含作为分散相的疏水性聚合物的细颗粒,其至少70%的重量包含:(a)衍生自含有磺酸的烯属单体的重复单元 或单体能够形成亲水均聚物的磺酸盐基团,所述单元包含0.5至1.5重量%的所述疏水性聚合物,(b)衍生自N-3-氧代 - 烷基取代的丙烯酰胺的重复单元,所述单元包含5 至25重量%的所述疏水性聚合物,和(c)衍生自TG低于0℃的丙烯酸酯单体的重复单元,所述单元包含至少43.5重量%的所述疏水性聚合物,剩余的聚合物重量 百分数,从零到30%,由衍生自惰性单体和/或交联单体的重复单元形成。 这样的聚合胶乳可以加载疏水性化合物,以获得适合在照相材料的亲水层中均匀分散的稳定的涂料组合物。

    Photosensitive silver halide material for obtaining half-tone
black-and-white images and method for half-tone high-contrast
reproduction
    4.
    发明授权
    Photosensitive silver halide material for obtaining half-tone black-and-white images and method for half-tone high-contrast reproduction 失效
    用于获得半色调黑白图像的感光卤化银材料和用于半色调高对比度再现的方法

    公开(公告)号:US4659647A

    公开(公告)日:1987-04-21

    申请号:US807285

    申请日:1985-12-10

    摘要: A photosensitive silver halide material for obtaining black and white half-tone dot or line images comprises a fine grain and high-chloride silver halide emulsion reactively associated with an aqueous latex of a hydrophobic vinyl addition polymer in combination with a stabilizer selected from the group consisting of 4-hydroxy-1,3,3a,7-tetrazaindenes, benzotriazoles and benzimidazoles. The silver halide emulsion has an average grain size lower than or equal to 0.20 micron with at least 60% of its molar halide content consisting of chloride ions.The material allows high-contrast and high resolving power images to be obtained.The material has a good developability in photographic processings and this reduces the development times and increases productivity.

    摘要翻译: 用于获得黑白色半色调点或线图像的感光卤化银材料包括与疏水性乙烯基加成聚合物的水性胶乳反应性相关的细晶粒和高氯化物卤化银乳剂,其与选自以下的稳定剂组合: 的4-羟基-1,3,3a,7-四唑烷酮,苯并三唑和苯并咪唑。 卤化银乳剂的平均粒度小于或等于0.20微米,其卤化物含量的至少60%由氯离子组成。 该材料可以获得高对比度和高分辨率的图像。 该材料在照相处理中具有良好的显影性,并且这减少了显影时间并且提高了生产率。

    Photographic elements containing polymers having
aminoallylidenemalononitrile units
    5.
    发明授权
    Photographic elements containing polymers having aminoallylidenemalononitrile units 失效
    含有具有氨基烯丙二腈单元的聚合物的照相元件

    公开(公告)号:US4307184A

    公开(公告)日:1981-12-22

    申请号:US189361

    申请日:1980-09-22

    摘要: The present invention refers to a photographic material including in one of its layers a polymeric product having an aminoallylidenemalononitrile ultraviolet absorber unit which can be introduced into a photographic layer by aqueous solutions, with the method according to this invention, of including said aminoallylidenemalononitrile unit in an allyl monomer and then copolymerizing it with an ethylenically unsaturated monomer in order to obtain said polymeric product to be added to the layer forming composition. This invention is of particular industrial interest in the field of color photographic materials.

    摘要翻译: 本发明涉及一种照相材料,其中的一层包括具有氨基烯丙二腈紫外线吸收剂单元的聚合产物,其可以通过水溶液引入照相层,按照本发明的方法将所述氨基烯丙二腈单元包括在 烯丙基单体,然后使其与烯键式不饱和单体共聚,以获得要添加到层形成组合物中的所述聚合产物。 本发明在彩色照相材料领域具有特别的工业意义。

    Photographic elements with improved surface characteristics
    7.
    发明授权
    Photographic elements with improved surface characteristics 失效
    具有改善表面特性的照相元件

    公开(公告)号:US4367284A

    公开(公告)日:1983-01-04

    申请号:US267073

    申请日:1981-05-26

    IPC分类号: G03C1/76 G03C1/95 G03C5/26

    摘要: It is generally undesirable to have surfaces on photographic elements which are highly reflective and therefore reduce the attractiveness of the image. One of the traditional means of correcting this reflectance is to coat the developed film or print with an anti-reflective coating or to place a glass cover over the imaged photographic element where the glass itself has an anti-reflective surface.According to the present invention, an anti-reflective surface may be provided within the photographic element itself by including within a top coat gelatin layer a combination of a first water-soluble soft matting agent incompatible with gelatin and a second water-insoluble soft matting agent.

    摘要翻译: 通常不希望在照相元件上具有高反射性的表面,因此降低图像的吸引力。 校正这种反射率的传统方法之一是用抗反射涂层涂覆显影的膜或印刷,或者将玻璃盖放置在成像的照相元件上,其中玻璃本身具有抗反射表面。 根据本发明,通过在顶涂层明胶层内包含与明胶不相容的第一水溶性软消光剂和第二水不溶性软消光剂的组合,可以在照相元件本身内设置抗反射表面 。

    Process for providing a matt surface on a photographic material and
photographic material provided with such matt surface
    8.
    发明授权
    Process for providing a matt surface on a photographic material and photographic material provided with such matt surface 失效
    在照相材料和提供有这种无光泽表面的照相材料上提供无光泽表面的方法

    公开(公告)号:US4447525A

    公开(公告)日:1984-05-08

    申请号:US419403

    申请日:1982-09-17

    CPC分类号: G03C1/95 Y10S430/151

    摘要: A matt surface can be provided on a photographic material comprising a support base, one or more light-sensitive gelatin silver halide emulsion layers and an outer non-light-sensitive gelatin layer coated on said layers if discrete particles, insoluble in water and substantially soluble in aqueous alkaline medium, of a carboxyl group containing copolymer are introduced into said outer layer. The particles, of a diameter between 0.5 and 4 micron, are introduced into the coating composition of the outer layer as a dispersion of a methacrylic acid and ethylmethacrylate copolymer containing 20 to 50 percent by weight of methacrylic acid, which dispersion is obtained by dispersing in an aqueous solution of a hydrophilic colloid a solution of said copolymer in ethylacetate or water-including ethylacetate.

    摘要翻译: 可以在包含支撑基底,一个或多个光敏明胶卤化银乳剂层和涂覆在所述层上的外部非光敏明胶层的照相材料上提供哑光表面,如果离散的颗粒不溶于水并且基本上可溶 在碱性水溶液中含有羧基的共聚物引入所述外层。 将直径在0.5至4微米之间的颗粒作为含有20至50重量%甲基丙烯酸的甲基丙烯酸和甲基丙烯酸乙酯共聚物的分散体引入外层的涂料组合物中,该分散体通过分散在 亲水胶体的水溶液,所述共聚物在乙酸乙酯或含水乙酸乙酯中的溶液。

    3-aminoallylidenemalononitrile UV-absorbing compounds and photographic
elements containing them
    9.
    发明授权
    3-aminoallylidenemalononitrile UV-absorbing compounds and photographic elements containing them 失效
    3-氨基烯丙基壬腈紫外线吸收化合物和含有它们的摄影元素

    公开(公告)号:US4946768A

    公开(公告)日:1990-08-07

    申请号:US881066

    申请日:1986-07-02

    申请人: Angelo Vallarino

    发明人: Angelo Vallarino

    摘要: 3-Aminoallylidenemalononitrile compounds corresponding to the formula: ##STR1## wherein R.sub.1 is a short alkyl chain having 1 to 3 carbon atoms and R is a substituted or unsubstituted long alkyl chain greater than 10 carbon atoms, are useful in photography for absorbing ultraviolet radiations in the range from 360 to 400 nm, with no undesired absorption near 420 nm, when introduced in a photographic gelatin layer.

    摘要翻译: 对应于下式的3-氨基亚丙二腈化合物:其中R1是具有1至3个碳原子的短烷基链,R是取代或未取代的大于10个碳原子的长烷基链,可用于吸收紫外线辐射的摄影 在360至400nm的范围内,当引入摄影明胶层中时,在420nm附近没有不期望的吸收。